CH2

Distribution by Scientific Domains
Distribution within Chemistry

Terms modified by CH2

  • ch2 group
  • ch2 groups

  • Selected Abstracts


    Dependency of Tritium Retention in Graphite on Temperature Control of Molecular Dynamics

    CONTRIBUTIONS TO PLASMA PHYSICS, Issue 3-5 2010
    A. Ito
    Abstract We have investigated the carbon plasma facing material and hydrogen atom interaction by the use of molecular dynamics simulation to clarify chemical erosion processes on divertor plate. The present paper is our first try at elucidation of temperature dependence by the molecular dynamics. Temperature was controlled by using Langevin thermostat method. As a result, the retention of hydrogen atom achieve steady state, and the CH4 was generated, which was not found MD simulations without a temperature control method. About 30 percent of injected hydrogen atoms are retained. CH4 yields has a peak at 600 K, which accords with experimental results. A dominant path of CH4 generation found by the present molecular dynamics simulation is as follows: a CH is detached from eroded surface and then it grows into CH4 adsorbing hydrogen atoms via CH2 and CH3. In addition, we propose the problem that the hydrogen atom retention and CH,, yields depend on the thermal relaxation time in MD simulation using temperature control methods (© 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


    Synthesis, growth and characterization of single crystals of pure and thiourea doped L-glutamic acid hydrochloride

    CRYSTAL RESEARCH AND TECHNOLOGY, Issue 1 2007
    R. Sathyalakshmi
    Abstract L(+)Glutamic acid hydrochloride [HOOC (CH2)2CH(NH2) COOH·HCl], a monoamino dicarboxylic acid salt of L-Glutamic acid was synthesized and the synthesis was confirmed by FTIR analysis. Solubility of the material in water was determined. Pure and Thiourea doped L-Glutamic acid hydrochloride crystals were grown by low temperature solution growth using solvent evaporation technique. XRD, UV-Vis-NIR analyses were carried out for both pure and thiourea doped crystals. The crystals were qualitatively analyzed by EDAX analysis and the presence of thiourea was confirmed. The cell parameters of L-Glutamic acid hydrochloride have been determined as a = 5.151 Å, b = 11.79 Å, c = 13.35 Å by X-ray diffraction analysis and it crystallizes in orthorhombic space group P212121. UV-Vis-NIR spectra analysis showed good optical transmission in the entire visible region for both pure and doped crystals. Micro hardness of both pure and doped crystals has been determined using Vickers micro hardness tester. The SHG efficiencies of both pure and doped crystals were determined using Kurtz powder test and pure L-Glutamic acid hydrochloride crystal was found to possess better efficiency than thiourea doped L-Glutamic acid hydrochloride crystals. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


    Influence of neurohumoral blockade on heart rate and blood pressure responses to haemorrhage in isoflurane anaesthetized rats

    ACTA PHYSIOLOGICA, Issue 3 2000
    UllmanArticle first published online: 24 DEC 200
    Four groups of Sprague,Dawley rats were anaesthetized with isoflurane (ISO) (1.7% end-tidal concentration) in 40% oxygen, and mechanically ventilated. The animals were bled 15 mL kg,1 b.w. from the femoral vein over 10 min, followed by an observation period of 30 min. Ten minutes before haemorrhage each group of animals was pre-treated with intravenous injection/infusion of either: isotonic saline (Group B; CON; n=7), vasopressin V1 -receptor antagonist [d(CH2)5Tyr(Me)AVP; 10 ,g kg,1] (Group C; AVP-a; n=7), the non-selective angiotensin II receptor antagonist saralasin (10 ,g kg,1 min,1) (Group D; SAR; n=7) or hexamethonium (10 mg kg,1) (Group E; HEX; n=7). A separate group of conscious animals were pre-treated with isotonic NaCl and subjected to the same haemorrhage protocol (Group A; AW; n=7). Mean arterial pressure (MAP), heart rate (HR) and blood gases were observed during the experiments. Only pre-treatment with SAR and HEX reduced MAP significantly. The pre-haemorrhage HR was only affected by HEX, which caused a reduction by 17%. The HR was significantly lower at the end of haemorrhage compared with pre-haemorrhage levels in all groups except that group treated with HEX. In that group the HR changed in the opposite direction. The ability to maintain MAP during haemorrhage, and the post-haemorrhage period, was significantly impaired in the groups treated with AVP-a, SAR or HEX compared with the group receiving NaCl. It is concluded that autonomic nervous activity is of major importance for the maintenance of MAP during isoflurane anaesthesia, whereas circulating angiotensin II and vasopressin levels contribute to a much smaller degree in this regard. General anaesthesia in combination with different degrees of neurohumoral blockade impairs the haemodynamic responses to blood loss, seen in conscious individuals. The impairment involves both the early and late phases during haemorrhage, as well as the post-bleeding recovery period. All three neurohumoral systems (autonomic nervous activity, angiotensin II and vasopressin) are of importance for regulating MAP during and after haemorrhage, although the autonomic nervous outflow appears to contribute to a larger extent. [source]


    Synthesis and calcium channel modulating effects of modified Hantzsch nitrooxyalkyl 1,4-dihydro-2,6-dimethyl-3-nitro-4-(pyridinyl or 2-trifluoromethylphenyl)-5-pyridinecarboxylates

