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Transfer Mechanism (transfer + mechanism)

Distribution by Scientific Domains
Chemistry38%
Engineering19%
Life Sciences14%
Polymers and Materials Science10%
Physics and Astronomy4%
Humanities and Social Sciences4%
4 Other Domains11%

Kinds of Transfer Mechanism

  • electron transfer mechanism
    		•
  • energy transfer mechanism
    		•
  • heat transfer mechanism
    		•

    Selected Abstracts

    Ratiometric Dual Fluorescent Receptors for Anions under Intramolecular Charge Transfer Mechanism.

    CHEMINFORM, Issue 10 2005
    Zhen-Chang Wen
    Abstract For Abstract see ChemInform Abstract in Full Text. [source]

    Nucleophilic Substitution Reaction of p -Dinitrobenzene by a Carbanion: Evidence for Electron Transfer Mechanism

    CHINESE JOURNAL OF CHEMISTRY, Issue 11 2002
    You-Cheng Liu
    Abstract On the basis of investigation of cyclic voltammetry, EPR spectroscopy and competition experiments, the nucleophilic substitution reaction of p - dinitrobenzene with the sodium salt of ethyl ,-cyanoacetate carbanion in dimethyl sulfoxide giving ethyl ,-cyano-,- (p-nitrophenyl) acetate is shown to take place via the intermediacy of p -dinitrobenzene radical anion. The reaction rate goes faster than that between p -nitrohalobenzenes and the same sodium salt of ethyl ,-cyanoacetate carbanion. There is an evidence for a single electron transfer mechanism. [source]

    Influence of Solid Phase Conductivity and Cellular Structure on the Heat Transfer Mechanisms of Cellular Materials: Diverse Case Studies,

    ADVANCED ENGINEERING MATERIALS, Issue 10 2009
    Eusebio Solórzano
    An analysis on the influence of solid phase thermal conductivity and cellular structure on the heat transfer mechanisms (HTMs) by means of studding diverse case studies combining theoretical and experimental data. The radiation and conduction mechanisms have been analyzed for cellular materials based on insulating and conductive matrixes using similar concepts and models for both types of materials. [source]

    Evaluation of Mass Transfer Mechanisms During Osmotic Treatment of Plant Materials

    JOURNAL OF FOOD SCIENCE, Issue 6 2000
    N.K. Rastogi
    ABSTRACT: The proportion of intact, damaged, and ruptured (non-intact) cells (Zp) due to osmotic stress during osmotic treatment of potato was monitored using electrophysical measurement based on electrical impedance analysis. Osmotic stress on potato cell culture made cell membranes shrink thereby damaging the cells. The proportion of the ruptured and shrunk cells within the samples increased with the increase in concentration of solute in the osmotic solution. The osmotic removal of water from thin potato slices started at a critical osmotic pressure. Once the critical osmotic pressure was exceeded, mass transfer was rapid and the cells lost substantial amounts of water due to rupture of cell membranes. [source]

    Assessing the Risk of Introducing Exotic Species via the Live Marine Species Trade

