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Biodegradable Composites (biodegradable + composite)
Selected AbstractsCreep behavior of biocomposites based on sisal fiber reinforced cellulose derivatives/starch blendsPOLYMER COMPOSITES, Issue 3 2004Vera A. Alvarez Biodegradable composites based on cellulose derivatives/starch blends reinforced with sisal short fibers were fabricated by injection molding. Results of short-term flexural creep tests are reported to investigate the time-dependence behavior of the composites. Fiber content and temperature effects are also considered, taking into account various methods and equations. At short times, a creep power law is employed. A master curve with the Arrhenius model is used to determine the creep resistance at longer times and different temperatures. Good fitting of the experimental results with the four-parameter model is reported, leading to a relationship between the observed creep behavior and the composite morphology. The addition of sisal fibers to the polymeric matrix promotes a significant improvement of the composite creep resistance. Polym. Compos. 25:280,288, 2004. © 2004 Society of Plastics Engineers. [source] Mechanical and thermal properties of poly(butylene succinate)/plant fiber biodegradable compositeJOURNAL OF APPLIED POLYMER SCIENCE, Issue 6 2010Zhichao Liang Abstract Biodegradable polymeric composites were fabricated from poly(butylene succinate) (PBS) and kenaf fiber (KF) by melt mixing technique. The mechanical and dynamic mechanical properties, morphology and crystallization behavior were investigated for PBS/KF composites with different KF contents (0, 10, 20, and 30 wt %). The tensile modulus, storage modulus and the crystallization rate of PBS in the composites were all efficiently enhanced. With the incorporation of 30% KF, the tensile modulus and storage modulus (at 40°C) of the PBS/KF composite were increased by 53 and 154%, respectively, the crystallization temperature in cooling process at 10°C/min from the melt was increased from 76.3 to 87.7°C, and the half-time of PBS/KF composite in isothermal crystallization at 96 and 100°C were reduced to 10.8% and 14.3% of that of the neat PBS, respectively. SEM analysis indicates that the adhesion between PBS and KF needs further improvement. These results signify that KF is efficient in improving the tensile modulus, storage modulus and the crystallization rate of PBS. Hence, this study provides a good option for preparing economical biodegradable composite. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 [source] Novel Thermoplastic Composites from Commodity Polymers and Man-Made Cellulose FibersMACROMOLECULAR SYMPOSIA, Issue 1 2006Hans-Peter Fink Abstract Summary: A new class of fibre reinforced commodity thermoplastics suited for injection moulding and direct processing applications has been developed using man-made cellulosic fibres (Rayon tire yarn, Tencel, Viscose, Carbacell) and thermoplastic commodity polymers, such as polypropylene (PP), polyethylene (PE), high impact polystyrene (HIPS), poly(lactic acid) (PLA), and a thermoplastic elastomer (TPE) as the matrix polymer. For compounding, a specially adapted double pultrusion technique has been employed which provides composites with homogeneously distributed fibres. Extensive investigations were performed with Rayon reinforced PP in view of applications in the automotive industry. The Rayon-PP composite is characterized by high strength and an excellent impact behaviour as compared with glass fibre reinforced PP, thus permitting applications in the field of engineering thermoplastics such as polycarbonate/acrylonitrile butadiene styrene blends (PC/ABS). With the PP based composites the influence of material parameters (e.g. fibre type and load, coupling agent) were studied and it has been demonstrated how to tailor the desired composite properties as modulus and heat distortion temperature (HDT) by varying the fibre type or adding inorganic fillers. Man-made cellulose fibers are also suitable for the reinforcement of further thermoplastic commodity polymers with appropriate processing temperatures. In case of PE modulus and strength are tripled compared to the neat resin while Charpy impact strength is increased five-fold. For HIPS mainly strength and stiffness are increased, while for TPE the property profile is changed completely. With Rayon reinforced PLA, a fully biogenic and biodegradable composite with excellent mechanical properties including highly improved impact strength is presented. [source] Injection molded composites of short Alfa fibers and biodegradable blendsPOLYMER COMPOSITES, Issue 4 2006I. Ammar Fully biodegradable composites made from two polymer blend matrices (SEVA-C: starch and a copolymer of ethylene vinyl alcohol; and SCA: starch and cellulose acetate) and short Alfa fibers were developed and processed by conventional injection molding into standard tensile specimens. For each kind of matrix, the influence of the reinforcement load was evaluated, using fiber amounts from 0 to 30% (wt/wt). An optimization study was carried out for the composite SEVA-C with 10% Alfa fiber. The obtained results establish that the produced biodegradable composites present a significant improvement in stiffness for both matrices. Improvements in the tensile strength were observed only for the Alfa fiber reinforced SEVA-C. However, for both matrices, the reinforcement causes a significant loss in the material ductility. Results from design of experiments (Hadamard plans) were used to explain the influence of the injection molding conditions on the mechanical behavior of the obtained composites, mainly on the stiffness values. POLYM. COMPOS., 27:341,348, 2006. © 2006 Society of Plastics Engineers [source] Processing, properties and stability of biodegradable composites based on Mater-Bi® and cellulose fibresPOLYMERS FOR ADVANCED TECHNOLOGIES, Issue 11-12 2003D. Puglia Abstract In this work, the behaviour of biocomposites obtained by the addition of flax cellulose pulp to Mater-Bi®, a commercial thermoplastic matrix based on starch, has been studied in comparison with traditional glass fibre composites. The composites were produced by compounding with a twin-screw extruder. Depending on the kind of fibre, reinforcement contents of 10,40% were obtained. The mechanical behaviour, both in normal conditions and after water absorption, was analysed. It has been noted that the addition of cellulose pulp increases the composite modulus more than glass fibre: in fact, a poor adhesion of the interface between the glass fibre and Mater-Bi® has been observed. The thermal degradation behaviour of the composite has been studied by thermogravimetric analysis (TGA). Different degradation peaks have been observed and the activation energies, related to the main peak, have been calculated. The addition of cellulose pulp produces better mechanical properties and higher thermal stability. Copyright © 2003 John Wiley & Sons, Ltd. [source] | ||||||||||