Certain Conditions (certain + condition)

Distribution by Scientific Domains
Distribution within Life Sciences


Selected Abstracts


Numerical simulation of non-isothermal phase change problem using ADRBEM with augmented items

HEAT TRANSFER - ASIAN RESEARCH (FORMERLY HEAT TRANSFER-JAPANESE RESEARCH), Issue 7 2007
Jie Liu
Abstract In this paper, the phase change moving interface problem along the axial direction of the cylinder in the lead alloys containing tin is simulated by the axisymmetric dual reciprocity boundary element method (ADRBEM) with augmented items. The numerical method is verified by comparing with the analytical solution under a certain condition. The calculating results show that the ADRBEM with augmented items is an effective numerical method to solve the analogous problem of non-isothermal phase change, which occurs in the crystal growth process. © 2007 Wiley Periodicals, Inc. Heat Trans Asian Res, 36(7): 408, 416, 2007; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/htj.20173 [source]


Hierarchy crystallization structure of a polypropylene random copolymer injection-molded bar induced by a nucleating agent

JOURNAL OF APPLIED POLYMER SCIENCE, Issue 1 2008
Yong Wang
Abstract In this work, the effect of a nucleating agent on the crystallization structure of an injection-molded bar of a polypropylene random copolymer (PPR) with sorbitol derivatives [1,2,3,4-dibenzylidene sorbitol (DBS)] has been studied. The results show that pure PPR forms a simple skin,core crystallization structure. However, PPR/DBS forms an interesting and complicated hierarchy crystallization structure: there is a transition layer between the skin layer and the core zone. In this transition layer, the crystallization structure consists of some perfect spherulites and many tiny crystallites. Further research suggests that the formation of the hierarchy crystallization structure depends on not only the content of the nucleating agent in the PPR matrix but also the mold temperature during the injection-molding processing. The crystallization behavior of PPR/DBS during the cooling process has been characterized with polarization optical microscopy and differential scanning calorimetry. The results suggest that there are different mechanisms in the crystallization process of PPR/DBS. The formation of a three-dimensional DBS network under a certain condition might be the main reason for the complicated hierarchy crystallization structure. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 [source]


Nonlinear incidence rate of a pest management SI model with impulsive control strategy

MATHEMATICAL METHODS IN THE APPLIED SCIENCES, Issue 5 2010
Jianjun Jiao
Abstract In this work, we consider a pest management SI model with concerns about releasing of infective pests and spraying pesticides at different fixed moments. We prove that all solutions the investigated system are uniformly ultimately bounded, and there exists globally asymptotic stable pest-extinction boundary periodic solution when certain condition is satisfied. Furthermore, the permanent condition of the system is also obtained. It is concluded that the approach, which combines releasing infective pests with spraying pesticides in different fixed moments, provides reliable tactic basis for the practical pest management. Copyright © 2009 John Wiley & Sons, Ltd. [source]


Magnon energy gap and the magnetically structural symmetry in a three-layer ferrimagnetic superlattice

PHYSICA STATUS SOLIDI (B) BASIC SOLID STATE PHYSICS, Issue 8 2006
Rong-ke Qiu
Abstract The magnon energy band in a ferrimagnetic superlattice with three layers in a unit cell is studied by employing retarded Green's functions and the spin-wave method. Two modulated energy gaps ,,13 and ,,23 are evaluated systematically, which exist in the magnon energy band along the Kx -direction perpendicular to the plane of the superlattice. It is revealed that the energy gap ,,13 has a direct relation with the symmetry among the spin quantum numbers and the interlayer exchange couplings, while the energy gap ,,23 relates to the symmetry among these spin quantum numbers only. These symmetries differ from the symmetry of crystallographic point groups. We define the magnetically structural symmetry that is dominated mainly by the magnetic parameters. The absence of the energy gap at a certain condition means that the system has a high magnetically structural symmetry. The magnetically structural symmetry of the superlattice, which is an intrinsic property, strongly affects the magnon energy band structure and thus the magnetic behaviors of the system. Furthermore, two complete bandgaps are observed to extend through the Brillouin zone (referred to as "magnonic crystal") in this superlattice system. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


Periodically Discontinuous Induction of Bone Marrow Stem Cells toward Osteogenic Differentiation in Vitro

