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Surface Water (surface + water)
Terms modified by Surface Water Selected AbstractsSTATEWIDE EMPIRICAL MODELING OF BACTERIAL CONTAMINATION OF SURFACE WATERS,JOURNAL OF THE AMERICAN WATER RESOURCES ASSOCIATION, Issue 3 2006James D. Wickham ABSTRACT: Bacterial contamination of surface waters is attributed to both urban and agricultural land use practices and is one of the most frequently cited reasons for failure to meet standards established under the Clean Water Act (CWA) (P.L. 92,500). Statewide modeling can be used to determine if bacterial contamination occurs predominantly in urban or agricultural settings. Such information is useful for directing future monitoring and allocating resources for protection and restoration activities. Logistic regression was used to model the likelihood of bacterial contamination using watershed factors for the state of Maryland. Watershed factors included land cover, soils, topography, hydrography, locations of septic systems, and animal feeding operations. Results indicated that bacterial contamination occurred predominantly in urban settings. Likelihood of bacterial contamination was highest for small watersheds with well drained and erodible soils and a high proportion of urban land adjacent to streams. The number of septic systems and animal feeding operations and the amount of agricultural land were not significant explanatory factors. The urban infrastructure tends to "connect" more of the watershed to the stream network through the creation of roads, storm sewers, and wastewater treatment plants. This may partly explain the relationship between urbanization and bacterial contamination found in this study. [source] Groundwater Banking in Aquifers that Interact With Surface Water: Aquifer Response Functions and Double-Entry Accounting,JOURNAL OF THE AMERICAN WATER RESOURCES ASSOCIATION, Issue 6 2009Bryce A. Contor Contor, Bryce A., 2009. Groundwater Banking in Aquifers That Interact With Surface Water: Aquifer Response Functions and Double-Entry Accounting. Journal of the American Water Resources Association (JAWRA) 45(6):1465-1474. Abstract:, Increasing worldwide demands for water call for mechanisms to facilitate storage of seasonal supplies and mechanisms to facilitate reallocation of water. Markets are economically efficient reallocation and incentive mechanisms when market conditions prevail, but special hydrologic and administrative conditions of water use and allocation interfere with required market conditions. Water banking in general can bring market forces to bear on water storage and reallocation, improving economic efficiency and therefore the welfare of society as a whole. Groundwater banking can utilize advantages of aquifers as storage vessels with vast capacity, low construction cost, and protection of stored water. For groundwater banking in aquifers that interact with surface water, an accounting system is needed that addresses the depletion of stored volumes of water as water migrates to surface water. Constructing such a system requires integration of hydrologic, economic, and legal principles with principles of financial accounting. Simple mass-balance accounting, even with allowances for depletion, is not adequate in these aquifers. Aquifer response functions are mathematical descriptions of the impact that aquifer pumping or recharge events have upon hydraulically connected surface water bodies. Double-entry accounting is a financial accounting methodology for tracking asset inventories and ownership claims upon assets. The powerful innovation of linking aquifer response functions with double-entry accounting technologies allows application of groundwater banking to aquifers where deposits can be depleted by migration to hydraulically connected surface water. It honors the hydrologic realities of groundwater/surface water interaction, the legal requirements of prior appropriation water law, and the economic requirements for equitable and efficient allocation of resources. [source] Particulate Matter in the Ross Sea: a Spreading ModelMARINE ECOLOGY, Issue 2002Sergio Tucci Abstract. Within the framework of the C.L.I.M.A. Project, a part of the Italian Research Program in Antarctica, the Total Particulate Matter (TPM) was used as a natural marker to characterise the water masses. The dynamics of TPM was estimated by using a numerical model capable of following the evolution of the basin during the ice absence in summer. The first numerical simulation, with horizontally constant initial conditions and the absence of TPM source areas, merely reveals how TPM passive dispersion is strongly influenced by the Ross Ice Shelf and bathymetry. The second simulation, with TPM concentration horizontally variable and vertically decreasing layers, shows a dynamic evolution of TPM that is in agreement with experimental data. On the surface, in correspondence with the shelf-break, an out-flowing flux with particulate matter contribution coming from Ross Ice Shelf is recognised. The TPM concentration may be linked to the ice melting due to the Antarctic Surface Water, with production of Shallow Ice Shelf Water. The numerical model produces, near the Drygalski area, two cells with high concentration. This numerical evolution is confirmed by the 1990 data (Spezie et al, 1993) that clearly show these two areas and their correlations with the Drygalski contributions (the inner area) and with the thermo-haline front (the external one). This condition is evident in the 1994-1995 data too (Bu-dillon et al, 1999). In this case the authors observed that the Circumpolar Deep Water penetrates onto the shelf at about 174°E; then, modifying its properties, it follows a southward path for about 200 km. The Antarctic Shelf Front (ASF) separates CDW from the colder shelf water with a high concentration of suspended matter. At the 300-meter level, the diffusion of the particulate matter directed under the RIS, towards the continental shelf, seems to be an important feature. Very high TPM values are also present in the deep water in the area off the Drygalski Glacier; this evolution agrees with the ,400 m data collected during the 1990,1991 cruise (Spezie et al., 1993). [source] Rehabilitation of Acidified Floating Fens by Addition of Buffered Surface WaterRESTORATION ECOLOGY, Issue 1 2002M. C. Bootsma Abstract Floating fens are species-rich succession stages in fen areas in the Netherlands. Many of these fens are deteriorating due to acidification; Sphagnum species and Polytrichum commune build 10,25 cm thick moss carpets, and the species diversity decreases. Earlier experiments in wet ecosystems indicate that successful restoration of circum-neutral and mesotrophic conditions requires a combination of hydrological measures and sod