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Several Materials (several + material)

Distribution by Scientific Domains
Polymers and Materials Science40%

Selected Abstracts

Biodegradable polylactide membranes for bone defect coverage: biocompatibility testing, radiological and histological evaluation in a sheep model

CLINICAL ORAL IMPLANTS RESEARCH, Issue 4 2006
Gerhard Schmidmaier
Abstract: Large bony defects often show a delayed healing and have an increasing risk of infection. Several materials are used for the coverage of large defects. These materials must be biocompatible, easy to use, and must have an appropriate stability to present a mechanical hindrance. Aim of this study was to investigate two different biodegradable membranes for defect coverage in a sheep model. Round cranial defects (1.5 cm diameter) were created in sheep. Six different treatments were investigated: defects without membrane, defects covered with a poly(d,l -lactide) or with a 70/30 poly(l/d,l -lactide) membrane and all defects with or without spongiosa filling. The sheep were sacrificed 12 or 24 weeks postoperatively. Bone formation in the defects was quantified by computer-assisted measurements of the area of the residual defect on CT radiographs. Histomorphometry and host-tissue response were evaluated by light microscopy. The biocompatibility was investigated by analyzing the amount of osteoclasts and foreign body cells. Both membranes served as a mechanical hindrance to prevent the prolapse of soft tissue into the defect. The biocompatibility test revealed no differences in the amount and distribution of osteoclasts at the two investigated time points and between the investigated groups. No negative effect on the tissue regeneration was detectable between the investigated groups related to the type of membrane, but a foreign body reaction around the two membrane types was observed. In the membrane-covered defects, the spongiosa showed a progressing remodeling to the native bony structure of the cranium. The groups without spongiosa partly revealed new bone formation, without complete bridging in any group or at any time point. Comparing the 12 and 24 weeks groups, an increased bone formation was detectable at the later time point. In conclusion, the results of the present in vivo study reveal a good biocompatibility and prevention of soft tissue prolapse of the two used membranes without differences between the membranes. An enhanced remodeling of the spongiosa into native bony structures under the membranes was detectable, but no osteopromoting effect was observed due to the membranes. [source]

An invariant-based approach for high-cycle fatigue calculation

FATIGUE & FRACTURE OF ENGINEERING MATERIALS AND STRUCTURES, Issue 4 2009
A. CRISTOFORI
ABSTRACT Fatigue failures of in-service components are frequently due to multiaxial loadings; therefore, damage quantification in such conditions is important to many industrial applications. In this work a multiaxial criterion suitable for high-cycle fatigue assessment is formalized. It makes use of hydrostatic stress component and deviatoric stress component to estimate fatigue damage. A new formulation for the equivalent amplitude of the deviatoric component is formalized and compared with definitions proposed by Deperrois and Li and De Freitas. Damage evaluation procedure is discussed for deterministic loads and explicit analytical formulation is presented for sinusoidal loadings. Fatigue criterion is applied to experimental data taken from literature, related to several materials subjected to either in-phase or out-of-phase loads. It is shown that the new approach gives good predictions for both smooth and notched specimens. A similar comparison between experimental and theoretical results is also presented for other common criteria. It appears that the quality of the fatigue assessments obtained with the present criterion is better or, at most, similar to that of the other criteria analysed. [source]

Bounds for mixtures of an arbitrary number of materials

MATHEMATICAL METHODS IN THE APPLIED SCIENCES, Issue 8 2001
Cristian Barbarosie
This paper studies the problem of bounding the effective conductivity coefficients of mixtures made of several materials, in given proportions. Lower and upper bounds are obtained, and the optimality of these bounds is proven under certain hypotheses. Also, necessary and sufficient conditions for a mixture to attain the bounds are described. Some of the results were already known, but we give simpler proofs. Copyright © 2001 John Wiley & Sons, Ltd. [source]

Photocatalytic Coatings for Environmental Applications,

PHOTOCHEMISTRY & PHOTOBIOLOGY, Issue 2 2005
Norman S. Allen
ABSTRACT A series of nano- and micronparticle-grade anatase and rutile titanium dioxide pigments have been prepared with various densities of surface treatments, particle size and surface area. Their photocatalytic activities have been determined in a series of paint films by FTIR, chalking, color, gloss change and weight loss after artificial weathering. The pigments have also been examined by rapid assessment methodologies using photodielectric microwave spectroscopy, 2-propanol oxidation and hydroxyl analysis. The microwave response under light and dark cycles provides an extended timescale probe of chargecarrier dynamics in the pigments. Pigment particle size, surface area and properties clearly play an important role in dispersion and any polymer-pigment interactions. Photooxidation studies on several types of paint films show a clear demarcation between nanoparticle- and pigmentary-grade titanium dioxide, with the former being more active because of their greater degree of catalytic surface activity. The photosensitivity of titanium dioxide is considered to arise from localized sites on the crystal surface (i.e. acidic OH), and occupation of these sites by surface treatments inhibits photoreduction of the pigment by ultraviolet radiation; hence, the destructive oxidation of the binder is inhibited. Coatings containing 2,5% by weight alumina or alumina and silica are satisfactory for generalpurpose paints. If greater resistance to weathering is desired, the pigments are coated more heavily to about 7,10% weight. The coating can consist of a combination of several materials, e.g. alumina, silica, zirconia, aluminum phosphates of other metals. For example, the presence of hydrous alumina particles lowers van der Waals forces between pigments particles by several orders of magnitude, decreasing particle-particle attractions. Hydrous aluminum oxide phases appear to improve dispersibility more effectively than most of the other hydroxides and oxides. Coated nanoparticles are shown to exhibit effective light stabilization in various water- and oilbased paint media in comparison with conventional organic stabilizers. Hindered piperidine stabilizers are shown to provide no additional benefits in this regard, often exhibiting strong antagonism. The use of photocatalytic titania nanoparticles in the development of self-cleaning paints and microbiological surfaces is also demonstrated in this study. In the former case, surface erosion is shown to be controlled by varying the ratio of admixture of durable pigmentary-grade rutile (heavily coated) and a catalytic-grade anatase nanoparticle. For environmental applications in the development of coatings for destroying atmospheric pollutants such as nitrogen oxide gases (NOX), stable substrates are developed with photocatalytic nanoparticle-grade anatase. In this study, porosity of the coatings through calcium carbonate doping is shown to be crucial in the control of the effective destruction of atmospheric NOx gases. For the development of microbiological substrates for the destruction of harmful bacteria, effective nanoparticle anatase titania is shown to be important, with hydrated high surface area particles giving the greatest activity. [source]

Gross melt fracture of polyethylene.

POLYMER ENGINEERING & SCIENCE, Issue 3 2002
II: Effects of molecular structure
The effect of molecular structure (MW, MWD and LCB) on the critical tensile stress (,c) for the onset of gross melt fracture (OGMF), proposed in Part I (1) as a material-dependent criterion for fracture, was determined for a group of polyethylenes varying in structure. These included linear low and high-density polyethylenes and several materials produced using metallocene and constrained geometry catalysts. It was found that the critical stress is independent of MW, for constant polydispersity but increases with increasing long chain branching and polydispersity. The addition of boron nitride particles had no effect on the ,c up to a level of 0.5% by weight. [source]