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Absorber
Kinds of Absorber Terms modified by Absorber Selected AbstractsAluminum "Egg-Box" Panel as an Energy Absorber for Pedestrian ProtectionADVANCED ENGINEERING MATERIALS, Issue 7 2010Sravanthi Nowpada Abstract This paper evaluates the quasi-static performance of lightweight aluminum "egg-box" panels which have an improved architecture specifically designed to increase the energy absorption capability. In its entirety, the egg-box panel structure investigated herein is made up of arrays of positive and negative frusta. To understand the collapse mechanism and the factors influencing the energy absorption thereof, compressive tests were conducted under similar test conditions on two single frusta, one constrained in situ and the other separated from the egg-box panel exposing the free,free edges. Their load-displacement histories show characteristics that are similar, with a rise in load to a point where they plateau at a steady state load for the entire collapse time. But the energy absorbed by the in situ constrained frustum is 80% greater than that separated from the egg-box panel with free,free edges. [source] Atomic-Layer Graphene as a Saturable Absorber for Ultrafast Pulsed LasersADVANCED FUNCTIONAL MATERIALS, Issue 19 2009Qiaoliang Bao Abstract The optical conductance of monolayer graphene is defined solely by the fine structure constant, ,,=, (where e is the electron charge, is Dirac's constant and c is the speed of light). The absorbance has been predicted to be independent of frequency. In principle, the interband optical absorption in zero-gap graphene could be saturated readily under strong excitation due to Pauli blocking. Here, use of atomic layer graphene as saturable absorber in a mode-locked fiber laser for the generation of ultrashort soliton pulses (756 fs) at the telecommunication band is demonstrated. The modulation depth can be tuned in a wide range from 66.5% to 6.2% by varying the graphene thickness. These results suggest that ultrathin graphene films are potentially useful as optical elements in fiber lasers. Graphene as a laser mode locker can have many merits such as lower saturation intensity, ultrafast recovery time, tunable modulation depth, and wideband tunability. [source] Photovoltaic Devices: High-Efficiency Solar Cell with Earth-Abundant Liquid-Processed Absorber (Adv. Mater.ADVANCED MATERIALS, Issue 20 201020/2010) The image shows a thin-film solar cell, deposited from a hybrid solution-nanoparticle ink, with a background scanning electron microscopy (SEM) image of the zinc-compound particle component of the ink. A cross-sectional SEM image of the device shows the large-grained kesterite absorber layer composed of readily available elements: Cu-Zn-Sn-S-Se. The solution-processed devices offer record power conversion efficiency for kesterite absorber layers, as presented by D. B. Mitzi et al. on page E156. [source] High-Efficiency Solar Cell with Earth-Abundant Liquid-Processed AbsorberADVANCED MATERIALS, Issue 20 2010Teodor K. Todorov A composite liquid deposition approach merging the concepts of solution and particle-based coating for multinary chalcogenide materials is demonstrated. Photovoltaic absorbers based on earth-abundant Cu,Zn,Sn,S,Se kesterites show exceptional phase purity and are incorporated into solar cells with power conversion efficiency above 9.6%, bringing the state of the art of kesterite photovoltaic materials to a level suitable for possible commercialization. [source] Absorber intercooling in CO2 absorption by piperazine-promoted potassium carbonateAICHE JOURNAL, Issue 4 2010Jorge M. Plaza Abstract Intercooling was evaluated as a process option in CO2 absorption by piperazine (PZ) promoted potassium carbonate. The system performance with 4.5 m K+/4.5 m PZ was simulated by a model in Aspen Plus® RateSepÔ. The absorber was evaluated for use with a double matrix stripper by optimizing the position of the semilean feed and intercooling stages to maximize CO2 removal. Additionally, a simple absorber system was modeled to observe the effect of intercooling on systems with variable CO2 lean loading. Intercooling increases CO2 removal by as much as 10% with the double matrix configuration. With a simple absorber, the effectiveness of intercooling depends on solvent rate. Near a critical liquid/gas ratio (L/G) there is a large improvement with intercooling. This is related to the position of the temperature bulge. An approximation is proposed to estimate the critical L/G where intercooling may maximize removal. © 2009 American Institute of Chemical Engineers AIChE J, 2010 [source] Synthesis and Characterization of Gadolinium Phosphate Neutron