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S/N Ratio (s/n + ratio)
Selected AbstractsA Study of the Determination of Cu(II) by Anodic Stripping Voltammetry on a Novel Nylon/Carbon Fiber ElectrodeELECTROANALYSIS, Issue 7 2004A. Mylonakis Abstract In this work we report a new electrode material formed by injection-moulding of a conducting polymer consisting of carbon fibers in a Nylon matrix. This material is highly conductive, inexpensive, easy to mould in different shapes and requires minimal pretreatment. The electrode was tested as a mercury-free sensor for the trace determination of Cu(II) by anodic stripping voltammetry (ASV). The deposition and stripping behavior of copper on the conducting material was initially studied by cyclic voltammetry and the chemical and instrumental parameters of the determination were investigated. The electrode has been shown to be suitable for the determination of Cu(II) in the range 8,,g L,1 to 30,mg,L,1 (with deposition times ranging from 30,s to 10,min) with a relative standard deviation of 2.2% (at the 0.5,mg,L,1 level) and a limit of detection of 8,,g L,1 Cu(II) for 10,min of accumulation (at a S/N ratio of 5). The electrode was, finally, applied to the determination of copper in tap-water, pharmaceutical tablets and bovine serum with recoveries of 97.4, 94.9 and 93.4%, respectively [source] Application of Hadamard transformation to MEKCELECTROPHORESIS, Issue 3 2007Kazuki Hata Abstract The Hadamard transform (HT) technique, which permits the S/N in CE to be improved, was applied to MEKC. Multiple sample injection of fluorescent analytes according to a Hadamard code sequence was performed using an optically gated sample injection technique, in which a sample plug was produced based on photodegradation by irradiation with an intense laser beam. The capillary and reservoirs were filled with a sample solution containing buffer components and SDS as a pseudostationary phase. A preliminary study confirmed that fluorescein ion could be photobleached in the presence of SDS. The optically gated sample injection technique was then applied to multiple sample injection, based on a Hadamard matrix. The S/N in the electropherogram obtained by HT-MEKC was improved substantially compared to that obtained by a single injection method. When the technique was applied to the separation of several amino acids labeled with FITC, the S/N ratio for each amino acid was enhanced, without any evidence of degradation in separation resolution. Moreover, HT-MEKC was applied to the analysis of amino acids contained in a Japanese beverage, resulting in improved S/Ns for the amino acids. [source] Magnetic Resonance Sounding: New Method for Ground Water AssessmentGROUND WATER, Issue 2 2004M. Lubczynski The advantage of magnetic resonance sounding (MRS) as compared to other classical geophysical methods is in its water selective approach and reduced ambiguity in determination of subsurface free water content and hydraulic properties of the media due to the nuclear magnetic resonance (NMR) principle applied. Two case examples are used to explain how hydrogeological parameters are obtained from an MRS survey. The first case example in Delft (the Netherlands) is a multiaquifer system characterized by large signal to noise ratio (S/N = 73), with a 24 m thick, shallow sand aquifer, confined by a 15 m thick clay layer. For the shallow aquifer, a very good match between MRS and borehole data was obtained with regard to effective porosity nc,28% and specific drainage Sd,20%. The MRS interpretation at the level deeper than 39 m was disturbed by signal attenuation in the low resistivity (,10 ,m) media. The second case of Serowe (Botswana) shows a fractured sandstone aquifer where hydrogeological parameters are well defined at depth >74 m below ground surface despite quite a low S/N = 0.9 ratio, thanks to the negligible signal attenuation in the resistive environment. Finally, capabilities and limitations of the MRS technology are reviewed and discussed. MRS can contribute to subsurface hydrostratigraphy description, hydrogeological system parameterization, and improvement of well siting. The main limitations are survey dependence upon the value of the S/N ratio, signal attenuation in electrically conductive environments, nonuniformity of magnetic field, and some instrumental limitations. At locations sufficiently resistive to disregard the signal attenuation problems, the MRS S/N ratio determines how successfully MRS data can be acquired. Both signal and noise vary spatially; therefore, world scale maps providing guidelines on spatial variability of signal and noise are presented and their importance with respect to the MRS survey results is discussed. The noise varies also temporally; therefore, its diurnal and seasonal variability impact upon the MRS survey is covered as well. [source] Determination of basic azaarenes in aviation kerosene by solid-phase extraction and HPLC-fluorescence detectionJOURNAL OF SEPARATION SCIENCE, JSS, Issue 12 2009Elaine Rocha da Luz Abstract SPE in combination with HPLC and fluorescence detection has been used for sensitive determination of six basic azaarenes (7,8-benzoquinoline, 7,9-dimethylbenz[c]acridine, 9-amino-1,2,3,4-tetrahydroacridine, 9-methylacridine, acridine, and dibenz[a,j]acridine) in aviation kerosene (jet fuel). SPE was performed in a single step using a strong cation exchange sorbent. The HPLC system consisted of C18 column with a selected detection program of optimal ,exc and ,em. A gradient elution with ACN and phosphate buffer (pH 6.5) at a flow rate of 1 mL/min allowed efficient and fast separation of azaarenes within 15 min. The LOD and LOQ values (S/N ratio 3:1 and 10:1, respectively) were between 0.0013 and 0.021 and from 0.0044 to 0.072 ng per injection. The calibration curves showed linear behavior from the LOQ to 250 ,g/L (r2 >0.99). For the spiked concentration of 6.0 ,g/L, recoveries were from 92 to 107% for jet fuel samples, except for 9-amino-1,2,3,4-tetrahydroacridine, which presented 68% recovery. The proposed method was applied to the quantification of those six basic azaarenes in one commercial kerosene and in three aviation kerosene samples. The presence of 7,8-benzoquinoline (up to 3.2 ,g/L) and dibenzo[a,j]acridine (up to 6.3 ,g/L) was confirmed in