removal. In an acidified fen recharged by rainwater in the nature reserve Ilperveld (The Netherlands), a ditch/trench system was dug for the purpose of creating a run-off channel for acid rainwater in wet periods and to enable circum-neutral surface water to enter the fen in dry periods. Moreover, the sod was removed in part of the fen. Ditch/trench creation or sod cutting had no effect individually, but a combination of the two measures led to a change in the abiotic conditions (higher pH and Ca), and in turn to an increase of species-richness and the reestablishment of a number of characteristic species. Reestablishment of rare vascular plant species and characteristic bryophytes might be a long-term process because of incomplete recovery of site conditions and constraints in seed dispersal. [source] Concentrations and partitioning of polychlorinated biphenyls in the surface waters of the southern Baltic Sea,seasonal effectsENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 10 2006Kilian E.C. Smith Abstract In the marine environment, the partitioning of hydrophobic organic contaminants, such as polychlorinated biphenyls (PCBs), between the dissolved and suspended matter phases in the water column plays a fundamental role in determining contaminant fate (e.g., air,water exchange or food-chain uptake). Despite the pronounced seasonality in physical, chemical, and biological conditions in temperate marine ecosystems, little is known about the seasonality in organic contaminant partitioning behavior. Surface water from the western Baltic Sea was sampled regularly during an 18-month period between February 2003 and July 2004. The concentrations of seven PCB congeners were determined in the dissolved and particulate organic carbon (POC) phases. An inverse relationship was found between KPOC (i.e., the ratio between the POC-normalized PCB concentration [pg/kg POC] and the dissolved concentration [pg/L]) and temperature. The decrease in the water temperature of 20°C between summer and winter resulted in an increase in KPOC by a factor of approximately five. The POC-normalized PCB concentrations were higher in winter than in summer by a factor of 9 to 20. This reflected the higher KPOC and somewhat greater PCB concentrations in the dissolved phase, and it could have consequences for bioaccumulation of these chemicals in aquatic food webs. The results demonstrate a clear seasonality in contaminant partitioning in the temperate marine environment that should be accounted for when interpreting field data or modeling contaminant fate. [source] The dispersal and deposition of hydrochorous plant seeds in drainage ditchesFRESHWATER BIOLOGY, Issue 10 2010HESTER SOOMERS Summary 1. Surface water is an important dispersal vector for wetland plant species. However, most previous studies on hydrochory (i.e. water dispersal) have focused on ecosystems with relatively rapid water flow. Therefore, there is a need to study such dispersal in slow-flowing or stagnant waterbodies, such as drainage ditches, which might act as dispersal corridors between habitat patches. 2. To gain insight into the mechanisms by which seeds are transported in drainage ditches, the effect of the velocity of wind and water on the rate of transport of floating seeds of three wetland species (Carex pseudocyperus L., Iris pseudacorus L. and Sparganium erectum L.) was investigated. Furthermore, in release and retrace experiments with painted C. pseudocyperus seeds, a number of factors potentially determining the probability of seed deposition were investigated. 3. Net wind speed was found to be the main factor determining the rate at which seeds are transported in drainage ditches. No relation between water flow at middepth in the ditches and seed transport was found. Wind speed and flow at the water surface were positively related. The effect of wind speed on the rate of transport of floating seeds was greater for S. erectum seeds, because a greater ratio of their volume protrudes from the water, than for C. pseudocyperus and I. pseudacorus seeds. 4. The principal factors that determine seed deposition were aquatic plant cover, ditch slope and indentations in the ditch bank. Seeds changed direction if the wind direction changed, or if there was a bend in the ditch. The final pattern of deposition was related to mean net wind speed. Mean transport distance after 2 days varied between 34 and 451 m. 5. Unlike in rivers, seed transport in ditches was determined by wind speed and direction, enabling multidirectional seed dispersal. We conclude that in slow-flowing waters, wind is a more important driver for hydrochorous seed transport than the flow of water. This sheds a new light on hydrochory and has important consequences for the management of otherwise fragmented wetland remnants. [source] Freshwater availability as the constraining factor in the Middle Paleoindian occupation of North-Central FloridaGEOARCHAEOLOGY: AN INTERNATIONAL JOURNAL, Issue 3 2009David K. Thulman The locations of reliable surface water exposures during the Middle Paleoindian period (10,800,10,200 14C yr B.P.) in north-central Florida are reconstructed and compared to the concentrations of Middle Paleoindian projectile points. Estimates of water table levels and surface water flow in Florida's karst geology confirm prior climate reconstructions for that time indicating the area was arid and supported a xeric ecology in most upland locales. Surface water flow data from recent extreme droughts and water table estimations are used to identify the areas of highest probability for surface water availability. The distribution of the highest concentrations of Middle Paleoindian points correlates with the areas of highest probability, indicating that scarce surface water sources were the strongest constraint on occupation location during that time. © 2009 Wiley Periodicals, Inc. [source] Hydrological influences on hyporheic water quality: implications for salmon egg survivalHYDROLOGICAL PROCESSES, Issue 9 2004I. A. Malcolm Abstract The spatial and temporal variability of groundwater,surface-water (GW,SW) interactions was investigated in an intensively utilized salmon spawning riffle. Hydrochemical tracers, were used along with high-resolution hydraulic head and temperature data to assess hyporheic dynamics. Surface and subsurface hydrochemistry were monitored at three locations where salmon spawning had been observed in previous years. Temperature and hydraulic head were monitored in three nests of three piezometers located to characterize the head, the run and the tail-out of the riffle feature. Hydrochemical gradients between surface and subsurface water indicated increasing GW influence with depth into the hyporheic zone. Surface water was characterized by high dissolved oxygen (DO) concentrations, low alkalinity and conductivity. Hyporheic water was generally characterized by high levels of alkalinity and conductivity indicative of longer residence times, and low DO, indicative of reducing conditions. Hydrochemical and temperature gradients varied spatially over the riffle in response to changes in local GW,SW interactions at the depths investigated. Groundwater inputs dominated the head and tail of the riffle. The influence of SW increased in the area of accelerating flow and decreasing water depth through the run of the riffle. Temporal GW,SW interactions also varied in response to changing hydrological conditions. Gross changes in hyporheic hydrochemistry were observed at the weekly scale in response to changing flow conditions and surface water inputs to the hyporheic zone. During low flows, caused by freezing or dry weather, hyporheic hydrochemistry was dominated by GW inputs. During higher flows hyporheic hydrochemistry indicated that SW contributions increased. In addition, high-resolution hydraulic head data indicated that rapid changes in GW,SW interactions occurred during hydrological events. The spatial, and possibly the temporal, variability of GW,SW interactions had a marked effect on the survival of salmon ova. It is concluded that hyporheic dynamics and their effect on stream ecology should be given increased consideration by fisheries and water resource managers. Copyright © 2004 John Wiley & Sons, Ltd. [source] Importance of soil surface characteristics on water erosion in a small grazed Sahelian catchmentHYDROLOGICAL PROCESSES, Issue 8 2003H. Karambiri Abstract This study concerns the problem of water erosion in the Sahel. Surface water and sediment yields (suspended matter and bedload) were monitored for 3 years (1998,2000) at the outlet of a small grazed catchment (1·4 ha) in the northern part of Burkina Faso. The catchment consists of about 64% sandy deposits (DRY soil surface type), which support most of the vegetation, and about 34% of crusted bare soils (ERO soil surface type). The annual solid-matter export is more than 90% suspended sediment, varying between 4·0 and 8·4 t ha,1. The bedload represents less than 10% of soil losses. In a single flood event (10 year return period), the sediment yield can reach 4·2 t ha,1. During the period studied, a small proportion (20 to 32%) of the floods was thus responsible for a large proportion (80%) of the solid transport. Seasonal variation of the suspended-matter content was also observed: high mean values (9 g l,1) in June, decreasing in July and stabilizing in August (between 2 and 4 g l,1). This behaviour may be a consequence of a reorganization of the soil surfaces that have been destroyed by trampling animals during the previous long dry season, vegetation growth (increase in the protecting effect of the herbaceous cover) and, to a lesser extent, particle-supply limitation (exhaustion of dust deposits during July). The particle-size distribution in the suspended matter collected at the catchment outlet is 60% made up of clay: fraction ,2 µ m. The contribution of this clay is maximum when the water rises and its kaolinite/quartz ratio is then close to that of the ERO-type surfaces. This indicates that these surfaces are the main source of clay within the catchment. Copyright © 2003 John Wiley & Sons, Ltd. [source] CHANGES IN LAND USE/MANAGEMENT AND WATER QUALITY IN THE LONG CREEK WATERSHED,JOURNAL OF THE AMERICAN WATER RESOURCES ASSOCIATION, Issue 6 2002Daniel E. Line ABSTRACT: Surface water in the Long Creek watershed, located in western Piedmont region of North Carolina, was monitored from 1993 to 2001. The 8,190 ha watershed has undergone considerable land use and management changes during this period. Land use surveys have documented a 60 percent decrease in cropland area and a more than 200 percent increase in areas being developed into new homes. In addition, more than 200 conservation practices have been applied to the cropland and other agricultural land that remains in production. The water quality of Long Creek was monitored by collecting grab samples at four sites along Long Creek and continuously monitoring discharge at one site. The monitoring has documented a 70 percent reduction in median total phosphorus (TP) concentrations, with little reductions in nitrate and total Kjel-dahl nitrogen, or suspended sediment levels. Fecal coliform (FC) and streptococci (FS) levels declined significantly downstream as compared to upstream during the last four years of monitoring. This decrease was attributed to the implementation of waste management practices and livestock exclusion fencing on three dairy operations in the watershed. Annual rainfall and discharge increased steadily until peaking in the third year of the monitoring period and varied while generally decreasing during the last four years of the project. An array of observation, pollutant concentration, and hydrologic data provide considerable evidence to suggest that the implementation of BMPs in the watershed have significantly reduced phosphorus and bacteria levels in Long Creek. [source] Self-Association Based on Interfacial Structured Water Leads to {Mo154},1165 Super Clusters: A Dielectric StudyCHEMPHYSCHEM, Issue 5 2007Alla Oleinikova Dr. Surface water does the job: Molybdenum blue solutions contain unique nanosized wheel-shaped polyoxometalate-type clusters, while structured surface water on the clusters initiates the assembly, leading to the super cluster shown in the figure, which contains an internal "water pool". [source] Hydrogeochemistry and Water Quality Evaluation along the Flow Path in the Unconfined Aquifer of the Düzce Plain, North-western TurkeyACTA GEOLOGICA SINICA (ENGLISH EDITION), Issue 1 2010Nail ÜNSAL Abstract: The Düzce Plain has a multi-aquifer system, which consists of a near surface unconfined aquifer, along with first and second deeper confined aquifers. Hydrochemical evolution and water quality are related to infiltration of the precipitation, recharge from the formations surrounding the plain, flow path of groundwater and the relationship between surface and groundwater. The groundwater in the unconfined aquifer flows towards the Efteni Lake and the Büyük Melen River. Surface waters are divided into two main hydrochemical facies in the study area: (a) Ca2+,HCO3,; and (b) Ca2+, Mg2+,HCO3, SO2,4. The groundwater has generally three main hydrochemical facies: (a) Ca2+,HCO,; (b) Ca2+, Mg2+,HCO,3; and (c) Ca2+, Mg2+,HCO,3, CI,. The hydrochemical facies "a" and "b" dominate within shallow depths in recharge areas under rapid flow conditions, while hydrochemical facies "c" characterizes shallow and mixed groundwater, which dominate intermediate or discharge areas (near Efteni Lake and Büyük Melen River) during low flow conditions and