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Water Analyses (water + analysis)
Selected AbstractsVegetation,environment relationships along El-Salam Canal, EgyptENVIRONMETRICS, Issue 3 2001Mamdouh S. Serag Abstract The bank and open water vegetation along El-Salam Canal in north-eastern Egypt were studied in relation to the prevailing environmental factors. The hypothesis that terresterial and aquatic species would show different downstream patterns of species richness was tested by sampling species composition and environmental variables along 80,km of the canal. Species richness was highest in the first 30,km of the canal. The downstream decrease in species richness exhibits interpretable downstream patterns. Total species richness increased with increasing organic matter in the soil and decreased with both increasing soil and water salinity along the gradient. The indicator species of TWINSPAN analysis are: Azolla filiculoides, Echinochloa stagnina, Eichhornia crassipes and Saccharum spontaneum (cluster I); Ceratophyllum demersum, Ludwigia stolonifera and Typha domingensis (cluster II); Potamogeton pectinatus and Phragmites australis (cluster III); Tamarix nilotica and Suaeda vera (cluster IV). The environmental factors influencing the vegetation clusters were analysed using canonical correspondence analysis ordination (CCA). The water salinity, total nitrogen and total phosphorus appeared to be the most important factors controlling the abundance of aquatic plant distribution along the canal. The shoreline vegetation is mainly controlled by salinity, K+ and organic carbon of the soil. Water analysis indicated that the salinity of the water increases southwards and the minimum salinity of the water (0.78,mS/cm) was recorded at the intake of the canal. The maximum value (7.5,mS/cm) of water salinity was recorded near the Suez Canal. Copyright © 2001 John Wiley & Sons, Ltd. [source] Effect of textile waste water on the spermatogenesis of male albino ratsJOURNAL OF APPLIED TOXICOLOGY, Issue 3 2003R. S. Gupta Abstract Textile waste water released from dyeing and printing industries situated in Sanganer, Jaipur (India), brought about inhibition of spermatogenesis in male rats. Water analysis showed the presence of heavy metals at more than permissible limits. Oral administration of waste water to the rats at the dose level of 26.6 ml kg,1 body wt. significantly reduced the weights of testes, epididymides and seminal vesicle. Treated animals showed a notable depression of various stages of spermatogenesis. The production of spermatids was inhibited by 70.8% in waste-water-treated rats. The populations of spermatogonia, preleptotene spermatocytes and secondary spermatocytes were decreased by 67.2, 71.1 and 73.2%, respectively. The total number of Sertoli cells was affected after waste water treatment. Reduced sperm count and motility resulted in treated groups. A significant fall in the content of various biochemical parameters of reproductive tissues was observed after water treatment. Copyright © 2003 John Wiley & Sons, Ltd. [source] Equations of state for basin geofluids: algorithm review and intercomparison for brinesGEOFLUIDS (ELECTRONIC), Issue 4 2002J. J. Adams ABSTRACT Physical properties of formation waters in sedimentary basins can vary by more than 25% for density and by one order of magnitude for viscosity. Density differences may enhance or retard flow driven by other mechanisms and can initiate buoyancy-driven flow. For a given driving force, the flow rate and injectivity depend on viscosity and permeability. Thus, variations in the density and viscosity of formation waters may have or had a significant effect on the flow pattern in a sedimentary basin, with consequences for various basin processes. Therefore, it is critical to correctly estimate water properties at formation conditions for proper representation and interpretation of present flow systems, and for numerical simulations of basin evolution, hydrocarbon migration, ore genesis, and fate of injected fluids in sedimentary basins. Algorithms published over the years to calculate water density and viscosity as a function of temperature, pressure and salinity are based on empirical fitting of laboratory-measured properties of predominantly NaCl solutions, but also field brines. A review and comparison of various algorithms are presented here, both in terms of applicability range and estimates of density and viscosity. The paucity of measured formation-water properties at in situ conditions hinders a definitive conclusion regarding the validity of any of these algorithms. However, the comparison indicates the versatility of the various algorithms in various ranges