aviation kerosene. [source] Confirmation and determination of carboxylic acids in root exudates using LC,ESI-MSJOURNAL OF SEPARATION SCIENCE, JSS, Issue 15 2007Zuliang Chen Abstract Reversed-phase liquid chromatography with UV detection is of limited applicability in the separation and identification of carboxylic acids because of the column's poor separation efficiency and the non-selective nature of the UV detector. To address this issue, RP-LC with electrospray ionization mass spectrometry has been explored for the confirmation and determination of carboxylic acids in plant root exudates, with ESI-MS providing structural information, high selectivity, and high sensitivity. The separation of 10 carboxylic acids (pyruvic, lactic, malonic, maleic, fumaric, succinic, malic, tartaric, trans -aconitic, and citric acid) was performed on a C18 column using an eluent containing 0.1% (v/v) acetic acid within 10 min, where the acidic eluent not only suppressed the ionization of the carboxylic acids to be retained on the column, but was also compatible with ESI-MS detection. In addition, an additional standard was used to overcome the matrix effect. The results showed that peak areas correlated linearly with the concentration of carboxylic acids over the range 0.05,10 mg/L. The detection limits of target acids (signal-to-noise S/N ratio of 3) ranged from 20 to 30 ,g/L. Finally, the proposed method was used for the confirmation and determination of low-molecular-weight carboxylic acids in plant root exudates, and provided a simple analytical procedure, including sample processing, fast separation, and high specificity and sensitivity. [source] Selective separation and enrichment of peptides for MS analysis using the microspheres composed of Fe3O4@nSiO2 core and perpendicularly aligned mesoporous SiO2 shellPROTEINS: STRUCTURE, FUNCTION AND BIOINFORMATICS, Issue 5 2010Hemei Chen Abstract In this work, we report the development of a novel enrichment protocol for peptides by using the microspheres composed of Fe3O4@nSiO2 Core and perpendicularly aligned mesoporous SiO2 shell (designated Fe3O4@nSiO2@mSiO2). The Fe3O4@nSiO2@mSiO2 microspheres possess useful magnetic responsivity which makes the process of enrichment fast and convenient. The highly ordered nanoscale pores (2,nm) and high-surface areas of the microspheres were demonstrated to have good size-exclusion effect for the adsorption of peptides. An increase of S/N ratio over 100 times could be achieved by using the microspheres to enrich a standard peptide, and the application of the microspheres to enrich universal peptides was performed by using myoglobin tryptic digest solution. The enrichment efficiency of re-used Fe3O4@nSiO2@mSiO2 microspheres was also studied. Large-scale enrichment of endogenous peptides in rat brain extract was achieved by the microspheres. Automated nano-LC-ESI-MS/MS was applied to analyze the sample after enrichment, and 60 unique peptides were identified in total. The facile and low-cost synthesis as well as the convenient and efficient enrichment process of the novel Fe3O4@nSiO2@mSiO2 microspheres makes it a promising candidate for selectively isolation and enrichment of endogenous peptides from complex biological samples. [source] Multimethodological approach to investigate chamber tombs in the Sabine Necropolis at Colle del Forno (CNR, Rome, Italy)ARCHAEOLOGICAL PROSPECTION, Issue 2 2009Salvatore Piro Abstract Non-destructive geophysical prospecting methods are increasingly used for the investigation of archaeological sites, especially where a detailed physical and geometrical reconstruction of structures is required prior to any excavation work. Often, due to the limited size and depth of an archaeological structure, it may be rather difficult to single out its position and extent because of the generally low signal-to noise (S/N) ratio. This can be overcome by improving data acquisition and processing techniques and integrating different geophysical methods. In this work the results of a multimethodological surveys, used with the aim of detecting sharp discontinuities (boundary of cavities and fractures in the host medium) at the Archaeological Test Site of Sabine Necropolis at Research Area of National Research Council of Rome (Montelibretti, Italy) are shown. For the survey a combination of passive and active methods (magnetic, ground-penetrating radar (GPR), and dipole,dipole geoelectric (DDG)), topographical and three-dimensional laser scanner surveys and archaeological excavations were used to study the state of conservation of underground tombs. With all geophysical methods a high-resolution data acquisition was adopted with the aim of reconstructing a global vision of the study area. Signal processing and amplitude time-slice representation techniques were used for the analysis of GPR data. The bi-dimensional cross-correlation technique was applied to enhance the S/N ratio of the magnetic data. An example of the integration (both qualitative and quantitative) of these results is presented for a portion of the investigated area in the Sabine Necropolis at Colle del Forno (Rome, Italy). Archaeological excavations were then conducted systematically after completing the geophysical surveys and interpretations (from 2000 to 2006), which confirmed the location and shape of the individual chamber tombs with associated corridors. Copyright © 2009 John Wiley & Sons, Ltd. [source] Non-LTE model atmospheres for supersoft X-ray sourcesASTRONOMISCHE NACHRICHTEN, Issue 2 2010T. Rauch Abstract In the last decade, X-ray observations of hot stellar objects became available with unprecedented resolution and S/N ratio. For an adequate interpretation, fully metal-line blanketed Non-LTE model-atmospheres are necessary. The Tübingen Non-LTE Model Atmosphere Package (TMAP) can calculate such model atmospheres at a high level of sophistication. Although TMAP is not especially designed for the calculation of spectral energy distributions (SEDs) at extreme photospheric parameters, it can be employed for the spectral analysis ofburst spectra of novae like V4743 Sgr or line identifications in observations of neutron stars with low magnetic fields in low-mass X-ray binaries (LMXBs) like EXO 0748-676 (© 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] | ||||||||||