agricultural contamination. Calcium and bicarbonate ions, total hardness and electrical conductivity of total dissolved solids (EC-TDS) values increase along the groundwater flow path; but these parameters remain within the limits specified by the standards set for industrial and agricultural usages. [source] Channel head location and characteristics using digital elevation modelsEARTH SURFACE PROCESSES AND LANDFORMS, Issue 7 2006G. R. Hancock Abstract The drainage network is the conduit through which much surface water and sediment are routed within a catchment. In a catchment, the position of where hillslopes begin and channels end has long been considered the position of transition between diffusive processes upslope and the more incisive fluvial processes downslope. Consequently, understanding channel head location is an important issue in understanding catchment hydrology and geomorphology. This study examines channel head position and characteristics in a catchment in Arnhem Land, Northern Territory, Australia. In this study the position of channel heads was mapped within the catchment and plotted on a reliable digital elevation model of the catchment. It was found that the majority of channel heads have relatively small source areas and that graphical catchment descriptors, such as the area,slope relationship and cumulative area distribution, can provide reliable measures of the field position of the heads of first-order streams and the transition from hillslope to channel. The area,slope relationship and cumulative area distribution are also shown to be good tools for determining digital elevation model grid size which can capture hillslope detail and the transition from hillslope to channel. Copyright © 2005 John Wiley & Sons, Ltd. [source] Gene diversity of CYP153A and AlkB alkane hydroxylases in oil-degrading bacteria isolated from the Atlantic OceanENVIRONMENTAL MICROBIOLOGY, Issue 5 2010Liping Wang Summary Alkane hydroxylases, including the integral-membrane non-haem iron monooxygenase (AlkB) and cytochrome P450 CYP153 family, are key enzymes in bacterial alkane oxidation. Although both genes have been detected in a number of bacteria and environments, knowledge about the diversity of these genes in marine alkane-degrading bacteria is still limited, especially in pelagic areas. In this report, 177 bacterial isolates, comprising 43 genera, were obtained from 18 oil-degrading consortia enriched from surface seawater samples collected from the Atlantic Ocean. Many isolates were confirmed to be the first oil-degraders in their affiliated genera including Brachybacterium, Idiomarina, Leifsonia, Martelella, Kordiimonas, Parvibaculum and Tistrella. Using degenerate PCR primers, alkB and CYP153A P450 genes were surveyed in these bacteria. In total, 82 P450 and 52 alkB gene fragments were obtained from 80 of the isolates. These isolates mainly belonged to Alcanivorax, Bacillus, Erythrobacter, Martelella, Parvibaculum and Salinisphaera, some of which were reported, for the first time, to encode alkane hydroxylases. Phylogenetic analysis showed that both genes were quite diverse and formed several clusters, most of which were generated from various Alcanivorax bacteria. Noticeably, some sequences, such as those from the Salinisphaera genus, were grouped into a distantly related novel cluster. Inspection of the linkage between gene and host revealed that alkB and P450 tend to coexist in Alcanivorax and Salinisphaera, while in all isolates of Parvibaculum, only P450 genes were found, but of multiple homologues. Multiple homologues of alkB mostly cooccurred in Alcanivorax isolates. Conversely, distantly related isolates contained similar or even identical sequences. In summary, various oil-degrading bacteria, which harboured diverse P450 and alkB genes, were found in the surface water of Atlantic Ocean. Our results help to show the diversity of P450 and alkB genes in prokaryotes, and to portray the geographic distribution of oil-degrading bacteria in marine environments. [source] Human enteric viruses in groundwater indicate offshore transport of human sewage to coral reefs of the Upper Florida KeysENVIRONMENTAL MICROBIOLOGY, Issue 4 2010J. Carrie Futch Summary To address the issue of human sewage reaching corals along the main reef of the Florida Keys, samples were collected from surface water, groundwater and coral [surface mucopolysaccharide layers (SML)] along a 10 km transect near Key Largo, FL. Samples were collected semi-annually between July 2003 and September 2005 and processed for faecal indicator bacteria (faecal coliform bacteria, enterococci and Clostridium perfringens) and human-specific enteric viruses (enterovirus RNA and adenovirus DNA) by (RT)-nested polymerase chain reaction. Faecal indicator bacteria concentrations were generally higher nearshore and in the coral SML. Enteric viruses were evenly distributed across the transect stations. Adenoviruses were detected in 37 of 75 samples collected (49.3%) whereas enteroviruses were only found in 8 of 75 samples (10.7%). Both viruses were detected twice as frequently in coral compared with surface water or groundwater. Offshore, viruses were most likely to be found in groundwater, especially during the wet summer season. These data suggest that polluted groundwater may be moving to the outer reef environment in the Florida Keys. [source] The use of technical knowledge in European water policy-makingENVIRONMENTAL POLICY AND GOVERNANCE, Issue 5 2010Perry J. M. van Overveld Abstract Environmental policy-making often involves a mix of technical knowledge, normative choice and uncertainty. Numerous actors, each with their own distinct objectives, are involved in these policy-making processes. One question these actors face, is how they can effectively communicate their technical knowledge and represent their interests in policy-making. The objective of this paper is to identify the factors that influence the use of technical knowledge and its impact on decision-making in the European Union. This is done for case of water policy-making for organic micropollutants, such as pesticides and pharmaceuticals. These pollutants enter the surface water in many ways and although concentrations are low, adverse effects cannot be ruled out. Via the EU Water Framework Directive, legislation has been developed to reduce the emissions of pollutants that pose a risk to ecology or public health. Using the advocacy coalition framework, the formal EU decision-making processes are analyzed for the identification of priority pollutants (Priority Substances) and the derivation of maximum allowable concentrations (Environmental Quality Standards). To enable a detailed analysis, the focus is on three specific micropollutants that pose health risks via drinking water supply. The