Absorber.CHEMINFORM, Issue 52 2003Paul A. Lessing Abstract For Abstract see ChemInform Abstract in Full Text. [source] Disappearance of gender-related difference in the toxicity of benzotriazole ultraviolet absorber in juvenile ratsCONGENITAL ANOMALIES, Issue 4 2009Mutsuko Hirata-Koizumi ABSTRACT 2-(2,-hydroxy-3,,5,-di- tert -butylphenyl)benzotriazole (HDBB) is an ultraviolet absorber used in plastic resin products, such as building materials and automobile components. In oral repeated dose toxicity studies using 5- or 6-week-old rats, this chemical induced hepatic histopathological changes, such as hypertrophy accompanied with eosinophilic granular changes and focal necrosis of hepatocytes, and male rats showed nearly 25 times higher susceptibility to the toxic effects than females. Castration at approximately 4 weeks of age markedly reduced the sex-related variation in HDBB toxicity, but some difference, less than five times, remained between male and female castrated rats. Following oral HDBB administration to male and female juvenile rats from postnatal days 4,21, such gender-related difference in toxic susceptibility was not detected; therefore, it is speculated that the determinants of susceptibility to HDBB toxicity are differentiated between sexes after weaning. In young rats given HDBB, there was no gender-related difference in plasma HDBB concentration, and no metabolites were detected in the plasma of either sex. HDBB induced lauric acid 12-hydroxylase activity in the liver and this change was more pronounced in males than in females. These findings indicate that HDBB could show hepatic peroxisome proliferation activity, and the difference in the susceptibility of male and female rats to this effect might lead to marked gender-related differences in toxicity. [source] Layer-by-Layer Interference Lithography of Three-dimensional Microstructures in SU-8,ADVANCED ENGINEERING MATERIALS, Issue 5 2009Andrés F. Lasagni We report on rapid fabrication of two-, two and a half-, and 3D planar periodic structures using layer-by-layer deposition and interference patterning of SU-8 photoresist. Complex structures with non-periodic vertical symmetry were fabricated controlling the cure depth by addition of a UV absorber. The fabrication method reported here can be applied for the high-volume manufacturing of solid structures for microelectromechanical systems and microfluidic devices. [source] Controlling Photoactivity in Ultrathin Hematite Films for Solar Water-SplittingADVANCED FUNCTIONAL MATERIALS, Issue 7 2010Florian Le Formal Abstract A promising route to increase the performance of hematite (,-Fe2O3) photoelectrodes for solar hydrogen production through water-splitting is to use an extremely thin layer of this visible light absorber on a nanostructured scaffold. However, the typically poor performance of ultrathin (ca. 20,nm) films of hematite has been the limiting factor in implementing this approach. Here, the surprising effect of a substrate pretreatment using tetraethoxysilicate (TEOS) is reported; it results in drastic improvements in the photoperformance of 12.5,nm thick films of hematite. These films exhibit a water oxidation photocurrent onset potential at 1.1,V versus the reversible hydrogen electrode (vs. RHE) and a plateau current of 0.63,mA cm,2 at 1.5,V vs. RHE under standard illumination conditions, representing the highest reported performance for ultrathin hematite films. In contrast, almost no photoactivity is observed for the photoanode with the same amount of hematite on an untreated substrate. A detailed study of the effects of the TEOS treatment shows that a monolayer of SiOx is formed, which acts to change the hematite nucleation and growth mechanism, increases its crystallinity, reduces the concentration of carrier trapping states of the ultrathin films, and suggests its further application to quantum-dot and extremely-thin-absorber (ETA)-type solar cells. [source] Atomic-Layer Graphene as a Saturable Absorber for Ultrafast Pulsed LasersADVANCED FUNCTIONAL MATERIALS, Issue 19 2009Qiaoliang Bao Abstract The optical conductance of monolayer graphene is defined solely by the fine structure constant, ,,=, (where e is the electron charge, is Dirac's constant and c is the speed of light). The absorbance has been predicted to be independent of frequency. In principle, the interband optical absorption in zero-gap graphene could be saturated readily under strong excitation due to Pauli blocking. Here, use of atomic layer graphene as saturable absorber in a mode-locked fiber laser for the generation of ultrashort soliton pulses (756 fs) at the telecommunication band is demonstrated. The modulation depth can be tuned in a wide range