BIOTECHNOLOGY PROGRESS, Issue 3 2008
Zhen Wang
This paper reveals that a discontinuous in vitro induction, namely, the periodic presence and absence of foreign induction factors, might be, under a certain condition, more effective to stimulate stem cells' differentiation than a continuous induction. Bone marrow stem cells (BMSCs) derived from Sprague Dawley rats were employed to examine the effects of discontinuous additions of osteogenic supplements with a series of alternate frequency in contrast to those with continuous induction or no induction. The results demonstrated that a suitable discontinuous induction was more able to achieve osteogenesis than not only no induction but also the associated continuous induction. Additionally, the osteogenic supplements were confirmed to enhance cell differentiation but suppress cell proliferation. So, the combination of differentiation extent per cell and cell number accounts for the "unexpected" good osteogenic effect of the discontinuous induction. The induction effect was found to be dependent upon alternate frequency, and the optimum alternate period in our experimental systems was determined to be around 4 days. Since it is very common to change culture medium every 2,4 days, such a strategy of discontinuous induction does not bring any extra manual work but reduces the consumption of foreign induction factors and significantly enhances the global differentiation efficacy. Our work thus affords a convenient and practical approach to achieve differentiation of BMSCs, which might be useful for potential large-scale culture and differentiation of stem cells. Meanwhile, the existence of optimum frequency implies some unknown inherent rhythms of cell proliferation and differentiation. [source]


Effective Synthesized/preappraised Evidence Formats in Emergency Medicine and the Use of Supplemental Knowledge Translation Techniques

ACADEMIC EMERGENCY MEDICINE, Issue 11 2007
Brian H. Rowe MD
Most clinicians, and especially emergency physicians, are increasingly faced with the need for valid and reliable evidence upon which to base practice decisions in a timely fashion. Despite the accumulation of synthesized evidence in emergency medicine over the past decade, knowledge gaps still exist between what is known and what is practiced. In many cases, this failure in knowledge uptake relates to barriers in uptake as well as the difficulty of translating evidence from research to the bedside. Preappraised evidence syntheses represent a potential partial solution to these problems by providing condensed summaries of the large volume of scientific literature in our field. The participants in this workshop examined the availability, utility, and impact of preappraised evidence and examined innovative ways to translate this knowledge into practice. In addition, the workshop participants also explored more globally all knowledge translation methods that are distinct from clinical pathways (e.g., audit and feedback, academic detailing, reminders, and local opinion leaders). These are initiatives that are instituted at the level of a particular hospital or with respect to a certain condition, and emergency physicians need to understand their definition and application. Overall, the recommendations arising from this workshop have the potential to alter future emergency care in important ways. [source]


A Study on the Effects of Damage Models and Wavelet Bases for Damage Identification and Calibration in Beams

COMPUTER-AIDED CIVIL AND INFRASTRUCTURE ENGINEERING, Issue 8 2007
Vikram Pakrashi
A numerical study has been performed in this article addressing these issues for single and multispan beams with an open crack. The first natural modeshapes of single and multispan beams with an open crack have been simulated considering damage models of different levels of complexity and analyzed for different crack depth ratios and crack positions. Gaussian white noise has been synthetically introduced to the simulated modeshape and the effects of varying signal-to-noise ratio have been studied. A wavelet-based damage identification technique has been found to be simple, efficient, and independent of damage models and wavelet basis functions, once certain conditions regarding the modeshape and the wavelet bases are satisfied. The wavelet-based damage calibration is found to be dependent on a number of factors including damage models and the basis function used in the analysis. A curvature-based calibration is more sensitive than a modeshape-based calibration of the extent of damage. [source]


Strategic Decisions of New Technology Adoption under Asymmetric Information: A Game-Theoretic Model*

DECISION SCIENCES, Issue 4 2003
Kevin Zhu
ABSTRACT In this paper we explore strategic decision making in new technology adoption by using economic analysis. We show how asymmetric information affects firms' decisions to adopt the technology. We do so in a two-stage game-theoretic model where the first-stage investment results in the acquisition of a new technology that, in the second stage, may give the firm a competitive advantage in the product market. We compare two information structures under which two competing firms have asymmetric information about the future performance (i.e., postadoption costs) of the new technology. We find that equilibrium strategies under asymmetric information are quite different from those under symmetric information. Information asymmetry leads to different incentives and strategic behaviors in the technology adoption game. In contrast to conventional wisdom, our model shows that market uncertainty may actually induce firms to act more aggressively under certain conditions. We also show that having better information is not always a good thing. These results illustrate a key departure from established decision theory. [source]


