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Thermal Events (thermal + event)
Selected AbstractsCenozoic stratigraphy and subsidence history of the South China Sea margin in the Taiwan regionBASIN RESEARCH, Issue 4 2003A. T. Lin Seismic reflection profiles and well data are used to determine the Cenozoic stratigraphic and tectonic development of the northern margin of the South China Sea. In the Taiwan region, this margin evolved from a Palaeogene rift to a latest Miocene,Recent foreland basin. This evolution is related to the opening of the South China Sea and its subsequent partial closure by the Taiwan orogeny. Seismic data, together with the subsidence analysis of deep wells, show that during rifting (,58,37 Ma), lithospheric extension occurred simultaneously in discrete rift belts. These belts form a >200 km wide rift zone and are associated with a stretching factor, ,, in the range ,1.4,1.6. By ,37 Ma, the focus of rifting shifted to the present-day continent,ocean boundary off southern Taiwan, which led to continental rupture and initial seafloor spreading of the South China Sea at ,30 Ma. Intense rifting during the rift,drift transition (,37,30 Ma) may have induced a transient, small-scale mantle convection beneath the rift. The coeval crustal uplift (Oligocene uplift) of the previously rifted margin, which led to erosion and development of the breakup unconformity, was most likely caused by the induced convection. Oligocene uplift was followed by rapid, early post-breakup subsidence (,30,18 Ma) possibly as the inferred induced convection abated following initial seafloor spreading. Rapid subsidence of the inner margin is interpreted as thermally controlled subsidence, whereas rapid subsidence in the outer shelf of the outer margin was accompanied by fault activity during the interval ,30,21 Ma. This extension in the outer margin (,,1.5) is manifested in the Tainan Basin, which formed on top of the deeply eroded Mesozoic basement. During the interval ,21,12.5 Ma, the entire margin experienced broad thermal subsidence. It was not until ,12.5 Ma that rifting resumed, being especially active in the Tainan Basin (,,1.1). Rifting ceased at ,6.5 Ma due to the orogeny caused by the overthrusting of the Luzon volcanic arc. The Taiwan orogeny created a foreland basin by loading and flexing the underlying rifted margin. The foreland flexure inherited the mechanical and thermal properties of the underlying rifted margin, thereby dividing the basin into north and south segments. The north segment developed on a lithosphere where the major rift/thermal event occurred ,58,30 Ma, and this segment shows minor normal faulting related to lithospheric flexure. In contrast, the south segment developed on a lithosphere, which experienced two more recent rift/thermal events during ,30,21 and ,12.5,6.5 Ma. The basal foreland surface of the south segment is highly faulted, especially along the previous northern rifted flank, thereby creating a deeper foreland flexure that trends obliquely to the strike of the orogen. [source] Fluid flow during exhumation of deeply subducted continental crust: zircon U-Pb age and O-isotope studies of a quartz vein within ultrahigh-pressure eclogiteJOURNAL OF METAMORPHIC GEOLOGY, Issue 2 2007Y.-F. ZHENG Abstract Quartz veins in high-pressure to ultrahigh-pressure metamorphic rocks witness channelized fluid flow that transports both mass and heat during collisional orogenesis. This flow can occur in the direction of changing temperature/pressure during subduction or exhumation. SHRIMP U-Pb dating of zircon from a kyanite-quartz vein within ultrahigh-pressure eclogite in the Dabie continental collision orogen yields two age groups at 212 ± 7 and 181 ± 13 Ma, which are similar to two groups of LA-ICPMS age at 210 ± 4 and 180 ± 5 Ma for the same sample. These ages are significantly younger than zircon U-Pb ages of 224 ± 2 Ma from the host eclogite. Thus the two age groups from the vein date two episodes of fluid flow involving zircon growth: the first due to decompression dehydration during exhumation, and the second due to heating dehydration in response to a cryptic thermal event after continental collision. Laser fluorination O-isotope analyses gave similar ,18O values for minerals from both vein and eclogite, indicating that the vein-forming fluid was internally