from 66.5% to 6.2% by varying the graphene thickness. These results suggest that ultrathin graphene films are potentially useful as optical elements in fiber lasers. Graphene as a laser mode locker can have many merits such as lower saturation intensity, ultrafast recovery time, tunable modulation depth, and wideband tunability. [source] Moonlighting in a High Growth Economy: Evidence from U.S. State-Level DataGROWTH AND CHANGE, Issue 4 2002Mark Partridge Despite the prevalence of multiple jobholding, there is relatively little research into its causes. Existing research has tested the predictions of standard labor models with micro data. Yet, there has been virtually no research into the relationship between moonlighting and structural differences in regional labor markets such as wages and employment growth. In this manner, this study examines the large differences in multiple jobholding rates across U.S. states. The findings indicate that multiple jobholding acts as a short-term shock absorber to cyclical changes. However, in the long-term, these effects dissipate, indicating that moonlighting plays a similar role as do changes in unemployment and labor-force participation to regional labor market shocks. Conversely, multiple jobholding rates are inversely related to average weekly earnings. Thus, job growth accompanied by real wage (and productivity) growth may result in a decline in multiple jobholding, further exacerbating potential labor shortages. Other key factors found to influence multiple jobholding include occupational structure and education. [source] Study on a reversible thermal panel for spacecraft (detailed design based on parametric studies and experimental verification)HEAT TRANSFER - ASIAN RESEARCH (FORMERLY HEAT TRANSFER-JAPANESE RESEARCH), Issue 7 2006Hosei Nagano Abstract This paper describes a new passive thermal control device,a Reversible Thermal Panel (RTP), which changes its function reversibly from a radiator to solar absorber by deploying/stowing the radiator/absorber reversible fin. Parametric studies were conducted and the RTP configuration which satisfies the thermal requirements was determined. The RTP engineering model was fabricated using highly oriented graphite sheets, honeycomb base plate, and shape memory alloy. The heat rejection performances and autonomous thermal controllability were evaluated by thermal vacuum tests. The test results show the excellent performances of heat rejection, absorption, and autonomous thermal control for the RTP. © 2006 Wiley Periodicals, Inc. Heat Trans Asian Res, 35(7): 464,481, 2006; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/htj.20131 [source] Experimental and analytical study on falling film absorption in smooth and chute low-ribbed tubesHEAT TRANSFER - ASIAN RESEARCH (FORMERLY HEAT TRANSFER-JAPANESE RESEARCH), Issue 1 2005Wang Meixia Abstract A mathematical model was applied to falling film absorption outside the smooth and chute low-ribbed tubes to analyze the heat and mass transfer in the absorber. The liquid film outside tubes was assumed to consist of two layers, i.e., internal and external layers. A numerical calculation method was used to solve for the outer layer model of smooth tubes and the chute low-ribbed tubes. An analytical method was employed to solve for the velocity, temperature, and concentration in the internal layer of the tubes mentioned above. A second-order coupling method was adopted to couple the results of the two layers. It was shown that the agreement between the calculation results and the experimental data is high, with all errors assessed at less than 10%. The causes leading to the errors were analyzed. It was concluded that the chute low-ribbed tubes could serve as intensification tubes suitable for use in the absorber of lithium bromide absorption. © 2004 Wiley Periodicals, Inc. Heat Trans Asian Res, 34(1): 29,39, 2005; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/htj.20039 [source] Organic Infrared Upconversion DeviceADVANCED MATERIALS, Issue 20 2010Do Young Kim Novel infrared-to-visible light upconversion devices are demonstrated by fabricating an organic light-emitting diode with an infrared-sensitizing layer. With a SnPc:C60 mixed layer as an infrared absorber and fac-tris(2-phenylpyridinato) iridium (III) (Irppy3) as an emitter, an infrared-to-green up-conversion device is demonstrated under 830-nm irradiation (see figure, ITO=indium tin oxide). The maximum photon-to-photon conversion efficiency is 2.7% at 15V. [source] Optimization of double-layer absorbers on constrained sound absorption system by using genetic algorithmINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN ENGINEERING, Issue 3 2005Ying-Chun Chang