findings show the extent to which actors can influence the decision-making process with technical knowledge. Early involvement in the drafting process that is led by the European Commission is important to influence decision-making outcomes. For this, organizational capacity in coalitions to mobilize and coordinate the required targeted contribution of technical knowledge is crucial. Copyright © 2010 John Wiley & Sons, Ltd and ERP Environment. [source] Ultrasonic treatment of waste activated sludgeENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY, Issue 2 2006Raf Dewil Abstract Activated sludge processes are key technologies to treat wastewater. These biological processes produce huge amounts of waste activated sludge (WAS), now commonly called biosolids. Mechanical, thermal, and/or chemical WAS conditioning techniques have been proposed to reduce the sludge burden. The ultrasonic treatment of WAS is quite novel. The present paper reports on extensive investigations using an ultrasonic treatment of WAS, to study its potential to meet one or all of four objectives: (1) reduce WAS quantities; (2) achieve a better dewaterability; (3) provoke a release of soluble chemical oxygen demand (COD) from the biosolids, preferably transformed into biodegradable organics; and (4) possibly destroy the filamentous microorganisms responsible for sludge bulking. Although meeting these objectives would help to solve the problems cited, the energy consumption could be a considerable drawback: the paper will thus assess whether all or some objectives are met, and at what operational cost. A literature survey defines the occurring phenomena (cavitation) and the important operation parameters [such as frequency, duration, specific energy input (SE)]. The experiments are carried out in a batch reactor of volume up to 2.3 L. The ultrasonic equipment consisted of a generator, a converter, and a sonotrode, supplied by Alpha Ultrasonics under the brand name of Telsonic. Three different kinds of sludge were tested, with different concentrations of dry solids (DS) between approximately 3.5 and 14 g DS/L WAS. Ultrasonic energy was introduced in a continuous manner (against possible pulsed operation). The major operational parameters studied include duration of the ultrasonic treatment and specific energy input. The applied frequency was set at 20 kHz. The release of COD from the WAS phase into the filtrate phase is a function of the specific energy input with yields of nearly 30% achievable at SE values of 30,000 kJ/kg DS. A major fraction of the COD is transformed into biodegradable organics (BOD). The reduction in DS fraction of the sludge is proportional to the COD release rates. Although the DS content is reduced, the dewaterability of the sludge is not improved. This reflects itself in increased filtration times during vacuum filtration and in increased values of the capillary suction time (CST). This more difficult dewaterability is the result of considerably reduced floc sizes, offering an extended surface area: more surface water is bound (CST increases) and the filterability decreases as a result of clogging of the cake. To reach the same dryness as for the untreated cake, the required dosage of polyelectrolyte is nearly doubled when the SE of the ultrasound treatment is increased from 7500 to 20,000 kJ/kg DS. The ultrasonic reduction of filamentous WAS organisms is not conclusive and very little effect is seen at low intensities and short treatment durations. Microscopic analysis of the WAS identified the dominant presence of Actynomyces. The release of soluble COD and BOD certainly merit further research. © 2006 American Institute of Chemical Engineers Environ Prog, 2006 [source] Phosphate regulates uranium(VI) toxicity to Lemna gibba L. G3ENVIRONMENTAL TOXICOLOGY, Issue 1 2007Martin Mkandawire Abstract The influence of phosphate on the toxicity of uranium to Lemna gibba G3 was tested in semicontinuous culture with synthetic mine water developed as an analogue of surface water of two abandoned uranium mining and ore processing sites in Saxony, Germany. Six concentrations of uranium were investigated under five different supply regimes of PO43, at constant pH (7.0 ± 0.5) and alkalinity (7.0 ± 1.6 mg L,1 total CO32,). The results showed significant inhibition of specific growth rates in cultures exposed to the highest uranium concentrations (3500 and 7000 ,g U L,1) at lowest PO43, supply of 0.01 mg L,1. An increase of phosphate concentration from 0.01 to 8.0 mg L,1 resulted in an increase of EC50 from 0.9 ± 0.2 to 7.4 ± 1.9 mg L,1 (significant with Student's t test, P > 0.05). The accumulation of uranium in L. gibba increased exponentially with the increase in uranium concentration in cultures with 0.01 and 0.14 mg PO43, L,1. Accumulation also increased significantly when PO43, supply was increased from 0.14 to 1.36 mg PO43, L,1 for all uranium concentrations. However, as the supply of PO43, gradually increased from 1.36 to 8.0 mg PO43, L,1, uranium bioaccumulation increased slightly but insignificantly before leveling off. Uranium speciation modeling with PhreeqC geochemical code predicted increases in the proportions of uranyl phosphate species when PO43, concentrations increase in the media. Most of these uranyl phosphate species have a high probability of precipitation [saturation indices (SI) > 0.93]. Therefore, the alleviation of uranium toxicity to L. gibba with phosphates is due to interactions among components of the media, mainly uranyl and phosphate which results in precipitation. Consequently, bioavailable fractions of uranium to L. gibba are reduced. This might explain lack of consistent EC50 values for uranium to most aquatic organisms. © 2007 Wiley Periodicals, Inc. Environ Toxicol 22: 9,16, 2007. [source] Occurrence and fate of micropollutants in the Vidy Bay of Lake Geneva, Switzerland.ENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 8 2010Part I: Priority list for environmental risk assessment of pharmaceuticals Abstract Pharmaceuticals are substances designed to have a biological effect in humans. Their presence in the environment, especially in surface waters, is of increasing concern because of their potential risk to non-target species. A large number of pharmaceuticals are on the market; for example, approximately 2,000 active ingredients are approved in Europe, and many of them have already been detected in surface water. It is therefore crucial to select the substances that may do the most harm to the environment prior to performing measurements and extensive risk assessment. In the present study, a method to determine a list of pharmaceuticals to survey in surface water is proposed. Inclusion of substances on the list was based on a screening procedure, the analytical feasibility, and previous