    CONSERVATION BIOLOGY, Issue 1 2005
    SHANNON M. WEIGLE
    especies estuarinas; introducción de especies; mecanismos de transferencia de especies invasoras; prevención de especies invasoras; riesgo de invasiones Abstract:,Although the shipping industry has received considerable attention as a dispersal mechanism for aquatic nuisance species, many invasions have been linked to other mechanisms of transfer. The threat posed to coastal ecosystems by these alternative mechanisms, however, remains largely unquantified. We assessed the potential risks of introducing marine and estuarine species associated with seven mechanisms of transfer: seafood companies, aquaculture operations, bait shops, stores that sell marine ornamental species, research and educational organizations, public aquariums, and coastal restoration projects. For each, we compiled a comprehensive database of organizations in coastal Massachusetts. We then designed and administered a survey to a subset of organizations that inquired about (1) their proximity to saltwater and methods of handling live imports; (2) the type and quantity of marine species being imported; and (3) the organization's familiarity with marine invasions. Respondents in five of the seven categories acknowledged importing nonlocal live marine species to the area. Seafood companies handled the majority of individuals but relatively few taxa. This mechanism of transfer also had the most complex trade patterns and the greatest number of operations located near saltwater. In contrast, the other transfer mechanisms each had simpler trade pathways and fewer operations but varied in the quantity and taxonomic diversity of their imports. Significantly, no single mechanism of transfer stood out as presenting a primary risk. Rather, each had characteristics or used handling practices at different points in the importation process that could facilitate introductions. To prevent future marine invasions, better reporting requirements for live species imports are needed, and best-management practices and outreach strategies specific to the transfer mechanism should be developed and implemented. Resumen:,Aunque la industria de transportación marítima ha recibido considerable atención como un mecanismo de dispersión de especies acuáticas molestas, muchas invasiones han sido relacionadas con otros mecanismos de transferencia. Sin embargo, la amenaza de estos mecanismos alternativos a los ecosistemas costeros permanece en gran parte sin cuantificar. Evaluamos los potenciales riesgos para especies marinas y estuarinas asociados con siete mecanismos de transferencia: compañías de mariscos, operaciones acuaculturales, tiendas de especies marinas ornamentales, organizaciones de investigación y educativas, acuarios públicos y proyectos de restauración costera. Para cada uno, compilamos una amplia base de datos de organizaciones en la costa de Massachussetts. Luego diseñamos y aplicamos una encuesta a un subconjunto de organizaciones para obtener información sobre (1) su proximidad al agua marina y sus métodos para el manejo de importaciones vivas, (2) el tipo y cantidad de especies marinas importadas y (3) la familiaridad de la organización con invasiones marinas. Evaluamos los potenciales riesgos de introducciones de especies marinas y estuarinas. Los encuestados en cinco de siete categorías reconocieron importar especies marinas vivas no locales al área. Las compañías de mariscos manejaron a la mayoría de los individuos pero relativamente pocos taxa. Este mecanismo de transferencia también tuvo los patrones comerciales más complejos y el mayor número de operaciones localizadas cerca de agua marina. En contraste, cada uno de los demás mecanismos de transferencia tuvo canales de comercialización más simples y menos operaciones, pero variaron en la cantidad y diversidad taxonómica de sus importaciones. Significativamente, ningún mecanismo individual resaltó como un riesgo primario. Más bien, cada uno tenía características o utilizaba prácticas de manejo en diferentes etapas del proceso de importación que podían facilitar las introducciones. Para prevenir futuras invasiones marinas, se necesitan mejores requerimientos para reportar la importación de especies vivas, y se deben desarrollar e implementar prácticas de manejo óptimo y estrategias de extensión específicas para el mecanismo de transferencia. [source]

    Development and validation of a metallic haunch seismic retrofit solution for existing under-designed RC frame buildings

    EARTHQUAKE ENGINEERING AND STRUCTURAL DYNAMICS, Issue 14 2006
    Stefano Pampanin
    Abstract The feasibility and efficiency of a seismic retrofit solution for existing reinforced concrete frame systems, designed before the introduction of modern seismic-oriented design codes in the mid 1970s, is conceptually presented and experimentally investigated. A diagonal metallic haunch system is introduced at the beam,column connections to protect the joint panel zone from extensive damage and brittle shear mechanisms, while inverting the hierarchy of strength within the beam,column subassemblies and forming a plastic hinge in the beam. A complete step-by-step design procedure is suggested for the proposed retrofit strategy to achieve the desired reversal of strength hierarchy. Analytical formulations of the internal force flow at the beam,column-joint level are derived for the retrofitted joints. The study is particularly focused on exterior beam,column joints, since it is recognized that they are the most vulnerable, due to their lack of a reliable joint shear transfer mechanism. Results from an experimental program carried out to validate the concept and the design procedure are also presented. The program consisted of quasi-static cyclic tests on four exterior, , scaled, beam,column joint subassemblies, typical of pre-1970 construction practice using plain round bars with end-hooks, with limited joint transverse reinforcement and detailed without capacity design considerations. The first (control specimen) emulated the as-built connection while the three others incorporated the proposed retrofitted configurations. The experimental results demonstrated the effectiveness of the proposed solution for upgrading non-seismically designed RC frames and also confirmed the applicability of the proposed design procedure and of the analytical derivations. Copyright © 2006 John Wiley & Sons, Ltd. [source]

    The Influence of Doping Levels and Surface Termination on the Electrochemistry of Polycrystalline Diamond

    ELECTROANALYSIS, Issue 6 2004
    Matthew
    Abstract The influence of surface chemistry and boron doping density on the redox chemistry of Fe(CN) at CVD polycrystalline diamond electrodes is considered. It is demonstrated that for this couple both the doping density and the surface chemistry are important in determining the rate of charge transfer at the electrode/electrolyte interface. For hydrogen terminated CVD diamond metallic electrochemical behavior is always observed, even at boron doping densities as low as 7×1018,cm,3. In contrast, the electrochemical behavior of oxygen terminated CVD diamond varies with doping density, a metallic response being observed at high doping density and semiconductor behavior at low doping density. It is shown that the results attained may be explained by a surface state mediated charge transfer mechanism, thus demonstrating the importance of controlling surface chemistry in electroanalytical applications of diamond. [source]

    Exploring the primary electron acceptor (QA)-site of the bacterial reaction center from Rhodobacter sphaeroides