Abstract As investigated by the Occupational Safety and Health Act (OSHA) in 1970, noise is highly responsible for the psychological and physiological ills to workers. Therefore, the noise control for an enclosed system with high echo effect becomes essential. Besides, the thickness of adopted sound absorber is occasionally constrained for maintenance, the interest in minimizing the noise under space constraint is then arising. In this paper, the shape optimization of double-layer absorber together with genetic algorithm (GA) is presented. Before optimization, one example is tested and compared with the experimental data for accuracy check of mathematical model. Thereafter, a simple optimal program in dealing with pure tone noise of 350 Hz has been pre-run to verify the correctness of genetic algorithm before the design in full band noise being performed. Results show that both the accuracy of mathematical model and the correctness of GA method are acceptable. Consequently, this study may provide a novel scheme with GA in solving the shape optimization of sound absorber on the constrained sound absorption system. Copyright © 2004 John Wiley & Sons, Ltd. [source] Eco-friendly methodologies for the synthesis of some aromatic esters, well-known cosmetic ingredientsINTERNATIONAL JOURNAL OF COSMETIC SCIENCE, Issue 1 2005C. Villa Synopsis Solid,liquid solvent-free phase transfer catalysis (PTC) and acidic catalysis in dry media were applied, with noticeable improvement and simplification over classical procedures in a Green Chemistry context, to the synthesis of some aromatic esters useful as cosmetic ingredients: 3-methylbutyl 4-methoxycinnamate, 2-ethylhexyl 4-methoxycinnamate, 2-ethylhexyl 4-(dimethylamino)benzoate and 2-ethylhexyl salicylate, well-known ultraviolet B sunscreen filters; 4-isopropylbenzyl salicylate, UV absorber and cutaneous antilipoperoxidant; propyl 4-hydroxybenzoate and butyl 4-hydroxybenzoate (parabens), antimicrobial agents. The reactions were performed under microwave (MW) activation and conventional heating. The best results for the synthesis of cinnamic, salicylic and 4-(dimethylamino)benzoic esters were achieved by in situ preformed carboxylates alkylation with alkyl bromides using PTC. The 4-hydroxybenzoates were obtained in good yields by classical esterification of the acid with alcohols using a simple heterogeneous mixture of reagents with catalytic amounts of p -toluenesulfonic acid (PTSA). The comparisons of yields and thermal profiles under either MW or conventional heating were studied and reported. Résumé La catalyse par transfert de phase (CTP) solide-liquide sans solvant et l'estérification acido-catalysée en ,,milieu sec'' ont été appliquées, dans le cadre de la ,,chimie verte'', avec des nettes améliorations et simplifications par rapport aux méthodes classiques, à la synthèse de certains esters aromatiques, ingrédients cosmétiques: 3-methylbutyl 4-méthoxycinnamate, 2-éthylhéxyl 4-méthoxycinnamate, 2-éthylhéxyl 4-(diméthylamino) benzoate et 2-éthylhéxyl salicylate, filtres solaires UVB bien connus; 4-isopropylbenzyl salicylate, filtre UV et antilipopéroxydant cutané; propyl 4-hydroxybenzoate et butyl 4-hydroxybenzoate (parabens), agents antimicrobien. Les réactions ont été procédées sous irradiation micro-onde et par chauffage classique. Pour la synthèse des esters dérivés de l'acide cinnamique, salicylique et 4-(diméthylamino)benzoïque les meilleurs résultats ont été obtenus grâce à la CTP par alkylation des carboxylates (préformés in situ) avec des bromures d'alkyle. Les esters de l'acide 4-hydroxybenzoique ont été obtenus avec de bons rendements par simple mélange hétérogène des réactifs et d'acide p-toluènesulfonique (PTSA) comme catalyseur. Les rendements et les profils de montée en température sous micro-ondes et par chauffage classique ont été comparés. [source] Theoretical analysis of LiBr/H2O absorption refrigeration systemsINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 15 2009Akhilesh Arora Abstract A computational model is developed for the parametric investigation of single-effect and series flow double-effect LiBr/H2O absorption refrigeration systems. The effects of generator, absorber, condenser, evaporator and dead state temperatures are examined on the performance of these systems. The parameters computed are coefficient of performance (COP), exergy destruction rates, thermal exergy loss rates, irreversibility and exergetic efficiency. The results indicate that COP and exergetic efficiency of both the systems increase with increase in the generator temperature. There exist different optimum values of generator temperature for maximum COP and maximum exergetic efficiency. The optimum generator