knowledge of pharmaceuticals detected in water. The screening procedure proposed here is an improvement on the standard procedure of the European Medicine Evaluation Agency (EMEA). It is designed to decrease the number of pharmaceuticals to be evaluated in a stepwise manner, thus decreasing the number of data necessary for the evaluation. We applied our approach to determine a list of 37 pharmaceuticals and four hormones to survey in a specific region of Switzerland, the Lake Geneva area, and discussed the advantages and weak points of the method. Environ. Toxicol. Chem. 2010; 29:1649,1657. © 2010 SETAC [source] Sampling in the Great Lakes for pharmaceuticals, personal care products, and endocrine-disrupting substances using the passive polar organic chemical integrative samplerENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 4 2010Hongxia Li Abstract The passive polar organic chemical integrative sampler in the pharmaceutical configuration (i.e., pharmaceutical-POCIS) was calibrated for sampling at water temperatures of 5, 15 and 25°C to determine the influence of temperature on chemical-specific sampling rates (RS), thus providing more robust estimates of the time-weighted average concentrations of pharmaceuticals and personal care products (PPCPs) and endocrine-disrupting substances (EDS) in surface water. The effect of water temperature and flow on the RS of these analytes was evaluated in the laboratory with a static system. The loss of the test compounds from water by uptake into POCIS was linear over an 8-d period, and these experimental data yielded RS values in the range of 0.07 to 2.46 L/d across the temperature range for the 30 compounds tested. Water temperature and flow influenced POCIS uptake rates, but these effects were relatively small, which is consistent with the theory for uptake into POCIS samplers. Therefore, under a narrow range of water temperatures and flows, it may not be necessary to adjust the RS for POCIS. Except for acidic drugs and sulfonamide antibiotics, RS values were positively correlated with octanol,water partition coefficients (log KOW) of the test compounds. A linear relationship was also observed between RS and chromatographic retention times on a C18 reversed-phase column. These observations may provide a rapid method for estimating the RS of additional chemicals in the POCIS. The application of the RS to POCIS deployed for one month in Lake Ontario, Canada, during the summers of 2006 and 2008 yielded estimates of PPCP and EDS concentrations that are consistent with conventional concentration measurements of these compounds in Lake Ontario surface water. Environ. Toxicol. Chem. 2010;29:751,762. © 2009 SETAC [source] Exposure assessment of 17,-ethinylestradiol in surface waters of the United States and Europe,ENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 12 2009Robert Hannah Abstract An evaluation of measured and predicted concentrations of 17,-ethinylestradiol in surface waters of the United States and Europe was conducted to develop expected long-term exposure concentrations for this compound. Measured environmental concentrations (MECs) in surface waters were identified from the literature. Predicted environmental concentrations (PECs) were generated for European and U.S. watersheds using the GREAT-ER and PhATEÔ models, respectively. The majority of MECs are nondetect and generally consistent with model PECs and conservative mass balance calculations. However, the highest MECs are not consistent with concentrations derived from conservative (worst-case) mass balance estimates or model PECs. A review of analytical methods suggests that tandem or high-resolution mass spectrometry methods with extract cleanup result in lower detection limits and lower reported concentrations consistent with model predictions and bounding estimates. Based on model results using PhATE and GREAT-ER, the 90th-percentile low-flow PECs in surface water are approximately 0.2 and 0.3 ng/L for the United States and Europe, respectively. These levels represent conservative estimates of long-term exposure that can be used for risk assessment purposes. Our analysis also indicates that average concentrations are one to two orders of magnitude lower than these 90th-percentile estimates. Higher reported concentrations (e.g., greater than the 99th-percentile PEC of ,1 ng/L) could result from methodological problems or unusual environmental circumstances; however, such concentrations are not representative of levels generally found in the environment, warrant special scrutiny, and are not appropriate for use in risk assessments of long-term exposures. [source] Field testing of equilibrium passive samplers to determine freely dissolved native polycyclic aromatic hydrocarbon concentrationsENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 3 2008Gerard Cornelissen Abstract Equilibrium passive samplers are promising tools to determine freely dissolved aqueous concentrations (CW,free) of hydrophobic organic compounds. Their use in the field, however, remains a challenge. In the present study on native polycyclic aromatic hydrocarbons (PAHs) in Oslo Harbor, Norway, two different passive sampler materials, polyoxymethylene (POM; thickness, 55 ,m [POM-55] and 500 ,m [POM-500]) and polydimethylsiloxane (PDMS; thickness, 200 ,m), were used to determine in the laboratory CW,free in sediment pore water (CPW,free), and the suitability of five passive samplers for determination of CW,free in overlying surface water was tested under field conditions. For laboratory determinations of CPW,free, both POM-55 and PDMS turned out to be suitable. In the field, the shortest equilibrium times (approximately one month) were observed for POM-55 and PDMS (thickness, 28 ,m) coatings on solid-phase microextraction fibers, with PDMS tubing as a good alternative. Low-density polyethylene (thickness, 100 ,m) and POM-500 did not reach equilibrium within 119 d in the field. Realistic values were obtained for dissolved organic carbon,water partition coefficients in the field (approximately one log unit under log KOW), which strengthened the conclusion that equilibrium was established in field-exposed passive samplers. At all four stations, chemical activity ratios between pore water and overlying water were greater than one for all PAHs, indicating that the sediment was a PAH diffusion source and that sediment remediation may be an appropriate treatment for PAH contamination in Oslo Harbor. [source] Degradation kinetics of ptaquiloside in soil and soil solutionENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 2 2008Rikke Gleerup Ovesen Abstract Ptaquiloside (PTA) is a carcinogenic norsesquiterpene glycoside produced in bracken (Pteridium aquilinum (L.) Kuhn), a widespread, aggressive weed. Transfer of PTA to