derived. Synchronous cooling between the vein and eclogite is suggested by almost the same quartz,mineral fractionation values, with regularly decreasing temperatures that are in concordance with rates of O diffusion in the minerals. While the quartz veining was caused by decompression dehydration at 700,650 °C in a transition from ultrahigh-pressure to high-pressure eclogite-facies retrogression, the postcollisional fluid flow was retriggered by heating dehydration at ,500 °C without corresponding metamorphism. In either case, the kyanite,quartz vein formed later than the peak ultrahigh-pressure metamorphic event at the Middle Triassic, pointing to focused fluid flow during exhumation rather than subduction. The growth of metamorphic zircon in the eclogite appears to have depended on fluid availability, so that their occurrence is a type of geohygrometer besides geochronological applicability to dating of metamorphic events in orogenic cycles. [source] Reclassification and thermal history of Trenzano chondriteMETEORITICS & PLANETARY SCIENCE, Issue 12 2007A. M. FIORETTI The quenched intracrystalline Fe2+ -Mg ordering state in orthopyroxene preserves the memory of the cooling rate near closure temperature Tc, thus yielding useful constraints on the last thermal event undergone by the host rock. The orthopyroxene Tc of 522 ± 13 °C, calculated using a new calibration equation obtained by Stimpfl (2005b), is higher than in previously published H chondrite data. The orthopyroxene cooling rate at this Tc is about 100 °C/kyr. This fast rate is inconsistent with the much slower cooling rate expected for H6 in the onion shell structural and thermal model of chondrite parent bodies. A petrographic study carried out at the same time indicated that the Trenzano meteorite is an H5 chondrite and not an H6 chondrite, as it is officially classified. Furthermore, the two-pyroxene equilibrium temperature of Trenzano (824 ± 24 °C), calculated with QUILF95, is similar to the two-pyroxene temperature of 750,840 °C obtained for the Carcote (H5) chondrite (Kleinschrot and Okrusch 1999). [source] Contrasting textural record of two distinct metamorphic events of similar P,T conditions and different durationsJOURNAL OF METAMORPHIC GEOLOGY, Issue 8 2005O. LEXA Abstract A structural, metamorphic and geochronological study of the Staré M,sto belt implies the existence of two distinct metamorphic events of similar peak P,T conditions (700,800 °C, 8,10 kbar) during the Cambro-Ordovician and the Carboniferous tectonometamorphic events. The hypothesis of two distinct periods of metamorphism was suggested on the basis of structural discordance between an undoubtedly Carboniferous granodiorite sill intrusion and earlier Cambro-Ordovician fabrics of a banded amphibolite complex. The analysis of crystal size distribution (CSD) shows high nucleation density (N0) and low average growth rate (Gt) for Carboniferous mylonitic metagabbros and mylonitic granodiorites. The parameter N0 decreases whereas the quantity Gt increases towards higher temperatures progressively approaching the values obtained from the Cambro-Ordovician banded amphibolite complex. The spatial distribution of amphibole and plagioclase shows intense mechanical mixing for lower-temperature mylonitic metagabbros. In high-temperature mylonites a strong aggregate distribution is developed. Cambro-Ordovician amphibolites unaffected by Carboniferous deformation show a regular to anticlustered spatial distribution resulting from heterogeneous nucleation of individual phases. This pattern, together with CSD, was subsequently modified by the grain growth and textural equilibration controlled by diffusive mass transfer during Carboniferous metamorphism. The differences between the observed textures of the amphibolites are interpreted to be a consequence of the different durations of the Carboniferous and Cambro-Ordovician thermal events. [source] Evolution of the Pan-African Wadi Haimur metamorphic sole, Eastern Desert, EgyptJOURNAL OF METAMORPHIC GEOLOGY, Issue 6 2000H. Abd El-Naby By comparison with the general features of metamorphic soles (e.g. vertical and lateral extension, metamorphic grade and diagnostic mineral parageneses, deformation and dominant rock types), it is inferred that the amphibolites, metagabbros and hornblendites of the Wadi Um Ghalaga,Wadi Haimur area in