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Thermal Characteristics (thermal + characteristic)
Selected AbstractsThermal Characteristics of the Embankment with Crushed Rock Side Slope to Mitigate Thaw Settlement Hazards of the Qinghai-Tibet RailwayACTA GEOLOGICA SINICA (ENGLISH EDITION), Issue 5 2009Guoyu LI Abstract: Permafrost (perennially frozen ground) appears widely in the Golmud-Lhasa section of the Qinghai-Tibet railway and is characterized by high ground temperature (,,1°C) and massive ground ice. Under the scenarios of global warming and human activity, the permafrost under the railway will gradually thaw and the massive ground ice will slowly melt, resulting in some thaw settlement hazards, which mainly include longitudinal and lateral cracks, and slope failure. The crushed rock layer has a thermal semiconductor effect under the periodic fluctuation of natural air. It can be used to lower the temperature of the underlying permafrost along the Qinghai-Tibet railway, and mitigate the thaw settlement hazards of the subgrade. In the present paper, the daily and annual changes in the thermal characteristics of the embankment with crushed rock side slope (ECRSS) were quantitatively simulated using the numerical method to study the cooling effect of the crushed rock layer and its mitigative ability. The results showed that the ECRSS absorbed some heat in the daytime in summer, but part of it was released at night, which accounted for approximately 20% of that absorbed. Within a year, it removed more heat from the railway subgrade in winter than that absorbed in summer. It can store approximately 20% of the "cold" energy in subgrade. Therefore, ECRSS is a better measure to mitigate thaw settlement hazards to the railway. [source] Surface modification of starch nanocrystals through ring-opening polymerization of ,-caprolactone and investigation of their microstructuresJOURNAL OF APPLIED POLYMER SCIENCE, Issue 4 2008Hassan Namazi Abstract Bionanoparticles of starch obtained by submitting native potato starch granules to acid hydrolysis conditions. The resulted starch nanoparticles were used as core or macro initiator for polymerization of ,-caprolactone (CL). Starch nanoparticle- g -polycaprolactone was synthesized through ring-opening polymerization (ROP) of CL in the presence of Sn(Oct)2 as initiator. The detailed microstructure of the resulted copolymer was characterized with NMR spectroscopy. Thermal characteristic of the copolymer was investigated using DSC and TGA. By introducing PCL, the range of melting temperature for starch was increased and degradation of copolymer occurred in a broader region. X-ray diffraction and TEM micrographs confirmed that there was no alteration of starch crystalline structure and morphology of nanoparticles, respectively. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 [source] Silicon transport under rotating and combined magnetic fields in liquid phase diffusion growth of SiGeCRYSTAL RESEARCH AND TECHNOLOGY, Issue 4 2010N. Armour Abstract The effect of applied rotating and combined (rotating and static) magnetic fields on silicon transport during the liquid phase diffusion growth of SiGe was experimentally studied. 72-hour growth periods produced some single crystal sections. Single and polycrystalline sections of the processed samples were examined for silicon composition. Results show that the application of a rotating magnetic field enhances silicon transport in the melt. It also has a slight positive effect on flattening the initial growth interface. For comparison, growth experiments were also conducted under combined (rotating and static) magnetic fields. The processed samples revealed that the addition of static field altered the thermal characteristics of the system significantly and led to a complete melt back of the germanium seed. Silicon transport in the melt was also enhanced under combined fields compared with experiments with no magnetic field. (© 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Impact of summer warming on the thermal characteristics of a polymictic lake and consequences for oxygen, nutrients and phytoplanktonFRESHWATER BIOLOGY, Issue 2 2008SUSANN WILHELM Summary 1. The impact of long thermal stratification events on some key properties in a polymictic lake was studied by determining the mixing regime of Müggelsee, Germany, using water temperature profiles taken hourly over 4 years. The period included two exceptional summer heatwaves. 