Catalytic Activity (catalytic + activity)

Distribution by Scientific Domains
Distribution within Chemistry

Kinds of Catalytic Activity

  • excellent catalytic activity
  • exhibit high catalytic activity
  • good catalytic activity
  • high catalytic activity
  • highest catalytic activity
  • low catalytic activity
  • their catalytic activity

  • Terms modified by Catalytic Activity

  • catalytic activity decreased

  • Selected Abstracts


    Titanium Containing ,-MnO2 (TM) Hollow Spheres: One-Step Synthesis and Catalytic Activities in Li/Air Batteries and Oxidative Chemical Reactions

    ADVANCED FUNCTIONAL MATERIALS, Issue 19 2010
    Lei Jin
    Abstract Titanium containing ,-MnO2 octahedral molecular sieves having hollow sphere structures are successfully prepared for the first time using a one-step synthesis method. Titanium cations are used as structure-directing agents in the synthesis process. The assembly of the hollow spheres is carried out at the beginning of the process. Various techniques including XRD, N2 adsorption, SEM, EDX, RAMAN, TEM, XPS, and TGA are employed for the materials characterization. Ti is incorporated into the MnO2 framework in isolated sites, and TiO2 phases (anatase and rutile) are not observed. When introduced in medium-sized lithium-air batteries, the materials give very high specific capacity (up to 2.3 A h g,1). These materials are also catalytically tested in the oxidation of toluene with molecular oxygen at atmospheric pressure, showing significant oxidative catalytic activities in this difficult chemical reaction. [source]


    Properties and Catalytic Activities of New Easily-Made Amphiphilic Phosphanes for Aqueous Organometallic Catalysis

    ADVANCED SYNTHESIS & CATALYSIS (PREVIOUSLY: JOURNAL FUER PRAKTISCHE CHEMIE), Issue 7 2010
    Michel Ferreira
    Abstract Mono- and disulfonated amphiphilic versions of triphenylphosphane (PPh3) and cyclohexyl(phenyl)phosphane were easily synthesized from commercial reagents and sulfuric acid. The behaviour of these phosphanes in solution was investigated by surface tension, isothermal titration calorimetry, nuclear magnetic resonance and cryo-transmission electron microscopy. Two different supramolecular assemblies were evidenced according to the degree of sulfonation. The monosulfonated phosphanes formed well organized micelle-like aggregates while the disulfonated phosphanes formed heterogeneous and disorganized vesicle-like assemblies. The efficiency of these amphiphilic phosphanes was evaluated in the aqueous biphasic, palladium-catalyzed cleavage of allyl alkyl carbonates. [source]


    Functional Characterization of CYP2C8.13 and CYP2C8.14: Catalytic Activities toward Paclitaxel

    BASIC AND CLINICAL PHARMACOLOGY & TOXICOLOGY, Issue 1 2010
    Nobumitsu Hanioka
    We recently identified two novel CYP2C8 alleles (CYP2C8*13 and CYP2C8*14; wild-type, CYP2C8*1A) with non-synonymous single nucleotide polymorphisms in a Japanese population. To precisely investigate the effect of amino acid substitutions (CYP2C8*13, Ile223Met; CYP2C8*14, Ala238Pro) on CYP2C8 function, CYP2C8 proteins of the wild-type (CYP2C8.1) and variants (CYP2C8.13 and CYP2C8.14) were heterologously expressed in yeast cells, and their paclitaxel 6,-hydroxylation activities were determined. The Km, Vmax and CLint values for paclitaxel 6,-hydroxylation of CYP2C8.1 were 2.3 ,M, 4.1 pmol/min./pmol CYP and 1.7 ,l/min./pmol CYP, respectively. The Km value of CYP2C8.14 was significantly higher (2.9-fold) than that of CYP2C8.1. The Vmax value of CYP2C8.14 was comparable to that of CYP2C8.1 and the CLint value was reduced to 46% of CYP2C8.1. In contrast, the Km, Vmax and CLint values of CYP2C8.13 were similar to those of CYP2C8.1. These results suggest that Ala238Pro substitution in CYP2C8.14 decreases the affinity toward paclitaxel of the CYP2C8 enzyme, and that the genetic polymorphism of the CYP2C8*14 allele may influence the clinical response to drugs metabolized mainly by CYP2C8. [source]


    ChemInform Abstract: Mesoionic Carbenes: Reactions of 1,3-Diphenyltetrazol-5-ylidene with Electron-Deficient Alkenes and Synthesis and Catalytic Activities of the (Tetrazol-5-ylidene)rhodium(I) Complexes.

