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Various Densities (various + density)
Selected AbstractsSANISAND: Simple anisotropic sand plasticity modelINTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS, Issue 8 2008Mahdi Taiebat Abstract SANISAND is the name used for a family of simple anisotropic sand constitutive models developed over the past few years within the framework of critical state soil mechanics and bounding surface plasticity. The existing SANISAND models use a narrow open cone-type yield surface with apex at the origin obeying rotational hardening, which implies that only changes of the stress ratio can cause plastic deformations, while constant stress-ratio loading induces only elastic response. In order to circumvent this limitation, the present member of the SANISAND family introduces a modified eight-curve equation as the analytical description of a narrow but closed cone-type yield surface that obeys rotational and isotropic hardening. This modification enables the prediction of plastic strains during any type of constant stress-ratio loading, a feature lacking from the previous SANISAND models, without losing their well-established predictive capability for all other loading conditions including the cyclic. In the process the plausible assumption is made that the plastic strain rate decomposes in two parts, one due to the change of stress ratio and a second due to loading under constant stress ratio, with isotropic hardening depending on the volumetric component of the latter part only. The model formulation is presented firstly in the triaxial stress space and subsequently its multiaxial generalization is developed following systematically the steps of the triaxial one. A detailed calibration procedure for the model constants is presented, while successful simulation of both drained and undrained behavior of sands under constant and variable stress-ratio loadings at various densities and confining pressures is obtained by the model. Copyright © 2007 John Wiley & Sons, Ltd. [source] Dielectric properties of pharmaceutical materials relevant to microwave processing: Effects of field frequency, material density, and moisture contentJOURNAL OF PHARMACEUTICAL SCIENCES, Issue 2 2010Paul W.S. Heng Abstract The rising popularity of microwaves for drying, material processing and quality sensing has fuelled the need for knowledge concerning dielectric properties of common pharmaceutical materials. This article represents one of the few reports on the density and moisture content dependence of the dielectric properties of primary pharmaceutical materials and their relevance to microwave-assisted processing. Dielectric constants and losses of 13 pharmaceutical materials were measured over a frequency range of 1,MHz,1,GHz at 23,±,1°C using a parallel-electrode measurement system. Effects of field frequency, material density and moisture content on dielectric properties were studied. Material dielectric properties varied considerably with frequency. At microwave frequencies, linear relationships were established between cube-root functions of the dielectric parameters ( and ) and density which enabled dielectric properties of materials at various densities to be estimated by regression. Moisture content was the main factor that contributed to the disparities in dielectric properties and heating capabilities of the materials in a laboratory microwave oven. The effectiveness of a single frequency density-independent dielectric function for moisture sensing applications was explored and found to be suitable within low ranges of moisture contents for a model material. © 2009 Wiley-Liss, Inc. and the American Pharmacists Association J Pharm Sci 99:941,957, 2010 [source] Photocatalytic Coatings for Environmental Applications,PHOTOCHEMISTRY & PHOTOBIOLOGY, Issue 2 2005Norman S. Allen ABSTRACT A series of nano- and micronparticle-grade anatase and rutile titanium dioxide pigments have been prepared with various densities of surface treatments, particle size and surface area. Their photocatalytic activities have been determined in a series of paint films by FTIR, chalking, color, gloss change and weight loss after artificial weathering. The pigments have also been examined by rapid assessment methodologies using photodielectric microwave spectroscopy, 2-propanol oxidation and hydroxyl analysis. The microwave response under light and dark cycles provides an extended timescale probe of chargecarrier dynamics in the pigments. Pigment particle size, surface area and properties clearly play an important role in dispersion and any polymer-pigment interactions. Photooxidation studies on several types of paint films show a clear demarcation between nanoparticle- and pigmentary-grade titanium dioxide, with the former being more active because of their greater degree of catalytic surface activity. The photosensitivity of titanium dioxide is considered to arise from localized sites on the crystal surface (i.e. acidic OH), and occupation