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Water Remediation (water + remediation)
Kinds of Water Remediation Selected AbstractsRECIRCULATING WELLS: GROUND WATER REMEDIATION AND PROTECTION OF SURFACE WATER RESOURCES,JOURNAL OF THE AMERICAN WATER RESOURCES ASSOCIATION, Issue 1 2000Keith W. Ryan ABSTRACT: Several chlorinated solvent plumes threaten the sole-source aquifer underlying the Massachusetts Military Reservation at the western end of Cape Cod. Sensitive surface water features including ponds, cranberry bogs, and coastal wetlands are hydraulically connected to the aquifer. For one of the plumes (CS-10 the original remedy of 120 extraction and reinjection wells has the potential for significant disruption of surface water hydrology, through the localized drawdown and mounding of the water table. Recirculating wells with in-well air stripping offer a cost-effective alternative to conventional pump-and-treat technology that does not adversely affect the configuration of the water table. Pilot testing of a two well system, pumping 300 gpm, showed a capture radius of > 200 feet per well, in-well trichloroethylene (TCE) removal efficiencies of 92 to 98 percent per recirculation cycle, an average of three recirculation cycles within the capture zone, and no measurable effect on water table elevations at any point within the recirculation/treatment zone. During 120 days of operation, the mean concentration of TCE in the treatment zone was reduced by 83 percent, from 1,111 ,g/l to 184 ,g/l. Full-scale design projections indicate that 60 wells at an average spacing of 160 feet, having an aggregate recirculation 11 MGD, can contain the CS-b plume without ground water extraction or adverse hydraulic effects on surface water resources. The estimated capital costs for such a system are about $7 million, and annual operations-and-maintenance costs should be about $1.4 million, 40 percent of those associated with a pump and treat system over a 20-year period. [source] Enhanced Photocatalytic Activity using Layer-by-Layer Electrospun Constructs for Water RemediationADVANCED FUNCTIONAL MATERIALS, Issue 15 2010Jung Ah Lee Abstract Endocrine disruptors such as bisphenol A (BPA) are environmental pollutants that interfere with the body's endocrine system because of their structural similarity to natural and synthetic hormones. Due to their strong oxidizing potential to decompose such organic pollutants, colloidal metal oxide photocatalysts have attracted increasing attention for water detoxification. However, achieving both long-term physical stability and high efficiency simultaneously with such photocatalytic systems poses many challenges. Here a layer-by-layer (LbL) deposition approach is reported for immobilizing TiO2 nanoparticles (NPs) on a porous support while maintaining a high catalytic efficiency for photochemical decomposition of BPA. Anatase TiO2 NPs ,7,nm in diameter self-assemble in consecutive layers with positively charged polyhedral oligomeric silsesquioxanes on a high surface area, porous electrospun polymer fiber mesh. The TiO2 LbL nanofibers decompose approximately 2.2,mg BPA per mg of TiO2 in 40,h of illumination (AM 1.5G illumination), maintaining first-order kinetics with a rate constant (k) of 0.15,h,1 for over 40,h. Although the colloidal TiO2 NPs initially show significantly higher photocatalytic activity (k,,,0.84,h,1), the rate constant drops to k,,,0.07,h,1 after 4,h of operation, seemingly due to particle agglomeration. In the BPA solution treated with the multilayered TiO2 nanofibers for 40,h, the estrogenic activity, based on human breast cancer cell proliferation, is significantly lower than that in the BPA solution treated with colloidal TiO2 NPs under the same conditions. This study demonstrates that water-based, electrostatic LbL deposition effectively immobilizes and stabilizes TiO2 NPs on electrospun polymer nanofibers for efficient extended photochemical water remediation. [source] Hydraulics of Recirculating Well Pairs for Ground Water RemediationGROUND WATER, Issue 6 2004Article first published online: 9 OCT 200 First page of article [source] Climate Change, Sustainability, and Ground Water Remediation: The ConnectionGROUND WATER MONITORING & REMEDIATION, Issue 4 2007Scott D. Warner No abstract is available for this article. [source] Enhanced Photocatalytic Activity using Layer-by-Layer Electrospun Constructs for Water RemediationADVANCED FUNCTIONAL MATERIALS, Issue 15 2010Jung Ah Lee Abstract Endocrine disruptors such as bisphenol A (BPA) are environmental pollutants that interfere with the body's endocrine system because of their structural similarity to natural and synthetic hormones. Due to their strong oxidizing potential to decompose