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Separation Processes (separation + process)
Kinds of Separation Processes Selected AbstractsCLARIFICATION AND PURIFICATION OF AQUEOUS STEVIA EXTRACT USING MEMBRANE SEPARATION PROCESSJOURNAL OF FOOD PROCESS ENGINEERING, Issue 3 2009M.H.M. REIS ABSTRACT Stevia rebaudiana Bertoni is a native plant from South America and its active constituents have been considered the "sweeteners of the future."Stevia is a natural diet-sweetening source, safe to health and without calories. However, the obtained raw extract is foul smelling, bitter tasting, dark brown colored, and presents suspension matter due to organic and inorganic compounds. Therefore, further purification/clarification is essential in order to get a product of commercial quality. In this work ceramic membranes were applied in the stevia extract clarification process. The process was carried out under different membrane pore sizes and at different pressure values. The best clarification result was obtained with the membrane of 0.1 µm at 4 bar. On the other hand, the best condition for the flux was obtained with the membrane of 0.2 µm at 6 bar. The process with all the tested membranes and conditions achieved recovery of sweeteners higher than 90%. Finally, a filtration mathematical model was applied to describe the flux behavior, showing that the main fouling phenomenon during the process occurred because of the complete blocking of pores. PRACTICAL APPLICATION Stevia is the world's only all-natural sweetener with zero calories, zero carbohydrates and a zero glycemic index. However, the obtained stevia extract has a dark brown appearance, mainly because of the presence of impurities. In this work the membrane separation process was studied for stevia extract clarification and purification in order to get a product with higher commercial acceptability. The obtained results showed that total clarification and recuperation of sweeteners was almost achieved. Nonetheless, membrane fouling is an inevitable problem during membrane filtration. The mathematical analysis of the fouling occurrences showed that the complete blocking of pores is the main cause for the membrane permeability decrease. [source] The Ludwig-Soret Effect on the Thermally Induced Phase Separation Process in Polymer Solutions: A Computational StudyMACROMOLECULAR THEORY AND SIMULATIONS, Issue 2 2009Sureshkumar B. Kukadiya Abstract The Ludwig-Soret effect was investigated in the thermally induced phase separation process via SD in polymer solutions under an externally imposed spatial linear temperature gradient using mathematical modeling and computer simulation. The mathematical model incorporated non-linear Cahn-Hilliard theory for SD, Flory-Huggins theory for thermodynamics, and the Ludwig-Soret effect for thermal diffusion. 2D simulation results revealed that the Ludwig-Soret effect had negligible impact on the phase separation mechanism in binary polymer solutions under a non-uniform temperature field, as reflected by the time evolution of the dimensionless structure factor and the transition time from the early to the intermediate stages of SD. [source] Computational Simulation of the Blood Separation ProcessARTIFICIAL ORGANS, Issue 8 2005Sandro De Gruttola Abstract:, The aim of this work is to construct a computational fluid dynamics model capable of simulating the quasitransient process of apheresis. To this end a Lagrangian,Eulerian model has been developed which tracks the blood particles within a delineated two-dimensional flow domain. Within the Eulerian method, the fluid flow conservation equations within the separator are solved. Taking the calculated values of the flow field and using a Lagrangian method, the displacement of the blood particles is calculated. Thus, the local blood density within the separator at a given time step is known. Subsequently, the flow field in the separator is recalculated. This process continues until a quasisteady behavior is reached. The simulations show good agreement with experimental results. They shows a complete separation of plasma and red blood cells, as well as nearly complete separation of red blood cells and platelets. The white blood cells build clusters in the low concentrate cell bed. [source] Buchbesprechung: Green Separation Processes.CHEMIE-INGENIEUR-TECHNIK (CIT), Issue 3 2006J. G. Crespo (Eds.)., Von C. A. M. Afonso No abstract is available for this article. [source] Auslegung und Optimierung von hybriden Trennverfahren,CHEMIE-INGENIEUR-TECHNIK (CIT), Issue 3 2004M. Franke Dipl.