    DRUG DEVELOPMENT RESEARCH, Issue 4 2000
    Ramin Miri
    Abstract A group of racemic nitrooxyalkyl 1,4-dihydro-2,6-dimethyl-3-nitro-4-(pyridinyl or 2-trifluoromethylphenyl)-5-pyridinecarboxylates 8a,o were synthesized using modified Hantzsch reactions. In vitro calcium channel antagonist activities, determined using a guinea pig ileum longitudinal smooth muscle (GPILSM) assay, showed that compounds 8a,o exhibited weaker calcium antagonist activity (10,5 to 10,7 M range) than the reference drug nifedipine (IC50 = 1.43 × 10,8 M). Compounds 8 possessing a C-4 R1 = 2-pyridyl substituent were always more potent than the approximately equiactive analogs having an R1 = 3-pyridyl, 4-pyridyl or 2-CF3 -C6H4 -substituent, within each subgroup of nitrooxyalkyl compounds [R2 = , (CH2)nONO2 (n = 2, 3, 4) or ,CH(CH2ONO2)2]. Although the length of the R2 = ,(CH2)nONO2 substituent (n = 2,4) was not a determinant of smooth muscle calcium antagonist activity when the C-4 R1 -substituent was 2-pyridyl, when R1 was a 3-pyridyl, 4-pyridyl, or 2-CF3 -C6H4 -substituent, the relative potency order with respect to the R2 = ,(CH2)nONO2 substituent was n = 3 and 4 > n = 2. Replacement of the isopropyl substituent of the ester moiety of the calcium antagonist (±)-2-pyridyl 3a by a ,(CH2)nONO2 (n = 2,4) moiety increased calcium antagonist activity on GPILSM by 8-fold. In contrast, replacement of the isopropyl substituent of the ester moiety of the calcium agonists (±)-3-pyridyl 3b, (±)-4-pyridyl 3c or the methyl substituent of the ester moiety of Bay K8644 by a R2 nitrooxyalkyl substituent resulted in abolition of their calcium agonist effects on GPILSM that is replaced by a smooth muscle calcium antagonist effect. These calcium antagonist data support the concept that incorporation of a nitrooxyalkyl ester substituent constitutes a valuable drug design strategy to enhance Hantzsch 1,4-dihydropyridine calcium antagonist and/or abolish calcium agonist effects on smooth muscle. Replacement of the isopropyl (8b,c), or the methyl (8d) group by a ,CH2CH2ONO2 moiety resulted in retention of the cardiac positive inotropic effect where the relative potency order with respect to the C-4 substituent was 2-CF3 -C6H6 - (8d) > 3-pyridyl (8b) , 4-pyridyl (8c). Model hybrid (calcium channel modulation, ·NO release) compounds, that exhibit dual cardioselective agonist / smooth muscle selective antagonist activities, represent a novel type of 1,4-dihydropyridine CC modulator that offers a potential approach to drug discovery targeted toward the treatment of congestive heart failure and for use as probes to study the structure,function relationship of calcium channels. Drug Dev. Res. 51:225,232, 2000. © 2001 Wiley-Liss, Inc. [source]


    Synthesis and Characterization of MWNTs/Au NPs/HS(CH2)6Fc Nanocomposite: Application to Electrochemical Determination of Ascorbic Acid

    ELECTROANALYSIS, Issue 16 2008
    Jian-Ding Qiu
    Abstract In this article, a detailed electrochemical study of a novel 6-ferrocenylhexanethiol (HS(CH2)6Fc) self-assembled multiwalled carbon nanotubes-Au nanoparticles (MWNTs/Au NPs) composite film was demonstrated. MWNTs/Au NPs were prepared by one-step in situ synthesis using linear polyethyleneimine (PEI) as bifunctionalizing agent. HS(CH2)6Fc, which acted as the redox mediator, was self-assembled to MWNTs/Au NPs via Au-S bond. Transmission electron microscopy (TEM), energy-dispersive X-ray analysis (EDX), Fourier transformed infrared absorption spectroscopy (FT-IR), UV-visible absorption spectroscopy, and cyclic voltammetry were used to characterize the properties of the MWNTs/Au NPs/HS(CH2)6Fc nanocomposite. The preparation of the nanocomposite was very simple and effectively prevented the leakage of the HS(CH2)6Fc mediator during measurements. The electrooxidation of AA could be catalyzed by Fc/Fc+ couple as a mediator and had a higher electrochemical response due to the unique performance of MWNTs/Au NPs. The nanocomposite modified electrode exhibited excellent catalytic efficiency, high sensitivity, good stability, fast response (within 3,s) and low detection limit toward the oxidation of AA at a lower potential. [source]


    Evaluation of carrier ampholyte-based capillary electrophoresis for separation of peptides and peptide mimetics,

    ELECTROPHORESIS, Issue 18 2008
    an Koval
    Abstract Carrier ampholyte-based capillary electrophoresis (CABCE) has recently been introduced as an alternative to CE (CZE) in the classical buffers. In this study, isoelectric BGEs were obtained by fractionation of Servalyt pH 4,9 carrier ampholytes to cuts of typical width of 0.2 pH unit. CABCE feasibility was examined on a series of insect oostatic peptides, i.e. proline-rich di- to decapeptides, and phosphinic pseudopeptides , tetrapeptide mimetics synthesized as a mixture of four diastereomers having the ,P(O)(OH),CH2, moiety embedded into the peptide backbone. With identical selectivity, the separation efficiency of CABCE proved to be as good as classical CE for the insect oostatic peptides and better for diastereomers of the phosphinic pseudopeptides. In addition, despite the numerous species present in the narrow pH cuts of carrier ampholytes, CABCE seems to be free of system zones that could hamper the analysis. Peak symmetry was good for moderately to low mobile peptides, whereas some peak distortion due to electromigration dispersion, was observed for short peptides of rather high mobility. [source]


    Compositional effects on electrophoretic and chromatographic figures of merit in electrokinetic chromatography with cetyltrimethylammonium bromide/sodium octyl sulfate vesicles as the pseudostationary phase.

    ELECTROPHORESIS, Issue 5 2008
    Part 1: Effect of the phase ratio
    Abstract The effect of the phase ratio on the electrophoretic and chromatographic properties of unilamellar vesicles comprised of cetyltrimethylammonium bromide (CTAB) and sodium octyl sulfate (SOS) was investigated in EKC. The surfactant concentration of the vesicles was 0.9, 1.2, 1.5, and 1.8% w/v, with a mole ratio of 1:3.66 (CTAB/SOS). Results were compared to those obtained using SDS micelles at concentrations of 1.0% (w/v, 35,mM) and 1.5% (52,mM). The CTAB/SOS vesicles (0.9,1.8% w/v) provided a significantly larger elution range (5.7,,,tves/t0,,,8.7) and greater hydrophobic (methylene) selectivity (2.8,,,,CH2,,,3.1) than SDS micelles (3.1,,,tmc/t0,,,3.3; ,CH2,=,2.2). Whereas the larger elution range can be attributed to the 25% reduction in EOF due to the interaction of unaggregated CTAB cations and the negatively charged capillary wall, the higher methylene selectivity is likely due to the lower concentration of water expected in the CTAB/SOS vesicle bilayer compared to the Palisades layer of SDS micelles. For a given phase ratio, CTAB/SOS vesicles are somewhat less retentive than SDS micelles, although retention factors comparable to those observed in 1.0,1.5% SDS can be obtained with 1.5,1.8% CTAB/SOS. A linear relationship was observed between phase ratio and retention factor, confirming the validity of the phase ratio model for these vesicles. Unique polar group selectivities and positional isomer shape selectivities were obtained with CTAB/SOS vesicles, with both types of selectivities being nearly independent of the phase ratio. For four sets of positional isomers, the elution order was always para < ortho < meta. Finally, the thermodynamics of solute retention was qualitatively similar to that reported for other surfactant aggregates (micelles and microemulsions); the enthalpic contribution to retention was consistently favorable for all compounds, whereas the entropic contribution was favorable only to hydrophobic solutes. [source]