    CHEMINFORM, Issue 36 2009
    Shuki Araki
    Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]


    ChemInform Abstract: N-Heterocyclic Carbene,Acetylamide Palladium Complexes and Their Catalytic Activities in Heck,Mizoroki Reactions.

    CHEMINFORM, Issue 3 2009
    Tao Zhang
    Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]


    ChemInform Abstract: Synthesis of New Aminophosphine Complexes and Their Catalytic Activities in C,C Coupling Reactions.

    CHEMINFORM, Issue 52 2008
    Nermin Biricik
    Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]


    Ruthenium-Catalyzed Asymmetric Epoxidation of Olefins Using H2O2, Part II: Catalytic Activities and Mechanism

    CHEMISTRY - A EUROPEAN JOURNAL, Issue 7 2006
    Man Kin Tse Dr.
    Abstract Asymmetric epoxidation of olefins with 30,% H2O2 in the presence of [Ru(pybox)(pydic)] 1 and [Ru(pyboxazine)(pydic)] 2 has been studied in detail (pybox=pyridine-2,6-bisoxazoline, pyboxazine=pyridine-2,6-bisoxazine, pydic=2,6-pyridinedicarboxylate). 35 Ruthenium complexes with sterically and electronically different substituents have been tested in environmentally benign epoxidation reactions. Mono-, 1,1-di-, cis - and trans -1,2-di-, tri-, and tetra-substituted aromatic olefins with versatile functional groups can be epoxidized with this type of catalyst in good to excellent yields (up to 100,%) with moderate to good enantioselectivies (up to 84,% ee). Additive and solvent effects as well as the relative rate of reaction with different catalysts have been established. It is shown that the presence of weak organic acids or an electron-withdrawing group on the catalyst increases the reactivity. New insights on the reaction intermediates and reaction pathway of the ruthenium-catalyzed epoxidation are proposed on the basis of density functional theory calculation and experiments. [source]


    Electrochemically Induced Modulation of the Catalytic Activity of a Reversible Redoxsensitive Riboswitch

    ELECTROANALYSIS, Issue 9 2008
    Denise Strohbach
    Abstract Over the past decade, RNA conformation has been shown to respond to external stimuli. Thus, dependent on the presence of a high affinity ligand, specifically designed ribozymes can be regulated in a classical allosteric way. In this scenario, a binding event in one part of the RNA structure induces conformational changes in a separated part, which constitutes the catalytic centre. As a result activity is switched on (positive regulation) or off (negative regulation). We have developed a hairpin aptazyme responding to flavine mononucleotide (FMN). Ribozyme activity is dependent on binding of FMN and thus is switched on in the presence of FMN in its oxidized form. Under reducing conditions, however, FMN changes its molecular geometry, which is associated with loss of binding and consequently down-regulation of ribozyme activity. While in previous experiments sodium dithionite was used for reduction of FMN, we now present an assay for electrochemically induced activity switching. We have developed an electrochemical microcell that allows for iterative cycles of reduction/oxidation of FMN in an oxygen free atmosphere and thus for reversible switching of ribozyme activity. The reaction proceeds in droplets of 3 to 10,,L at micro- to nanomolar concentrations of the reaction components. [source]


    Discrete, Base-Free, Cationic Alkaline-Earth Complexes , Access and Catalytic Activity in the Polymerization of Lactide

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 22 2010
    Yann Sarazin
    Abstract Well-defined, base free cations of zinc and the alkaline-earth metals (Mg, Ca, Sr, Ba) supported by a multidentate phenolate ligand and stabilized by perfluorinated weakly coordinating counterions are readily available by simple procedures; the solid-state structures of the magnesium and calcium derivatives were elucidated. Upon treatment with an excess of iPrOH, these complexes generate highly efficient binary catalytic systems for the immortal ring-opening polymerization of L -lactide, yielding poly(L -lactide)s with controlled architectures and molecular features. [source]