2. Long thermal stratification events lasted from about 1 week to 2 months, and exhibited a high variability in thermocline depth and stratification intensity within and between events. 3. During stratification events, hypolimnetic oxygen concentrations strongly decreased while hypolimnetic SRP accumulation increased, depending on the duration and intensity of stratification and on hypolimnetic water temperature. 4. The impact of stratification on the functional phytoplankton composition increased with increasing stratification duration, but was rather different for the heatwaves. 5. Stratification events were followed by strong nutrient pulses into the euphotic zone and intense phytoplankton growth, particularly after the heatwaves. Hence, the influence of the climate extremes counteracted effects of reduced external nutrient loading. [source] Predicting river water temperatures using the equilibrium temperature concept with application on Miramichi River catchments (New Brunswick, Canada)HYDROLOGICAL PROCESSES, Issue 11 2005Daniel Caissie Abstract Water temperature influences most of the physical, chemical and biological properties of rivers. It plays an important role in the distribution of fish and the growth rates of many aquatic organisms. Therefore, a better understanding of the thermal regime of rivers is essential for the management of important fisheries resources. This study deals with the modelling of river water temperature using a new and simplified model based on the equilibrium temperature concept. The equilibrium temperature concept is an approach where the net heat flux at the water surface can be expressed by a simple equation with fewer meteorological parameters than required with traditional models. This new water temperature model was applied on two watercourses of different size and thermal characteristics, but within a similar meteorological region, i.e., the Little Southwest Miramichi River and Catamaran Brook (New Brunswick, Canada). A study of the long-term thermal characteristics of these two rivers revealed that the greatest differences in water temperatures occurred during mid-summer peak temperatures. Data from 1992 to 1994 were used for the model calibration, while data from 1995 to 1999 were used for the model validation. Results showed a slightly better agreement between observed and predicted water temperatures for Catamaran Brook during the calibration period, with a root-mean-square error (RMSE) of 1·10 °C (Nash coefficient, NTD = 0·95) compared to 1·45 °C for the Little Southwest Miramichi River (NTD = 0·94). During the validation period, RMSEs were calculated at 1·31 °C for Catamaran Brook and 1·55 °C for the Little Southwest Miramichi River. Poorer model performances were generally observed early in the season (e.g., spring) for both rivers due to the influence of snowmelt conditions, while late summer to autumn modelling performances showed better results. Copyright © 2005 John Wiley & Sons, Ltd. [source] Composition, soaking, cooking properties and thermal characteristics of starch of chickpeas, wrinkled peas and smooth peasINTERNATIONAL JOURNAL OF FOOD SCIENCE & TECHNOLOGY, Issue 5 2001Beata Klamczynska We investigated both the distribution of protein, ash and starch in legume (chickpeas, smooth and wrinkled peas) cotyledons, and the soaking and cooking characteristics, including gelatinization and retrogradation, of the starch. There were large differences in composition between different types of legumes and also between the outer and inner parts of legume cotyledons. Wrinkled peas exhibited much higher water absorption during prolonged soaking and there were higher hardness value determined for cooked seeds compared with chickpeas and smooth peas. While the hardness of cooked seeds decreased continuously as cooking time increased to 110 min, all legume starch was fully gelatinized after cooking for 70 min. [source] Numerical analysis on thermal characteristics for chip scale package by integrating 2D/3D modelsINTERNATIONAL JOURNAL OF NUMERICAL MODELLING: ELECTRONIC NETWORKS, DEVICES AND FIELDS, Issue 1 2009Ping Yang Abstract The objective of this paper is to investigate