temperature is lower corresponding to maximum exergetic efficiency as compared to optimum generator temperature corresponding to maximum COP. The effect of increase in absorber, condenser and evaporator temperatures is to decrease the exergetic efficiency of both the systems. The irreversibility is highest in absorber in both systems. Copyright © 2009 John Wiley & Sons, Ltd. [source] Experimental study on sulfur trioxide decomposition in a volumetric solar receiver,reactorINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 9 2009Adam Noglik Abstract Process conditions for the direct solar decomposition of sulfur trioxide have been investigated and optimized by using a receiver,reactor in a solar furnace. This decomposition reaction is a key step to couple concentrated solar radiation or solar high-temperature heat into promising sulfur-based thermochemical cycles for solar production of hydrogen from water. After proof-of-principle a modified design of the reactor was applied. A separated chamber for the evaporation of the sulfuric acid, which is the precursor of sulfur trioxide in the mentioned thermochemical cycles, a higher mass flow of reactants, an independent control and optimization of the decomposition reactor were possible. Higher mass flows of the reactants improve the reactor efficiency because energy losses are almost independent of the mass flow due to the predominant contribution of re-radiation losses. The influence of absorber temperature, mass flow, reactant initial concentration, acid concentration, and residence time on sulfur trioxide conversion and reactor efficiency has been investigated systematically. The experimental investigation was accompanied by energy balancing of the reactor for typical operational points. The absorber temperature turned out to be the most important parameter with respect to both conversion and efficiency. When the reactor was applied for solar sulfur trioxide decomposition only, reactor efficiencies of up to 40% were achieved at average absorber temperature well below 1000°C. High conversions almost up to the maximum achievable conversion determined by thermodynamic equilibrium were achieved. As the re-radiation of the absorber is the main contribution to energy losses of the reactor, a cavity design is predicted to be the preferable way to further raise the efficiency. Copyright © 2009 John Wiley & Sons, Ltd. [source] Energy and exergy analysis of a double absorption heat transformer operating with water/lithium bromideINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 7 2009H. Martínez Abstract In the present study, the first and second law of thermodynamics have been used to analyze in detail the performance of a double absorption (lift) heat transformer operating with the water,lithium bromide mixture. A mathematical model was developed to estimate the coefficient of performance (COP), the exergy coefficient of performance (ECOP), the total exergy destruction in the system (,TD) and the exergy destruction (,D) in each one of the main components, as a function of the system temperatures, the efficiency of the economizer (EFEC), the gross temperature lift and flow ratio (FR). The results showed that the generator is the component with the highest irreversibilities or exergy destruction contributing to about 40% of the total exergy destruction in the whole system, reason why this component should be carefully designed and optimized. The results also showed that the COP and ECOP increase with increase in the generator, the evaporator and the absorber,evaporator temperatures and decrease with the absorber and condenser temperatures. Finally, it was observed that the COP and ECOP are very dependent of the FR and the economizer efficiency (EFEC) values. Also the optimum operating region of the analyzed system is shown in the present study. Copyright © 2009 John Wiley & Sons, Ltd. [source] Crimp morphology in relaxed and stretched rat Achilles tendonJOURNAL OF ANATOMY, Issue 1 2007Marco Franchi Abstract Fibrous extracellular matrix of tendon is considered to be an inextensible anatomical structure consisting of type I collagen fibrils arranged in parallel bundles. Under polarized light microscopy the collagen fibre bundles appear crimped with alternating dark and light transverse bands. This study describes the ultrastructure of the collagen fibrils in crimps of both relaxed and in vivo stretched rat Achilles tendon. Under polarized light microscopy crimps of relaxed Achilles tendons appear as isosceles or scalene triangles of different size. Tendon crimps observed via SEM and TEM show the single collagen fibrils that suddenly change their direction containing knots. The fibrils appear partially