    Dual Luminescent Dinuclear Gold(I) Complexes of Terpyridyl-Functionalized Alkyne Ligands and Their Efficient Sensitization of EuIII and YbIII Luminescence

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 22 2010
    Xiu-Ling Li
    Abstract Reaction of (tpyC6H4C,CAu)n {tpyC6H4C,CH = 4,-(4-ethynylphenyl)-2,2,:6,,2,-terpyridine} with diphosphane ligands Ph2P(CH2)xPPh2 (x = 2 dppe, 3 dppp, 4 dppb, 5 dpppen, 6 dpph) in CH2Cl2 afforded the corresponding dual luminescent binuclear gold(I) complexes [(tpyC6H4C,CAu)2(,-dppe)] (1), [(tpyC6H4C,CAu)2(, - dppp)] (2), [(tpyC6H4C,CAu)2(,-dppb)] (3), [(tpyC6H4C,CAu)2(,-dpppen)] (4), [(tpyC6H4C,CAu)2(,-dpph)] (5). Crystal structural analysis of complexes 1·2CH2Cl2 and 2·2CH2Cl2 show that the terpyridine moieties are free of coordination in these gold(I)-acetylide-phosphane complexes. Spectrophotometric titration between complex 1 and [Eu(tta)3] (Htta = 2-thenoyltrifluoroacetone) or [Yb(hfac)3(H2O)2] (Hhfac = hexafluoroacetylacetone) gave a 2:1 ratio between Ln(,-diketonate)3 (Ln = Eu, Yb) units and the complex 1 moiety, indicating the formation of Au2Ln2 complexes. Both the luminescence titrations and the luminescence quantum yields of Au2Ln2 (Ln = Eu, Yb) solutions show that the energy transfer occurs efficiently from the binuclear gold(I) antennas 1,5 to EuIII and YbIII centers, and all complexes 1,5 are good energy donors for sensitization of visible and NIR luminescence of EuIII and YbIII ions. [source]


    Scandium-Catalyzed Polymerization of CH3(CH2)nCH=CH2 (n = 0,4): Remarkable Activity and Tacticity Control

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 7 2009
    Benjamin D. Ward
    Abstract The C3 -symmetric trisoxazoline-supported scandium complex [Sc(iPr-trisox)(CH2SiMe3)3] (2) is highly active in the stereospecific polymerization of propene, 1-butene, 1-pentene, 1-hexene and 1-heptene, when activated with two equivalents of [Ph3C][B(C6F5)4]. The polymers thus produced were found to possess narrow molecular weight distributions and high levels of tacticity control (up to 99,% mmmm). Some insight into the nature of the active species was obtained by 1H, 13C and 29Si NMR experiments. In particular, the formation of two equivalents of Ph3CCH2SiMe3 at ambient temperature was observed alongside a C3 -symmetric scandium complex tentatively assigned as the dication [Sc(iPr-trisox)(CH2SiMe3)]2+.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009) [source]


    Uncommon Solvent Effect in Oxidative Addition of MeI to a New Dinuclear Platinum Complex Containing a Platina(II)cyclopentane Moiety

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 32 2008
    S. Jafar Hoseini
    Abstract The reaction of the known complex cis,cis -[Me2Pta(,-dppm)(,-SMe2)Ptb,CH2(CH2)2CcH2(Ptb,Cc)] [dppm = bis(diphenylphosphanyl)methane] with phthalazine (NN) proceeded by replacement of the labile bridging SMe2 ligand with the bidentate N-donor ligand NN to give cis,cis -[Me2Pta(,-dppm)(,-NN)Ptb,CH2(CH2)2CcH2(Ptb,Cc)] (1) as a pale red solid in good yield. The complex was fully characterized by multinuclear (1H, 31P, 195Pt) NMR spectroscopy. The subsequent reaction of complex 1 with excess MeI gave the colorless diplatinum(IV) complex [Me3Pta(,-dppm)(,-I)2Ptb{CH2(CH2)2CcH2(Ptb,Cc)}Me], in which the bridging NN ligand is replaced by bridging iodido ligands. The reddish color of complex 1, which is due to a metal-to-ligand charge transfer (MLCT) band in the visible region, was used to monitor its reaction with MeI in the solvents acetone, CH2Cl2, and benzene. The kinetic data revealed that the reactions in nonpolar benzene or slightly polar CH2Cl2 proceeded in two steps, each following a common SN2 mechanism. In the first step, MeI attacked the platina(II)cyclopentane center rather than the dimethylplatinum(II) center, because the first center is more electron-rich than the second center. In the more polar acetone, the reaction proceeded similarly, with the exception that each step was accompanied by a solvolytic reaction, which was suggested to be responsible for the unusually slower reaction rate in acetone than in benzene or CH2Cl2. Consistently, the reaction rate in the highly polar solvent CH3CN was too slow for any meaningful measurement.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008) [source]


    Monocyclopentadienyl Phenoxido,Amino and Phenoxido,Amido Titanium Complexes: Synthesis, Characterisation, and Reactivity of Asymmetric Metal Centre Derivatives

