Urea Hydrogen Peroxide (urea + hydrogen_peroxide)

Distribution by Scientific Domains


Selected Abstracts


ChemInform Abstract: Selective Oxidation of Uracil and Adenine Derivatives by the Catalytic System MeReO3/H2O2 and MeReO3/Urea Hydrogen Peroxide.

CHEMINFORM, Issue 14 2001
Raffaele Saladino
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]


Bis(salicylaldehyde-1,2-phenylene diimine)Mn(III) Chloride (Mn(III)-Salophen) Catalyzed Oxidation of Thiols to Symmetrical Disulfides Using Urea Hydrogen Peroxide (UHP) as Mild and Efficient Oxidant.

CHEMINFORM, Issue 1 2007
Bahador Karami
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF. [source]


Synthesis, Crystal Structure, and Catalytic Properties of Novel Dioxidomolybdenum(VI) Complexes with Tridentate Schiff Base Ligands in the Biomimetic and Highly Selective Oxygenation of Alkenes and Sulfides

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 5 2010
Abdolreza Rezaeifard
Abstract Four novel dioxidomolybdenum(VI) complexes [MoO2(Lx)(CH3OH)] have been synthesized, using 2[(E)-(2-hydroxy-2-phenylethylimino)methyl]phenol derivatives as tridentate ONO donor Schiff base ligands (H2Lx) and MoO2(acac)2. A monoclinic space group was determined by X-ray crystallography from single-crystal data of a sample of these new complexes. The epoxidation of alkenes by using tert -butyl hydroperoxide and oxidation of sulfides to sulfoxides by urea hydrogen peroxide were efficiently enhanced with excellent selectivity under the catalytic influence these new MoVI complexes. The high efficiency and relative stability of the catalysts have been observed by turnover numbers and UV/Vis investigations. The electron-poor and bulky ligands promoted the effectiveness of the catalysts. [source]


The influence of organic solvent and ionic liquids on the selective formation of 2-(2-ethylhexyl)-3-phenyl-1,2-oxaziridine mediated by lipases,

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, Issue 10 2010
Thiago Bergler Bitencourt
Abstract This paper describes the influence of the addition of ionic liquids (ILs) based on [BMIm][X], where [X],=,SCN, Cl, BF4, and PF6, on the chemo-enzymatic oxidation of N -benzyliden-2-ethylhexylamine to form the corresponding E- and Z -isomers of oxaziridines mediated by Pseudomonas sp. (PSL) and Candida antarctica (CAL-B) lipases in various organic solvents at room temperature (25,C) with urea hydrogen peroxide (UHP). The results showed that the use of different organic solvents in the presence of ILs, critically changes the conversions (5,99%) and the isomeric ratio E:Z, (50,100% E -isomer) of the products formed. Copyright 2010 John Wiley & Sons, Ltd. [source]