of conditions found in sedimentary basins. The applicability of these algorithms to the density of formation waters in the Alberta Basin is also examined using a high-quality database of 4854 water analyses. Consideration is also given to the percentage of cations that are heavier than Na in the waters. [source] Accuracy and precision of different sampling strategies and flux integration methods for runoff water: comparisons based on measurements of the electrical conductivityHYDROLOGICAL PROCESSES, Issue 2 2006Patrick Schleppi Abstract Because of their fast response to hydrological events, small catchments show strong quantitative and qualitative variations in their water runoff. Fluxes of solutes or suspended material can be estimated from water samples only if an appropriate sampling scheme is used. We used continuous in-stream measurements of the electrical conductivity of the runoff in a small subalpine catchment (64 ha) in central Switzerland and in a very small (0·16 ha) subcatchment. Different sampling and flux integration methods were simulated for weekly water analyses. Fluxes calculated directly from grab samples are strongly biased towards high conductivities observed at low discharges. Several regressions and weighted averages have been proposed to correct for this bias. Their accuracy and precision are better, but none of these integration methods gives a consistently low bias and a low residual error. Different methods of peak sampling were also tested. Like regressions, they produce important residual errors and their bias is variable. This variability (both between methods and between catchments) does not allow one to tell a priori which sampling scheme and integration method would be more accurate. Only discharge-proportional sampling methods were found to give essentially unbiased flux estimates. Programmed samplers with a fraction collector allow for a proportional pooling and are appropriate for short-term studies. For long-term monitoring or experiments, sampling at a frequency proportional to the discharge appears to be the best way to obtain accurate and precise flux estimates. Copyright © 2006 John Wiley & Sons, Ltd. [source] Discrepancies between isotope ratio infrared spectroscopy and isotope ratio mass spectrometry for the stable isotope analysis of plant and soil watersRAPID COMMUNICATIONS IN MASS SPECTROMETRY, Issue 14 2010Adam G. West The use of isotope ratio infrared spectroscopy (IRIS) for the stable hydrogen and oxygen isotope analysis of water is increasing. While IRIS has many advantages over traditional isotope ratio mass spectrometry (IRMS), it may also be prone to errors that do not impact upon IRMS analyses. Of particular concern is the potential for contaminants in the water sample to interfere with the spectroscopy, thus leading to erroneous stable isotope data. Water extracted from plant and soil samples may often contain organic contaminants. The extent to which contaminants may interfere with IRIS and thus impact upon data quality is presently unknown. We tested the performance of IRIS relative to IRMS for water extracted from 11 plant species and one organic soil horizon. IRIS deviated considerably from IRMS for over half of the samples tested, with deviations as large as 46, (,2H) and 15.4, (,18O) being measured. This effect was reduced somewhat by using activated charcoal to remove organics from the water; however, deviations as large as 35, (,2H) and 11.8, (,18O) were still measured for these cleaned samples. Interestingly, the use of activated charcoal to clean water samples had less effect than previously thought for IRMS analyses. Our data show that extreme caution is required when using IRIS to analyse water samples that may contain organic contaminants. We suggest that the development of new cleaning techniques for removing organic contaminants together with instrument-based software to flag potentially problematic samples are necessary to ensure accurate plant and soil water analyses using IRIS. Copyright © 2010 John Wiley & Sons, Ltd. [source] Shrinkage of initially very wet soil blocks, cores and clods from a range of European Andosol horizonsEUROPEAN JOURNAL OF SOIL SCIENCE, Issue 2 2007F. Bartoli Summary In advanced stages of volcanic ash soil formation, when more clay is formed, soil porosity values and soil water retention capacities are large and the soils show pronounced shrinkage on drying. Soil shrinkage is a key issue in volcanic soil environments because it often occurs irreversibly when topsoils dry out after changes from permanent grassland or forest to agriculture. European Andosols have developed in a wide range of climatic conditions, leading to a wide range in