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Various Cases (various + case)
Selected AbstractsReproducible protein analysis by CE using linear polyacrylamide-coated capillaries and hydrochloric acid rinsingELECTROPHORESIS, Issue 13 2007Adhitasari Suratman Abstract Hydrochloric acid was investigated as a rinsing reagent to remove adsorbed proteins from linear polyacrylamide-coated capillaries for electrophoresis. Three model proteins were used, namely cytochrome c as a basic protein, ,-lactoglobulin as an acidic protein, and ,-casein as a more easily denaturing protein. In order to regenerate capillary surfaces, they have been rinsed for 5,min with 2,M hydrochloric acid, 5,min with water, and then 30,min with buffer after every tenth run. It was found important to perform this regeneration procedure on time. The obtained results show good repeatability of the apparent EOF mobility with percentage RSDs below 3% (n,=,60) in various cases. These good results were mainly confirmed in long-term series with more than 200 runs each. Only very high concentrations (175,,M) of ,-lactoglobulin and ,-casein at pH,3.5 gave RSD% values above 5%. For these conditions, the further test of 85% m/m phosphoric acid as rinsing reagent showed a good repeatability of the apparent EOF mobilities as well. [source] Modelling electromagnetic responses of 2-D structures due to spatially non-uniform inducing fields.GEOPHYSICAL JOURNAL INTERNATIONAL, Issue 2 2003Analysis of magnetotelluric source effects at coastlines SUMMARY In previous works, we presented 2-D and 3-D magnetotelluric modelling methods based on Rayleigh,Fourier expansions. These methods are an alternative to finite-element and finite-difference techniques and are especially suitable for modelling multilayered structures, with smooth irregular boundaries. Here we generalize the 2-D method for the calculation of the electromagnetic response of 2-D structures to arbitrary, spatially non-uniform 2-D and 3-D inducing magnetic fields. These fields are characteristic of low- and high-latitude regions. We calculate the response to different 2-D and 3-D sources, of a 2-D structure representative of the conductivity distribution which could be found at a coastline, which includes deep conductive anomalies in the lower crust and upper mantle. Then, we investigate source effects, comparing these responses to that obtained for a uniform source. These effects become noticeable for periods greater than approximately 6 h and increase with the period of the source. They are highly dependent on the morphology of the source and also on the orientation of the external field relative to the strike direction of the structure. In various cases, they totally mask the uniform source response. [source] Numerical simulations of simple shear with non-coaxial soil modelsINTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS, Issue 1 2006Yunming Yang Abstract This paper investigates the effects of a non-coaxial model on simulated stress,strain behaviour of granular materials subject to simple shearing under various initial conditions. In most cases, a significant difference of predictions between coaxial and non-coaxial modelling is found during the early stage in shearing. With the increase in shearing, non-coaxial simulations approach and tend to coincide with coaxial simulations. It is also found that the roles of non-coaxial modelling in simulating simple shear behaviour are considerably influenced by hardening rules, flow rules, initial static lateral pressure coefficients. In some cases, the non-coaxial modelling gives a similar simulation as the coaxial modelling. In other cases, the non-coaxial modelling decreases the hardening response or softening response of materials, compared with the coaxial modelling. Under certain conditions, the predicted peak strength of materials with non-coaxial modelling is larger than that for coaxial modelling. Some of these observations can be attributed to the amount of principal stress rotation in various cases analysed. Others can be attributed to the difference between the directions of the non-coaxial plastic flow and those for coaxial plastic flow. Copyright © 2005 John Wiley & Sons, Ltd. [source] Generalization of robustness test procedure for error estimators.INTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN ENGINEERING, Issue 4 2005Part II: test results for error estimators using SPR Abstract In this part of the paper we shall use the formulation given in the first part to assess the quality of recovery-based error estimators using two recovery methods, i.e. superconvergent patch recovery (SPR) and recovery by equilibrium in patches (REP). The recovery methods have been shown to be asymptotically robust and superconvergent when applied to two-dimensional problems. In this study we shall examine the behaviour of the recovery methods on several three-dimensional mesh patterns for patches located either inside or at boundaries. This is performed by first finding an asymptotic finite element solution, irrespective of boundary conditions at far ends of the domain, and then applying the recovery methods. The test procedure near kinked boundaries is explained in a step-by-step manner. The results are given in a series of tables and figures for various cases of three-dimensional mesh patterns. It has been experienced that the full superconvergent property is generally lost due to presence of boundary layer solution and the definition of the recoveries near boundaries though the results of the robustness test is still within an acceptable range. Copyright © 2005 John Wiley & Sons, Ltd. [source] Comparison of entropy minimization principles in heat exchange and a short-cut principle: EoTDINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 11 2003F. Balkan Abstract In this paper the principles called ,equipartition of forces, EoF' and ,equipartition of entropy production, EoEP' are compared in minimizing the entropy production in heat exchange. Entropy production rates for various cases are calculated according to both principles. The calculations show that entropy productions calculated with EoEP principle are always smaller than those calculated with EoF principle although the differences are considerably small. It is also shown that the heat exchange with EoEP principle implied TH/TC=const. Additionally, a new approach, equipartition of temperature difference, EoTD, has been tested comparatively. Although the entropy production rates calculated by this approach are