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 29 2008
    Giuseppe Alesso
    Abstract Reduction of phenol,imine derivatives R,N=CH(3,5-R2C6H2 -2-OH) (R = tBu; R, = C6H51a, p -MeC6H41b, Cy 1c, tBu 1d, 2,6-Me2C6H31e; R = H; R, = p -MeC6H41f; Cy = cyclohexyl) with MBH4 (M = Li, Na) or AlLiH4 in ethyl ether or thf at room temperature affords the phenol,amine compounds R,NHCH2(3,5-R2C6H2 -2-OH) 2a,c and 2e,f. The N -R-[2,4-di- tert -butyl]benzo-1-oxa-3-azine species (R = tBu 2d1, 2,6-Me2C6H32e1) are obtained by Mannich reaction of 2,4-di- tert -butylphenol with RNH2 in refluxing methanol. Intermediate 2d1 is converted in ethanol at room temperature into N - tert -butyl[2-hydroxy-3,5-di- tert -butyl]benzylamine (2d), whereas 2e is not obtained from 2e1 by using this procedure.N -alkyl,N - tert -butyl[2-hydroxy-3,5-di- tert -butyl]benzylaminecompounds tBuN(R)CH2(3,5- tBu2C6H2 -2-OH) (R = Me 2g, Et 2h, nPr 2i, CH2Ph 2j) are also prepared by the appropriate synthetic method. Treatment of 2a,c with 1 equiv. of TiCpCl3 in the presence of 2.5 equiv. of NEt3 in hexane at room temperature gives the monocyclopentadienyl phenoxido,amido monochloride complexes TiCp[R,NCH2(3,5- tBu2C6H2 -2-O)]Cl (R, = C6H53a, R, = p -MeC6H43b, R, = Cy 3c). The analogous complex Ti(,5 -C5H4SiMe2Cl)[C6H5NCH2(3,5- tBu2C6H2 -2-O)]Cl (4a) results from the reaction of 2a with Ti(,5 -C5H4SiMe2Cl)Cl3. Nevertheless, 2d reacts with TiCpCl3 in hexane in the presence of NEt3 at room temperature yielding the monocyclopentadienyl phenoxido dichloride compound TiCp[tBuNHCH2(3,5- tBu2C6H2 -2-O)]Cl2 (5), whereas in ethyl ether and in the absence of NEt3 adduct 5·HCl is obtained, which is further converted into TiCp[tBuNCH2(3,5- tBu2C6H2 -2-O)]Cl (3d) by addition of a NEt3/ethyl ether solution. The reaction of TiCpCl3 with 2a in the presence of 2.5 equiv. of NEt3 in a polar solvent (thf, CH2Cl2 or toluene) at room temperature affords TiCp[Ph(H)NCH2(3,5- tBu2C6H2 -2-O)]Cl (6a) as a mixture of two stereoisomers. All the reported compounds were characterised by the usual analytical and spectroscopic methods and the molecular structures of 2a, 2d, 2e and 3d were determined by X-ray diffraction analysis from suitable single crystals. Preliminary studies of catalytic activity for ethylene polymerisation by using solid methylaluminoxane as cocatalyst were performed.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008) [source]


    Reactions of Pendant Boryl Groups in Cp,Metal Complexes: Heterocyclic Ring Annelation in a CpIr System

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 14 2008
    Christoph Herrmann
    Abstract Treatment of (cod)IrCl dimer with Li(allyl)cyclopentadienide gave (C5H4,CH2,CH=CH2)Ir(cod) (11). At 100 °C, 11 isomerizes cleanly into its ring-conjugated (trans -CH3,CH=CH,C5H4)Ir(cod) isomer (13). Subsequent addition of HB(C6F5)2 results in the formation of a product (16) that contains an annelated five-membered borata heterocycle at the Cp ring. This is probably formed by means of a reaction sequence involving regioselective hydroboration, followed by an electrophilic substitution reaction at the Cp ring by the strongly Lewis acidic ,B(C6F5)2 group, in which the iridium metal base acts as the proton abstractor. Products 13 and 16 were characterized by X-ray diffraction. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008) [source]


    Synthesis and Reactivity of Oxametallacyclic Niobium Compounds by Using ,,,-Unsaturated Carbonyl Ligands,

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 14 2008
    Rocío A. Arteaga-Müller
    Abstract Reduction of mono(cyclopentadienyl)niobium complexes [NbCpRCl4] [CpR = C5Me4H (1), C5H4SiMe2Cl (2), C5H4SiMe3 (3)] with Na/Hg in the presence of methyl methacrylate [MMA, CH2=C(Me)C(O)OMe (a)], methyl acrylate [MA, CH2=CHC(O)OMe (b)] and mesityl oxide [MO, CMe2=CHC(O)Me (c)] afforded the corresponding derivatives [NbCpRCl2(LL)] [CpR = C5Me4H, LL = MMA (1a); CpR = C5H4SiMe2Cl, LL = MMA (2a), MA (2b), MO (2c); CpR = C5H4SiMe3, LL = MMA (3a), MA (3b)] in variable yields depending on both the cyclopentadienyl and the ,,,-unsaturated carbonyl compounds. The reactivity of these complexes was studied toward protic and Lewis acids. Addition of triflic acid TfOH (Tf = CF3SO2) to 3b gave the triflate complex [NbCpRCl2{(CH2)2C(O)OMe}(OTf)] [CpR = C5H4SiMe3 (4)]. The Lewis acids E(C6F5)3 (E = B, Al) reacted with complexes 2b and 3b to give the three-membered metallacyclic (or ,2 -enone) compounds [NbCpRCl2{,2 -CH2=CHC(OMe){O·E(C6F5)3}}] [CpR = C5H4SiMe2Cl, E = B (5), Al (6); CpR = C5H4SiMe3, E = B (7), Al (8)], which decomposed to the corresponding adducts MA·E(C6F5)3. The same reaction with the 2a and 3a derivatives only allowed the observation of the corresponding adducts MMA·E(C6F5)3. Complexes 2a,b and 3a,b reacted with CO with elimination of the acrylate compounds, MA and MMA, respectively, to give the carbonylniobium(III) compounds [NbCpRCl2(CO)2]2 [CpR = C5H4SiMe2Cl (9), C5H4SiMe3 (10)]. Analogous reactions with CNAr showed the elimination of the free MA and MMA compounds. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008) [source]


    Liquid Crystal Imidazolium Salts: Towards Materials for Catalysis and Molecular Electronics

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 24 2007
    Jean-Moïse Suisse
    Abstract 1,3-Bis(4-alkyloxyphenyl)-3H -imidazol-1-ium trifluoromethanesulfonates, alkyl = CH3(CH2)n,1, n = 8, 10, 12, 14 and 16, can be derived from the analogous 4-alkyloxyphenylamines. These imidazolium salts exhibit a lamellar liquid-crystal mesophase between 99 °C and 191 °C. The smectic-A phase was fully characterised by polarising optical microscopy, differential scanning calorimetry and X-ray diffraction. We report also the synthesis, lamellar crystal structure and catalytic activity of the PdII complex of the (deprotonated) carbene form of one of these salts. In addition, we measured the charged carrier mobilities in the mesophase.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007) [source]