intensity of both weathering and organo-mineral interactions. The question arises as to whether these differences affect their shrinkage properties. We aimed to identify common physically based shrinkage laws which could be derived from soil structure, the analysis of soil constituents, the selected sampling size and the drying procedure. We found that the final volumetric shrinkage of the initially field-wet (56,86% of total porosity) or capillary-wet (87,100% of total porosity) undisturbed soil samples was negatively related to initial bulk density and positively related to initial capillary porosity (volumetric soil water content of soil cores after capillary rise). These relationships were linear for the soil clods of 3,8 cm3, with final shrinkage ranging from 21.2 to 52.2%. For soil blocks of 240 cm3 and soil cores of 28.6 cm3 we found polynomial and exponential relationships, respectively, with thresholds separating shrinkage and nearly non-shrinkage domains, and larger shrinkage values for the soil cores than for the soil blocks. For a given sample size, shrinkage was more pronounced in the most weathered and most porous Andosol horizons, rich in Al-humus, than in the less weathered and less porous Andosol horizons, poor in Al-humus. The Bw horizons, being more weathered and more porous, shrank more than the Ah horizons. We showed that the structural approach combining drying kinetics under vacuum, soil water analysis and mercury porosimetry is useful for relating water loss and shrinkage to soil structure and its dynamics. We also found that the more shrinkage that occurred in the Andosol horizon, the more pronounced was its irreversible mechanical change. [source] The effect of environmental factors on the distribution of Neoparamoeba pemaquidensis in TasmaniaJOURNAL OF FISH DISEASES, Issue 10 2005M Douglas-Helders Abstract Aquaculture in Tasmania is mostly carried out in estuaries. These estuarine habitats show a great variety and form unique environments in which Neoparamoeba pemaquidensis, the amoebic gill disease (AGD)-causing protozoan, may or may not survive. Tasmania is divided into two zones, one where AGD is present and one where AGD is absent, but any ecological data to rationalize this distribution is lacking. In in vitro trials N. pemaquidensis strains were exposed to different concentrations of ammonium sulphate, copper sulphate, copper sulphate and tannin, and different Neoparamoeba densities, salinities and temperatures. A trial using field water samples investigated the survival of N. pemaquidensis in waters sourced from AGD-free and AGD-positive zones, and water analysis was performed to determine any differences. Significantly decreased protozoan survival was found with exposure to increasing copper sulphate concentrations from 10 to 100 000,m (P < 0.001), salinity of 15, (P < 0.001), low Neoparamoeba densities of 625 and 1250 cells mL,1 (P = 0.0005), and water sourced from Macquarie Harbour (P < 0.001). The water chemistry of this AGD-free zone showed significantly lower dissolved calcium and magnesium concentrations which may contribute to this area being AGD-free. Understanding of the ecology of N. pemaquidensis will enable better control and prevention strategies for Tasmanian salmon growers. [source] Automated stir plate (bar) sorptive extraction coupled to high-performance liquid chromatography for the determination of polycyclic aromatic hydrocarbonsJOURNAL OF SEPARATION SCIENCE, JSS, Issue 14 2010Chunhe Yu Abstract Automated methods of PDMS/,-CD/divinylbenzene-coated stir plate sorptive extraction (SPSE) coupled to HPLC-fluorescence detector were reported for the first time. Three automation modes, static SPSE, circular flow SPSE and continuous flow SPSE, were evaluated and critically compared with stir bar sorptive extraction by using six polycyclic aromatic hydrocarbons as model analytes. It was found that the operable sample volume for circular flow SPSE and continuous flow SPSE was larger than that for static SPSE. Under the same extraction conditions, continuous flow SPSE exhibited the highest extraction efficiencies in all automated modes and manual stir bar sorptive extraction for the target compounds. Compared with the manual operation (approximately 5,10,min), automated SPSE required a relatively short time (117,180,s) to finish sampling, washing and sample loading. Besides being labor-saving and time-saving, automated SPSE has other advantages, such as no time limit and non-attended operation. The proposed continuous flow PDMS/,-CD/divinylbenzene-coated SPSE-HPLC-fluorescence detector was successfully applied to environmental water analysis. 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