the southern part of the Eastern Desert of Egypt represent the metamorphic sole of the Wadi Haimur ophiolite belt. The overlying ultramafic rocks represent overthrusted mantle peridotite. Mineral compositions and thermobarometric studies indicate that the rocks of the metamorphic sole record metamorphic conditions typical of such an environment. The highest P,T conditions (c. 700 °C and 6.5,8.5 kbar) are preserved in clinopyroxene amphibolites and garnet amphibolites from the top of the metamorphic sole, which is exposed in the southern part of the study area. The massive amphibolites and metagabbros further north (Wadi Haimur) represent the basal parts of the sole and show the lowest P,T conditions (450,620 °C and 4.7,7.8 kbar). The sole is the product of dynamothermal metamorphism associated with the tectonic displacement of ultramafic rocks. Heat was derived mainly from the hot overlying mantle peridotites, and an inverted P,T gradient was caused by dynamic shearing during ophiolite emplacement. Sm/Nd dating of whole-rock,metamorphic mineral pairs yields similar ages of c. 630 Ma for clinopyroxene and hornblende, which is interpreted as a lower age limit for ophiolite formation and an upper age limit for metamorphism. A younger Sm/Nd age for a garnet-bearing rock (c. 590 Ma) is interpreted as reflecting a meaningful cooling age close to the metamorphic peak. Hornblende K/Ar ages in the range 570,550 Ma may reflect thermal events during late orogenic granite magmatism. [source] Thermal analysis of frozen solutions: Multiple glass transitions in amorphous systemsJOURNAL OF PHARMACEUTICAL SCIENCES, Issue 9 2009Gregory A. Sacha Abstract Frozen aqueous solutions of sucrose exhibit two "glass transition-like" thermal events below the melting endotherm of ice when examined by DSC, but the physical basis of these events has been a source of some disagreement. In this study, a series of sugars, including sucrose, lactose, trehalose, maltose, fructose, galactose, fucose, mannose, and glucose were studied by modulated DSC and freeze-dry microscopy in order to better understand whether sucrose is unique in any way with respect to this behavior, as well as to explore the physical basis, and the pharmaceutical significance of these multiple transitions. Double transitions were found to be a common feature of all sugars examined. The results are consistent with both thermal events being glass transitions in that (1) both events have second-order characteristics that appear in the reversing signals, (2) annealing experiments reveal that enthalpy recovery is associated with each transition, and (3) Lissajous plots indicate that no detectable latent heat of melting is associated with either transition. The data in this study are consistent with the idea that the lower temperature transition arises from a metastable glassy mixture containing more water than that in the maximally freeze-concentrated solute. Freeze-dry microscopy observations show that for all of the sugars examined, it is the higher temperature transition that is associated with structural collapse during freeze-drying. There is no apparent pharmaceutical significance associated with the lower-temperature transition. © 2009 Wiley-Liss, Inc. and the American Pharmacists Association J Pharm Sci 98:3397,3405, 2009 [source] Process induced disorder in crystalline materials: Differentiating defective crystals from the amorphous form of griseofulvinJOURNAL OF PHARMACEUTICAL SCIENCES, Issue 8 2008Tao Feng Abstract This research investigates milling induced disorder in crystalline griseofulvin. Griseofulvin was subjected to cryogenic milling for various lengths of time. For comparison, the amorphous form of griseofulvin was also prepared by the quench melt method. Different analytical techniques were used to study the differences between the cryomilled, amorphous and crystalline forms of the drug. Cryogenic milling of griseofulvin progressively reduces the crystallinity of the drug by inducing crystal defects, rather than amorphous materials. Raman analysis provides evidence of structural differences between the two. The differences between the defective crystals produced by milling and the amorphous form are significant enough as to be measurable in their bulk thermal properties. Defective crystals show significant decrease in the heat of fusion as