Access to Land, Rural Development and Public Action: The When and the How

DEVELOPMENT POLICY REVIEW, Issue 1 2009
Pablo Bandeira
After being marginalised in the 1980s, land-reform policies came back to national and international development agendas during the 1990s, resulting in a revival of academic research on the subject. This article reviews the empirical literature on access to land, rural development and public action for evidence on when and how the state should intervene in the allocation of rural land. The review suggests that positive impacts are obtained if, and only if, public actions on the allocation of land are carried out under certain conditions and in a certain way. The article ends by highlighting the need to elaborate empirical models that take into consideration opportunity costs and interactions, and that integrate individual responses with aggregate effects. [source]


The next exclusion debate: Assessing technology, ethics, and intellectual disability after the human genome project

DEVELOPMENTAL DISABILITIES RESEARCH REVIEW, Issue 2 2007
Kelly M. Munger
Abstract Recent scientific discoveries have made it much easier to test prenatally for various genetic disabilities, such as Down syndrome. However, while many observers have heralded such "advances" for their effectiveness in detecting certain conditions, others have argued that they perpetuate discrimination by preventing the birth of children with disabilities. This article examines the ethical and social implications of the Human Genome Project for individuals with intellectual disabilities and their families. It details the critique of prenatal testing articulated by many disability rights activists as well as scholarly and professional responses to that critique. A review of the pertinent research literature includes perspectives of genetic professionals, ethicists, disability studies scholars, parents of children with disabilities, and disabled individuals themselves. Finally, the article explores how future research endeavors, policies, and practices may more effectively integrate and respect the positions of these various stakeholders. © 2007 Wiley-Liss, Inc. MRDD Research Reviews 2007;13:121,128. [source]


Numerical and dietary responses of a predator community in a temperate zone of Europe

ECOGRAPHY, Issue 2 2009
Gilles Dupuy
The generalist predation hypothesis predicts that the functional responses of generalist predator species should be quicker than those of specialist predators and have a regulating effect on vole populations. New interpretations of their role in temperate ecosystems have, however, reactivated a debate suggesting generalist predators may have a destabilizing effect under certain conditions (e.g. landscape homogeneity, low prey diversity, temporary dominance of 1 prey species associated with a high degree of dietary specialization). We studied a rich predator community dominated by generalist carnivores (Martes spp., Vulpes vulpes, Felis catus) over a 6 yr period in farmland and woodland in France. The most frequent prey were small rodents (mostly Microtus arvalis, a grassland species, and Apodemus spp., a woodland species). Alternative prey were diverse and dominated by lagomorphs (Oryctolagus cuniculus, Lepus europeus). We detected a numerical response among specialist carnivores but not among generalist predators. The dietary responses of generalist predators were fairly complex and most often dependent on variation in density of at least 1 prey species. These results support the generalist predation hypothesis. We document a switch to alternative prey, an increase of diet diversity, and a decrease of diet overlap between small and medium-sized generalists during the low density phase of M. arvalis. In this ecosystem, the high density phases of small mammal species are synchronous and cause a temporary specializing of several generalist predator species. This rapid functional response may indicate the predominant role of generalists in low amplitude population cycles of voles observed in some temperate areas. [source]


Unemployment and Search Externalities in a Model with Heterogeneous Jobs and Workers

ECONOMICA, Issue 273 2002
Pieter A. Gautier
This paper presents a matching model with low, and high,skilled workers and simple and complex jobs. I show that the degree to which low,skilled workers are harmed by high,skilled workers who are willing to temporarily accept simple jobs depends on the relative productivity of high, and low,skilled workers on simple jobs and on the quit rate of high,skilled workers. Under certain conditions, low,skilled workers can benefit from job competition with high,skilled workers. Within this framework, some explanations for the high and persistent unemployment rates of lower educated workers in the 1990s are evaluated. [source]


Campaign War Chests, Entry Deterrence, and Voter Rationality

ECONOMICS & POLITICS, Issue 3 2002
Dhammika Dharmapala
It is often claimed that the accumulation of "war chests" by incumbents deters entry by high,quality challengers in Congressional elections. This paper presents a game,theoretic analysis of the interaction between an incumbent, potential challengers, an interest group, and a representative (rational) voter, where the incumbent's "quality" (or "legislative effectiveness") is known to the interest group, but not to the voter or to potential challengers. Under certain conditions, a perfectly revealing equilibrium exists; the incumbent signals her quality by raising funds from the interest group to accumulate a war chest. The entry deterrence effect thus operates solely through the role of war chests in signaling incumbent quality. [source]


Electrochemical Behavior of Catecholamines and Related Compounds at In Situ Surfactant Modified Carbon Paste Electrodes