    Construction of 1D and 2D Copper(I) Coordination Polymers Assembled by PhS(CH2)nSPh (n = 1, 2) Dithioether Ligands: Surprising Effect of the Spacer Length on the Dimensionality, Cluster Nuclearity and the Fluorescence Properties of the Metal,Organic Framework,

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 13 2007
    Harmel N. Peindy
    Abstract Treatment of CuI with PhSCH2SPh in MeCN solution affords, by a self-assembly reaction, the monodimensional metal,organic coordination polymer [Cu4I4{,-PhS2CH2SPh}2]n (1), in which Cu4(,3 -I)4 cluster units are linked by the dithioether ligand in a 1D necklace structure. In contrast, the reaction of PhSCH2CH2SPh with CuI results in the formation of the metallopolymer [(CuI)2{,-PhS(CH2)2SPh}2]n (2). The 2D network of 2 is built from dimeric Cu2I2 units which are connected by 1,2-bis(phenylthio)ethane bridging ligands. The solid-state luminescence spectrum of 1 exhibits a strong emission around 532 nm, whereas a weak emission centred at 413 nm is observed in the case of 2. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007) [source]


    Reactivity and X-ray Structural Studies in Ligand Substitution of [Cp/(Ind)Ru(dppf)Cl] , Epimerisation in [Cp/(Ind)Ru(Josiphos)Cl] {Cp = ,5 -C5H5, Ind = ,5 -C7H9, dppf = 1,1,-Bis(diphenylphosphanyl)ferrocene, Josiphos = (R)-(,)-1-[(S)-2-(Diphenylphosphanyl)ferrocenyl]ethyldicyclohexylphosphane}

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 3 2007
    Sin Yee Ng
    Abstract Ligand substitution of [(Ind)Ru(PPh3)2Cl] (1) led to the isolation of [(Ind)Ru(PPh3){Ph2P(CH2)2C9H7}Cl] (2), [(Ind)Ru(dppf)Cl] (3) and [(Ind)Ru{(Ph2PCH2)3CMe}]PF6 ([4]PF6), and diastereoisomers [(R)- and (S)-(Ind)Ru(Josiphos)Cl] [(R)- 5 and (S)- 5], where (R)-(S)-Josiphos is the ferrocene-based chiral diphosphane ligand (R)-(,)-1-[(S)-2-(diphenylphosphanyl)ferrocenyl] ethyldicyclohexylphosphane. The Cp analogues of 5, viz. (R)- 6 and (S)- 6, were also obtained from [CpRu(PPh3)2Cl] (1a). Josiphos-dependent epimerisation was observed, with conversion of the (S) isomer to the (R) isomer in both cases. Chloride abstraction of 3 with NaPF6 in CH3CN and NaN3 in EtOH gave [(Ind)Ru(dppf)(CH3CN)]PF6 ([7]PF6) and [(Ind)Ru(dppf)(N3)] (8), respectively. The azido ligand in 8 underwent [3+2] dipolar cycloaddition with dimethyl acetylenedicarboxylate to give a N -bound bis(methoxycarbonyl)-1,2,3-triazolato complex, 9. X-ray crystal structures of the new complexes, except (R)- 5, (S)- 5 and (S)- 6, have been determined. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007) [source]


    Synthesis and Structure of [nPr3N(CH2)6NnPr3][CuFe3Br3(SePh)6], [Cu5Fe(SePh)7(PPh3)4] and [Cu4Fe3(SePh)10(PPh3)4],

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 1 2007
    Andreas Eichhöfer
    Abstract CuBr and Fe(OOCCH3)2 react with PhSeSiMe3 in acetonitrile in the presence of the diammonium salt [nPr3N(CH2)6NnPr3]Br2 to yield ionic [nPr3N(CH2)6NnPr3][CuFe3Br3(SePh)6]. The neutral complexes [Cu5Fe(SePh)7(PPh3)4] and [Cu4Fe3(SePh)10(PPh3)4] were obtained by similar reactions of different stoichiometric mixtures of CuOOCCH3 and FeCl2 with PPh3 and PhSeSiMe3. The crystal structures of the compounds were determined by single-crystal X-ray analysis to give new structural types of molecular cluster compounds formed by copper, iron and selenium. Thermal treatment of [Cu5Fe(SePh)7(PPh3)4] and [Cu4Fe3(SePh)10(PPh3)4] resultsin the formation of mixtures of binary Cu2Se and ternaryCuFeSe2.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007) [source]


    Synthesis and Properties of Organometallic PtII and PtIV Complexes with Acyclic Selenoether and Telluroether Ligands and Selenoether Macrocycles

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 21 2006
    William Levason
    Abstract The first series of planar dimethyl(selenoether)PtII complexes, [PtMe2L] [L = MeSe(CH2)nSeMe (n = 2 or 3), o -C6H4(CH2SeMe)2, [8]aneSe2 (1,5-diselenacyclooctane), or [16]aneSe4 (1,5,9,13-tetraselenacyclohexadecane)], have been obtained by treatment of [PtMe2(SMe2)2] with L in Et2O solution and characterised by VT 1H, 13C{1H}, 77Se{1H} and 195Pt{1H} NMR spectroscopy, electrospray MS and microanalysis. The corresponding dimethyl(telluroether)PtII complexes do not form under similar reaction conditions. The distorted octahedral [PtMe3I(L)] [L = o -C6H4(CH2SeMe)2, [8]aneSe2, [16]aneSe4 or MeC(CH2SeMe)3] form as stable complexes in good yield from reaction of PtMe3I with L in refluxing CHCl3 and have been characterised similarly. These all show bidentate selenoether coordination, with fast pyramidal inversion occurring at room temperature. The distorted octahedral coordination environment at PtIV is also confirmed from a crystal structure of [PtMe3I{o -C6H4(CH2SeMe)2}]. Rare examples of (telluroether)PtIV complexes, [PtMe3I{o -C6H4(CH2TeMe)2}] and the dinuclear [Me3Pt(,2 -I)2(,2 -MeTeCH2TeMe)PtMe3], have also been prepared and characterised similarly (and also by 125Te{1H} NMR spectroscopy). The [8]aneSe2 and [16]aneSe4 species are the first examples of alkyl PtII or PtIV complexes with (macro)cyclic selenoether coordination. Halide abstraction (TlPF6) from [PtMe3I(,2 -[16]aneSe4)] affords [PtMe3(,3 -[16]aneSe4)]PF6; a rare example of a cationic PtIV selenoether. The (diselenoether)PtII complexes undergo oxidative addition of MeI to yield the corresponding PtIV species [PtMe3I(diselenoether)]. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006) [source]


