Chloride Environment (chloride + environment)

Distribution by Scientific Domains
Polymers and Materials Science100%

Selected Abstracts

Corrosion fatigue behaviour of a 15Cr-6Ni precipitation-hardening stainless steel in different tempers

FATIGUE & FRACTURE OF ENGINEERING MATERIALS AND STRUCTURES, Issue 6 2000
C.-K. Lin
Systematic fatigue experiments, including both high-cycle axial fatigue (S,N curves) and fatigue crack growth (FCG, da/dN,,K curves), were performed on a precipitation-hardening martensitic stainless steel in laboratory air and 3.5 wt% NaCl solution. Specimens were prepared in three tempers, i.e. solution-annealed (SA), peak-aged (H900) and overaged (H1150) conditions, to characterize the effects of ageing treatment on the corrosion fatigue (CF) resistance. S,N results indicated that fatigue resistance in all three tempers was dramatically reduced by the aqueous sodium chloride environment. In addition, the smooth-surface specimens in H900 temper exhibited longer CF lives than the H1150 ones, while those in SA condition stood in between. However, for precracked specimens, the H1150 temper provided superior corrosive FCG resistance than the other two tempers. Comparison of the S,N and FCG curves indicated that early growth of crack-like defects and short cracks played the major role in determining the CF life for smooth surface. The differences in the CF strengths for the S,N specimens of the given three tempers were primarily due to their inherent differences in resistance to small crack growth, as they were in the air environment. [source]

Initiation and propagation of stainless steel pitting corrosion under heat flux

MATERIALS AND CORROSION/WERKSTOFFE UND KORROSION, Issue 12 2003
T. Pro
nichtrostender Stahl; Lochkorrosion; Wärmeübergang; Wärmefluss Abstract An effect of heat flux on initiation and propagation of pitting corrosion of austenitic stainless steel in chloride environment has been studied using electrochemical and exposure methods. The experiments were performed at constant surface temperature of 60°C and heat flux from , 15 to + 74 kW m,2. The presence of heat flux from metal to solution shifted the breakdown potential towards noble values and lowered the pit density, whereas the pit propagation rate increased. Presence of maximum heat flux caused, in comparison with isothermal conditions, increase of the breakdown potential by approx. 100 mV, reduction of pit density by 30% and increase of the average pit depth by 40%. The positive effect of heat flux from metal to solution was given mainly by improving the protective ability of the passive film, as the amount of oxygen available at the metal surface increased. With a smaller significance, the effect of intensified mass transfer, which made accumulation of the chloride ions on the surface more difficult, occurred. Entstehung und Fortschreiten der Lochkorrosion von nichtrostendem Stahl bei Wärmefluss Der Einfluss von Wärmefluss auf die Entstehung und das Fortschreiten der Lochkorrosion bei austenitischen nichtrostenden Stählen in chloridhaltiger Umgebung wurden unter Verwendung elektrochemischer Methoden und in Auslagerungsversuchen untersucht. Die Versuche wurden bei einer konstanten Oberflächentemperatur von 60°C und einem Wärmefluss von , 15 bis 74 kWm2 durchgeführt. Ein Wärmefluss vom Metall hin zur Lösung verschob das Durchbruchspotential hin zu edleren Werten, es verringerte sich die Lochdichte, während eine Zunahme der Lochbildungsrate erfolgte. Ein Maximum des Wärmeflusses bewirkte im Vergleich mit isothermen Bedingungen eine Zunahme des Potentials um ca. 100 mV, eine Verringerung der Lochdichte um 30% und eine Zunahme des Wertes für die Lochtiefe um 40%. Der positive Einfluss des Wärmeflusses in Richtung vom Metall zur Lösung ergab im wesentlichen eine Verbesserung der Schutzwirkung des Passivfilms, da sich die verfügbare Menge Sauerstoff an der Metalloberfläche erhöhte. Weniger signifikant war der Effekt eines erhöhen Stofftransportes, der eine Akkumulation von Chlorid-Ionen an der Oberfläche erschwerte. [source]

The wet corrosion of molybdenum thin film , Part III: The effect of Ti and Nb

MATERIALS AND CORROSION/WERKSTOFFE UND KORROSION, Issue 5 2006
C. R. Tomachuk
Abstract Magnetron sputtering has become the process of choice for the deposition of a wide range of industrially important coatings. Over the last decade, interest in molybdenum thin films prepared by magnetron sputtering has been increasing; however, little research has been done on molybdenum-titanium and molybdenum-niobium alloy thin films. During the current study, electrochemical impedance spectroscopy (EIS) was employed to investigate the effect on the corrosion resistance in basic chloride environments of adding titanium and niobium species to molybdenum thin films deposited by physical vapor deposition. The results indicate that the MoTi alloy thin films exhibit better protective properties than either the molybdenum-niobium alloy or unalloyed molybdenum thin films. [source]

Electrochemical impedance spectroscopy study of surface films formed on copper in aqueous environments

MATERIALS AND CORROSION/WERKSTOFFE UND KORROSION, Issue 9 2005
A. Srivastava
Abstract The electrochemical behavior of pure copper has been studied in aqueous environments using linear polarization and electrochemical impedance spectroscopy (EIS) techniques as a function of immersion time. The effect of pollutants (like chloride, sulfide and ammonium ions) on the nature of films formed on the copper surface has been studied. All the surfaces revealed the presence of a porous oxide layer. The corrosion resistance decreased with increasing amount of chloride ions. The addition of Na2S in the environments in the absence of any chloride species was beneficial for corrosion resistance. EIS data suggested that the capacitance of the films formed in chloride environments was higher. The surfaces obtained in presence of chloride ions were relatively rough and deeply attacked. The total impedance decreased after 432 h of immersion in solutions possessing chloride ions. The damaging role of chloride ions and the relatively less severe effect of sulfide ions were noted. [source]