    FEBS JOURNAL, Issue 4 2002
    Binding mode of vitamin K derivatives
    The functional replacement of the primary ubiquinone (QA) in the photosynthetic reaction center (RC) from Rhodobacter sphaeroides with synthetic vitamin K derivatives has provided a powerful tool to investigate the electron transfer mechanism. To investigate the binding mode of these quinones to the QA binding site we have determined the binding free energy and charge recombination rate from QA, to D+ (kAD) of 29 different 1,4-naphthoquinone derivatives with systematically altered structures. The most striking result was that none of the eight tested compounds carrying methyl groups in both positions 5 and 8 of the aromatic ring exhibited functional binding. To understand the binding properties of these quinones on a molecular level, the structures of the reaction center-naphthoquinone complexes were predicted with ligand docking calculations. All protein,ligand structures show hydrogen bonds between the carbonyl oxygens of the quinone and AlaM260 and HisM219 as found for the native ubiquinone-10 in the X-ray structure. The center-to-center distance between the naphthoquinones at QA and the native ubiquinone-10 at QB (the secondary electron acceptor) is essentially the same, compared to the native structure. A detailed analysis of the docking calculations reveals that 5,8-disubstitution prohibits binding due to steric clashes of the 5-methyl group with the backbone atoms of AlaM260 and AlaM249. The experimentally determined binding free energies were reproduced with an rmsd of ,,4 kJ·mol,1 in most cases providing a valuable tool for the design of new artificial electron acceptors and inhibitors. [source]

    An epidemic of plasmids?

    FEMS IMMUNOLOGY & MEDICAL MICROBIOLOGY, Issue 2 2008
    Dissemination of extended-spectrum cephalosporinases among Salmonella, other Enterobacteriaceae
    Abstract CTX-M- and AmpC-type ,-lactamases comprise the two most rapidly growing populations among the extended-spectrum cephalosporinases. The evolution and dissemination of resistance genes encoding these enzymes occur mostly through the transmission of plasmids. The high prevalence of clinical isolates of Enterobacteriaceae producing the plasmid-mediated extended-spectrum cephalosporinases resembles an epidemic of plasmids, and has generated serious therapeutic problems. This review describes the emergence and worldwide spread of various classes of plasmid-mediated extended-spectrum cephalosporinases in Salmonella and other Enterobacteriaceae, the transfer mechanism of the plasmids, detection methods, and therapeutic choices. [source]

    A quantitative identification technique for a two-dimensional subsurface defect based on surface temperature measurement

    HEAT TRANSFER - ASIAN RESEARCH (FORMERLY HEAT TRANSFER-JAPANESE RESEARCH), Issue 4 2009
    Chunli Fan
    Abstract The inverse identification of a subsurface defect boundary is an important part of an inverse heat conduction problem, and is also the basis for the quantitative development of a nondestructive thermographic inspection technique. For the commonly encountered quantitative thermographic defect identification problem when the test piece is heated from one part of the outer boundary, our previous study showed that some parts of the defect boundary are sensitive to the initial defect boundary prediction of the conjugate gradient method. In this paper, the heat transfer mechanism inside a test piece with this problem is analyzed by building a two-dimensional model. A new method, the multiple measurements combination method (MMCM), is also presented which combines the identification algorithm study with the optimization of the thermographic detection technique to solve the problem. Numerical experiments certified the effectiveness of the present method. The temperature measurement error and the initial prediction of the defect boundary shape have little effect on the identification result. © 2009 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/htj.20251 [source]

    Effect of pressure on thermal aspects in the riser column of a pressurized circulating fluidized bed

    INTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 3 2006
    A. V. S. S. K. S. Gupta
    Abstract In the present paper the effect of pressure on bed-to-wall heat transfer in the riser column of a pressurized circulating fluidized bed (PCFB) unit is estimated through a modified mechanistic model. Gas,solid flow structure and average cross-sectional solids concentration play a dominant role in better understanding of bed-to-wall heat transfer mechanism in the riser column of a PCFB. The effect of pressure on average solids concentration fraction ,c' in the riser column is analysed from the experimental investigations. The basic cluster renewal model of an atmospheric circulating fluidized bed has been modified to consider the effect of pressure on different model parameters such as cluster properties, gas layer thickness, cluster, particle, gas phase, radiation and bed-to-wall heat transfer coefficients, respectively. The cluster thermal conductivity increases with system pressure as well as with bed temperature due to higher cluster thermal properties. The increased operating pressure enhances the particle and dispersed phase heat transfer components. The bed-to-wall heat transfer coefficient increases with operating pressure, because of increased particle concentration. The predicted results from the model are compared with the experimentally measured values as well as with the published literature, and a good agreement has been observed. The bed-to-wall heat transfer coefficient variation along the riser height is also reported for different operating pressures. Copyright © 2005 John Wiley & Sons, Ltd. [source]

    Fundamental heat transfer mechanism between bed-to-membrane water-walls in circulating fluidized bed combustors

    INTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 9 2003
    B.V. Reddy
    Abstract In the present work, the fundamental mechanism between bed-to-membrane water-walls in the riser column of a circulating fluidized bed (CFB) combustor is presented. The bed-to-membrane water-wall heat transfer depends on the contributions of particle heat transfer, dispersed phase heat transfer and radiation heat transfer. The fundamental mechanism of particle heat transfer and the effect of fraction of wall exposed to clusters and gas gap thickness between cluster and wall on particle heat transfer coefficient and bed-to-wall heat transfer coefficient are investigated. The influence of operating parameters like cross-sectional average volumetric solids concentration and bed temperature on particle and bed-to-wall heat transfer are also reported. The present work contributes some fundamental information on particle heat transfer mechanism, which is responsible for increasing the bed-to-wall heat transfer coefficient (apart from dispersed phase convection and radiation heat transfer). The details on particle heat transfer mechanism will enable to understand the basic heat transfer phenomena between bed-to-membrane water-walls in circulating fluidized bed combustors in a detailed way, which in turn will aid for better design of CFB combustor units. The particle heat transfer mechanism is significantly influenced by the fraction of wall exposed to clusters and gas gap thickness between clusters and wall. Copyright © 2003 John Wiley & Sons, Ltd. [source]

    Effect of pressure and temperature on cluster and particle heat transfer in a pressurized circulating fluidized bed

    INTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 14 2001
    B. V. Reddy
    Abstract The present work reports the influence of pressure and bed temperature on particle-to-wall heat transfer in a pressurized circulating fluidized bed (PCFB). The particle convection heat transfer plays a dominant role in determining the bed-to-wall heat transfer coefficient. So far, no information is reported on the effect of pressure and bed temperature on particle-to-wall heat transfer in a PCFB in the published literature. The present investigation reports some information in this direction. The effect of system pressure and bed temperature are investigated to study their influence on cluster and particle heat transfer. The particle convection heat transfer coefficient increases with system pressure and bed temperature due to higher cluster thermal conductivity. The increase in particle concentration (suspension density) results in greater cluster solid fraction and also the particle concentration near the wall is enhanced. This results in higher cluster and particle convection heat transfer between the bed and the wall. Higher particle convection heat transfer coefficient results in enhanced heat transfer between the bed and the wall. The results will also help to understand the bed-to-wall heat transfer mechanism in a better way in a PCFB. Copyright © 2001 John Wiley & Sons, Ltd. [source]

    Polymer characterization by ultrasonic wave propagation

    ADVANCES IN POLYMER TECHNOLOGY, Issue 2 2008
    Francesca Lionetto
    Abstract The propagation of low-intensity ultrasound in polymers, acting as a high-frequency dynamic mechanical deformation, can be successfully used to monitor changes in the modulus of polymers associated with glass transition, crystallization, cross-linking, and other chemical and physical phenomena related to changes in the viscoelastic behavior, such as gelation phenomena. The velocity of sound is related to the polymer storage modulus and density, whereas the absorption of ultrasonic waves is related to the energy dissipation in the material and, therefore, to the loss modulus. Accordingly, ultrasonic measurements have been used by several authors to monitor the evolution of the viscoelastic moduli of polymers as a function of time or temperature and, recently, become a characterization technique of its own right, generally known as ultrasonic dynamic mechanical analysis (UDMA). Often the technique is used in conjunction with rheological methods as a means of providing a better insight into the viscoelastic behavior of polymer systems. As yet UDMA is underutilized primarily because of the low operating temperatures (usually below 100,C) of commercially available ultrasonic transducers, and also due to the requirement of a coupling medium to ensure an efficient energy transfer mechanism between the transducer and the test material. Despite these limitations, this paper shows that the use of ultrasonics is potentially a powerful method for the characterization of polymers, particularly as a tool for online monitoring of events occurring during polymer processing and in the manufacture of polymer matrix composites. The aim of this paper is to review the progress made in recent years, highlighting the potential and reliability of UDMA for monitoring physical transitions in polymers such as glass transition, melting, crystallization, as well as physical changes taking place during curing of thermosetting resins. © 2009 Wiley Periodicals, Inc. Adv Polym Techn 27:63,73, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/adv.20124 [source]

    Fat Migration in Chocolate: Diffusion or Capillary Flow in a Particulate Solid?,A Hypothesis Paper