ELECTROANALYSIS, Issue 2-3 2007
M.Carmen Blanco-López
Abstract The voltammetric characteristics of catecholamines: epinephrine (E) and norepinephrine (NE) and related compounds: isoproterenol, metanephrine, L -dopa, methyldopa, vanillylmandelic acid (VMA), and homovanillic acid (HVA) at unmodified and in situ surfactant- modified carbon paste electrodes were comparatively evaluated. For the basic and amphoteric compounds the modification of the electrode surface with submicellar concentrations of anionic surfactants (sodium dodecylsulfate, sodium decylsulfate or sodium dodecylsulfonate) produce an important current enhancement in its oxidation and reduction peak current together with the improvement in the reversibility of the processes. These effects were explained in basis on electrostatic and hydrophobic interactions. On the other hand, the oxidation of acidic metabolites, HVA and VMA, was studied at electrodes modified in situ with cationic surfactants. Under certain conditions the surfactant could stabilise some of the electrochemical reaction intermediates, thus explaining the different voltammetric behaviour of HVA and VMA. [source]


Comprehensive proteome analysis by chromatographic protein prefractionation

ELECTROPHORESIS, Issue 7-8 2004
Pierre Lescuyer
Abstract Protein copy number is distributed from 7 to 8 orders of magnitude in cells and probably up to 12 orders of magnitude in plasma. Classical silver-stained two-dimensional electrophoresis (2-DE) can only display up to four orders of magnitude. This is a major drawback since it is assumed that most of the regulatory proteins are low-abundance gene products. It is thus clear that the separation of low copy number proteins in amounts sufficient for postseparation analysis is an important issue in proteome studies to complete the comprehensive description of the proteome of any given cell type. The visualization of a polypeptide on a 2-DE gel will depend on the copy number, on the quantity loaded onto the gel and on the method of detection. As the amount of protein that can be loaded onto a gel is limited, one efficient solution is to fractionate the sample prior to 2-DE analysis. Several approaches exist including subcellular fractionation, affinity purification and chromatographic and electrophoretic protein prefractionation. The chromatographic step adds a new dimension in the protein separation using specific protein properties. It allows proteins to be adsorbed to a surface and eluted differentially under certain conditions. This review article presents studies combining chromatography-based methods to 2-DE analysis and draws general conclusions on this strategy. [source]


Multiparasitism of Choristoneura fumiferana by the ichneumonid Tranosema rostrale and the tachinid Actia interrupta: occurrence in the field and outcome of competition under laboratory conditions

ENTOMOLOGIA EXPERIMENTALIS ET APPLICATA, Issue 2 2002
Michel Cusson
Abstract Tranosema rostrale (Brishke) (Hymenoptera, Ichneumonidae) and Actia interrupta Curran (Hymenoptera: Tachinidae) are the two endoparasitoids most frequently encountered in low-density populations of the spruce budworm, Choristoneura fumiferana (Clemens) (Lepidoptera, Tortricidae), in the Quebec City region. Monitoring of attack rates of implanted C. fumiferana larvae at two different study sites suggested the possible existence of competition between the two parasitoids, with A. interrupta seemingly displacing T. rostrale. Here, we show that multiparasitism involving these two species does occur in the field, but at a frequency too low to explain the seasonal pattern of decline in apparent parasitism by T. rostrale that accompanies the rise of A. interrupta attack rates. We also provide preliminary evidence, from laboratory experiments, that A. interrupta has a competitive advantage over T. rostrale and that the success of parasitism by A. interrupta may be enhanced by prior parasitism by T. rostrale under certain conditions, possibly due to the presence of the latter species' polydnavirus. In addition, we describe a PCR-based method that we developed to help detect the presence of T. rostrale eggs which often escape detection by simple visual examination of the dissected host larvae; DNA sequences specific to the polydnavirus injected by the female wasp at the time of oviposition can be readily amplified from whole host larvae. [source]


Cryogenic condensation: A cost-effective technology for controlling VOC emissions

ENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY, Issue 2 2002
Robert J. Davis
Cryogenic condensation is an extremely cost-effective technology for controlling emissions of Volatile Organic Compounds (VOCs) from chemical processing facilities under certain conditions. This paper describes the technology and provides the case history of an application in the pharmaceutical industry, in which its cost effectiveness was compared with a range of alternative technologies, including thermal oxidation, catalytic oxidation, flaring, carbon adsorption, and scrubbing. Because the facility already used significant quantities of liquid and gaseous nitrogen for inerting, blanketing, and purging, a very convenient cold source for cryogenic condensation was already present. On a lifetime cost basis, cryogenic condensation was significantly less costly than all other technologies evaluated. [source]


