Water Quality Conditions (water + quality_condition)

Distribution by Scientific Domains


Selected Abstracts


Evaluation of water quality using acceptance sampling by variables

ENVIRONMETRICS, Issue 4 2003
Eric P. Smith
Abstract Under section 303(d) of the Clean Water Act, states must identify water segments where loads of pollutants are violating numeric water quality standards. Consequences of misidentification are quite important. A decision that water quality is impaired initiates the total maximum daily load or TMDL planning requirement. Falsely concluding that a water segment is impaired results in unnecessary TMDL planning and pollution control implementation costs. On the other hand, falsely concluding that a segment is not impaired may pose a risk to human health or to the services of the aquatic environment. Because of the consequences, a method is desired that minimizes or controls the error rates. The most commonly applied approach is to use the Environmental Protection Agency (EPA)'s raw score approach in which a stream segment is listed as impaired when greater than 10 per cent of the measurements of water quality conditions exceed a numeric criteria. An alternative to the EPA approach is the binomial test that the proportion exceeding the standard is 0.10 or less. This approach uses the number of samples exceeding the criteria as a test statistic along with the binomial distribution for evaluation and estimation of error rates. Both approaches treat measurements as binary; the values either exceed or do not exceed the standard. An alternative approach is to use the actual numerical values to evaluate standard. This method is referred to as variables acceptance sampling in quality control literature. The methods are compared on the basis of error rates. If certain assumptions are met then the variables acceptance method is superior in the sense that the variables acceptance method requires smaller sample sizes to achieve the same error rates as the raw score method or the binomial method. Issues associated with potential problems with environmental measurements and adjustments for their effects are discussed. Copyright © 2003 John Wiley & Sons, Ltd. [source]


Sampling Strategies for Volatile Organic Compounds at Three Karst Springs in Tennessee

GROUND WATER MONITORING & REMEDIATION, Issue 1 2006
Shannon D. Williams
The influence of different sampling strategies on characterizing volatile organic compound (VOC) concentrations and estimating VOC loads was evaluated at three karst springs in Tennessee. During a 6-month period, water samples for VOC analyses were collected weekly at all three springs and as frequently as every 20 min during storms at the two springs with variable water quality conditions. Total 6-month loads for selected VOCs were calculated, and VOC data were systematically subsampled to simulate and evaluate several potential sampling strategies. Results from the study indicate that sampling strategies for karst springs need to be developed on a site-specific basis. The use of fixed sampling intervals (as infrequently as quarterly or semiannually) produced accurate concentration and load estimates at one of the springs; however, additional sampling was needed to detect storm-related changes at a second spring located in a similar hydrogeologic setting. Continuous discharge data and high-frequency or flow-controlled sampling were needed at the third spring, which had the most variable flow and water quality conditions. The lack of continuous discharge data at the third spring would substantially affect load calculations, and the use of fixed sampling intervals would affect load calculations and the ability to detect pulses of high contaminant concentrations that might exceed toxicity levels for aquatic organisms. [source]


Effects of urbanization on stream water quality in the city of Atlanta, Georgia, USA,

HYDROLOGICAL PROCESSES, Issue 20 2009
Norman E. Peters
Abstract A long-term stream water quality monitoring network was established in the city of Atlanta, Georgia during 2003 to assess baseline water quality conditions and the effects of urbanization on stream water quality. Routine hydrologically based manual stream sampling, including several concurrent manual point and equal width increment sampling, was conducted ,12 times annually at 21 stations, with drainage areas ranging from 3·7 to 232 km2. Eleven of the stations are real-time (RT) stations having continuous measures of stream stage/discharge, pH, dissolved oxygen, specific conductance, water temperature and turbidity, and automatic samplers for stormwater collection. Samples were analyzed for field parameters, and a broad suite of water quality and sediment-related constituents. Field parameters and concentrations of major ions, metals, nutrient species and coliform bacteria among stations were evaluated and with respect to watershed characteristics and plausible sources from 2003 through September 2007. Most constituent concentrations are much higher than nearby reference streams. Concentrations are statistically different among stations for several constituents, despite high variability both within and among stations. Routine manual sampling, automatic sampling during stormflows and RT water quality monitoring provided sufficient information about urban stream water quality variability to evaluate causes of water quality differences among streams. Fecal coliform bacteria concentrations of most samples exceeded Georgia's water quality standard for any water-usage class. High chloride concentrations occur at three stations and are hypothesized to be associated with discharges of chlorinated combined sewer overflows, drainage of swimming pool(s) and dissolution and transport during rainstorms of CaCl2, a deicing salt applied to roads during winter storms. One stream was affected by dissolution and transport of ammonium alum [NH4Al(SO4)2] from an alum-manufacturing plant; streamwater has low pH (<5), low alkalinity and high metals concentrations. Several trace metals exceed acute and chronic water quality standards and high concentrations are attributed to washoff from impervious surfaces. Published in 2009 by John Wiley & Sons, Ltd. [source]