stress and strain of a special scale package-substrate on chip for reliability evaluation or manufacture strategy in deep-seated situation. A two-dimensional model with one-half of cross-section (2D model) and a three-dimensional model with one-fourth of whole package (3D model) were built, respectively, to simulate the thermal stress and strain of CSP-SOC under the condition of the standard industry thermal cycling temperature ,40 to125°C. The different locations can be processed by using the two models, respectively, based on different modeling simplified modes. By using 2D model, the numerical simulation shows that the maximum deformation of the prototype occurs in printed circuit board (PCB), the maximum stress and strain occurs in the outer solder balls. In the meantime, by the results of 3D model, the simulation shows that the maximum elastic strain occurs in the interface between the solder balls and PCB, the minimum strain occurs in the underfill tape, the maximum packaging stress occurs in the edge area of the chip. The result from 3D model maybe more impersonal to reflect the stress and strain characteristics because the third direction is considered in modeling. The analysis by integrating the 2D model and 3D model can get a more comprehensive profile for the thermal investigation of chip scale package (CSP) than by using any single model. The investigation built a basis for improving reliability in engineering design of CSP product. Copyright © 2008 John Wiley & Sons, Ltd. [source] Mechanical and thermal properties of polypropylene/sugarcane Bagasse compositesJOURNAL OF APPLIED POLYMER SCIENCE, Issue 6 2007B. Ramaraj Abstract To determine the possibility of using sugarcane bagasse (SCB) waste as reinforcing filler in the thermoplastic polymer matrix, SCB-reinforced polypropylene (PP) composites were prepared. The PP and SCB composites were prepared by the extrusion of PP resin with 5, 10, 15, and 20 wt % of SCB filler in a corotating twin screw extruder. The extruded strands were cut into pellets and injection molded to make test specimens. These specimens were tested for physicomechanical properties such as tensile, flexural, Izod, and Charpy impact strengths, density, water absorption, and thermal characteristics, namely, heat deflection temperature (HDT), melt flow index, and thermogravimetric analysis. It was found that the flexural strength increased from 23.66 to 26.84 MPa, Izod impact strength increased from 10.499 to 13.23 Kg cm/cm, Charpy impact strength increased from 10.096 to 13.98 Kg cm/cm, and HDT increased from 45.5 to 66.5°C, with increase in filler loading from 5 to 20% in the PP matrix. However, the tensile strength and elongation decreased from 32.22 to 27.21 MPa and 164.4 to 11.20% respectively. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3827,3832, 2007 [source] Kinetic study of the curing of mixtures of DGEBA and five-membered cyclic carbonates with lanthanum triflate as cationic initiatorJOURNAL OF APPLIED POLYMER SCIENCE, Issue 5 2007Roser Cervellera Abstract Mixtures of diglycidylether of bisphenol A (DGEBA) with 1,3-benzodioxolane-2-one (CC) or 4-phenoxymethyl-1,3-dioxolane-2-one (PGEC) were cured in the presence of lanthanum triflate. FTIR/ATR was used to study the evolution of carbonate and epoxide groups to follow the reactive processes that take place during curing. DSC was applied to study the thermal characteristics of the curing process and to determine the glass-transition temperatures of the cured materials. The kinetics of the curing was studied isothermally by means of FTIR and the kinetic model was selected through the isokinetic relationships. DSC experiments were used to study the kinetics in nonisothermal conditions by means of isoconversional procedures and the Coats,Redfern and Criado methodologies. By TMA we could monitor the evolution of the shrinkage during isothermal curing. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2875,2884, 2007 [source] ELECTRICAL CONDUCTIVITY OF HEATED CORNSTARCH,WATER MIXTURESJOURNAL OF FOOD PROCESS ENGINEERING, Issue 6 2009EDUARDO MORALES-SANCHEZ ABSTRACT Electrical conductivity (EC) of cornstarch,water mixtures in the range 10:90 to 70:30 (w/w) was studied as a function of temperature. An external resistive heating system equipped with an electronic device capable of monitoring EC in real time was used and EC of the mixtures was measured while heated at a rate of 5C/min. Results showed that EC went through four different temperature-dependent stages (A, B, C and D). Stage B (41C to 64C) showed a lower EC increasing rate when compared with that of Stage A (from 25C to 41C), probably as a result of starch granule swelling. In Stage C (64C to 78C), EC behavior was found to be dependent on water content. When water content was more than 50%, the value for EC increased. On the other side, EC decreased when water content was less than 50%. Stage C was related to starch gelatinization, according to differential scanning calorimetry results obtained in this study. In Stage D (78C to 92C), a steady increase in EC was observed, probably as a result of the total solubilization of starch in water. It was concluded that Stage C in EC graphs corresponded to cornstarch gelatinization, so it might be possible to use EC monitoring as an alternative technique to measure cornstarch thermal characteristics with different contents of water. PRACTICAL APPLICATIONS Electrical conductivity can be used as an adequate technique to monitor gelatinization, granule swelling and phase change of starch as a function of temperature in corn starch,water mixtures with a wide range of water contents. With this technique, it is also possible to calculate important thermal parameters, such as the beginning and end of the gelatinization and the energy activation for the heating process of cornstarch. This can lead to a better design and control of important industrial corn processes such as alkaline cooking. [source] Effect of Pasteurization, High-Pressure Processing, and Retorting on the Barrier Properties of Nylon 6, Nylon 6/Ethylene Vinyl Alcohol, and Nylon 6/Nanocomposites FilmsJOURNAL OF FOOD SCIENCE, Issue 1 2009L. Halim ABSTRACT:, This study determined the impact of pasteurization, high-pressure processing (HPP), and retorting on the barrier properties of nylon 6 (N6), nylon 6/ethylene vinyl alcohol (N6/EVOH), and nylon 6/nanocomposite (N6/nano) materials. The pasteurized and high-pressure treated films were coextruded with low-density polyethylene (PE) as the heat-sealing layer. The retorted films were coextruded with polypropylene (PP). Oxygen transmission rate (OTR) and water vapor transmission rate (WVTR) of the samples were measured after pasteurization (75 °C for 30 min), HPP (800 MPa for 10 min at 70 °C), and retorting (121 °C for 30 min) treatments. These were compared with the thermal characteristics and morphologies of the samples using differential scanning calorimetry (DSC) and X-ray diffraction (XRD). Results showed that OTR of N6 and N6/Nano increased after HPP (16.9% and 39.7%), pasteurization (13.3% and 75.9%), and retorting (63.3% and 112.6%), respectively. For N6/EVOH, a decrease in OTR after HPP (53.9%) and pasteurization (44.5%) was observed. The HPP treatment increased the WVTR of N6 (21.0%), N6/EVOH (48.9%), and N6/Nano (21.2%). The WVTR of N6, N6/EVOH, and N6/Nano increased by 96.7%, 43.8%, and 40.7%, respectively, after pasteurization. The DSC analyses showed that the enthalpy and percent crystallinity increased (2.3% to 6.5%) in the N6/Nano when compared with the N6 material after each treatment. Retorting caused a decrease (3.5%) in the percent crystallinity of the polypropylene material. HPP did not cause major morphological changes to the samples. Results of the barrier studies were influenced by the crystallinity changes in the materials as seen in the XRD diffractograms. [source] Synthesis and application of novel styryl dyes derived from 1,4-diethyl-1,2,3,4-tetrahydro-6-methoxyquinoxalineJOURNAL OF HETEROCYCLIC CHEMISTRY, Issue 2 2009Vijay Satam The novel 1,4-diethyl-1,2,3,4-tetrahydro-7-methoxyquinoxalin-6-carboxaldehyde was synthesized, characterized, and condensed with suitably substituted active methylene compounds by classical Knoevenagel condensation reaction to obtain novel monostyryl dyes 8a-8e and a bis-styryl dye 8f. These novel styryl dyes have hue varying from orange to violet. The dyes were applied to polyester fibers. The spectral and thermal characteristics of the dyes and fastness properties of the dyed polyester fabric were investigated. J. Heterocyclic Chem., 46, 221 (2009). [source] Thermal characterisation of