Direct toxicity assessment of wastewater: Baroxymeter, a portable rapid toxicity device and the industry perspective

ENVIRONMENTAL TOXICOLOGY, Issue 3 2002
Achilles Tzoris
Abstract Direct toxicity assessment of wastewater is becoming necessary, and new legislation may render it compulsory for the water industry. At present such assessment is performed at a laboratory away from a site, at considerable cost, and results often come too late, after a toxic event has occurred and the toxin has been released into the environment. Some of the rapid toxicity tests available today require certain conditions to function properly, or their results do not always correlate with other methods. The objective of this study was to assess a portable device, the Baroxymeter, for its suitability as an instrument to test wastewater toxicity. The way the device works is based on monitoring respiration of a bacterial culture by pressure measurements and using respiration inhibition as a toxicity alert. It has been shown that it is possible to detect toxic substances such as 3,5-dichlorophenol and bronopol within 5 min from a 1-mL sample. The benefits and future applications of the Baroxymeter as a high-throughput, cost-effective alternative for toxicity screening are discussed in this article. © 2002 Wiley Periodicals, Inc. Environ Toxicol 17: 284,290, 2002; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/tox.10059 [source]


Ontogenic delays in effects of nitrite exposure on tiger salamanders (Ambystoma tigrinum tigrinum) and wood frogs (Rana sylvatica)

ENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 6 2005
Kerry L. Griffis-Kyle
Abstract Under certain conditions, nitrite can be present in freshwater systems in quantities that are toxic to the fauna. I exposed wood frog (Rana sylvatica) and eastern tiger salamander (Ambystoma tigrinum tigrinum) embryos and young tadpoles and larvae to elevated concentrations of nitrite in chronic toxicity tests: 0, 0.3, 0.6, 1.2, 2.1, 4.6, and 6.1 mg/L NO2 -N, exposing individuals as both embryos and larvae. Nitrite caused significant declines in wood frog hatching success (3.4 mg/L NO2 -N, wood frog), and lower concentrations caused significant mortality during the early larval stages (4.6 mg/L NO2 -N, salamander; 0.5 mg/L NO2 -N, wood frog). Later tests exposing individuals to nitrite only after hatching showed that both wood frog and tiger salamander vulnerability to nitrite declined shortly after hatching. Hence, examining a single life-history stage, especially later in development, may miss critical toxic effects on organisms, causing the researcher potentially to underestimate seriously the ecological consequences of nitrite exposure. [source]


Male Mate Choice in the Guppy (Poecilia reticulata): Do Males Prefer Larger Females as Mates?

ETHOLOGY, Issue 2 2004
Emily J. E. Herdman
Although females are the choosier sex in most species, male mate choice is expected to occur under certain conditions. Theoretically, males should prefer larger females as mates in species where female fecundity increases with body size. However, any fecundity-related benefits accruing to a male that has mated with a large female may be offset by an associated fitness cost of shared paternity if large females are more likely to be multiply mated than smaller females in nature. We tested the above hypothesis and assumption using the Trinidadian guppy (Poecilia reticulata) by behaviourally testing for male mate choice in the laboratory and by ascertaining (with the use of microsatellite DNA genotyping) patterns of male paternity in wild-caught females. We observed significant positive relationships between female body length and fecundity (brood size) and between body length and level of multiple paternity in the broods of females collected in the Quaré River, Trinidad. In laboratory tests, a preference for the larger of two simultaneously-presented virgin females was clearly expressed only when males were exposed to the full range of natural stimuli from the females, but not when they were limited to visual stimuli alone. However, as suggested by our multiple paternity data, males that choose to mate with large females may incur a larger potential cost of sperm competition and shared paternity compared with males that mate with smaller females on average. Our results thus suggest that male guppies originating from the Quaré River possess mating preferences for relatively large females, but that such preferences are expressed only when males can accurately assess the mating status of encountered females that differ in body size. [source]


Here today , not gone tomorrow: Roles for activating receptors in sustaining NK cells during viral infections

