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Wavelength Dependence (wavelength + dependence)
Selected AbstractsWavelength dependence of the modal refractive index in 1.3 ,m InGaAsP, AlGaInAs and GaInNAs lasers using high pressurePHYSICA STATUS SOLIDI (B) BASIC SOLID STATE PHYSICS, Issue 2 2003S. R. Jin Abstract We report the variation of the modal refractive index at threshold with lasing wavelength in 1.3,,m InGaAsP, AlGaInAs and GaInNAs multiple quantum well lasers by measuring mode spectra under pressure up to 15,kbar. It is shown that the decrease of index with lasing wavelength is about 4% on average in the pressure range studied. We also find that the modal refractive index reduces with increasing injection current and is very sensitive to the injection current around laser threshold. [source] Radiative heat exchange modeling inside an ovenAICHE JOURNAL, Issue 9 2009Ashish Dhall Abstract The 3D nongray radiative heat exchange in a near-infrared commercial oven is modeled. The spectrum is divided into into four gray bands to model the narrow wavelength range in which the halogen heat source radiates, the wavelength dependence of the food surface emittance, and the absorption coefficient of the heat source cover glass. The model is used to estimate the heating of a cuboidal food sample for 1 min at different cyclic settings of a halogen radiant heat source. The model predictions agree with the experimental data, and capture the cover-glass and the food-surface temperature and heat flux histories very well. The band-wise distribution of energy absorption by the food reveals the separate contributions from the source and the oven walls. Comparison of the heating rates between the measured non-gray food-surface and the different gray food-surface emittance values establishes the necessity of the nongray treatment. © 2009 American Institute of Chemical Engineers AIChE J, 2009 [source] Determination of Scattering and Absorption Coefficients for Plasma-Sprayed Yttria-Stabilized Zirconia Thermal Barrier CoatingsJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 5 2008Jeffrey I. Eldridge Prediction of radiative transport through translucent thermal barrier coatings (TBCs) can only be performed if the scattering and absorption coefficients and index of refraction of the TBC are known. To date, very limited information on these coefficients, which depend on both the coating composition and the microstructure, has been available for the very commonly utilized plasma-sprayed 8 wt% yttria-stabilized zirconia (8YSZ) TBCs. In this work, the scattering and absorption coefficients of freestanding plasma-sprayed 8YSZ coatings were determined from room-temperature normal-incidence directional-hemispherical reflectance and transmittance spectra over the wavelength range from 0.8 to 7.5 ,m. Spectra were collected over a wide range of coating thickness from 60 to almost 900 ,m. From the reflectance and transmittance spectra, the scattering and absorption coefficients as a function of wavelength were obtained by fitting the reflectance and transmittance values predicted by a four flux model to the experimentally measured values at all measured 8YSZ thicknesses. While the combined effects of absorption and scattering were shown in general to exhibit a nonexponential dependence of transmittance on specimen thickness, it was shown that for sufficiently high absorption and optical thickness, an exponential dependence becomes a good approximation. In addition, the implications of the wavelength dependence of the plasma-sprayed 8YSZ scattering and absorption coefficients on (1) obtaining accurate surface-temperature pyrometer measurements and on (2) applying mid-infrared reflectance to monitor TBC delamination are discussed. [source] Very high contrast integral field spectroscopy of AB Doradus C: 9-mag contrast at 0.2 arcsec without a coronagraph using spectral deconvolution,MONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, Issue 4 2007Niranjan Thatte ABSTRACT We present an extension of the spectral deconvolution (SD) method to achieve very high contrast at small inner working radii. We apply the method to the specific case of ground-based adaptive optics fed integral field spectroscopy (without a coronagraph). Utilizing the wavelength dependence of the Airy and speckle patterns, we make an accurate estimate of the point spread function that can be scaled and subtracted from the data cube. The residual noise in the resulting spectra is very close to the photon noise from the starlight halo. We utilize the technique to extract a very high signal-to-noise ratio H - and K -band spectrum of AB Doradus (AB Dor) C, the low-mass companion to AB Dor A. By effectively eliminating all contamination from AB Dor A, the extracted spectrum retains both continuum and spectral features. The achieved 1, contrast is 9 mag at 0.2 arcsec, 11 mag at 0.5 arcsec, in 20 min exposure time, at an effective spectral bandwidth of 5.5 nm, proving that the method is applicable even in low-Strehl regimes. The SD method clearly demonstrates the efficacy of image slicer based integral field units in achieving very high contrast imaging spectroscopy at small angular separations, validating their use as high-contrast spectrographs/imagers for extreme adaptive optics systems. [source] Ascorbate Enhances Photogeneration of Hydrogen Peroxide Mediated by the Iris Melanin,PHOTOCHEMISTRY & PHOTOBIOLOGY, Issue 3 2008Albert R. Wielgus The iris in the human eye is exposed to UV and visible light transmitted by the cornea. This pigmented tissue is bathed with the aqueous humor (AqH), which contains high concentration of ascorbate. It has been postulated that the presence of ascorbate in AqH can contribute to increased photoproduction of H2O2 mediated by the iris melanin. In this study, we monitored generation of H2O2 induced by UV,VIS irradiation of bovine irides, bovine and human iris homogenates and iris melanin. Our data show that exogenous ascorbate significantly amplified the rate of H2O2 photoformation in all melanotic samples. Deactivation of endogenous catalase with NaN3 in bovine irides increased the level of the accumulated H2O2 in the bathing solution following sample irradiation. Photoformation of H2O2 in samples with exogenous ascorbate was accompanied by its photo-oxidation. Both photoprocesses exhibited significant wavelength dependence. EPR spectroscopy measurements showed that ascorbyl