a function of milling time but do not exhibit a glass transition nor recrystallization from the amorphous form. Crystal defects undergo recrystallization upon heating at temperatures well below the glass transition temperature (Tg) in a process that is separate and completely independent from the crystallization of the amorphous griseofulvin, observed above Tg. Physical mixtures of defective crystals and amorphous drug demonstrate that the thermal events associated with each form persist in the mixtures, unaffected by the presence of the other form. © 2007 Wiley-Liss, Inc. and the American Pharmacists Association J Pharm Sci 97: 3207,3221, 2008 [source] Characterization of amorphous solids with weak glass transitions using high ramp rate differential scanning calorimetryJOURNAL OF PHARMACEUTICAL SCIENCES, Issue 2 2008Derrick S. Katayama Abstract Measurement of the glass transition temperature (Tg) of proteins and other high molecular weight polymers in the amorphous state is often difficult, since the transition is extremely weak, that is, the ,Cp at the glass transition temperature is small. For example, little is known about the solid-state properties of hydroxyethyl starch (HES), which is beginning to become more commonly evaluated as a bulking agent in pharmaceutical products. For weak thermal events, such as the change in heat capacity at the Tg of a pure protein or large synthetic polymer, increased heating rate should produce greater sensitivity in terms of heat flow. Recent innovations in rapid scanning technology for differential scanning calorimetry (DSC) allow measurements on materials where the thermal events are difficult to detect by conventional DSC. In the current study, measurements of the Tg of proteins in the solid state, amorphous pharmaceutical excipients which have small ,Cp at the glass transition temperature, and bacterial spores, have all been made using high ramp rate DSC, providing information on materials that was inaccessible using conventional DSC methods. © 2007 Wiley-Liss, Inc. and the American Pharmacists Association J Pharm Sci 97:1013,1024, 2008 [source] New Route for the Extraction of Crude Zirconia from ZirconJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 9 2002Nicholas J. Welham A commercial grade of zircon (ZrSiO4) concentrate was mechanically milled with MgO for up to 100 h in a laboratory-scale mill. The resultant powders were subjected to thermal processing, chemical leaching, and X-ray diffraction (XRD). There was no direct evidence of reaction during the milling step, with no new phases evident from XRD. Leaching of the powder showed that a reaction had occurred, and increased solubility with milling time was attributed to the formation of a nanostructured Mg-Zr-Si oxide, which dissolved congruently. Heating the powders resulted in a number of thermal events, including the formation/crystallization of ZrO2 and Mg2SiO4. Thermal treatment of the milled powders allowed selective chemical leaching of the magnesium and silicon, leaving a powder containing ,90% ZrO2. [source] Optical-thermal simulation of tonsillar tissue irradiationLASERS IN SURGERY AND MEDICINE, Issue 4 2001Rahul K. Shah MD Abstract Background and Objective Despite laser applications targetted toward tonsillar tissue, there has been no characterization of underlying optical and thermal events during laser irradiation of tonsillar tissue. Study Design/Materials and Methods The optical properties of canine and human tonsils were determined at 805 nm (diode laser) and 1,064 nm (Nd:YAG laser). An optical-thermal simulation was developed to predict the temperature rise in irradiated human tonsils. Results The optical properties of human and canine tonsillar tissue are similar at both wavelengths. The optical-thermal simulation was validated and predicts that at 10 W and 1 minute of irradiation, the heat will be contained within the human tonsil. The diode laser causes more superficial heating than the Nd:YAG laser. Conclusions The safety of irradiating human tonsils was shown. The diode laser is superior to the Nd:YAG laser because less heat affects collateral structures. The optical-thermal simulation detailed in this study can be used to predict the temperature rise in tissues undergoing irradiation. Lasers Surg. Med. 28:313,319, 2001. © 2001 Wiley-Liss, Inc. [source] | ||||||||||