|
| ||
|
|
||
Czochralski Method (czochralski + method)
Selected AbstractsEffect of reduction/oxidation treatment on blue photorefraction in In:Fe:Cu:LiNbO3 crystalsCRYSTAL RESEARCH AND TECHNOLOGY, Issue 4 2010Suhua Luo Abstract In:Fe:Cu:LiNbO3 crystals with reduced/oxidized treatments were prepared by the Czochralski method. The defect structure was analyzed by the UV-Visible absorption spectra. The blue photorefractive properties, such as the refractive index change, response time, recording sensitivity, dynamic range as well as two-wave coupling gain coefficient, were also investigated at 488 nm wavelength using the two-wave coupling experiment. Comparing the as-grown and oxidized In:Fe:Cu:LiNbO3 crystals, the reduced sample has the highest recording sensitivity and largest dynamic range. Meanwhile, the high diffraction efficiency is still maintained. Experimental results definitely show that reduction treatment is an effective method to improve the blue photorefractive performance of In:Fe:Cu:LiNbO3 crystals. (© 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Growth, etching morphology and spectra of LiAlO2 crystalCRYSTAL RESEARCH AND TECHNOLOGY, Issue 8 2008Taohua Huang Abstract ,-LiAlO2 single crystal was successfully grown by Czochralski method. The crystal quality was characterized by X-ray rocking curve and chemical etching. The effects of air-annealing and vapor transport equilibration (VTE) on the crystal quality, etch pits and absorption spectra of LiAlO2 were also investigated in detail. The results show that the as-grown crystal has very high quality with the full width at half maximum (FWHM) of 17.7-22.6 arcsec. Dislocation density in the middle part of the crystal is as low as about 3.0×103 cm,2. The VTE-treated slice has larger FWHM value, etch pits density and absorption coefficient as compared with those of untreated and air-annealed slices, which indicates that the crystal quality became inferior after VTE treatment. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Growth and characterization of near stoichiometric LiNbO3 single crystalCRYSTAL RESEARCH AND TECHNOLOGY, Issue 2 2007S. H. Yao Abstract A near stoichiometric LiNbO3 single crystal has been grown by the Czochralski method from a 58.5% Li melt hold in a large platinum crucible. High resolution X-ray rocking curves of 300 and 0006 reflections indicated that the near stoichiometric LiNbO3 crystal possesses the high structural quality. Compared with the congruent LiNbO3, the near stoichiometric LiNbO3 possesses shorter ultraviolet absorption edge, thus higher Li concentration. The OH, infrared absorption band analyses showed that the Li concentration in the near stoichiometric LiNbO3 crystal is higher than that in the congruent LiNbO3 crystal. This result is in good agreement with that of the ultraviolet absorption edge. The electro-optic (EO) coefficient ,22 of the near stoichiometric LiNbO3 crystal was measured to be 6.75 pm/V higher than that of congruent LiNbO3 crystal. It also proves the near stoichiometric LiNbO3 electro-optic Q-switched requires a low driving voltage and it is advantageous for the device performance. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Spectroscopic properties of La3Ga5SiO14:Er3+ (1%) crystalsCRYSTAL RESEARCH AND TECHNOLOGY, Issue 11 2006Zeng M. Wang Abstract Single crystals of Erbium (Er) doped La3Ga5SiO14 (LGS) have been grown along c-axis by using the Czochralski method. The absorption and fluorescence spectra of LGS: Er3+ single crystals have been measured and analyzed according to the Judd-Ofelt theory. When applied, the following spectral parameters have been obtained: intensity parameters ,t, ,2= 2.741674×10 -20cm2, ,4= 0.66934×10 -20 cm2 and ,6= 0.592591×10 -20 cm2, radiative transition probabilities AJ,J", PJ,J". The radiative lifetime of levels 4I13/2, 4H9/2, 4S3/2 are 11.333ms, 0.447ms and 0.704ms, respectively. The fluorescence branching ratios and the integrated emission cross sections are also calculated. The results suggest that LGS: Er crystals have potential applications as a laser material. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Growth and photorefractive properties of Mg:Ce:Cu:LiNbO3 crystals grown by Czochralski methodCRYSTAL RESEARCH AND TECHNOLOGY, Issue 8 2006Y. X. Fan Abstract In this paper, photorefractive properties of Mg:Ce:Cu:LiNbO3 crystals were studied. The crystals doped with different concentration of Mg ions have been grown by the Czochralski method. Mg concentrations in grown crystals were analyzed by an inductively coupled plasma optical emission spectrometry (ICP-OE/MS). The crystal structures were analyzed by the X-ray powder diffraction (XRD), ultraviolet-visible (UV-Vis) absorption spectra and infrared (IR) transmitatance spectra. The photorefractive properties of crystals were experimentally studied by using two-beam coupling. In this experiment we determined the writing time, maximum diffraction efficiency and the erasure time of crystals samples with He-Ne laser. The results showed that the dynamic range (M/#), sensitivity (S) and diffraction efficiency (,) were dependent on the Mg doping concentration, and the Mg(4.58mol%):Ce:Cu:LiNbO3 crystal was the most proper holographic recording media material among the six crystals studied in the paper. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Growth and optical damage resistance of Sc, Er Co-doped LiNbO3 crystalsCRYSTAL RESEARCH AND TECHNOLOGY, Issue 7 2005X. H. Zhen Abstract A series of Sc:Er:LiNbO3 crystals have been grown by Czochralski method. Their ultraviolet-visible (UV-Vis) absorption spectra was measured and discussed to investigate their defect structure. The optical damage resistance of Sc:Er:LiNbO3 crystals was characterized by the transmitted beam pattern distortion method. It increases remarkably when the concentration of Sc2O3 exceeds a threshold concentration. The optical damage resistance of Sc (3.0mol %):Er:LiNbO3 is much higher than that of the Er:LiNbO3. The intrinsic and extrinsic defects were discussed to explain the enhance of the optical damage resistance in the Sc:Er:LiNbO3 crystals. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Equilibrium and growth shapes of crystals: how do they differ and why should we care?CRYSTAL RESEARCH AND TECHNOLOGY, Issue 4-5 2005Robert F. SekerkaArticle first published online: 15 MAR 200 Abstract Since the death of Prof. Dr. Jan Czochralski nearly 50 years ago, crystals grown by the Czochralski method have increased remarkably in size and perfection, resulting today in the industrial production of silicon crystals about 30 cm in diameter and two meters in length. The Czochralski method is of great technological and economic importance for semiconductors and optical crystals. Over this same time period, there have been equally dramatic improvements in our theoretical understanding of crystal growth morphology. Today we can compute complex crystal growth shapes from robust models that reproduce most of the features and phenomena observed experimentally. We should care about this because it is likely to result in the development of powerful and economical design tools to enable future progress. Crystal growth morphology results from an interplay of crystallographic anisotropy and growth kinetics by means of interfacial processes and long-range transport. The equilibrium shape of a crystal results from minimizing its anisotropic surface free energy under the constraint of constant volume; it is given by the classical Wulff construction but can also be represented by an analytical formula based on the ,-vector formalism of Hoffman and Cahn. We now have analytic criteria for missing orientations (sharp corners or edges) on the equilibrium shape, both in two (classical) and three (new) dimensions. Crystals that grow under the control of interfacial kinetic processes tend asymptotically toward a "kinetic Wulff shape", the analogue of the Wulff shape, except it is based on the anisotropic interfacial kinetic coefficient. If it were not for long range transport, crystals would presumably nucleate with their equilibrium shape and then evolve toward their "kinetic Wulff shape". Allowing for long range transport leads to morphological instabilities on the scale of the geometric mean of a transport length (typically a diffusivity divided by the growth speed) and a capillary length (of the order of atomic dimensions). Resulting crystal growth shapes can be cellular or dendritic, but can also exhibit corners and facets related to the underlying crystallographic anisotropy. Within the last decade, powerful phase field models, based on a diffuse interface, have been used to treat simultaneously all of the above phenomena. Computed morphologies can exhibit cells, dendrites and facets, and the geometry of isotherms and isoconcentrates can also be determined. Results of such computations are illustrated in both two and three dimensions. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Growth and characterization of LiCaGaF6CRYSTAL RESEARCH AND TECHNOLOGY, Issue 1-2 2005E. Sani Abstract Optically clear LiCaGaF6 (LiCGaF) single crystals up to 15 mm length were grown by the Czochralski method from CaF2 deficient melts. The substance melts incongruently at 751 °C. No significant deviations of the crystal composition from the nominal stoichiometry Li:Ca:Ga=1:1:1 could be found. X-ray structure analysis revealed that the substance crystallizes in the colquiriite type structure. LiCaGaF6 is transparent for optical wavelengths >140 , 150 nm. The thermal expansion of the trigonal crystals is ,11 = ,22 = 18.7×10 -6 K -1 perpendicular [001] and ,33 = 2.7×10 -6 K -1 parallel [001]. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Growth and characterization of La3Ga5.5Ta0.5O14 crystalCRYSTAL RESEARCH AND TECHNOLOGY, Issue 8 2004Haikuan Kong Abstract La3Ga5.5Ta0.5O14 (LGT) crystal was grown by using the Czochralski method. The as-grown crystal is transparent, free from inclusions and with no cracks. Specific heat, thermal expansion, dielectric constants, transmission spectrum and optical damage threshold of LGT have been measured, and the results show general properties of LGT are similar to that of La3Ga5SiO14 (LGS) crystal. The experiment to research the Q-switch properties of LGT has been performed and the results show LGT possesses smaller electrooptic coefficients than that of LGS and may not be an ideal material used as a Q-switch. (© 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] The