OVERCOMING THE NATION'S BEST LANDSCAPED SEWER: RECREATORS' PERCEPTIONS OF THE CONNECTICUT RIVER,

JOURNAL OF THE AMERICAN WATER RESOURCES ASSOCIATION, Issue 1 2003
Jo Beth Mullens
ABSTRACT: Once referred to as America's "best landscaped sewer," the Connecticut has undergone a dramatic transformation in the last three decades. During this time, a number of public agencies and private organizations have worked diligently to implement policies and measures aimed at improving the river's quality. Ample data collected over the years indicate that the actual water quality conditions of the Connecticut River, as measured by empirical parameters, have improved. However, prior to this study, no data existed regarding the public's perceptions of these changes. This paper will address this issue by presenting the results of a multiyear survey designed to assess the public's perceptions regarding the Connecticut's current quality, and its suitability in supporting various recreational activities. The results suggest that the majority of individuals perceive the Connecticut's water quality to be high enough to support a wide range of recreational activities including those involving physical contact with the water. Additionally, this research concludes that the vast majority of individuals who have recreated on the river for 20 years or more do perceive a significant improvement in the river's overall quality. Thus, it appears that policies and actions taken to improve the Connecticut's quality have been successful in the public's eye. [source]


EPA'S BASINS MODEL: GOOD SCIENCE OR SERENDIPITOUS MODELING?,

JOURNAL OF THE AMERICAN WATER RESOURCES ASSOCIATION, Issue 3 2000
Ray C. Whittemore
ABSTRACT: Better Assessment Science Integrating Point and Non-point Sources (BASINS) is a geographic-based watershed assessment tool developed by EPA's Office of Water to help states more efficiently target and evaluate water-bodies that are not meeting water quality standards. BASINS (EPA, 1996a, 1998) brings together data on water quality and quantity, land uses, point source loadings, and other related spatial data with supporting nonpoint and water quality models at a quicker and more effective pace. EPA developed BASINS, to better integrate point and nonpoint source water quality assessments for the Nation's 2100+ watersheds. In its zeal to achieve this endpoint, EPA has initiated a simplistic approach that was expected to grow through scientific enhancements as TMDL developers become more familiar with modeling requirements. BASINS builds upon federal databases of water quality conditions and point source loadings for numerous parameters where quality assurance is suspect in some cases. Its design allows comprehensive assessments and modeling in typical Total Maximum Daily Load (TMDL) computations. While the TMDL utility is the primary reason BASINS was developed, other longer-range water quality assessments will become possible as the Agency expands the suite of assessment models and databases in future releases. The simplistic approach to modeling and user-friendly tools gives rise, however, to technical and philosophical concerns related to default data usage. Seamless generation of model input files and the failure of some utilities to work properly suggest to NCASI that serious problems may still exist and prompts the need for a more rigorous peer-review. Furthermore, sustainable training becomes paramount, as some older modelers will be unfamiliar with Geographic Information System (GIS) technology and associated computer skills. Overall, however, BASINS was judged to be an excellent beginning tool to meet the complex environmental modeling needs in the 21st Century. [source]