active layer across a soil moisture gradient in the McMurdo Dry Valleys, AntarcticaPERMAFROST AND PERIGLACIAL PROCESSES, Issue 1 2009Scott J. Ikard Abstract Heat transport into active layer soils is important to understanding potential responses to changes in surface energy balance, particularly in the context of changing climate. Here we present results of a study to characterise soil thermal properties along a soil moisture gradient adjacent to Lake Fryxell in Taylor Valley, Antarctica. Our goals were to characterise the thermal characteristics of these relatively wet soils (compared to the rest of the McMurdo Dry Valleys landscape), and to assess the response of the active layer to possible increases in soil moisture. We measured subsurface temperatures at depths from 3 to 50,cm at four locations along a natural gradient of wet to dry soils adjacent to Lake Fryxell from January 2006 to January 2007. We used a numerical model to estimate apparent thermal diffusivity (ATD) and simulate observed temperature time series. Calculations of ATD at discrete locations yielded values ranging from 1.0,×,10,9 , 2.4,×,10,5,m2,s,1, and the corresponding range of bulk (i.e. depth averaged at a single surface location) ATD was 2.9,×,10,9,1.2,×,10,7,m2,s,1. Thawed soils had a range of bulk ATD during warming of 2.9,×,10,9,3.8,×,10,8,m2,s,1, and during cooling of 2.9,×,10,9,4.8,×,10,8,m2,s,1. When soils were frozen, however, the range of bulk ATD was 7.6,×,10,9,1.2,×,10,7,m2,s,1 during warming, and 7.8,×,10,9,1.1,×,10,7,m2,s,1 during cooling. Estimated bulk ATD values were consistently greater in locations of enhanced soil moisture, so lakeside soils were more likely to conduct energy into the subsurface. Increased soil moisture across the landscape would likely increase ATD, allowing for greater heat exchange between the atmosphere and the subsurface. Copyright © 2009 John Wiley & Sons, Ltd. [source] Polydimethylsiloxane,cristobalite composite adhesive system for aerospace applicationsPOLYMERS FOR ADVANCED TECHNOLOGIES, Issue 5 2009Seema Ansari Abstract The effect of phase-pure cristobalite (a high temperature crystalline polymorph of silica) on the adhesive characteristics of hydroxyl terminated polydimethylsiloxane (PDMS) was studied. The potential advantages of PDMS/cristobalite composite system as an adhesive for aerospace applications are also discussed. A PDMS/cristobalite composite adhesive system containing different filler contents (0,46 volume percentage, vol%) was prepared. The filler material, phase-pure cristobalite, was synthesized by the pyrolysis of fused silica at 1400°C. The mechanical, rheological, and thermal characteristics of the composites were studied. A high yield stress (0.151,Pa), shear-thinning index (1.051), and fast recovery rate were observed for ,34,vol% cristobalite loading, which indicate that PDMS retains its excellent adhesive and flow characteristics even at high filler loading with enhanced mechanical characteristics. Thermal analysis shows the onset of degradation of PDMS shifts to higher temperatures, 372,438°C and 317,417°C in nitrogen and air atmosphere respectively, which shows excellent thermal stability. The residual component yields after thermal degradation of PDMS/cristobalite composite system in nitrogen and air atmosphere show different degradation mechanisms. Copyright © 2008 John Wiley & Sons, Ltd. [source] Structural characterization of silica modified polyimide membranesPOLYMERS FOR ADVANCED TECHNOLOGIES, Issue 1 2006Mehtap Safak Boroglu Abstract Polyimide and hybrid polyimide-siloxane were synthesized by polycondensation, imidization, and sol-gel reaction. The polyimides were prepared from pyromellitic dianhydride (PMDA) and 4,4-oxydianiline (ODA) in N -methyl-2-pyrollidone (NMP). Trimethoxyvinyl silane (TMVS) was used as a source of silica. Their surface morphologies, structures and thermal performances were determined using scanning electron microscopy (SEM), infrared spectroscopy (IR), thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The results showed that the silica particles were finely and rather homogeneously dispersed in polymers. The glass transition temperature (Tg) of hybrid membrane materials increased with the increasing silica content. TGA analysis showed that polyimides were thermally stable with silica. Modified