growth and photorefractive effect of co-doped Ce:Cu:BSO crystalsCRYSTAL RESEARCH AND TECHNOLOGY, Issue 12 2003Wei Zheng Abstract In the paper Ce:Cu:BSO crystal has been grown by Czochralski method for the first time with doping CeO2 and CuO into BSO(Bi12SiO20) crystal. The exponential gain coefficient and respond time of Ce:Cu:BSO crystal are measured by two-wave-coupling technology. The results indicate that exponential gain coefficient of Ce:Cu:BSO is more than two times as that of non-doped BSO and the response time exhibits in microsecond level. Furthermore its exponential gain coefficient improves greatly compared with Ce:BSO's at the same doping level of Ce, while its response time is less than Ce:BSO's. The improvement mechanism of photorefractive effect of Ce:Cu:BSO crystal is investigated systematically. (© 2003 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Influence of internal radiation on the heat transfer during growth of YAG single crystals by the Czochralski methodCRYSTAL RESEARCH AND TECHNOLOGY, Issue 10 2003Z. Galazka Abstract Heat and mass transfer taking place during growth of Y3Al5O12 (YAG) crystals by the Czochralski method, including inner radiation, is analyzed numerically using a Finite Element Method. For inner radiative heat transfer through the crystal the band approximation model and real transmission characteristics, measured from obtained crystals, are used. The results reveal significant differences in temperature and melt flow for YAG crystals doped with different dopands influencing the optical properties of the crystals. When radiative heat transport through the crystal is taken into account the melt-crystal interface shape is different from that when the radiative transport is not included. Its deflection remains constant over a wide range of crystal rotation rates until it finally rapidly changes in a narrow range of rotation rates. (© 2003 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Morphological study of Czochralski-grown lanthanide orthovanadate single crystals and implications on the mechanism of bulk spiral formationJOURNAL OF APPLIED CRYSTALLOGRAPHY, Issue 2 2010Hengjiang Cong Single crystals of monoclinic Nd:LaVO4 with dimensions up to Ø28 × 21,mm have been grown from the near-stoichiometric melt by the Czochralski method, making use of various seed orientations that are perpendicular to the (010), (10), (001) and (00) crystal planes. A sample was also prepared with the seed orientation in an arbitrary direction relative to the crystal. The anisotropic properties of the crystal are manifested in the growth morphology of the as-grown crystals, where different degrees of bulk spiral growth were observed. It was also found that employing the (001) or (00) seed faces severely suppressed the bulk spiral growth, and thus high quality and large-scale Nd:LaVO4 crystals were obtained. The constituent segregation coefficients and high-temperature stability, including the melting point, were determined and evaluated. Based on the attachment energy model of Hartman,Perdok theory, morphology predictions were made for monoclinic LaVO4 and tetragonal YVO4 orthovanadate single crystals. Correlating with the as-grown morphology of both crystals developed along different seed orientations, a theoretical explanation is provided for the influences of seed crystals on bulk spiral formation, crystal quality and utilization ratio. It suggests that breaking the axial symmetry of the ideal atomic level interface between crystal and melt plays a crucial triggering role in bulk spiral formation in the Czochralski growth of lanthanide orthovanadate single crystals. Selecting a proper seed orientation that yields such a highly axially symmetric surface structure consisting of a series of large-area facets with similar growth velocities can greatly reduce bulk spiral formation and thus is preferable in the Czochralski growth of large-sized low-symmetry oxide crystals. [source] Spectroscopic properties of Yb3+ -doped Ca4Gd0.5Y0.5O(BO3)3 single crystalsPHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 6 2010Yan Zhang Abstract Yb3+ -doped Ca4Gd0.5Y0.5O(BO3)3 single crystals with good optical quality have been grown by the Czochralski method. The grown crystal was characterized using X-ray powder diffraction. The polarized absorption and emission spectra and fluorescence lifetime of anisotropic monoclinic crystal Yb3+: Ca4Gd0.5Y0.5O(BO3)3 (Yb: GdYCOB) have been measured. Based on the absorption and emission spectra, the Stark energy-level distribution was located. The spectrum and laser parameters of Yb3+: Ca4Gd0.5Y0.5O(BO3)3 (Yb: GdYCOB) crystal have been calculated. [source] Scintillation properties of lead tungstate crystals doped with the monovalent ion lithiumPHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 13 2004Yanlin Huang Abstract Lithium-doped PbWO4 crystals have been grown by the Czochralski method. Optical absorbance, X-ray excited luminescence, light yield measurements and X-ray pulsed excited decays have been investigated. Li+ doping has a very good uniformity and could enhance the luminescence of PbWO4, give some contributions to the "fast" decay components. (© 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] | ||||||||||