    Gold(I) Complexes of P,N Ligands and Their Catalytic Activity

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 7 2010
    Chosu Khin
    Abstract Gold(I) complexes were readily prepared by reaction of the respective ligands with (Me2S)AuCl in CH2Cl2. Complexes of formula LAuCl {L = diphenyl(2-pyridyl)phosphane (PPh2Py), (R)-(+)-4-[(2)-(diphenylphosphanyl)-1-naphthyl]- N -[(R)-1-phenylethyl]-1-phthalazinamine (PINAP)} were obtained when a 1:1 molar ratio of ligand to starting gold precursor was used. When a 2:1 ratio of ligand to gold precursor was used with PPh2Py or MandyPhos as ligands, complexes of the type L2AuCl were obtained. All complexes were fully characterized, and single-crystal X-ray structures could be determined for four complexes. Chloride ions were removed by reaction with silver salts, such as AgNTf2, AgOTf and AgBF4, for the use of these complexes as catalysts. After the catalytic reaction with alkynes and alcohols in acetonitrile, a unique trinuclear gold(I) complex derived from [(PPh2Py)Au]BF4 could be characterized by X-ray structural analysis, showing a mode of catalyst deactivation. [source]


    Self-Assembled Two-Dimensional Water-Soluble Dipicolinate Cu/Na Coordination Polymer: Structural Features and Catalytic Activity for the Mild Peroxidative Oxidation of Cycloalkanes in Acid-Free Medium

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 22 2008
    Marina V. Kirillova
    Abstract The new water-soluble 2D Cu/Na coordination polymer [Cu(,-dipic)2{Na2(,-H2O)4}]n·2nH2O (1) has been synthesized by self-assembly in aqueous medium from copper(II) nitrate, dipicolinic acid (H2dipic) and sodium hydroxide in the presence of triethanolamine. It has been characterized by IR spectroscopy, FAB+ -MS, elemental and single-crystal X-ray diffraction analyses, the latter featuring a layered 2D metal,organic structure that is extended to a 3D supramolecular assembly by extensive hydrogen bonding between adjacent layers and involving crystallization water molecules. Compound 1 has been shown to act as a catalyst precursor for the peroxidative oxidation of cyclohexane and cyclopentane to the corresponding cyclic ketones and alcohols by aqueous H2O2 in MeCN solution and in the absence of acid additives.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008) [source]


    A Two-Dimensional, Hydrogen-Bond-Cross-Linked Molybdenum(VI) Network Polymer with Catalytic Activity

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 9 2007
    Yi Luan
    Abstract The new hybrid inorganic,organic polymer [MoO2Cl2(H2O)2]·(H2dipy-pra)Cl2 (1), where dipy-pra = 1,3-bis(4-pyridyl)propane, has been synthesized and crystallographically characterized. MoO2Cl2(H2O)2 and the [H2dipy-pra]2+ cation are cross-linked by Mo,H2O···Cl and H2dipy-pra···Cl hydrogen bonds to form a two-dimensional layer structure. Complex 1 is an efficient catalyst, with H2O2 as the oxygen-source oxidant and NaHCO3 as the cocatalyst, in the epoxidation of olefinic compounds under ambient conditions.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007) [source]


    Structure, Electrochemistry and Hydroformylation Catalytic Activity of the Bis(pyrazolylborato)rhodium(I) Complexes [RhBp(CO)P] [P = P(NC4H4)3, PPh3, PCy3, P(C6H4OMe-4)3]

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 7 2004
    Anna M. Trzeciak
    Abstract Rhodium complexes of formula [RhBp(CO)P] [Bp = bis(pyrazolylborate), P = P(NC4H4)31, PPh32, PCy33, P(C6H4OMe-4)34] have been prepared by exchange of the acetylacetonate (acac,) ligand in [Rh(acac)(CO)P] complexes. The spectroscopic and electrochemical properties as well as X-ray data of [Rh(acac)(CO)P] and [RhBp(CO)P] complexes have been compared with the aim to estimate the relative donor properties of both anionic ligands (acac, and Bp,). The cyclic voltammetric results indicate that the Bp, ligand behaves as a much stronger electron donor than acac, and a value of the Lever EL ligand parameter identical to that of the pyrazolate ligand (,0.24 V vs. NHE for each coordinating arm) is proposed for the bis- and tris(pyrazolyl)borate ligands, whereas P(C6H4OMe-4)3 is also shown to have an identical EL value (0.69 V) to that of P(NC4H4)3. An improved linear relationship between the oxidation potential and the sum of the ligand EL values for square-planar RhI complexes is also obtained and adjusted values for the Lever SM and IM parameters for the RhI/RhII redox couple are given. The trans influence of phosphanes was not observed in crystals of complexes 2 and 3, in contrast to analogous acetylacetonato complexes in which the Rh,O bonds differ by ca. 0.04,0.06 Å. Complexes 1,4 are very attractive precursors for hydroformylation catalysts and yields of aldehydes of 80,87% have been obtained with all complexes without extra phosphane as co-catalyst. During the hydroformylation reaction, however, small amounts of a catalytically inactive [RhBp(CO)2] complex were formed. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004) [source]