    JOURNAL OF FOOD SCIENCE, Issue 7 2004
    J. M. Aguilera
    ABSTRACT: The exact mechanism of fat and oil migration in chocolate and chocolate coatings is still unknown. Nevertheless, the so-called "diffusion equation" derived from Fick's 2nd law has been extensively used to model the phenomenon, giving the impression that molecular diffusion is the single transport mechanism. We propose that chocolate may be microstructurally regarded as a particulate medium formed by an assembly of fat-coated particles (for example, cocoa solids, sugars crystals, and milk powder). Within this matrix the liquid fraction of cocoa fat (which increases with temperature) is likely to move under capillary forces through interparticle passages and connected pores. Based on available evidence (microstructure, kinetic data, temperature dependence of liquid fat fraction, and so on) we demonstrate that capillary forces may have an important role to play in bulk flow of liquid fat and oils. The Lucas-Washburn equation for capillary rise fits available data under most reported experimental conditions. Detailed microstructural analysis in actual products as well as data on key parameters (surface tension, contact angle, viscosity) is necessary to confirm this hypothesis. Bulk flow due to capillary effects, highly disregarded in structured foods, should be considered as a mass transfer mechanism in liquid-filled porous or particulate foods. [source]

    Convection, diffusion, and exothermic zero-order reaction in a porous catalyst slab: Scaling and perturbation analysis

    AICHE JOURNAL, Issue 10 2009
    João P. Lopes
    Abstract The analysis of the interaction between transport phenomena and chemical reaction inside large-pore catalyst particles needs to include intraparticular convection as an additional mass/heat transfer mechanism. In this work, we describe by a 3D regime diagram the global behavior of a permeable catalyst slab, where an exothermic, zero-order reaction is occurring. An order of magnitude estimate for the maximum temperature change is obtained by scaling techniques in each regime of operation. Specific operating regimes of fast mass/heat transport, dominant reaction and strong intraparticular convection, are then studied in more detail using perturbation analysis. The results include approximate concentration and temperature profiles, which allow the estimation of both the effectiveness factor and maximum temperature attained inside the catalyst in these regimes. © 2009 American Institute of Chemical Engineers AIChE J, 2009 [source]

    Addition, elimination, exchange, and epimerization in nitro sulfones

    JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, Issue 3 2007
    Charles A. Kingsbury
    Abstract Three reactions were studied in the diastereomers of 1-(benzenesulfonyl)-2-nitro-1-phenylpropane (1A and 1B) and briefly in related compounds: elimination of the benzenesulfonyl group, epimerization of one diastereomer to the other, and deuterium/hydrogen exchange at the methine group next to nitro in starting material. The two diastereomers showed quite different reactivity. The high melting diasteromer showed rapid elimination and some exchange. The low melting diastereomer (at approximately a half-life) showed extensive epimerization, and elimination to the alkene, but little exchange. There is little effect of aromatic substituents on reaction course. The situation is complicated by re-addition of benzenesulfinate to the alkene. The addition reaction was similar to elimination in agreement with the Principle of Microscopic Reversibility expectations. An electron transfer mechanism for addition is calculated to be comparatively favorable. Copyright © 2007 John Wiley & Sons, Ltd. [source]

    Outer-sphere electron transfer metal-catalyzed polymerization of styrene using a macrobicyclic ligand

    JOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 1 2008
    Craig A. Bell
    Abstract The CuBr-catalyzed polymerizations of styrene in the presence of a macrobicyclic mixed donor (N and S) encapsulating ligand, NH2capten, were carried out in toluene at 60 and 100 °C. The macrobicyclic nature of the ligand ensures that a transition metal ion is effectively encapsulated (caged) within the three-dimensional cavity, resulting in activation of radicals through an outer-sphere electron transfer mechanism. The kinetic data showed that the polymerizations were uncontrolled with little "living" behavior. The external orders of reaction in [CuBr], [NH2capten], and [CuBr2] were 0.5, 0.5, and close to zero, respectively, in agreement with the postulated mechanism of little or no deactivation of polymeric radicals and a significant amount of bimolecular termination. Although "living" behavior was not found using the cage ligand, it was decided that it would provide an ideal method for radical coupling experiments to make high-molecular weight multiblock copolymers from a difunctional PSTY (Br-PSTY-Br, PDI = 1.11). The coupling reaction of Br-PSTY-Br using CuBr/NH2capten and excess Cu(0) in toluene at 100 °C gave no loss of the starting Br-PSTY-Br. Changing the solvent to the aprotic DMSO resulted in a significant increase in the rate of consumption of starting Br-PSTY-Br, with over 87% being used in under 10 min at 60 °C. In addition, higher molecular weight species were also formed, suggesting that OSET gives little or no side reactions on this time scale. It was initially thought that to get such high rates of reaction that the SET-LRP disproportionation mechanism (2Cu(I) , Cu(0) + Cu(II)) was at play. However, UV,Vis experiments of the CuBr/NH2capten showed little or no disproportionation products. This important result suggests that DMSO catalyzes the OSET reaction through the stabilization of the radical-anion intermediate, which then rapidly fragments to a polymeric radical. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 146,154, 2008 [source]

    The relaxations of temporal bond polarizabilities of methylviologen adsorbed on the Ag electrode by 514.5 nm excitation: a Raman intensity study