    Preparation of Hydroxylamine and O -Methylhydroxylamine Complexes of Manganese and Rhenium

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 17 2006
    Gabriele Albertin
    Abstract Hydroxylamine and O -methylhydroxylamine complexes [M(NH2OH)(CO)nP5,n]BPh4 and [M(NH2OCH3)(CO)nP5,n]BPh4 [M = Mn, Re; n = 1, 2, 3; P = P(OEt)3, PPh(OEt)2, PPh2OEt] were prepared by allowing hydrides MH(CO)nP5,n to react first with triflic acid and then with an excess of hydroxylamine. Bidentate phosphane and phosphite can also be used to prepare both NH2OH and NH2OCH3 complexes of manganese and rhenium of the [M(NH2OR)(CO)2(P,P)-{P(OEt)3}]BPh4 and [M(NH2OR)(CO)3(P,P)]BPh4 [R = H, CH3; P,P = Ph2POCH2CH2OPPh2, Ph2PO(CH2)3OPPh2, Ph2PN(CH3)CH2CH2N(CH3)PPh2] types with the use of MH(CO)2(P,P){P(OEt)3} and MH(CO)3(P,P) as precursors. The complexes were characterized spectroscopically and by theX-ray crystal-structure determination of [Re(NH2OCH3)(CO)2{PPh(OEt)2}3]BPh4 and [Re(NH2OCH3)(CO)3{Ph2PO(CH2)3OPPh2}]BPh4. Oxidation of the hydroxylamine complexes with Pb(OAc)4 was studied at ,40 °C and led to an unstable compound tentatively characterized as a nitroxyl [M],N(H)=O derivative.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006) [source]


    Amine-Intercalated Layered SnII Phosphates with Open-Framework Structures

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 17 2006
    Padmini Ramaswamy
    Abstract Three new SnII phosphate materials, [NH3(CH2)3NH2(CH2)2NH2(CH2)3NH3]·2[Sn2P2O8] (I), [(N2C5H14)2][Sn4P4O16]·3H2O (II) and [(N2C5H14)][Sn2P2O8]·H2O (III), have been synthesised by means of hydrothermal methods using N,N, -bis(3-aminopropyl)ethylenediamine (BAPEN; for I) and homopiperazine (H-PIP; for II and III), respectively, as the structure-directing organic amines. The solids I,III have layered architectures. The structures of all three compounds consist of strictly alternating vertex-sharing trigonal-pyramidal SnO3 and tetrahedral PO4 moieties forming infinite layers possessing apertures bound by 4- and 8-T atoms (T = Sn, P). The distorted 4- and 8-membered apertures within the layers suggest the subtle influence of the lone-pair of electrons of SnII on the structure. The interlamellar space is occupied by the protonated organic amine molecules which interact with the framework through N,H···O hydrogen bonding. The compounds I,III bear some structural relationship to the layered zinc phosphite phases. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006) [source]


    Dicopper(II) Complexes with the Enantiomers of a Bidentate Chiral Reduced Schiff Base: Inclusion of Chlorinated Solvents and Chiral Recognition of1,2-Dichloroethane Rotamers in the Crystal Lattice

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 14 2006
    Vamsee Krishna Muppidi
    Abstract Bisphenoxo-bridged dicopper(II) complexes [Cu2Ln2Cl2] {1 (n = 1) and 2 (n = 2)} with the N,O-donor reduced Schiff bases N -(2-hydroxybenzyl)-(R)-,-methylbenzylamine (HL1) and N -(2-hydroxybenzyl)-(S)-,-methylbenzylamine (HL2) have been synthesised and characterised. In both 1 and 2, the bidentate chiral ligands coordinate the metal centres through the secondary amine N atom and the bridging phenolate O atom. The chloride ion occupies the fourth coordination site and completes a slightly distorted square-planar NO2Cl environment around each copper(II) centre. Magnetic susceptibility measurements in the solid state suggest a strong antiferromagnetic interaction between the metal centres in both complexes. Both 1 and 2 readily form 1:1 host-guest compounds with chlorinated solvents such as CH2Cl2, CHCl3 and Cl(CH2)2Cl. All the host-guest compounds crystallise in noncentrosymmetric space groups. 1·CH2Cl2 and 2·CH2Cl2 crystallise in the P21 space group while 1·CHCl3, 2·CHCl3, 1·Cl(CH2)2Cl and 2·Cl(CH2)2Cl crystallise in the P212121 space group. In these inclusion crystals, the C,H···Cl interactions between the guest and the host molecules are primarily responsible for enclatheration of the chloroalkane molecules. In the case of CH2Cl2, one of its Cl atoms acts as the acceptor. On the other hand, for CHCl3 and Cl(CH2)2Cl, the metal coordinated Cl atom of the host complex acts as the acceptor. The structures of 1·(P)-Cl(CH2)2Cl and 2·(M)-Cl(CH2)2Cl provide rare examples for chiral recognition of the right handed (P) and the left handed (M) gauche forms of Cl(CH2)2Cl in molecular assemblies. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006) [source]


    Syntheses, Spectroscopic Studies, and Crystal Structures of Chiral [Rh(aminocarboxylato)(,4 -cod)] and Chiral [Rh(amino alcohol)(,4 -cod)](acetate) Complexes with an Example of a Spontaneous Resolution of a Racemic Mixture into Homochiral Helix-Enantiomers