slightly larger than those of two other principles, it can be used as a new principle for quick determination. Copyright © 2003 John Wiley & Sons, Ltd. [source] BSSE-free hardness profiles of hydrogen bond exchange in the hydrogen fluoride dimerINTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, Issue 14 2006David Asturiol Abstract Hardness profiles are calculated for the hydrogen bond interchange in the hydrogen fluoride dimer; the study is carried out at the Hartree,Fock and second-order Møller,Plesset (MP2) levels of theory with three different basis sets. The basis set superposition error (BSSE) is corrected by means of the chemical Hamiltonian approach (CHA). Uncorrected and BSSE-corrected energy and hardness profiles are compared. Their analysis shows that hardness profiles do not lead to spurious minima as energy profiles do in various cases. The CHA methodology is shown to be valuable in the analysis of intermolecular interactions, with BSSE observed to carry smaller modifications on hardness profiles than on energy curves. © 2006 Wiley Periodicals, Inc. Int J Quantum Chem, 2006 [source] Low-dimensional models for real time simulations of catalytic monolithsAICHE JOURNAL, Issue 7 2009Saurabh Y. Joshi Abstract We present accurate low-dimensional models for real time simulation, control, and optimization of monolithic catalytic converters used in automobile exhaust treatment. These are derived directly by averaging the governing equations and using the concepts of internal and external mass transfer coefficients. They are expressed in terms of three concentration and two temperature modes and include washcoat diffusional effects without using the concept of the effectiveness factor. The models reduce to the classical two-phase models in the limit of vanishingly thin washcoat. The models are validated by simulating the transient behavior of a three-way converter for various cases and comparing the predictions with detailed solutions. It is shown that these new models are robust and accurate with practically acceptable error, speed up the computations by orders of magnitude, and can be used with confidence for the real time simulation and control of monolithic and other catalytic reactors. © 2009 American Institute of Chemical Engineers AIChE J, 2009 [source] Thermophoresis of axisymmetric aerosol particles along their axes of revolutionAICHE JOURNAL, Issue 1 2009Yu C. Chang Abstract The axisymmetric thermophoretic motion of an aerosol particle of revolution in a uniformly prescribed temperature gradient is studied theoretically. The Knudsen number is assumed to be small so that the fluid flow is described by a continuum model. A method of distribution of a set of spherical singularities along the axis of revolution within a prolate particle or on the fundamental plane within an oblate particle is used to find the general solutions for the temperature distribution and fluid velocity field. The jump/slip conditions on the particle surface are satisfied by applying a boundary-collocation technique to these general solutions. Numerical results for the thermophoretic velocity of the particle are obtained with good convergence behavior for various cases. For the axisymmetric thermophoresis of an aerosol spheroid with no temperature jump and frictional slip at its surface, the agreement between our results and the available analytical solutions is very good. The thermophoretic velocity of a spheroid along its axis of revolution in general increases with an increase in its axial-to-radial aspect ratio, but there are exceptions. For most practical cases of a spheroid with a specified aspect ratio, its thermophoretic mobility is not a monotonic function of its relative jump/slip coefficients and thermal conductivity. © 2008 American Institute of Chemical Engineers AIChE J, 2009 [source] Pseudo-reflection phenomena for singularities in thin elastic shellsMATHEMATICAL METHODS IN THE APPLIED SCIENCES, Issue 17 2003P. Karamian-Surville We consider problems of statics of thin elastic shells with hyperbolic middle surface subjected to boundary conditions ensuring the geometric rigidity of the surface. The asymptotic behaviour of the solutions when the relative thickness tends to zero is then given by the membrane approximation. It is a hyperbolic problem propagating singularities along the characteristics. We address here the reflection phenomena when the propagated singularities arrive to a boundary. As the boundary conditions are not the classical ones for a hyperbolic system, there are various cases of reflection. Roughly speaking, singularities provoked elsewhere are not reflected at all at a free boundary, whereas at a fixed (or clamped) boundary the reflected singularity is less singular than the incident one. Reflection of singularities provoked along a non-characteristic curve C are also considered. Copyright © 2003 John Wiley & Sons, Ltd. [source] Variability of the administered radioiodine doses for the treatment of hyperthyroidism in BelgiumCLINICAL ENDOCRINOLOGY, Issue 2 2006Marianne Tondeur Summary Objective,, When using radioiodine for hyperthyroidism there is no consensus regarding the administration of fixed or calculated doses. Guidelines do not specify the preferable approach or the parameters to use to calculate the dose. Therefore, the dose might be quite different with regard to the chosen procedure. This study was undertaken to evaluate the variability of the amount of radioiodine administered in Belgium in various cases of hyperthyroidism. Design and patients, Twenty-one Belgian nuclear medicine physicians received summarized clinical files from 10 patients suffering from overt hyperthyroidism (n = 7) or subclinical hyperthyroidism (n = 3). Five patients had homogeneous goiters, one had multinodular goiter, and four had hot nodule. Participants had to determine the radioiodine dose (millicuries, mCi) they would give in each case. Results,, Proposed doses varied between 2 mCi and 25 mCi. Mean proposed dose for nodular disease was 10·71 mCi; it was 6·79 mCi for homogeneous goiter. For individual cases, a difference between the lowest and the highest dose of more than 17 mCi was observed in more than 50% of the cases. Conclusions,, We believe that more precise guidelines are mandatory, underlying uncertainties, controversies but recommending however, as minimal and maximal doses to administer, as well as clinical and biological parameters, if any, to be taken into account in order to modulate these doses. [source] | |||||||||||||