EUROPEAN JOURNAL OF IMMUNOLOGY, Issue 4 2010
Seung-Hwan Lee
Abstract The conclusive evidence supporting a role for NK cells in defense against viruses has been obtained under conditions of NK cell deficiencies prior to infections. NK cell proliferation can be induced during infections, but the advantages of resulting expansion have been unclear because NK cell basal frequency is already high. However, NK cell decreases are also observed during certain conditions of viral infection. Given the range of potent antiviral and immunoregulatory functions of NK cells, such "disappearance" dramatically changes the resources available to the host. New studies demonstrate that proliferation dependent on activating receptors for virus-induced ligands is key for NK cell maintenance, and allows their continued availability for control of adaptive immune responses and immunopathology. This pathway for sustaining NK cells may represent a system used generally to select subsets for rescue during homeostatic purging. In the case of NK cells, though, nonselection limits continued access to the many beneficial functions of NK cells. The observations resolve the long-standing conundrum of reported NK cell increases and decreases during viral infections. Moreover, they demonstrate a previously unappreciated role for activating receptors, i.e. to keep NK cells here today and also tomorrow. [source]


Amino-phosphanes in RhI -Catalyzed Hydroformylation: New Mechanistic Insights Using D2O as Deuterium-Labeling Agent

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 1 2006
Jacques Andrieu
Abstract In previous work, we have demonstrated that the dangling amino group in amino-phosphane ligands increases the rate of Rh-catalyzed styrene hydroformylation as a function of the amino group basicity and of the distance between the P and N functions. We now report additional stereochemical and mechanistic insights resulting from new catalytic experiments performed with Rh-,-P,N catalytic systems in the presence of D2O. In addition to the expected D0 product, the formation of the ,-D1 aldehyde, PhCH(CH2D)CHO was observed in all cases by 1H and 13C NMR spectroscopy, indicating that H/D exchange occurs for the rhodium-hydride complex. Minor amounts of a ,-D2 product, PhCH(CHD2)CHO, were also formed under certain conditions, demonstrating the reversibility of the olefin coordination step. The composition of the aldehyde mixture is slightly affected by the nature of the catalytic precursor or the P,N ligand used. In the specific case of the ,-P,N ligand [,-P,N = (SAr,SC)-Ph2PCH{o -C6H4Cl(Cr(CO)3)}NHPh], in combination with the [RhCl(COD)]2 precatalyst, products PhCD(CH3)CHO (,-D1) and PhCD(CH2D)CHO (,,,-D2) were also produced. This result suggests a reversible deprotonation assisted by an intramolecular H-bonding interaction between the dangling ammonium function and the carbonyl moiety. This isotopic exchange process decreases the asymmetric induction from 14 to 7,% ee when using the enantiopure version of this ligand. Aldehydes bearing a D atom on the formyl group, e.g. PhCH(CH3)CDO, were never observed. The latter observation excludes protonolysis of the rhodium-acyl intermediate as the aldehyde forming step. In addition, it also excludes a bimolecular reaction involving the rhodium-acyl and rhodium-hydride intermediates.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006) [source]


Ultra-Fast Atomic Transport in Severely Deformed Materials,A Pathway to Applications?,

ADVANCED ENGINEERING MATERIALS, Issue 8 2010
Sergiy Divinski
Abstract Severe plastic deformation of pure Cu and Cu-rich alloys was found to create a hierarchical combination of fast and ultra-fast diffusion paths ranging from non-equilibrium grain boundaries to non-equilibrium triple junctions, vacancy clusters, nano- and micro-pores, and finally to general high-angle grain boundaries. Under certain conditions, a percolating network of porosity can be introduced in the ultra-fine grained materials by a proper mechanical and thermal treatment. This network may offer promising opportunities for creating materials with tailor-made properties, including combinations of improved mechanical performance with a possibility of self repair using "vascular structures" for atom transport. Applications in such areas as drug eluting bioimplants and lead or polymer eluting materials for reduction of friction based on impregnation of porosity networks with these agents are also envisaged. [source]


The Illegal Way In and The Moral Way Out

EUROPEAN JOURNAL OF PHILOSOPHY, Issue 2 2007
Gerhard Øverland
At the heart of the current debate about immigration we find a conflict of convictions. Many people seem to believe that a country has a right to decide who to let in and who to keep out, but quite often they appear equally committed to the view that it is morally wrong to expel someone from within the borders of their country if that would seriously jeopardise the person in question. While the first conviction leads to stricter border controls in an attempt to prevent would-be immigrants from entering the country illegally, the latter conviction ensures that aliens with a legitimate claim on protection will not be removed forcibly. It is not strange, therefore, that the task of pinning down a morally sound immigration policy is such an elusive enterprise. In this paper I take it for granted that no electorate would be prepared to accept the kind of policy they ought to, and that we in consequence will continue to let in as few immigrants as is currently the case. Given this constraint I argue against two common assumptions concerning a viable immigration policy. First, granted that certain conditions are satisfied, professional smugglers should not face legal sanctions for bringing asylum seekers to a potential host country. Second, countries that limit immigration should not treat people seeking family reunion preferentially or on a par with other immigrants, but rather act so as to maximise the number of refugees allowed to enter. [source]