    JOURNAL OF RAMAN SPECTROSCOPY, Issue 3 2009
    Chao Fang
    Abstract An algorithm to elucidate the temporal bond polarizabilities from the surface enhanced Raman (SERS) intensities was employed to the case of methylviologen (MV) adsorbed on the Ag electrode. This enables us to obtain the properties of its SERS mechanisms and the effect of its adsorption. The analysis shows that the charge transfer and electromagnetic mechanisms involving in this MV SERS system possess different relaxation times for its various temporal bond polarizabilities. The physics is that the process involved in the charge transfer mechanism will take longer time than that involved in the electromagnetic mechanism since it needs more time to redistribute the charges during relaxation. The time division between these two mechanisms is figured out to be around 3 ps for this system. Adsorption also enhances the relaxation of the temporal bond polarizabilities, in general. The adsorption effect is indicated by the temporal bond polarizabilities close to the final stage of relaxation. They are, in fact, the quantities parallel to the bond electronic densities in the molecular orbital (MO) concept. For comparison, the case of MV solid was also analyzed. Copyright © 2008 John Wiley & Sons, Ltd. [source]

    The Role of Allylanisole in Metallocene-Catalyzed Propylene Polymerization and Synthesis of End-Capped Oligomers

    MACROMOLECULAR REACTION ENGINEERING, Issue 4 2008
    Muhammad Atiqullah
    Propylene was copolymerized with allylanisole (AA) using Me2Si(Ind)2ZrCl2 and Et(Ind)2ZrCl2, and the methylaluminoxane MAO cocatalyst at 70,°C and a cocatalyst to catalyst (Al:Zr) molar ratio of 1,000. It was fed at 8.5 bar(g). The weight-average molecular weight, , for both metallocenes decreased as the AA feed concentration increased. Therefore, allylanisole acted as an in situ chain transfer agent. The chain transfer constants, ktr/kp, of AA for Et(Ind)2ZrCl2 and Me2Si(Ind)2ZrCl2 turned out to be 0.33 and 0.40, respectively. The characterization of the resulting products by 1H NMR demonstrated that AA end-capped the isotactic poly(propylene) chains which showed to be low molecular weight oligomers; 4.96,×,103,,,,,,9.80,×,103. An appropriate chain transfer mechanism for AA has been proposed. [source]

    Addition-Fragmentation Chain Transfer to Polymer in the Free Radical Ring-Opening Polymerization of an Eight-membered Cyclic Allylic Sulfide Monomer

    MACROMOLECULAR THEORY AND SIMULATIONS, Issue 2 2005
    Marisa Phelan
    Abstract Summary: A detailed investigation of chain transfer to polymer during free radical ring-opening polymerization of the eight-membered disulfide monomer 2-methyl-7-methylene-1,5-dithiacyclooctane (MDTO) is presented. It has been shown that extensive chain transfer to polymer occurs involving both poly(MDTO) radicals and cyanoisopropyl radicals. Significant decreases in molecular weight were observed when cyanoisopropyl radicals were generated in the presence of poly(MDTO) in the absence of monomer. The molecular weight distribution (MWD) obtained from polymerization of MDTO in the presence of pre-added poly(MDTO) was markedly different from that obtained without pre-added polymer. A kinetic model was constructed in an attempt to quantitatively describe the chain transfer to polymer process based on the addition fragmentation chain transfer mechanism. It was found however that the simulated MWDs were considerably broader than the experimental MWDs, which were similar to the Schulz-Flory distribution. Mechanism for chain transfer to polymer. [source]

    A phenomenon of waiting time in phase change problems driven by radiative heat transfer

    MATHEMATICAL METHODS IN THE APPLIED SCIENCES, Issue 9 2009
    A. Fasano
    Abstract In the paper (J. Food Process Eng. 2008; in press) we emphasized that during a phase change process in which the heat input is driven by a radiation transfer mechanism, a peculiar phenomenon may occur, characterized by a temporary stop of the increase of the boundary temperature due to a sudden change of the heat transfer coefficient upon phase transition. This time interval is needed to allow the thermal properties of the surface to evolve toward a state that is compatible with the heat intake rate corresponding to the new phase. The occurrence of the waiting time is motivated and studied for a general one-dimensional Stefan problem. Then an application is presented to the much complicated problem considered in (J. Food Process Eng. 2008; in press), namely, the model for frying process. Copyright © 2008 John Wiley & Sons, Ltd. [source]

    Wettbewerb in kapitalgedeckten Krankenversicherungssystemen: Ein risikogerechter Ansatz zur Übertragung von Alterungsrückstellungen in der Privaten Krankenversicherung