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 11 2006
    Mohammed Enamullah
    Abstract The dimeric complex acetato(,4 -cycloocta-1,5-diene)rhodium(I), [Rh(O2CMe)(,4 -cod)]2 (cod = cycloocta-1,5-diene), reacts with amino acids [HAA = L -alanine, (S)-2-amino-2-phenylacetic acid (L -phenylglycine), N -methylglycine, and N -phenylglycine] and with the amino alcohol (S)-2-amino-2-phenylethanol to afford the aminocarboxylato(,4 -cycloocta-1,5-diene)rhodium(I) complexes [Rh(AA)(,4 -cod)] (AA = deprotonated amino acid = aminocarboxylato ligand) and [(S)-2-amino-2-phenylethanol](,4 -cycloocta-1,5-diene)rhodium(I) acetate, [Rh{(S)-HOCH2,CH(Ph)-NH2}(,4 -cod)](O2CMe) (V). The complexes are characterized by IR, UV/Vis, 1H/13C NMR and mass spectroscopy. The achiral N -phenylglycine ligand gives a chiral N -phenylglycinato complex [Rh(O2C,CH2,NHPh)(,4 -cod)] (IV) with the amine nitrogen atom becoming the stereogenic center upon metal coordination. Complex IV crystallizes in the tetragonal, chiral space group P43 and the crystal structure reveals twofold spontaneous resolution of a racemic mixture into homochiral helix-enantiomers. The investigated crystal contained only one type of helix, namely (left-handed or M- ) 43 -helical chains. This is traced first to an intermolecular N,H···O hydrogen bonding from the stereogenic amino group to a neighboring unligated carboxyl oxygen atom that connects only molecules of the same (R)-configuration into (left-handed or M- ) 43 -helical chains. This intrachain homochirality is supplemented, secondly, by the interlocking of adjacent chains with their corrugated van der Waals surface to allow for an interchain transmission of the sense of helicity, building the single crystal from the same homochiral helix-enantiomer. The enantiomeric amino alcohol complex V crystallizes in the monoclinic, noncentrosymmetric (Sohncke) space group P21. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006) [source]


    Syntheses, Crystal Structures, and Characterizations of a Series of New Layered Lanthanide Carboxylate-Phosphonates

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 10 2006
    Si-Fu Tang
    Abstract Hydrothermal reactions of different lanthanide(III) salts with (H2O3PCH2)2NCH2COOH (H5L1) led to two new layeredlanthanide(III) carboxylate-diphosphonates, namely La(H2L1)(H2O)2·H2O (1) and La(H2L1)(H2O) (2). The structure of compound 1 features a layered architecture in which the nine-coordinate La3+ ions are bridged by phosphonate groups of the ligands. The carboxylate group of the phosphonate ligand remains protonated and is involved in the interlayer hydrogen bonding. Compound 2 features a double layer structure in which the La3+ ion is eight-coordinated and the carboxylate group of the ligand is chelated to a La3+ ion in a bidentate fashion. Hydrothermal reactions of lanthanide(III) salts with 4-HOOC,C6H4,CH2N(CH2PO3H2)2 (H5L2) afforded three new compounds, namely, La(H4L2)(H3L2)(H2O)·2H2O (3), Er(H3L2)(H4L2) (4), and Er(HL3)(H2L3)(H2O) (5) [H2L3 = H2O3PCH2N(CHO)(CH2,C6H4,COOH)]. H2L3 was formed by the in situ oxidation of one P,C bond of the H5L2 ligand. Compound 3 features a (002) lanthanum(III) phosphonate layer in which the seven-coordinate La3+ ions are bridged by diphosphonate moieties of the ligands. The carboxylate group remains protonated and is involved in the interlayer hydrogen bonding. The structure of compound 4 contains a 1D chain along the a axis in which each pair of ErO6 octahedra is bridged by a pair of phosphonate groups. These 1D chains are further interconnected by hydrogen bonds between noncoordinated phosphonate oxygen atoms into a (002) layer with the phenyl carboxylate groups hanging on the interlayer space. The structure of compound 5 is also layered. The interconnection of Er3+ ions by bidentate and tetradentate bridging phosphonate groups resulted in a (002) inorganic layer with the organic groups orientated to the interlayer space. Luminescence properties of compounds 4 and 5 have also been studied.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006) [source]


    Self-Assembly of a Tetranuclear CoIII -Metallacycle from the Reaction of a Bis(benzene- o -dithiolato) Ligand with CoII and Subsequent Aerial Oxidation

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 3 2006
    F. Ekkehardt Hahn
    Abstract The bis(benzene- o -dithiol) ligand [(HS)2 -2,3-C6H3,CH2,C6H3 -2,3-(SH)2] (H4 - 1) reacts, after deprotonation with Li2CO3, with CoCl2·6H2O. Aerial oxidation in methanol gives the tetranuclear metallacycle Li4[Co4(1)4]. The X-ray structure analysis of (PNP)4[Co4(1)4] (7) reveals a cyclic structure in which each of the bis(benzene- o -dithiolato) ligands forms a bridge between two cobalt centers. Two differently coordinated cobalt atoms (syn and anti) are observed in the tetranuclear complex. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006) [source]


    Carbosilane Dendrons Functionalized at Their Focal Point

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 18 2005
    Román Andrés
    Abstract The Si,Ph bond of PhSi[(CH2)3SiMe2Bz]3 (5) is cleaved with triflic acid to give TfOSi[(CH2)3SiMe2Bz]3, which, in turn, reacts with triethylammonium chloride or potassium cyclopentadienide to give, respectively, ClSi[(CH2)3SiMe2Bz]3 (8) and (C5H5)Si[(CH2)3SiMe2Bz]3 (10). This strategy can be applied to the post-growth incorporation of nucleophiles to the focal point of carbosilane dendritic wedges. In this way, cyclopentadiene-functionalized dendritic wedges of second and third generation C5H5 -Gn -[(CH2)3SiMe2Bz]x (n = 2, x = 9, 11; n = 3, x = 27, 12) have been obtained starting from Ph-Gn -[(CH2)3SiMe2Bz]x (6, 7). The metallocenes [{(BzMe2SiCH2CH2CH2)3SiC5H4}2MCl2] (M = Ti, 14; Zr, 15) have also been obtained from 10 and their catalytic behavior in ethylene and propylene polymerization, using MAO as a cocatalyst, has been studied and compared to that of related non-dendritic complexes. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005) [source]


    Reaction of 1,3,5-Triazacyclohexanes with TiCl4: Formation of Cationic Complexes

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 16 2005
    Randolf D. Köhn
    Abstract N -substituted 1,3,5-triazacyclohexanes [R3TAC; R = cyclohexyl, p -fluorobenzyl or Ph(CH2)n (n = 1, 2, 3)] react with excess TiCl4 to give the corresponding cationic ,3 complexes [(R3TAC)TiCl3][Ti2Cl9]. Attempts to prepare complexes with titanium-free anions at lower Ti:R3TAC ratio or with added Me3SiOTf lead to the same cations with [Ti2Cl10]2, and [Ti2Cl8(OTf)], anions. Five complexes as well as (p -fluorobenzyl)3TAC have been characterised by X-ray crystallography. The ring C,H bonds engage in hydrogen bonding interactions in the crystals and strongly solvent and anion dependent 1H NMR signals are detected in solution. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005) [source]