Economic performance of ,weak' governments and their interaction with central banks and labour: Deficits, economic growth, unemployment and inflation, 1961,1998

EUROPEAN JOURNAL OF POLITICAL RESEARCH, Issue 6 2005
TAKAYUKI SAKAMOTO
Comparative political economists have conventionally claimed that the strength and stability of governments affect policy making and performance, and that what they call ,weak governments', multiparty, minority and short-lived governments , show poorer economic performance. This article tests this and related hypotheses on deficits, economic growth, unemployment and inflation by examining data from 17 OECD countries. I find that there is generally little evidence to indicate that so-called ,weak governments', when considered independently, produce poorer performance than strong ones. However, the effects of different government types are partly contingent on central bank independence and labour organization. When central banks are independent, coalition governments exhibit better inflation and economic growth performance than one-party governments, but the opposite happens when central banks are dependent. I attempt an explanation for these relationships. I also find that independent central banks, under certain conditions, lead to lower growth and higher inflation. Thus, some of the benefits of central bank independence are context-specific, depending on other political-economic factors. [source]


Effect of ionic strength and clay mineralogy on Na,Ca exchange and the SAR,ESP relationship

EUROPEAN JOURNAL OF SOIL SCIENCE, Issue 5 2006
P. M. Kopittke
Summary The relationship between sodium adsorption ratio (SAR) and exchangeable sodium percentage (ESP) for all soils has traditionally been assumed to be similar to that developed by the United States Salinity Laboratory (USSL) in 1954. However, under certain conditions, this relationship has been shown not to be constant, but to vary with both ionic strength and clay mineralogy. We conducted a detailed experiment to determine the effect of ionic strength on the Na+,Ca2+ exchange of four clay minerals (kaolinite, illite, pyrophyllite, and montmorillonite), with results related to the diffuse double-layer (DDL) model. Clays in which external exchange sites dominated (kaolinite and pyrophyllite) tended to show an overall preference for Na+, with the magnitude of this preference increasing with decreasing ESP. For these external surfaces, increases in ionic strength were found to increase preference for Na+. Although illite (2:1 non-expanding mineral) was expected to be dominated by external surfaces, this clay displayed an overall preference for Ca2+, possibly indicating the opening of quasicrystals and the formation of internal exchange surfaces. For the expanding 2:1 clay, montmorillonite, Na+,Ca2+ exchange varied due to the formation of quasicrystals (and internal exchange surfaces) from individual clay platelets. At small ionic strength and large ESP, the clay platelets dispersed and were dominated by external exchange surfaces (displaying preference for Na+). However, as ionic strength increased and ESP decreased, quasicrystals (and internal exchange surfaces) formed, and preference for Ca2+ increased. Therefore, the relationship between SAR and ESP is not constant and should be determined directly for the soil of interest. [source]


CASE STUDIES AND MATHEMATICAL MODELS OF ECOLOGICAL SPECIATION.

EVOLUTION, Issue 10 2009

We build a spatial individual-based multilocus model of homoploid hybrid speciation tailored for a tentative case of hybrid origin of Heliconius heurippa from H. melpomene and H. cydno in South America. Our model attempts to account for empirical patterns and data on genetic incompatibility, mating preferences and selection by predation (both based on coloration patterns), habitat preference, and local adaptation for all three Heliconius species. Using this model, we study the likelihood of recombinational speciation and identify the effects of various ecological and genetic parameters on the dynamics, patterns, and consequences of hybrid ecological speciation. Overall, our model supports the possibility of hybrid origin of H. heurippa under certain conditions. The most plausible scenario would include hybridization between H. melpomene and H. cydno in an area geographically isolated from the rest of both parental species with subsequent long-lasting geographic isolation of the new hybrid species, followed by changes in the species ranges, the secondary contact, and disappearance of H. melpomene -type ecomorph in the hybrid species. However, much more work (both empirical and theoretical) is necessary to be able to make more definite conclusions on the importance of homoploid hybrid speciation in animals. [source]