polyimide-siloxane films, thermal characteristics were found to be better than the polyimide films without silica. Copyright © 2006 John Wiley & Sons, Ltd. [source] Wärme- und Feuchtetransport in VakuumisolationspaneelenBAUPHYSIK, Issue 6 2008Andreas Beck Prof. Dr. Wegen ihrer extrem niedrigen Wärmeleitfähigkeit und der damit verbundenen Möglichkeiten, mit geringen Bauteildicken hochwertig zu dämmen, haben Vakuumisolationspaneele (VIP) innerhalb kurzer Zeit Verbreitung im Bauwesen gefunden , insbesondere in Situationen, in denen andere Dämmstoffe aus Platzgründen nicht in Frage kommen. Da noch keine Langzeiterfahrungen über die Alterung der Paneele vorhanden sind, muss beim Bemessungswert der Wärmeleitfähigkeit im Moment allerdings noch mit hohen Sicherheitszuschlägen gerechnet werden, vor allem wegen des über die Nutzungsdauer stattfindenden Gaseintrags. Besonders von Interesse ist hierbei das Verhalten von aus der Umgebung eindiffundierendem Wasserdampf. Während die Auswirkungen von trockenen Gasen genau bezifferbar sind, überlagern sich beim Stoff- und Wärmetransport durch Wasser verschiedene Vorgänge, die die Wärmeleitung im VIP deutlich erhöhen, aber messtechnisch nur schwer erfassbar sind. Daher wurde ein theoretisches Modell entwickelt, das den Wärmestrom auf Grundlage der kinetischen Gastheorie für Molekularströmung und Oberflächendiffusion beschreibt und darüber hinaus Rückschlüsse auf die Diffusionseigenschaften des Kernmaterials zulässt. Heat and Moisture Transport in Vacuum Insulation Panels. Due to their extremely low thermal conductivity, vacuum insulation panels (VIP) allow for high standard thermal insulation with slim building components. Within few years, this led to widespread use especially in building situations where space is limited. As there are no long-term experiences concerning the thermal characteristics of VIPs, however, their rated values of thermal conductivity are notably higher than the actual measured values at present, which primarily represents effects of degradation caused by gases infiltrating the panel. Most significant is the influence of water vapour diffusing into the VIP. Whereas the effects of dry gases are well known and can be exactly quantified, water vapour causes different processes of heat and matter transfer which increase thermal conduction within the VIP considerably, but which cannot be separated accurately by means of measuring. Thus a theoretical model was developed which describes heat flux basing on the kinetic theory of gases for molecular diffusion and surface diffusion. It moreover provides information about the diffusion characteristics of the core material. [source] Thermal Characteristics of the Embankment with Crushed Rock Side Slope to Mitigate Thaw Settlement Hazards of the Qinghai-Tibet RailwayACTA GEOLOGICA SINICA (ENGLISH EDITION), Issue 5 2009Guoyu LI Abstract: Permafrost (perennially frozen ground) appears widely in the Golmud-Lhasa section of the Qinghai-Tibet railway and is characterized by high ground temperature (,,1°C) and massive ground ice. Under the scenarios of global warming and human activity, the permafrost under the railway will gradually thaw and the massive ground ice will slowly melt, resulting in some thaw settlement hazards, which mainly include longitudinal and lateral cracks, and slope failure. The crushed rock layer has a thermal semiconductor effect under the periodic fluctuation of natural air. It can be used to lower the temperature of the underlying permafrost along the Qinghai-Tibet railway, and mitigate the thaw settlement hazards of the subgrade. In the present paper, the daily and annual changes in the thermal characteristics of the embankment with crushed rock side slope (ECRSS) were quantitatively simulated using the numerical method to study the cooling effect of the crushed rock layer and its mitigative ability. The results showed that the ECRSS absorbed some heat in the daytime in summer, but part of it was released at night, which accounted for approximately 20% of that absorbed. Within a year, it removed more heat from the railway subgrade in winter than that absorbed in summer. It can store approximately 20% of the "cold" energy in subgrade. Therefore, ECRSS is a better measure to mitigate thaw settlement hazards to the railway. [source] | ||||||||||||||||