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Bulk Temperature (bulk + temperature)
Selected AbstractsKinetics of Calcium Carbonate (CaCO3) Precipitation from a Icel-Yavca Dolomite Leach Solution by a Gas (Carbon Dioxide)/Liquid ReactionHELVETICA CHIMICA ACTA, Issue 3 2009Mehmet Yildirim Abstract The effects of time, CO2 -gas-injection pressure, and bulk temperature on the precipitation of Ca2+ ions as a precipitated calcium carbonate (PCC) from a dolomite leach solution were investigated. Precipitation periods from 1 to 7,min were examined, and experiments were run at CO2 -injection pressures of 200,800,kPa. Effects of bulk temperature were studied in the range from 40 to 70°, and precipitation rates of PCC were determined by measuring the Ca2+ concentrations in the initial and effluent solutions. Influences of these parameters on the subsequent incorporation of Mg2+ ions with the precipitate are discussed in detail. Kinetic analysis of the precipitation was performed by considering the rates as a function of CO -ion concentrations. Results obtained by this process clearly show that Ca2+ ions in the solution can successfully be precipitated as a calcium carbonate product containing 54.70% of CaO and 0.77% MgO, at the rate of 2.01,mM h,1. [source] Modeling and experimental studies on combustion characteristics of porous coal char: Volume reaction modelINTERNATIONAL JOURNAL OF CHEMICAL KINETICS, Issue 5 2010Anup Kumar Sadhukhan A generalized single-particle model for the prediction of combustion dynamics of a porous coal char in a fluidized bed is analyzed in the present work using a volume reaction model (VRM). A fully transient nonisothermal model involving both heterogeneous and homogeneous chemical reactions, multicomponent mass transfer, heat transfer with intraparticle resistances, as well as char structure evolution is developed. The model takes into account convection and diffusion inside the particle pores, as well as in the boundary layer. By addressing the Stefan flow originated due to nonequimolar mass transfer and chemical reactions, this work enables a more realistic analysis of the combustion process. The model, characterized by a set of partial differential equations coupled with nonlinear boundary conditions, is solved numerically using the implicit finite volume method (FVM) with a FORTRAN code developed in-house. The use of a FVM for solving such an elaborate char combustion model, based on the VRM, was not reported earlier. Experiments consisting of fluidized-bed combustion of a single char particle were carried out to determine the internal surface area of a partially burned char particle and to enable model validation. Predicted results are found to compare well with the reported experimental results for porous coal char combustion. The effects of various parameters (i.e., bulk temperature and initial particle radius) are examined on the dynamics of combustion of coal char. The phenomena of ignition and extinction are also investigated. © 2010 Wiley Periodicals, Inc. Int J Chem Kinet 42: 299,315, 2010 [source] Modeling of transport phenomena and melting kinetics of starch in a co-rotating twin-screw extruder,ADVANCES IN POLYMER TECHNOLOGY, Issue 1 2006Lijun Wang A mathematical model was developed to simulate fluid flow, heat transfer, and melting kinetics of starch in a co-rotating intermeshing twin-screw extruder (TSE). The partial differential equations governing the transport phenomena of the biomaterial in the extruder were solved by a finite element scheme. For validating the model, the predicted product pressure, bulk temperature at the entrance of the die, and minimum residence time of the biomaterial in the extruder were compared with experimental data. Standard errors of product pressure, bulk temperature at the die entrance, and minimum residence time were about 8.8, 2.8, and 17.3%. Simulations were carried out to investigate profiles of product pressure, bulk temperature, and melt fraction within the extruder during extrusion. © 2006 Wiley Periodicals, Inc. Adv Polym Techn 25: 22,40, 2006; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/adv.20055 [source] DEVELOPMENT and EVALUATION of MICROWAVE HEATING of APPLE MASH AS A PRETREATMENT to PRESSINGJOURNAL OF FOOD PROCESS ENGINEERING, Issue 1 2004J.S. ROBERTS ABSTRACT Fuji, McIntosh, and Red Delicious apple mashes were heated in a 2450 MHz oven to achieve bulk temperatures of 40, 50, 60, and 70C. Three kilograms of mash at a depth of 0.016 m heated using 1500 W were the optimum parameters to heat