such organic pollutants, colloidal metal oxide photocatalysts have attracted increasing attention for water detoxification. However, achieving both long-term physical stability and high efficiency simultaneously with such photocatalytic systems poses many challenges. Here a layer-by-layer (LbL) deposition approach is reported for immobilizing TiO2 nanoparticles (NPs) on a porous support while maintaining a high catalytic efficiency for photochemical decomposition of BPA. Anatase TiO2 NPs ,7,nm in diameter self-assemble in consecutive layers with positively charged polyhedral oligomeric silsesquioxanes on a high surface area, porous electrospun polymer fiber mesh. The TiO2 LbL nanofibers decompose approximately 2.2,mg BPA per mg of TiO2 in 40,h of illumination (AM 1.5G illumination), maintaining first-order kinetics with a rate constant (k) of 0.15,h,1 for over 40,h. Although the colloidal TiO2 NPs initially show significantly higher photocatalytic activity (k,,,0.84,h,1), the rate constant drops to k,,,0.07,h,1 after 4,h of operation, seemingly due to particle agglomeration. In the BPA solution treated with the multilayered TiO2 nanofibers for 40,h, the estrogenic activity, based on human breast cancer cell proliferation, is significantly lower than that in the BPA solution treated with colloidal TiO2 NPs under the same conditions. This study demonstrates that water-based, electrostatic LbL deposition effectively immobilizes and stabilizes TiO2 NPs on electrospun polymer nanofibers for efficient extended photochemical water remediation. [source] Estimating Persistent Mass Flux of Volatile Contaminants from the Vadose Zone to Ground WaterGROUND WATER MONITORING & REMEDIATION, Issue 2 2009M.J. Truex Contaminants may persist for long time periods within low permeability portions of the vadose zone where they cannot be effectively treated and are a potential continuing source of contamination to ground water. Setting appropriate vadose zone remediation goals typically requires evaluating these persistent sources in terms of their impact on meeting ground water remediation goals. Estimating the impact on ground water can be challenging at sites with low aqueous recharge rates where vapor-phase movement is the dominant transport process in the vadose zone. Existing one-dimensional approaches for simulating transport of volatile contaminants in the vadose zone are considered and compared to a new flux-continuity-based assessment of vapor-phase contaminant movement from the vadose zone to the ground water. The flux-continuity-based assessment demonstrates that the ability of the ground water to move contaminant away from the water table controls the vapor-phase mass flux from the vadose zone across the water table. Limitations of these approaches are then discussed with respect to the required assumptions and the need to incorporate three-dimensional processes when evaluating vapor-phase transport from the vadose zone to the ground water. The carbon tetrachloride plume at the U.S. Department of Energy Hanford Site is used as the example site where persistent vadose zone contamination needs to be considered in the context of ground water remediation. [source] Nitrate Removal Rates in a 15-Year-Old Permeable Reactive Barrier Treating Septic System NitrateGROUND WATER MONITORING & REMEDIATION, Issue 3 2008W.D. Robertson Permeable reactive barriers (PRBs) have gained popularity in recent years as a low-cost method for ground water remediation. However, their cost advantage usually requires that these barriers remain maintenance free for a number of years after installation. In this study, sediment cores were retrieved from a pilot-scale PRB consisting of a sand and wood particle (sawdust) mixture that has been in continuous operation for 15 years treating nitrate from a septic system plume in southern Ontario (Long Point site). Reaction rates for the 15-year-old media were measured in dynamic flow column tests and were compared to rates measured in year 1 using the same reactive mixture. Nitrate removal rates in the 15-year-old media varied, as expected, with temperature in the range of 0.22 to 1.1 mg N/L/d at 6 °C to 10 °C to 3.5 to 6.0 mg N/L/d at 20 °C to 22 °C. The latter rates remained within about 50% of the year 1 rates (10.2 ± 2.7 mg N/L/d at 22 °C). Near the end of the year 15 column test, media particles >0.5 mm in diameter, containing most of the wood particles, were removed from the reactive media by sieving. Nitrate removal subsequently declined by about 80%, indicating that the wood particles were the principal energy source for denitrification. This example shows that some denitrifying PRBs can remain maintenance free and be adequately reactive for decades. [source] |