of these sites by surface treatments inhibits photoreduction of the pigment by ultraviolet radiation; hence, the destructive oxidation of the binder is inhibited. Coatings containing 2,5% by weight alumina or alumina and silica are satisfactory for generalpurpose paints. If greater resistance to weathering is desired, the pigments are coated more heavily to about 7,10% weight. The coating can consist of a combination of several materials, e.g. alumina, silica, zirconia, aluminum phosphates of other metals. For example, the presence of hydrous alumina particles lowers van der Waals forces between pigments particles by several orders of magnitude, decreasing particle-particle attractions. Hydrous aluminum oxide phases appear to improve dispersibility more effectively than most of the other hydroxides and oxides. Coated nanoparticles are shown to exhibit effective light stabilization in various water- and oilbased paint media in comparison with conventional organic stabilizers. Hindered piperidine stabilizers are shown to provide no additional benefits in this regard, often exhibiting strong antagonism. The use of photocatalytic titania nanoparticles in the development of self-cleaning paints and microbiological surfaces is also demonstrated in this study. In the former case, surface erosion is shown to be controlled by varying the ratio of admixture of durable pigmentary-grade rutile (heavily coated) and a catalytic-grade anatase nanoparticle. For environmental applications in the development of coatings for destroying atmospheric pollutants such as nitrogen oxide gases (NOX), stable substrates are developed with photocatalytic nanoparticle-grade anatase. In this study, porosity of the coatings through calcium carbonate doping is shown to be crucial in the control of the effective destruction of atmospheric NOx gases. For the development of microbiological substrates for the destruction of harmful bacteria, effective nanoparticle anatase titania is shown to be important, with hydrated high surface area particles giving the greatest activity. [source] The influence of light environment on photosynthesis and basal methylbutenol emission from Pinus ponderosaPLANT CELL & ENVIRONMENT, Issue 12 2005DENNIS W. GRAY ABSTRACT Methylbutenol is a 5-carbon alcohol that is produced and emitted by several species of pine in western North America, and may have important impacts on the tropospheric chemistry of this region. In the present study the response of methylbutenol basal emission rate (measured at a constant light intensity of 1500 µmol m,2 s,1 and temperature of 30 °C) to the light and temperature conditions of the growth environment was examined, using field-grown plants shielded with shade cloth of various densities. Methylbutenol basal emission rates increased linearly with the temperature of the growth environment but did not respond to the shading of foliage during growth and development. Both photosynthesis and basal methylbutenol emission rate declined in older needles; however, these declines appear to result from parallel but independent processes and not from basal MBO emission rate directly tracking photosynthetic rates. Older needles did not occupy cooler microenvironments within the canopy; and thus differing thermal microenvironment could not explain the reduced MBO emission in older needles. [source] Lolium multiflorum density responses under ozone and herbicide stressAUSTRAL ECOLOGY, Issue 8 2009M. ALEJANDRA MARTÍNEZ-GHERSA Abstract Adaptations to overcrowding of individual plants result in density dependant control of growth and development. There is little information on how anthropogenic stresses modify these responses. We investigated whether combinations of diclofop-methyl herbicide and tropospheric ozone alter the pattern of expected growth compensation with density changes resulting from intraspecific competition in Lolium multiforum Lam (Poacea) plants. Individual plant vegetative parameters and total seed production were assessed for plants growing under various densities and different herbicide rates and ozone treatments. The stressors differently changed the frequency distribution for average individual plant weight resulting from increasing densities. Only herbicide affected seedling mortality. Plants were able to compensate during grain filling maintaining similar seed production , density relationships in all treatments. Our findings contribute to the understanding of the impact of stress factors on the demographic changes in plant populations. Important ecological implications arise: (i) contrasting responses to ozone and herbicide, alone and in combination of individual plants resulted in different biomass , density relationships; (ii) stress effects on plant populations could not be predicted from individual responses; and (iii) changes in competitive outcome by single or combined stress factors may alter the expected genotype frequency in a crowded population with few dominant individuals. [source] | ||||||||||