    Adenylate Deaminase (5,-Adenylic Acid Deaminase, AMPDA)-Catalyzed Deamination of 5,-Deoxy-5,-Substituted and 5,-Protected Adenosines: A Comparison with the Catalytic Activity of Adenosine Deaminase (ADA)

    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Issue 24 2003
    Pierangela Ciuffreda
    Abstract The enzyme adenylate deaminase (AMPDA) is able to catalyze the hydrolytic deamination of 5,-substituted and 5,-protected 5,-deoxyadenosines, whereas limited or no activity is shown by adenosine deaminase (ADA) towards the same substrates. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003) [source]


    Synthesis and Enzymic Hydrolysis of Oligoribonucleotides Incorporating 3-Deazaguanosine: The Importance of the Nitrogen-3 Atom of Single Conserved Guanosine Residues on the Catalytic Activity of the Hammerhead Ribozyme

    HELVETICA CHIMICA ACTA, Issue 8 2003
    Frank Seela
    Four base-modified hammerhead ribozyme/substrate complexes were constructed in which single guanosine (1) residues were replaced by 3-deazaguanosine (2) in the positions G5, G8, GL2.1, and G12. The base-modified ribozyme complexes were prepared by solid-phase synthesis of oligoribonucleotides employing the novel phosphoramidite 3 derived from 2. Phosphoramidite 3 carried a phenoxyacetyl group at the amino function and a diphenylcarbamoyl residue at the oxo group of the nucleobase. The 2,-hydroxy group was blocked with a triisopropylsilyl residue. Kinetic analysis of the phosphodiester hydrolysis showed a moderate decrease of the ribozyme catalytic activity when the residues G5 or G8 were replaced by 3-deazaguanosine and a 200-fold decrease when G12 was substituted. A 6-fold catalytic increase occurred when 3-deazaguanosine was replacing GL2.1 in the loop region. The data indicate that the N(3) atom of compound 2, in particular at position G12 is critical for the ribozyme activity. [source]


    Cover Picture: Functionalized Gold Nanoparticles Mimic Catalytic Activity of a Polysiloxane-Synthesizing Enzyme (Adv. Mater.

    ADVANCED MATERIALS, Issue 10 2005
    10/2005)
    Abstract A system that acts as a biomimetic of the silica-synthesizing enzyme found in a marine sponge is reported by Morse and co-workers on p.,1234. Gold nanoparticles (GNPs) are functionalized with the same organic moieties that are found in the enzyme's catalytic site. Interaction between the nucleophilic (OH-terminated) and hydrogen-bonding (imidazole-terminated) GNPs, as shown on the cover, is required for the hydrolysis of a silicon alkoxide precursor and subsequent polycondensation to form silica at a low temperature and near-neutral pH. Replacement of either of the required functional groups by a non-reactive methyl group abolishes catalysis in this synthetic system, as it does in the biological enzyme. Cover art provided by Peter Allen. [source]


    Functionalized Gold Nanoparticles Mimic Catalytic Activity of a Polysiloxane-Synthesizing Enzyme,

    ADVANCED MATERIALS, Issue 10 2005
    D. Kisailus
    A synthetic analogue of a naturally occurring enzyme has been produced by grafting appropriate nucleophilic and hydrogen-bonding functionalities to gold nanoparticles via self-assembled monolayers (see Figure and cover). The synthetic analogue mimics silicatein proteins, which act as both catalysts and templates for formation of silica needles in a marine sponge, converting silicon alkoxide precursors to silica at low temperatures and near-neutral pH. [source]


    Immobilization of Porphyrinatocopper Nanoparticles onto Activated Multi-Walled Carbon Nanotubes and a Study of its Catalytic Activity as an Efficient Heterogeneous Catalyst for a Click Approach to the Three-Component Synthesis of 1,2,3-Triazoles in Water