squeezed in the knots, bent on the same plane like bayonets, or twisted and bent. Moreover some of them lose their D-period, revealing their microfibrillar component. These particular aspects of collagen fibrils inside each tendon crimp have been termed ,fibrillar crimps' and may fulfil the same functional role. When tendon is physiologically stretched in vivo the tendon crimps decrease in number (46.7%) (P < 0.01) and appear more flattened with an increase in the crimp top angle (165° in stretched tendons vs. 148° in relaxed tendons, P < 0.005). Under SEM and TEM, the ,fibrillar crimps' are still present, never losing their structural identity in straightened collagen fibril bundles of stretched tendons even where tendon crimps are not detectable. These data suggest that the ,fibrillar crimp' may be the true structural component of the tendon crimp acting as a shock absorber during physiological stretching of Achilles tendon. [source] In-line analysis of the influence of monomeric and oligomeric hindered amine on the hydrolysis of polycarbonate in a PC/ABS blendJOURNAL OF APPLIED POLYMER SCIENCE, Issue 6 2010Vipin V. Rajan Abstract The polycarbonate/polyacrylonitrile butadiene styrene (PC/ABS) blends lose mechanical properties when exposed to outdoor conditions. This is due to the ultraviolet (UV) induced photo-oxidation of the PC phase and the polybutadiene portion of the ABS. It is known that ABS can be stabilised against terrestrial light by the use of hindered amine in combination with a UV absorber. However, such hindered amine cannot be used when PC is present in a multi component polymer blend. The hydrolysis of PC is accelerated when a small amount of hindered amine light stabilisers (HALS) is incorporated in the resin and is exposed to elevated temperature. In this article the effect of monomeric and oligomeric hindered amine on the hydrolysis of PC during the compounding of PC/ABS blend in a twin screw extruder at 240°C is observed by means of in-line UV-vis spectroscopy. Tinuvin 765 was used as monomeric hindered amine and Tinuvin 622 as oligomeric hindered amine. The molecular weight of the compounded sample was determined by gel permeation chromatography (GPC) and the rheological properties were observed using an online viscometer. It was found that the extent of hydrolysis induced by the oligomeric hindered amine is less compared to monomeric amine. It was also observed that polymeric hindered amine imparts better dispersion of the ABS phase into the polymer blend. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 [source] Effect of Oxygen-Absorbing Packaging on the Shelf Life of a Liquid-Based Component of Military Operational RationsJOURNAL OF FOOD SCIENCE, Issue 4 2009Carmen Gomes ABSTRACT:, Oxygen within the sealed package can reduce the quality of liquid-based food products with high oil content such as hot-filled meal-ready-to-eat (MRE) cheese spread, a component of military operational rations. The aim of this study was to test a novel oxygen absorber-containing laminate material and its ability to maintain and/or extend shelf life of a cheese-spread MRE item. An iron-based oxygen absorber (ABSO2RB®) activated by moisture was incorporated into the laminate and used to pack hot-filled cheese spread MREs. The kinetics of oxygen absorption due to humidity and temperature were characterized and peel tests performed to ensure pouch seal integrity. Accelerated shelf-life tests of ABSO2RB and regular MRE pouches without the O2 -absorber were conducted for 3 mo at 51.7 °C (125 °F), and 6 mo at 37.8 °C (100 °F) by measuring oxygen concentration (Mocon O2 -analyzer), microbiological, and physicochemical quality characteristics, including color, texture, moisture, free fatty acid (FFA), pH, water activity, and vitamins and A. Pouches stored at 26.7 °C (80 °F) for 12 mo served as calibrated controls. Consumer tests were conducted in-house and a confirmatory sensory test was conducted at Natick by a trained panel using a 9-point hedonic scale. ABSO2RB-laminates maintain the same seal integrity and strength as those of the control samples. The headspace oxygen concentrations in these pouches reached (P < 0.05) < 0.5% in 11 d of storage at 26.7 °C (80 °F) and remained below this level throughout the storage period (1 y). No microbial growth (aerobic, coliforms, yeast, and molds) was detected (P < 0.05) for both packages. Overall, the ABSO2RB-pouches indicate an improved reduction in oxygen and vitamin C retention compared with MRE controls and maintained product quality (physicochemical and organoleptic). ABSO2RB-laminates met the accelerated shelf-life requirement of 1 mo at 51.7 °C (125 °F), and 6 mo at 37.8 °C (100 °F). This study