apple mash in the microwave. Variety of the apple mash was shown not to have a significant effect on the heating performance. Comparing actual bulk temperature to the predicted bulk temperatures of 40, 50, 60, and 70C showed reproducibility of heating these mashes using microwave energy. Average variation between actual and predicted bulk temperatures were 1.48C for the Fuji mash, 0.98C for the McIntosh mash, and 1.13C for the Red Delicious mash. In addition, regional heating was investigated and four distinct regions of heating were observed: the corner, the edge, the middle, and the center. Color and moisture content of the mash were also measured and compared to unheated mash at 21C. [source] Experimental evaluation of friction between contacting discs for the simulation of gear contactLUBRICATION SCIENCE, Issue 1 2007J. Kleemola Abstract Instant gear contact can be simulated with contacting discs, which provides steady operating conditions and eliminates most of the dynamics and manufacturing tolerances involved in real gears, resulting in an accurately controlled contact condition. A high-pressure twin-disc test device was developed, where loading and rolling velocity can be varied continuously. It is equipped with disc bulk temperature, mean contact resistance and friction moment measurements. The test discs were grinded transversal to the disc rolling direction with proper crowning corresponding to the real gear flank properties. The test device was applied by studying the friction behaviour against the slide-to-roll ratio at different contact pressures, rolling velocities and surface roughness. The measurements were performed using mineral base oil in the range of operation conditions often used in industrial gears. In general, the measured friction coefficient behaviour correlates with earlier published results and is logical with measured bulk temperature and mean contact resistance. The limiting shear stress of the lubricant has an essential role in friction behaviour. Copyright © 2006 John Wiley & Sons, Ltd. [source] DEVELOPMENT and EVALUATION of MICROWAVE HEATING of APPLE MASH AS A PRETREATMENT to PRESSINGJOURNAL OF FOOD PROCESS ENGINEERING, Issue 1 2004J.S. ROBERTS ABSTRACT Fuji, McIntosh, and Red Delicious apple mashes were heated in a 2450 MHz oven to achieve bulk temperatures of 40, 50, 60, and 70C. Three kilograms of mash at a depth of 0.016 m heated using 1500 W were the optimum parameters to heat apple mash in the microwave. Variety of the apple mash was shown not to have a significant effect on the heating performance. Comparing actual bulk temperature to the predicted bulk temperatures of 40, 50, 60, and 70C showed reproducibility of heating these mashes using microwave energy. Average variation between actual and predicted bulk temperatures were 1.48C for the Fuji mash, 0.98C for the McIntosh mash, and 1.13C for the Red Delicious mash. In addition, regional heating was investigated and four distinct regions of heating were observed: the corner, the edge, the middle, and the center. Color and moisture content of the mash were also measured and compared to unheated mash at 21C. [source] The use of post-mortem Raman spectroscopy in explaining friction and wear behaviour of sintered polyimide at high temperatureLUBRICATION SCIENCE, Issue 3 2006P. Samyn Abstract Due to their thermal stability and high strength, polyimides are an aromatic type of polymer that is used in sliding equipment functioning under high loads and elevated temperature. However, its tribological behaviour under high temperature and atmospheric conditions is not fully understood. It has been reported that a transition from high towards lower friction occurs ,somewhere' in the temperature region between 100°C and 200°C; however, a correlation with changes in the polyimide molecular structure remains difficult to illustrate and it is not certain whether or not this transition is correlated to lower wear. In the present work sliding experiments under controlled bulk temperatures between 100°C and 260°C are performed. A transition is observed in both friction and wear at 180°C which is further explained by microscopic analysis of the transfer film on the steel counterface and Raman spectroscopy of the worn polymer surfaces. A close examination of the spectra reveals transitions in relative intensity of certain absorption bands, pointing to different orientation effects of the molecular conformation at the polymer sliding surface at 180°C. Copyright © 2006 John Wiley & Sons, Ltd. [source] | ||||||||||