soil and soil solution eventually may contaminate groundwater and surface water. Degradation rates of PTA were quantified in soil and soil solutions in sandy and clayey soils subjected to high natural PTA loads from bracken stands. Degradation kinetics in moist soil could be fitted with the sum of a fast and a slow first-order reaction; the fast reaction contributed 20 to 50% of the total degradation of PTA. The fast reaction was similar in all horizons, with the rate constant k1F ranging between 0.23 and 1.5/h. The slow degradation, with the rate constant k1S ranging between 0.00067 and 0.029/h, was more than twice as fast in topsoils compared to subsoils, which is attributable to higher microbial activity in topsoils. Experiments with sterile controls confirmed that nonmicrobial degradation processes constituted more than 90% of the fast degradation and 50% of the slow degradation. The lower nonmicrobial degradation rate observed in the clayey compared with the sandy soil is attributed to a stabilizing effect of PTA by clay silicates. Ptaquiloside appeared to be stable in all soil solutions, in which no degradation was observed within a period of 28 d, in strong contrast to previous studies of hydrolysis rates in artificial aqueous electrolytes. The present study predicts that the risk of PTA leaching is controlled mainly by the residence time of pore water in soil, soil microbial activity, and content of organic matter and clay silicates. [source] Modeling polycyclic aromatic hydrocarbon composition profiles of sources and receptors in the Pearl River Delta, China,ENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 1 2008Chang Lang Abstract Changes in concentration profiles of polycyclic aromatic hydrocarbons (PAHs) from emission sources to various environmental media in the Pearl River Delta, China were investigated using fugacity modeling under steady state assumption. Both assumed evenly and observed unevenly distributed PAH moles emission profiles were applied. Applicability of the fugacity model was validated against the observed media PAH concentrations and profiles. At equal emission rates, the differences of media concentrations among various PAHS were as high as three (air) to seven (soil and sediment) orders of magnitude. Dramatic changes of PAH profiles from emission sources to various bulk environmental media also were demonstrated by using the actual emission rates. In general, the fractions of higher molecular weight PAHs in air and water were much lower than those at the emission sources, although the PAH profiles in soil and sediment were characterized by a significant reduction of lower molecular weight PAHs. It is likely that the field-measured median concentration profiles cannot be adopted directly for source apportionment without rectification. The most influential parameters affecting PAH profiles in the study area were emission rates, degradation rates, adsorption coefficient, Henry's law constant, PAH concentrations in upstream surface water, fugacity ratio, vapor pressure, and diffusion coefficient in air. [source] Bioassays with caged Hyalella azteca to determine in situ toxicity downstream of two Saskatchewan, Canada, uranium operations,ENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 11 2007Erin L. Robertson Abstract The main objectives of this in situ study were to evaluate the usefulness of an in situ bioassay to determine if downstream water bodies at the Key Lake and Rabbit Lake uranium operations (Saskatchewan, Canada) were toxic to Hyalella azteca and, if toxicity was observed, to differentiate between the contribution of surface water and sediment contamination to in situ toxicity. These objectives were achieved by performing 4-d in situ bioassays with laboratory-reared H. azteca confined in specially designed, paired, surface water and sediment exposure chambers. Results from the in situ bioassays revealed significant mortality, relative to the respective reference site, at the exposure sites at both Key Lake (p , 0.001) and Rabbit Lake (p = 0.001). No statistical differences were found between survival in surface water and sediment exposure chambers at either Key Lake (p = 0.232) or Rabbit Lake (p = 0.072). This suggests that surface water (the common feature of both types of exposure chambers) was the primary cause of in situ mortality of H. azteca at both operations, although this relationship was stronger at Key Lake. At Key Lake, the primary cause of aquatic toxicity to H. azteca did not appear to be correlated with the variables measured in this study, but most likely with a pulse of organic mill-process chemicals released during the time of the in situ study , a transient event that was caused by a problem with the mill's solvent extraction process. The suspected cause of in situ toxicity to H. azteca at Rabbit Lake was high levels of uranium in surface water, sediment, and pore water. [source] Wastewater treatment plants as a pathway for aquatic contamination by pharmaceuticals in the Ebro river basin (Northeast Spain)ENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 8 2007Meritxell Gros Abstract The occurrence of 28 pharmaceuticals of major human consumption in Spain, including analgesics and anti-inflam-matories, lipid regulators, psychiatric drugs, antibiotics, antihistamines, and ,-blockers, was assessed along the Ebro river basin, one of the biggest irrigated lands in that country. Target compounds were simultaneously analyzed by off-line solid-phase extraction, followed by liquid chromatography-tandem mass spectrometry. The loads of detected pharmaceuticals and their removal rates were studied in seven wastewater treatment plants (WWTPs) located in the main cities along the basin. Total loads ranged from 2 to 5 and from 0.5 to 1.5 g/d/1,000 inhabitants in influent and effluent wastewaters, respectively. High removal rates (60,90%) were achieved mainly for analgesics and anti-inflammatories. The other groups showed lower rates, ranging from 20 to 60%, and in most cases, the antiepileptic carbamazepine, macrolide antibiotics, and trimethoprim were not eliminated at all. Finally, the contribution of WWTP effluents to the presence of pharmaceuticals in receiving river waters was surveyed. In receiving surface water, the most ubiquitous compounds were the analgesics and anti-inflammatories ibuprofen, diclofenac, and naproxen; the lipid regulators bezafibrate and gemfibrozil; the antibiotics erythromycin, azithromycin, sulfamethoxazole, trimethoprim, and less frequently, ofloxacin; the antiepileptic carbamazepine; the antihistamine ranitidine; and the ,-blockers atenolol and sotalol. Although levels found in WWTP effluents ranged from low ,g/L to high ng/L, pharmaceuticals in river waters occurred at levels at least one order of magnitude lower (low ng/L range) because of dilution effect. From the results obtained, it was proved that WWTP are hot spots of aquatic contamination concerning pharmaceuticals of human consumption. [source] Perchlorate assessment of the Nakdong and Yeongsan watersheds, Republic of KoreaENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 7 2007Oscar Quiñones Abstract The objective of the present study was to conduct a preliminary assessment for perchlorate in surface water, drinking water, and wastewater treatment plant effluent samples obtained from the Nakdong and Yeongsan watersheds in the Republic of Korea. Samples were analyzed for perchlorate using ion chromatography with suppressed conductivity detection (IC-CD) and/or liquid chromatography with tandem mass spectrometry detection (LC-MS/MS). Method reporting limits were 5.0 ,g/L for IC-CD and 0.05 ,g/L for LC-MS/MS analysis. At perchlorate levels above 5.0 ,g/L, IC-CD and LC-MS/MS provided comparable results. The levels of perchlorate detected in the samples procured from the Yeongsan watershed were <5.0 ,g/L in each case. However, Nakdong watershed samples contained perchlorate at levels up to 60 ,g/L. The highest concentrations of perchlorate were found in surface water samples, although drinking water contained perchlorate at concentrations up to 35 ,g/L. In a subset of samples analyzed by LC-MS/MS, chlorate and bromate also were detected at concentrations ranging from <0.10 to 44 ,g/L and <0.10 to 2.6 ,g/L, respectively. To the best of the authors' knowledge, this is the first perchlorate assessment reported for water sources in the Republic of Korea. [source] Seasonality effects on pharmaceuticals and s -triazine herbicides in wastewater effluent and surface water from the Canadian side of the upper Detroit RiverENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 9 2006Wen Yi Hua Abstract The influence of seasonal changes in water conditions and parameters on several major pharmacologically active compounds (PhACs) and s -triazine herbicides was assessed in the wastewater and sewage treatment plant (WSTP) effluent as well as the downstream surface water from sites on the Canadian side of the upper Detroit River, between the Little River WSTP and near the water intake of a major drinking water treatment facility for the City of Windsor (ON, Canada). The assessed PhACs were of neutral (carbamazepine, cotinine, caffeine, cyclophosphamide, fluoxetine, norfluoxetine, pentoxifylline, and trimethoprim) and acidic (ibuprofen, bezafibrate, clofibric acid, diclofenac, fenoprofen, gemfibrozil, indomethacin, naproxen, and ketoprofen) varieties. The major assessed s -triazine herbicides were atrazine, simazine, propazine, prometon, ametryn, prometryn, and terbutryn. At sampling times from September 2002 to June 2003, 15 PhACs were detected in the WSTP effluent at concentrations ranging from 1.7 to 1,244 ng/L. The PhAC concentrations decreased by as much 92 to 100% at the Little River/Detroit River confluence because of the river dilution effect, with further continual decreases at sites downstream from the WSTP. The only quantifiable s -triazine in WSTP effluent, atrazine, ranged from 6.7 to 200 ng/L and was higher in Detroit River surface waters than in WSTP effluent. Only carbamazepine, cotinine, and atrazine were detectable at the low-nanogram and subnanogram levels in surface waters near a drinking water intake site. Unlike the PhACs, atrazine in the Detroit River is not attributable to point sources, and it is heavily influenced by seasonal agricultural usage and runoff. Detroit River surface water concentrations of carbamazepine, cotinine, and atrazine may present a health concern to aquatic wildlife and to humans via the consumption of drinking water. [source] Bioconcentration of persistent organic pollutants in four species of marine phytoplanktonENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 11 2005Antje Gerofke Abstract The uptake of polychlorinated biphenyls (PCBs) was studied in four species of marine algae. A novel experimental system to establish and maintain constant dissolved concentrations of PCBs was employed. Headspace sampling was used to verify that the freely dissolved concentrations remained constant with time. The headspace analysis also allowed sorption to dissolved organic carbon (DOC) to be quantified for all but the most lipophilic PCB congeners. Equilibration with the dissolved phase was rapid for three of the four algae species (<1 d for the majority of congeners). Organic carbon,normalized algae/water partition coefficients (KAlgW) were similar for three of the four species, but were lower by a factor of 10 to 20 for Phaeodactylum tricornutum. The KAlgW values of the first three species were similar to the octanol/water partition coefficient (KOW) for those PCB congeners for which DOC sorption could be quantified. These KAlgW values also agreed well with organic carbon,normalized bioconcentration factors for PCBs in suspended particulate matter (BCFSPM) sampled in Baltic Sea surface water during the summer. [source] Toxicity of fluoroquinolone antibiotics to aquatic organismsENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 2 2005April A. Robinson Abstract Toxicity tests were performed with seven fluoroquinolone antibiotics, ciprofloxacin, lomefloxacin, ofloxacin, levofloxacin, clinafloxacin, enrofloxacin, and flumequine, on five aquatic organisms. Overall toxicity values ranged from 7.9 to 23,000 ,g/L. The cyanobacterium Microcystis aeruginosa was the most sensitive organism (5-d growth and reproduction, effective concentrations [EC50s] ranging from 7.9 to 1,960 ,g/L and a median of 49 ,g/L), followed by duckweed (Lemna minor, 7-d reproduction, EC50 values ranged from 53 to 2,470 ,g/L with a median of 106 ,g/L) and the green alga Pseudokirchneriella subcapitata (3-d growth and reproduction, EC50 values ranged from 1,100 to 22,700 ,g/L with a median 7,400 ,g/L). Results from tests with the crustacean Daphnia magna (48-h survival) and fathead minnow (Pimephales promelas, 7-d early life stage survival and growth) showed limited toxicity with no-observed-effect concentrations at or near 10 mg/L. Fish dry weights obtained in the ciprofloxacin, levofloxacin, and ofloxacin treatments (10 mg/L) were significantly higher than in control fish. The hazard of adverse effects occurring to the tested organisms in the environment was quantified by using hazard quotients. An estimated environmental concentration of 1 ,g/L was chosen based on measured environmental concentrations previously reported in surface water; at this level, only M. aeruginosa may be at risk in surface water. However, the selective toxicity of these compounds may have implications for aquatic community structure. [source] | |||||||||||||||||||||||||||||||||||||||||||