radical is an intermediate product of the ascorbate photo-oxidation. The photoproduction of H2O2 and photo-oxidation of ascorbate appear to be stoichiometric processes. No significant differences in the photoreactivity of iridial melanin from donors of different age and iris color was found. We postulate that also in vivo ascorbate increases the rate of iris melanin-mediated photoformation of H2O2 and its steady state concentration in AqH. [source] Coexistence of Domains with Distinct Order and Polarity in Fluid Bacterial Membranes,PHOTOCHEMISTRY & PHOTOBIOLOGY, Issue 1 2002Sharon Vanounou ABSTRACT In this study we sought the detection and characterization of bacterial membrane domains. Fluorescence generalized polarization (GP) spectra of laurdan-labeled Escherichia coli and temperature dependencies of both laurdan's GP and fluorescence anisotropy of 1,3-diphenyl-1,3,5-hexatriene (DPH) (rDPH) affirmed that at physiological temperatures, the E. coli membrane is in a liquid-crystalline phase. However, the strong excitation wavelength dependence of rlaurdan at 37°C reflects membrane heterogeneity. Time-resolved fluorescence emission spectra, which display distinct biphasic redshift kinetics, verified the coexistence of two subpopulations of laurdan. In the initial phase, <50 ps, the redshift in the spectral mass center is much faster for laurdan excited at the blue edge (350 nm), whereas at longer time intervals, similar kinetics is observed upon excitation at either blue or red edge (400 nm). Excitation in the blue region selects laurdan molecules presumably located in a lipid domain in which fast intramolecular relaxation and low anisotropy characterize laurdan's emission. In the proteo-lipid domain, laurdan motion and conformation are restricted as exhibited by a slower relaxation rate, higher anisotropy and a lower GP value. Triple-Gaussian decomposition of laurdan emission spectra showed a sharp phase transition in the temperature dependence of individual components when excited in the blue but not in the red region. At least two kinds of domains of distinct polarity and order are suggested to coexist in the liquid-crystalline bacterial membrane: a lipid-enriched and a proteo-lipid domain. In bacteria with chloramphenicol (Cam),inhibited protein synthesis, laurdan showed reduced polarity and restoration of an isoemissive point in the temperature-dependent spectra. These results suggest a decrease in membrane heterogeneity caused by Cam-induced domain dissipation. [source] High resolution near-field spectroscopy investigation of tilted InGaN quantum wellsPHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 7 2003F. Hitzel Abstract We studied the emission wavelength dependence of InGaN quantum wells on surface tilt. A sample was prepared by overgrowing an SiC substrate with etched trenches and was investigated by a high resolution near field optical spectroscope (spectroscopy SNOM). We found out that emission wavelength on tilted surfaces is strongly blue shifted even by small surface tilts of about 1 degree. Possible explanations for the blue shift are a reduced growth rate and therefore a reduced quantum well thickness, a reduced piezoelectric field or a different In incorporation during growth. The significance of each of these effects are discussed in this paper. [source] 4241: Optical characterization of PCOACTA OPHTHALMOLOGICA, Issue 2010TJTP VAN DEN BERG Purpose Opacification of the posterior capsule (PCO) is known to degrade visual function on both counts: small angle resolution (visual acuity and contrast sensitivity) as well as large angle light scatter (straylight). No studies have been performed to delineate the optical characteristics of PCO as a basis for explanation of these visual function defects. Methods Preparations of IOL-capsule combinations were harvested from donor eyes after removal of the cornea. They were mounted submersed in saline in an optical set-up, used earlier to characterize the optics of the crystalline lens (van den Berg et al. VR 1999). Illuminated by monochromatic beams of light, the light spreading originating from different areas of the preparation was measured as function of wavelength for different angles. Based on physical optics theory, the optical characteristics of PCO was derived. The data will be presented translated into the straylight parameter, directly comparable to the figures obtained in vivo using the clinical straylight meter (C-Quant from Oculus). Results Twenty successful preparations were harvested with at least some PCO areas. PCO grades varied from severe to slight. Two physically different types of light spreading could be discriminated. One type corresponding to pearl-like appearance, characterized by little wavelenght dependence and smal angle dominance. The other type corresponding to diffuse scatter, characterized by strong wavelength dependence and large angle dominance. The scatter values measured corresponded to clinical measures of straylight in PCO patients using the C-Quant. Conclusion The light scattering characteristics of PCO show two types of optical disturbance: a refractile type, probably dominated by pearl-like structures, and a diffuse type of scattering of yet unclear origin. [source] Femtosecond Time-Resolved Geometry Relaxation and Ultrafast Intramolecular Energy Redistribution in Ag2AuCHEMPHYSCHEM, Issue 2 2005Thorsten M. Bernhardt Dr. Abstract The ultrafast dynamics of the bimetallic cluster Ag2Au is investigated by pump,probe negative ion-to-neutral-to-positive ion (NeNePo) spectroscopy. Preparation of the neutral cluster in a highly nonequilibrium state by electron detachment from the mass-selected anion, and subsequent probing of the neutral nuclear dynamics through two-photon ionization to the cationic state, leads to strongly probe-energy-dependent transient cation-abundance signals. The origin of this pronounced time and wavelength dependence of the ionization probability on the femtosecond scale is revealed by ab initio theoretical simulations of the transient spectra. Based on the analysis of underlying dynamics, two fundamental processes involving geometry relaxation from linear to triangular structure followed by ultrafast intramolecular vibrational energy redistribution (IVR) have been identified and for the first time experimentally observed in the frame of NeNePo spectroscopy under conditions close to zero electron kinetic energy. [source] | |||||||||||||