    The Reductive Elimination of Methane from ansa -Hydrido(methyl)metallocenes of Molybdenum and Tungsten: Application of Hammond's Postulate to Two-State Reactions

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 15 2005
    José-Luis Carreón-Macedo
    Abstract The energetic profile of the methane reductive elimination from a selected number of hydrido(methyl)molybdenocene and -tungstenocene derivatives has been calculated by DFT methods. The calculations were carried out for the CH2(C5H4)2M (a -M), SiH2(C5H4)2M (a -H2Si,M), and SiMe2(C5Me4)2M (a -Me2Si,M*) ansa -metallocene systems for M = Mo, W. They include the full optimization of minima [the hydrido(methyl) starting complexes, M(H)(CH3), the intermediate methane complexes, M(CH4), and the metallocene products in the singlet and triplet configurations, (3M and 1M)], transition states (for the methyl hydride reductive elimination, M,TSins, and for the hydrogen exchange, M,TSexch), and the minimum energy crossing point (M,MECP) leading from the singlet methane complexes to the corresponding triplet metallocenes. The results are compared with those previously obtained for the simpler (C5H5)2M (Cp2M) systems (J. C. Green, J. N. Harvey, and R. Poli, J. Chem. Soc., Dalton Trans.2002, 1861). The calculated energy profiles, notably the relative energies of M,TSins and M,MECP, are in agreement with available experimental observations for the a -Me2Si,M* systems. The comparison of the energies and geometries of the rate-determining M,TSins and M,MECP structures with those of the thermodynamically relevant minima for the various systems show the applicability of Hammond's postulate to two-state reactions. However, one notable exception serves to show that the principle is only quantitatively reliable when all the potential energy surfaces for the set of analogous reactions have similar shapes. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005) [source]


    Synthesis and Structural Characterization of Three-Coordinate MnII, FeII, and ZnII Complexes Containing a Bulky Diamide Ligand [DippN(CH2)3NDipp]2, (Dipp = 2,6- iPr2C6H3)

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 24 2004
    Jianfang Chai
    Abstract The reaction of DippNH(CH2)3NHDipp (1) (Dipp = 2,6- iPr2C6H3) with 2 equiv. of MeLi in diethyl ether resulted in the formation of the monomeric dilithium salt [(Dipp)N(CH2)3N(Dipp)][Li(OEt2)]2 (2) in high yield. Further reactions of 2 with MnCl2, FeCl2, and ZnCl2, respectively, afforded the complexes [M2{N(Dipp)(CH2)3N(Dipp)}2] [M = Mn (3), Fe (4), Zn (5)] with three-coordinate metal centers. Complexes 2,5 were characterized by X-ray structural analysis. The complexes contain a nonplanar MNMN central core. The diamide ligand in complexes 3,5 displays a boat conformation and is both chelating and bridging, so that one of the nitrogen atoms is three-coordinate and the other four-coordinate. Complexes 3,5 are the first examples with diamide ligands in such a bonding mode. The magnetic investigations of compounds 3 and 4 reveal an antiferromagnetic exchange between the metal atoms. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004) [source]


    Reactions of the Aluminum(I) Monomer LAl [L = HC{(CMe)(NAr)}2; Ar = 2,6- iPr2C6H3] with Imidazol-2-ylidene and Diphenyldiazomethane.

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 20 2004
    A Hydrogen Transfer from the L Ligand to the Central Aluminum Atom, Formation of the Diiminylaluminum Compound LAl(N=CPh2)
    Abstract The solid-state reaction of LAl and imidazol-2-ylidene at elevated temperature (120 °C) yielded the aluminum monohydride N -heterocyclic carbene adduct [{HC[C(CH2)NAr] (CMeNAr)}AlH-{CN(R)C2Me2N(R)}] [R = iPr (1), Me (2)]. Compounds 1 and 2 have been characterized by spectroscopic (IR, and 1H and 13C NMR), mass spectrometric, and elemental analyses, and 1 was further characterized by X-ray structural analysis. These experimental data indicate that the Al,H bond is formed by hydrogen migration from one of the methyl groups of the ,-diketiminato ligand backbone. The reaction of LAl with two equivalents of diphenyldiazomethane afforded the diiminylaluminum compound LAl(N=CPh2)2 (3), while an excess of diphenyldiazomethane resulted in the formation of Ph2C=N,N=CPh2. This suggests that Ph2C=N,N=CPh2 is initially generated and then reacts further by oxidative addition to yield 3. The X-ray structural analysis reveals that compound 3 contains the shortest Al,Niminyl bond among those with a four-coordinate aluminum center. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004) [source]


    Novel Cadmium(II) Adipate Coordination Polymers with Structural Transformation via Oxalate Ligand: Syntheses, Structures and Fluorescence Properties

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 20 2004
    Na Hao
    Abstract Two novel cadmium adipate coordination polymers [Cd{O2C(CH2)4CO2}{1,10-phen}]n (1) and [Cd2(C2O4){O2C(CH2)4CO2(OH2)2}{2,2,-bipy}]·H2O (2) [adipic acid = HO2C(CH2)4CO2H] have been hydrothermally synthesized and characterized by elemental analyses, IR spectroscopy, thermogravimetric analysis and single-crystal X-ray diffraction. Crystallographic data for 1: monoclinic, C2/c, a = 16.186(3) Å, b = 15.487(3) Å, c = 14.052(3) Å, , = 112.73(3)°, Z = 8. Crystal data for 2: monoclinic, Cc, a = 23.448(5) Å, b = 11.826(2) Å, c = 8.3163(17) Å, , = 99.08(3)°, Z = 4. The structural analysis reveals that 1 forms a novel one-dimensional chain in which the binuclear Cd centers are linked by adipate anions. Compound 2 is the first example in which both a 2,2,-bipy ligand and an oxalate group are found in the {M/adipate} system. Compound 2 possesses one-dimensional sine- or cosine-type chains, which are alternately connected together by the oxalate group to form a three-dimensional framework. The structural determination reveals that the introduction of the oxalate ligand causes the dimensional transformation of the compounds. Compounds 1 and 2 show strong fluorescent properties at room temperature. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004) [source]