    PERSPEKTIVEN DER WIRTSCHAFTSPOLITIK, Issue 2 2008
    Martin Nell
    Therefore the transfer of ,individual ageing provisions, has been discussed for many years, but it is mostly regarded as impracticable due to information and incentive problems. In this article a transfer mechanism based consequently on the risk allocation in the PKV is derived. This mechanism can solve the information and incentive problems linked with the transfer of ageing provisions. The result is that the PKV can be extended to a very attractive model to organize health insurance markets. [source]

    Photophysics and Photochemistry of z -Chlorprothixene in Acetonitrile,

    PHOTOCHEMISTRY & PHOTOBIOLOGY, Issue 4 2009
    Luis E. Piñero
    Chlorprothixene (CPTX, Taractan®) is a low potency antipsychotic mainly used for the treatment of psychotic disorders (e.g. schizophrenia) and acute mania occurring as part of bipolar disorders. As in the case of other numerous drugs used in the treatment of psychiatric disorders, CPTX presents geometric isomerism. Therefore, in vitro irradiation induces a rapid Z/E isomerization, which can affect its pharmacokinetic properties. This photoisomerization is not dependent on the oxygen concentration. The Z/E quantum yields determined for zCPTX in acetonitrile are 0.22 and 0.21 in anaerobic and aerobic environments, respectively. In the presence of water, both isomers decompose to produce 2-chlorothioxanthone (CTX) after prolonged irradiation. This process strongly depends on the water concentration and the irradiation time, i.e. it is autocatalyzed by the CTX through a triplet-energy transfer mechanism. The protonation state of the terminal amino group, on the other hand, has no effect on the isomerization process, but inhibits the formation of CTX. These results indicate that the phototoxicity of zCPTX is somehow affected by the formation of CTX. [source]

    Photophysical Properties of Terbium Molecular-based Hybrids Assembled with Novel Ureasil Linkages

    PHOTOCHEMISTRY & PHOTOBIOLOGY, Issue 4 2007
    Bing Yan
    Three silica-based organic,inorganic hybrid systems composed of hydroxyl aromatic derivatives (2-acetylphenol [HAP], 2-hydroxy-3-methylbenzoic acid [HMBA], 3-hydroxy-meta-phthalic acid [HMPHTH] complexes) were prepared via a sol,gel process. The active hydroxyl groups of the three ligands grafted by 3-(triethoxysilyl)-propyl isocyanate (TESPIC) through hydrogen transfer addition reaction were used as multi-functional bridge components, which can coordinate to Tb3+ with carbonyl groups, strongly absorb ultraviolet light and effectively transfer energy to Tb3+ through their triplet excited state, as well as undergo polymerization or crosslinking reactions with tetraethoxysilane (TEOS), for anchoring terbium ions to silica backbone. NMR, FT-IR, UV,vis absorption, luminescence spectroscopy was used to investigate the obtained hybrid material. UV excitation in the organic component resulted in strong green emission from Tb3+ ions due to an efficient ligand-to-metal energy transfer mechanism. [source]

    Survey of heat transfer mechanisms in a slurry bubble column

    THE CANADIAN JOURNAL OF CHEMICAL ENGINEERING, Issue 5 2001
    Hanning Li
    Abstract Heat transfer mechanisms in the bulk and distributor regions of a slurry bubble column are investigated based on the measurements of local heat transfer in a 0.28 m diameter Plexiglas column. The gas, liquid and solid phases used are oil-free compressed air, tap water and 35 ,m glass beads. The slurry concentration and superficial gas velocity are varied from 0 to 40 vol% and 0.05 to 0.30 m/s respectively. Measurements have been made with a fast response heat flux probe which provided local instantaneous heat transfer coefficients. The time-averaged heat transfer coefficients in the bulk region were on average about 50% higher than the distributor region of the column. The wall region heat transfer coefficients are well predicted by the correlation of Deckwer et al. (1980). Heat transfer mechanism in column centre can be adequately described by the consecutive film and surface renewal model. Les mécanismes de transfert de chaleur dans le coeur et dans la région du distributeur d'une colonne à bulles à suspensions sont étudiés en mesurant le transfert de chaleur local dans une colonne en plexiglass de 0.28 m. Les phases gazeuse, liquide et solide utilisées sont de l'air cornprimé déhuilé, de l'eau du robinet et des billes de verre de 35 ,m. On a fait varier la concentration des suspensions et la vitesse de gaz superficielle de 0 à 40% en volume et de 0.05 à 0.30 m/s, respectivement. Les mesures ont été faites à l'aide d'une sonde de flux de chaleur à réponse rapide qui fournit les coefficients de transfert de chaleur instantanés locaux. Les coefficients de transfert de chaleur moyennés dans le temps dans le coeur étaient, en rnoyenne, environ 50% supérieurs à ceux de la région du distributeur dans la colonne. Les coefficients de transfert de chaleur de la région de la paroi sont bien predits par la cordation de Deckwer et al. (1980). Le mécanisme de transfert de chaleur au centre de la colonne peut ,tre adéquatement décrit par le modéle de renouvellement de surface et de film consécutif. [source]