THE DIFFUSIVE SPREAD OF ALLELES IN HETEROGENEOUS POPULATIONS

EVOLUTION, Issue 3 2004
Garrick T. Skalski
Abstract The spread of genes and individuals through space in populations is relevant in many biological contexts. I study, via systems of reaction-diffusion equations, the spatial spread of advantageous alleles through structured populations. The results show that the temporally asymptotic rate of spread of an advantageous allele, a kind of invasion speed, can be approximated for a class of linear partial differential equations via a relatively simple formula, c= 2,rD, that is reminiscent of a classic formula attributed to R. A. Fisher. The parameters r and D, represent an asymptotic growth rate and an average diffusion rate, respectively, and can be interpreted in terms of eigenvalues and eigenvectors that depend on the population's demographic structure. The results can be applied, under certain conditions, to a wide class of nonlinear partial differential equations that are relevant to a variety of ecological and evolutionary scenarios in population biology. I illustrate the approach for computing invasion speed with three examples that allow for heterogeneous dispersal rates among different classes of individuals within model populations. [source]


THE EVOLUTION OF FILIAL CANNIBALISM AND FEMALE MATE CHOICE STRATEGIES AS RESOLUTIONS TO SEXUAL CONFLICT IN FISHES

EVOLUTION, Issue 2 2000
Kai Lindström
Abstract., Filial cannibalism (the consumption of one's own viable offspring) is common among fish with paternal care. In this study, I use a computer simulation to study simultaneous evolution of male filial cannibalism and female mate choice. Under certain conditions, selection on parental males favors filial cannibalism. When filial cannibalism increases a male's probability to raise the current brood successfully, filial cannibalism also benefits the female. However, when egg eating is a male investment into future reproduction, a conflict between female and male interests emerges. Here I investigate how female discrimination against filial cannibals affects evolution of filial cannibalism and how different female choice criteria perform against filial cannibalism. The introduction of discriminating females makes the fixation of filial cannibalism less likely. I introduced three different female choice criteria: (1) females who could discern a male's genotype, that is, whether the male was going to eat eggs as an investment in future reproductive events; (2) energy-choosing females that preferred to mate with males who had enough energy reserves to live through the current brood cycle without consuming eggs; and (3) females that preferred to mate with already mated males, that is, males with eggs in their nest. Genotype choice never coexisted with filial cannibals at fixation and filial cannibals were unable to invade a population with genotype-choosing females. Energy choice was successful only when males had high energy reserves and were less dependent on filial cannibalism as an alternative energy source. The egg choosers frequently coexisted with the cannibals at fixation. When the female strategies were entered simultaneously, the most frequent outcome for low mate sampling costs was that both the cannibals and the egg choice was fixed and all other strategies went extinct. These results suggest that sexual conflicts may not always evolve toward a resolution of the conflict, but sometimes the stable state retains the conflict. In the present case, this was because the egg-preference strategy had a higher fitness than the other female strategies. The outcome of this simulation is similar to empirical findings. In fish with paternal care, male filial cannibalism and female preference for mates with eggs commonly co-occur. [source]


Ecophysiology of the filamentous Alphaproteobacterium Meganema perideroedes in activated sludge

FEMS MICROBIOLOGY ECOLOGY, Issue 1 2005
Caroline Kragelund
Abstract A comprehensive study of the ecophysiology of the filamentous Meganema perideroedes affiliated to the Alphaproteobacteria, possessing a "Nostocoida limicola Type II" filamentous morphology was conducted. This morphotype often causes serious bulking problems in activated sludge wastewater treatment plants, and hardly anything is known about its physiology. The study was carried out by applying a suite of in situ methods in an industrial activated sludge treatment plant with excessive growth of this species. The experiments revealed a very versatile organism able to take up a large variety of organic substrates under aerobic conditions. It had a remarkably high storage capacity forming polyhydroxyalkanoates from most substrates tested. When nitrate was present as e-acceptor, the number of substrates to be consumed by M. perideroedes was more restricted compared to aerobic conditions. With nitrite as e-acceptor, only acetate and glucose among the substrates tested could be assimilated and used for storage and possibly growth. This indicated that M. perideroedes might be able to denitrify under certain conditions, which is unusual for filamentous bacteria in activated sludge. No substrate uptake or storage was seen under anaerobic conditions. M. perideroedes was relatively hydrophobic, compared to other filamentous bacteria and microcolonies present in the sludge, indicating the presence of a hydrophobic sheath. Several excreted surface-associated exoenzymes were detected in the sludge, but M. perideroedes never showed any activity, except once after a breakdown in the production facility. This confirmed that M. perideroedes mainly grows on soluble substrates. Based on the studies of the ecophysiology of M. perideroedes, potential control strategies are suggested. [source]