clearly shows the benefits of using active packaging technology on retaining nutrition and prolonging shelf life of high-fat, liquid content MRE items. [source] Absorber intercooling in CO2 absorption by piperazine-promoted potassium carbonateAICHE JOURNAL, Issue 4 2010Jorge M. Plaza Abstract Intercooling was evaluated as a process option in CO2 absorption by piperazine (PZ) promoted potassium carbonate. The system performance with 4.5 m K+/4.5 m PZ was simulated by a model in Aspen Plus® RateSepÔ. The absorber was evaluated for use with a double matrix stripper by optimizing the position of the semilean feed and intercooling stages to maximize CO2 removal. Additionally, a simple absorber system was modeled to observe the effect of intercooling on systems with variable CO2 lean loading. Intercooling increases CO2 removal by as much as 10% with the double matrix configuration. With a simple absorber, the effectiveness of intercooling depends on solvent rate. Near a critical liquid/gas ratio (L/G) there is a large improvement with intercooling. This is related to the position of the temperature bulge. An approximation is proposed to estimate the critical L/G where intercooling may maximize removal. © 2009 American Institute of Chemical Engineers AIChE J, 2010 [source] Drug release into external absorber: Concentration-dependent diffusivityAICHE JOURNAL, Issue 2 2009Sung-Hwa Lin First page of article [source] Experimental validation of a rigorous absorber model for CO2 postcombustion captureAICHE JOURNAL, Issue 4 2007Finn Andrew Tobiesen Abstract A rigorous rate-based model for acid gas absorption was developed and validated against mass-transfer data obtained from a 3-month campaign in a laboratory pilot-plant absorber in which the experimental gas,liquid material balance was within an average of 6%. The mass-transfer model is based on the penetration theory where the liquid film is discretized using an adaptive grid. The model was validated against all data and the deviation between simulated and averaged gas and liquid side experimental mass-transfer rates yielded a total variability of 6.26%, while the total average deviation was 6.16%. Simpler enhancement factor mass-transfer models were also tested, but showed slight over-prediction of mass-transfer rates. A sensitivity analysis shows that the accuracy of the equilibrium model is the single most important source of deviation between experiments and model, in particular at high loadings. Experimental data for the absorber in the integrated pilot plant are included. © 2007 American Institute of Chemical Engineers AIChE J, 2007 [source] Modeling of CO2 absorber using an AMP solutionAICHE JOURNAL, Issue 10 2006Jostein Gabrielsen Abstract An explicit model for carbon dioxide (CO2) solubility in an aqueous solution of 2-amino-2-methyl-1-propanol (AMP) has been proposed and an expression for the heat of absorption of CO2 has been developed as a function of loading and temperature. A rate-based steady-state model for CO2 absorption into an AMP solution has been proposed, using both the proposed expression for the CO2 solubility and the expression for the heat of absorption along with an expression for the enhancement factor and physicochemical data from the literature. The proposed model has successfully been applied to absorption of CO2 into an AMP solution in a packed tower and validated against pilot-plant data from the literature. © 2006 American Institute of Chemical Engineers AIChE J, 2006 [source] Effect of the combination of a benzophenone-type ultraviolet absorber with thermal stabilizers on the photodegradation of poly(vinyl chloride)JOURNAL OF VINYL & ADDITIVE TECHNOLOGY, Issue 1 2010Xiuqin Xiang The effect of the combination of a UV absorber (Chimassorb 81) with different types of thermal stabilizers, including an organic calcium complex and an organotin mercaptide, on the photodegradation of poly(vinyl chloride) (PVC) was investigated by color difference measurements, UV,Vis spectroscopy, Fourier-transform infrared spectroscopy, thermogravimetric (TG) analysis, and viscosity-average molecular weight determination. Films of PVC containing 0.5 phr of Chimassorb 81, with and without 2 phr of a thermal stabilizer, were prepared by solution casting. Then the accelerated UV weathering of the films was carried out under xenon light with an irradiance of 0.51 W/(m2 · nm) at 65°C. The results showed that both Chimassorb 81 and the mixture of Chimassorb 81 with the organic calcium complex showed good behavior in inhibiting the photodehydrochlorination and photooxidation of PVC. In contrast, the combination of Chimassorb 81 and methyltin mercaptide significantly accelerated initial color development