    ADVANCED SYNTHESIS & CATALYSIS (PREVIOUSLY: JOURNAL FUER PRAKTISCHE CHEMIE), Issue 14-15 2009
    Hashem Sharghi
    Abstract An efficient, regioselective, one-pot and two-step synthesis of ,-hydroxy 1,4-disubstituted 1,2,3-triazoles from a wide range of non-activated terminal alkynes and epoxides and sodium azide by way of a three-component click reaction using a catalytic amount of [meso -tetrakis(o -chlorophenyl)porphyrinato]copper(II) (5,mol%) in excellent isolated yields is described. The reactions were performed in water as a green solvent at ambient temperature without any additives. By performing two reaction steps in one pot and purifying only at the final step, this procedure excludes any interim purification of in situ generated organic azide intermediates, which significantly improves the overall yield and reduces the reaction time. To benefit from the recovery and reuse of the catalyst, a new heterogeneous catalyst was prepared by simple and successful impregnation of the catalyst onto activated multi-walled carbon nanotubes (AMWCNT). The heterogeneous catalyst was characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), atomic forced microscopy (AFM), and thermogravimetric (TG) analysis to estimate the amount of nitrogen adsorption, and Raman and FT-IR spectroscopy. Leaching experiments after ten successive cycles showed that the catalyst is most strongly anchored to the AMWCNT support. Mechanistically, porphyrinatocopper catalyzes each step of the reaction in different ways as a bifunctional catalyst including epoxide ring opening by azide delivery to epoxide, forming in situ generated 2-azido alcohols followed by activation of the CC triple bond of the starting terminal alkynes by forming a porphyrinatocopper-acetylide intermediate and thereby promoting the [3+2]-cycloaddition reaction as the key step to form the triazole framework. [source]


    Size-Dependent Catalytic Activity of Supported Palladium Nanoparticles for Aerobic Oxidation of Alcohols

    ADVANCED SYNTHESIS & CATALYSIS (PREVIOUSLY: JOURNAL FUER PRAKTISCHE CHEMIE), Issue 3 2008
    Jing Chen
    Abstract Silica-alumina (SiO2 -Al2O3)-supported palladium catalysts prepared by adsorption of the tetrachloropalladate anion (PdCl42,) followed by calcination and reduction with either hexanol or hydrogen were studied for the aerobic oxidation of alcohols. The mean size of the Pd particles over the SiO2 -Al2O3 support was found to depend on the Si/Al ratio, and a decrease in the Si/Al ratio resulted in a decrease in the mean size of the Pd nanoparticles. By changing the Si/Al ratio, we obtained supported Pd nanoparticles with mean sizes ranging from 2.2 to 10,nm. The interaction between the Pd precursor and the support was proposed to play a key role in tuning the mean size of the Pd nanoparticles. The Pd/SiO2 -Al2O3 catalyst with an appropriate mean size of Pd particles could catalyze the aerobic oxidation of various alcohols to the corresponding carbonyl compounds, and this catalyst was particularly efficient for the solvent-free conversion of benzyl alcohol. The intrinsic turnover frequency per surface Pd atom depended significantly on the mean size of Pd particles and showed a maximum at a medium mean size (3.6,4.3,nm), revealing that the aerobic oxidation of benzyl alcohol catalyzed by the supported Pd nanoparticles was structure-sensitive. [source]


    Improved Catalytic Activity of a Purified Multienzyme from a Modular Polyketide Synthase after Coexpression with Streptomyces Chaperonins in Escherichia coli.

    CHEMBIOCHEM, Issue 18 2008
    Lorena Betancor
    Folding helpers: Coexpression of Streptomyces coelicolor chaperonins GroEL1, GroEL2 and GroES with an actinomycete-derived polyketide synthase multienzyme in Escherichia coli has beneficial effects on yield, folding and specific activity of the purified enzyme. The results strongly suggest the utility of chaperones derived from polyketide-producing actinomycete bacteria in optimising the recombinant production of PKS proteins in E. coli for detailed studies of structure and function. [source]


    Nanostructured Praseodymium Oxide: Correlation Between Phase Transitions and Catalytic Activity