    The Referral of Juvenile Offenders to the Adult Court in Belgium: Theory and Practice

    THE HOWARD JOURNAL OF CRIMINAL JUSTICE, Issue 2 2005
    Catherine Van Dijk
    As in the UK and the USA, this transfer mechanism is increasingly pushed forward as a preferential solution for serious juvenile offenders. With this, a more classic penal angle and an increased repressive tenor seem to have entered the juvenile justice system and are replacing the individualised justice and rehabilitative ideal. That this new culture of control with facilitated waiver conditions and ,populist' policy discourse does not necessarily result in more repressive judicial practices can be illustrated with Belgian transfer statistics and interviews with magistrates. [source]

    Femoral intra-arterial injection: a tool to deliver and assess recombinant AAV constructs in rodents whole hind limb

    THE JOURNAL OF GENE MEDICINE, Issue 6 2005
    Patrick Gonin
    Abstract With the aim of simplifying recombinant-adeno-associated virus (rAAV) delivery in muscle, a new femoral intra-arterial technique was designed and tested in rodents (rats and mice). Two serotypes, several promoters and transgenes (reporter or therapeutic) were tested using this administration route. The new route is both easy to perform and efficient. Its usefulness as a tool to assess gene delivery constructs in the muscle was established in the context of recombinant AAV serotypes 1 and 2, and with the ubiquitous CMV and two muscle-specific (C5-12 and CK6) promoters. Both serum monitoring of a secreted protein (murine alkaline phosphatase: muSEAP) and slide staining were used to compare the different constructs. Significantly different patterns of expression in kinetics of expression (muSEAP) and homogeneity of fiber transduction (staining) were evidenced with the different promoters tested, and compared with intra-muscular expression patterns. Detailed studies of differential transduction in leg and thigh muscles showed equivalent efficacy, except in rectus femoris, and to a lesser extent in soleus. In light of these results and prior data, intra-arterially mediated gene transfer mechanism is discussed. Copyright © 2005 John Wiley & Sons, Ltd. [source]

    Nucleophilic Substitution Reaction of p -Dinitrobenzene by a Carbanion: Evidence for Electron Transfer Mechanism

    CHINESE JOURNAL OF CHEMISTRY, Issue 11 2002
    You-Cheng Liu
    Abstract On the basis of investigation of cyclic voltammetry, EPR spectroscopy and competition experiments, the nucleophilic substitution reaction of p - dinitrobenzene with the sodium salt of ethyl ,-cyanoacetate carbanion in dimethyl sulfoxide giving ethyl ,-cyano-,- (p-nitrophenyl) acetate is shown to take place via the intermediacy of p -dinitrobenzene radical anion. The reaction rate goes faster than that between p -nitrohalobenzenes and the same sodium salt of ethyl ,-cyanoacetate carbanion. There is an evidence for a single electron transfer mechanism. [source]

    The lateral intercellular space as osmotic coupling compartment in isotonic transport

    ACTA PHYSIOLOGICA, Issue 1 2009
    E. H. Larsen
    Abstract Solute-coupled water transport and isotonic transport are basic functions of low- and high-resistance epithelia. These functions are studied with the epithelium bathed on the two sides with physiological saline of similar composition. Hence, at transepithelial equilibrium water enters the epithelial cells from both sides, and with the reflection coefficient of tight junction being larger than that of the interspace basement membrane, all of the water leaves the epithelium through the interspace basement membrane. The common design of transporting epithelia leads to the theory that an osmotic coupling of water absorption to ion flow is energized by lateral Na+/K+ pumps. We show that the theory accounts quantitatively for steady- and time dependent states of solute-coupled fluid uptake by toad skin epithelium. Our experimental results exclude definitively three alternative theories of epithelial solute,water coupling: stoichiometric coupling at the molecular level by transport proteins like SGLT1, electro-osmosis and a ,junctional fluid transfer mechanism'. Convection-diffusion out of the lateral space constitutes the fundamental problem of isotonic transport by making the emerging fluid hypertonic relative to the fluid in the lateral intercellular space. In the Na+ recirculation theory the ,surplus of solutes' is returned to the lateral space via the cells energized by the lateral Na+/K+ pumps. We show that this theory accounts quantitatively for isotonic and hypotonic transport at transepithelial osmotic equilibrium as observed in toad skin epithelium in vitro. Our conclusions are further developed for discussing their application to solute,solvent coupling in other vertebrate epithelia such as small intestine, proximal tubule of glomerular kidney and gallbladder. Evidence is discussed that the Na+ recirculation theory is not irreconcilable with the wide range of metabolic cost of Na+ transport observed in fluid-transporting epithelia. [source]