during the final 200 h of exposure because of the UV sensitivity of the organotin. Moreover, when Chimassorb 81 and the methyltin mercaptide were used together to stabilize PVC films, the expected antioxidant effect of the mixture was not observed, in contrast to the behavior found with other stabilized systems, perhaps because the Chimassorb 81 had been depleted by the methyltin mercaptide during the UV irradiation. The TG analysis revealed that ultraviolet irradiation had caused severe destruction of the PVC chains. However, addition of Chimassorb 81 or the combination of Chimassorb 81 with the organic calcium complex effectively prevented the destruction, as was demonstrated by changes in the activation energies for thermal degradation. J. VINYL ADDIT. TECHNOL., 2010. © 2010 Society of Plastics Engineers [source] A radically new UV stabilizer for flexible PVC roofing membranesJOURNAL OF VINYL & ADDITIVE TECHNOLOGY, Issue 3 2005Gerald Capocci Ultraviolet absorbers, such as those from the hydroxyphenylbenzotriazole and hydroxybenzophenone classes of compounds, are typically added to flexible PVC roofing membranes in order to protect the membranes during long-term exposure to sunlight. In this article a radically new UV stabilizer, one that is not just another UV absorber, is introduced. This new UV stabilizer, which is chemically a low-basicity hindered piperidine derivative, was found to dramatically increase the weatherability of PVC roofing membranes. The performance of the new light stabilizer is documented and compared to that of traditional PVC membranes containing just a UV absorber. Although the article focuses on PVC roofing membranes, examples are provided of other durable applications that could benefit from the new light stabilizer technology. J. VINYL ADDIT. TECHNOL., 11:91,94, 2005. © 2005 Society of Plastics Engineers [source] Effect of hindered piperidine light stabilizer molecular structure and UV-absorber addition on the oxidation of HDPE.JOURNAL OF VINYL & ADDITIVE TECHNOLOGY, Issue 2 2004Part 1: Long-term thermal, photo-oxidation studies This series of papers explores the effect of structural characteristics of 2,2,6,6-tetramethylpiperidine-based hindered amine light stabilizers (HALS) on the long-term (40 months) thermal (110°C in air) and photo-stabilization (Microscal unit wavelength >300 nm) performance characteristics of high-density polyethylene formulations. Possible synergism with a triazine functional UV absorber is also explored. Under thermal degradation (measured by carbonyl index) the polymeric HALS performed best, mainly because of reduced volatilization. Additionally, >N-methyl HALS generally showed superior performance under thermal degradation. There was no synergism between an N-CH3 polymeric HALS and the UV1164 triazine additive. However, the equivalent N-H polymeric HALS interacted in a complex manner with UV1164, giving synergism and antagonism, depending on HALS/UV1164 ratio. Strong synergism was evident with the monomeric HALS when the total stabilizer level was 0.2% w/w. Reduction in the overall stabilizer level to 0.05% w/w eliminated the synergism. The UV1164 alone led to rapid and intense yellowing; however, the rate and intensity of yellowing reduced dramatically upon combination with HALS, particularly when the UV1164 level was above 0.1% w/w. When the formulation was under UV attack, the molar mass and the type of N-substitution had no influence on stabilization performance because of the relatively low temperature of testing (leading to reduced volatilization), and the similarly effective UV-stabilization routes for N-methyl HALS and N-H HALS. Under UV attack, yellowing reached a maximum and then decreased to approximately the initial level, while HALS/UV1164 combinations generally showed weak antagonism. J. Vinyl Addit. Technol. 10:79,87, 2004. © 2004 Society of Plastics Engineers. [source] Diode-pumped passively Q-switching mode-locked Nd:Gd0.5Y0.5VO4/V3+:YAG laser at 1.34, mLASER PHYSICS LETTERS, Issue 11 2009H.-T. Huang Abstract A diode-pumped passively Q-switching mode-locked Nd:Gd0.5Y0.5VO4 laser at 1.34 , m using V3+:YAG as the saturable absorber has been demonstrated for the first time to the best of our knowledge. At the pump power of 7 W, the maximum average output power of 0.83 W and Q-switched pulse repetition rate of 140 kHz were obtained with absorber's initial transmission of 96%, with the corresponding Q-switched pulse energy estimated to be 6 , J. The duration of mode-locked pulse within Q-switched envelop was estimated to be 750 ps with 333.3 MHz repetition rate. (© 2009 by Astro Ltd., Published exclusively by WILEY-VCH Verlag GmbH & Co. KGaA) [source] | ||||||||||||||||||||||||||||