    CHEMCATCHEM, Issue 6 2010
    Patrick Sonström
    Abstract Praseodymia gives rise to a rich phase diagram with a large number of phases between the limiting stoichiometries Pr2O3 and PrO2 that differ only slightly in oxygen content (PrnO2n,2). This chemical and crystallographic variability allows the system to release or incorporate lattice oxygen easily at sufficiently high temperatures and thus renders the material interesting as a catalyst for redox reactions according to a Mars,van,Krevelen mechanism. Nanostructured praseodymia samples are investigated in this study with respect to their catalytic properties, focusing on methane oxidation and selective NO reduction by CO and CH4. To correlate catalytic activity and crystallographic changes, complementary high-temperature X-ray diffraction measurements have been carried out. The determined temperatures of transitions between different oxide phases agree well with peaks in the temperature-programmed reduction measurements, confirming the direct connection between the availability of lattice oxygen and crystallographic transformations. The catalytic activity for methane oxidation and NO reduction sets in at 450,500,°C, at which temperature the starting material,mainly Pr6O11,transforms into the next oxygen-depleted phase Pr7O12. With respect to NO reduction, the results show that it is possible to employ both methane and carbon monoxide as reducing agents in the absence of oxygen, in agreement with a Mars,van,Krevelen mechanism. Nevertheless, the use of CO instead of CH4 offers considerable advantages, as no deactivation due to carbon residues takes place in this case. Whereas, in an excess of oxygen, NO reduction is inhibited independently of the reducing agent, it is shown that NO reduction can proceed if the O2 concentration remains below a critical concentration. [source]


    Catalytic Activity of Metal Nanoparticles Supported on Nitrogen-Doped Carbon Spheres

    CHEMCATCHEM, Issue 1 2010

    Sphere of influence: Various transition metal (Ru, Pd and V) particles supported on nitrogen-doped carbon nanospheres have been synthesized and their catalytic activity studied for the chemoselective hydrogenation of diketones, the oxidation of styrene, and CC bond formation (Heck and Suzuki) reactions. The catalysts show very high activity, selectivity, and recyclability in these reactions. [source]


    ChemInform Abstract: Synthesis and Microwave-Assisted Catalytic Activity of Novel Bis-Benzimidazole Salts Bearing Furfuryl and Thenyl Moieties in Heck and Suzuki Cross-Coupling Reactions.

    CHEMINFORM, Issue 38 2010
    Uelkue Yilmaz
    Abstract Bis(benzimidazolium) dichlorides (I) and (II) are synthesized and examined as ligands for each aryl halogenide (III) in both the Suzuki and the Heck reaction under optimized conditions. [source]


    ChemInform Abstract: New Indenyl Phosphinooxazoline Complexes of Iron and Their Catalytic Activity in the Mukaiyama Aldol Reaction.

    CHEMINFORM, Issue 35 2010
    Matthew Lenze
    Abstract It is demonstrated that a new iron-indenyl PHOX complex is efficient for the title reaction of the 1-siloxy 1-methoxyethene with aromatic aldehydes. [source]


    ChemInform Abstract: Salen and Half-Salen Palladium(II) Complexes: Synthesis, Characterization and Catalytic Activity Toward Suzuki,Miyaura Reaction.

    CHEMINFORM, Issue 22 2010
    Ping Liu
    Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]


    ChemInform Abstract: New Route to Synthesis of PVP-Stabilized Palladium(0) Nanoclusters and Their Enhanced Catalytic Activity in Heck and Suzuki Cross-Coupling Reactions.

    CHEMINFORM, Issue 15 2010
    Feyyaz Durap
    Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]


    ChemInform Abstract: Catalytic Activity of Iron(III), Aluminum(III), Cobalt(II), and Magnesium(II) Chloride Crystal Hydrates in the Condensation of Aniline with Butyraldehyde.

    CHEMINFORM, Issue 9 2010
    R. G. Bulgakov
    Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]


    ChemInform Abstract: Structures, Preparation and Catalytic Activity of Ruthenium Cyclopentadienyl Complexes Based on Pyridyl-Phosphine Ligand.

    CHEMINFORM, Issue 7 2010
    Prashant Kumar
    Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]


    ChemInform Abstract: Trisguanidinate Lanthanide Complexes: Syntheses, Structures, and Catalytic Activity for Mild Amidation of Aldehydes with Amines.

    CHEMINFORM, Issue 49 2009
    Cunwei Qian
    Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]


    ChemInform Abstract: Synthesis, Characterization, Selective Catalytic Activity, and Reactivity of Rare Earth Metal Amides with Different Metal,Nitrogen Bonds.

    CHEMINFORM, Issue 49 2009
    Shaowu Wang
    Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]