-Ing. Abstract Unter hybriden Trennverfahren versteht man die Verschaltung von mindestens zwei verschiedenen, apparativ getrennten Grundoperationen, die zur Trennaufgabe beitragen. Hybride Trennverfahren werden bei schwierigen Trennungen, wie bei engsiedenden oder azeotropen Gemischen, eingesetzt, wenn eine einzelne Grundoperation, z.,B. Rektifikation, Extraktion, Kristallisation, Membranverfahren oder Chromatographie, gar nicht oder nur mit sehr großem Aufwand zum Ziel führt. Aufgrund der Struktur des Hybridprozesses, die das Vorhandensein mindestens zwei verschiedener Grundoperationen und eine entsprechende Anzahl von Rückführungen impliziert, ist die Auslegung komplex, sie wird deshalb z.,Z. systematisch in der Forschung untersucht. In dieser Arbeit werden die Anforderungen an eine Auslegungsmethodik für hybride Trennverfahren dargestellt. Es wird eine Methodik vorgestellt, die auf einer detaillierten Modellierung der Grundoperationen und einer simultanen Mehrvariablen-Optimierung beruht. Die Anwendbarkeit dieser Methodik wird anhand einer Isomerentrennung gezeigt. Design and Optimization of Hybrid Separation Processes Hybrid separation processes are defined as the combination of at least two different unit operations in different apparatus which contribute to the separation task. Hybrid processes are used for difficult separations, e.g., close-boiling mixtures and azeotropes, if a single unit operation, e.g., distillation, membranes, extraction, crystallization or chromatography, is not efficient or even not feasible. Because of the structure of a hybrid process which implies two or more unit operations and recycle streams, the design is not straightforward and therefore subject of today's research. In this work general criteria for such a consistent design method are described and a design approach for hybrid separation processes is presented. It bases on rigorous modeling of the unit operations and simultaneous multivariable optimization. The approach feasibility is demonstrated by the separation of an isomer mixture. [source] Design of reactive distillations for acetic acid esterificationAICHE JOURNAL, Issue 6 2005Yeong-Tarng Tang Abstract The reactive distillation provides an attractive alternative for reaction/separation processes with reversible reactions, especially for etherification and esterification. The discrete nature of chemical species and the complexity of phase equilibria seem to cloud the picture in understanding reactive distillation. The esterifications of acetic acid with five different alcohols, ranging from C1 to C5, are studied. First, qualitative relationships between macroscopic process flowsheet and microscopic phase equilibria are established, and the process flowsheets are classified into type I, II, and III for these five systems. Next, a systematic design procedure is devised to optimize the design, based on the total annual cost (TAC) and dominant design variables are identified for different flowsheets. Once quantitative design is available, process characteristic are analyzed and potential problems in process operation are identified. Finally, the economic potentials of these three different flowsheets are explored and explanations are given. The results clearly indicate that it is possible to systemize the design of reactive distillation by qualitatively generating flowsheet from phase equilibria and by quantitatively completing the process flow diagram from a sequential design procedure. Moreover, some of the flowsheets presented in this work cannot be found elsewhere in the open literature. © 2005 American Institute of Chemical Engineers AIChE J, 2005 [source] Simulations of IEF in microchannel with variable cross-sectional areaELECTROPHORESIS, Issue 5 2009Yin Chou Abstract This study develops a 1-D mass transport model to describe the electrophoresis transport behavior within a microchannel with a variable cross-sectional area. Utilizing three different numerical schemes, simulations are performed to investigate the IEF of proteins in ampholyte-based pH gradients within both a planar microchannel and a contraction,expansion microchannel, respectively. The simulation results obtained using the modified 1-D mass transport model and the finite-volume method (FVM) for the IEF separation of a single protein sample in a ten-ampholyte-based pH gradient within a planar microchannel are consistent with those presented by Shim et al. [Electrophoresis 2007, 28, 572,586] using a 2-D FVM scheme. In addition, the Courant,Friedrichs,Lewy number insensitive conservation element and solution element (CNI-CESE) method is found to be both more robust and more computationally efficient than the conventional CESE scheme when modeling IEF phenomena within a contraction,expansion microchannel. In modeling the IEF separation of four sample ampholytes in a 20-ampholtye-based pH gradient within a contraction,expansion microchannel, the results obtained using the CNI-CESE scheme are in good agreement with those published in literature. Moreover, the simulations can be performed significantly faster with the new 1-D model and the CNI-CESE scheme. Finally, the results obtained using the modified 1-D mass transport model and the CNI-CESE scheme demonstrate that the concentration of the focused test sample and the resolution of the pH gradient within the microchannel increase as the number of ampholytes used to accomplish the IEF separation process is increased. [source] Macrocyclic polyamine-modified poly(glycidyl methacrylate- co -ethylene dimethacrylate) monolith for capillary electrochromatographyELECTROPHORESIS, Issue 11 2008Yun Tian Abstract 1,4,10,13,16-Pentaazatricycloheneicosane-9,17-dione (macrocyclic polyamine)-modified polymer-based monolithic column for CEC was prepared by ring opening reaction of epoxide groups from poly(glycidyl methacrylate- co -ethylene dimethacrylate) (GMA- co -EDMA) monolith with macrocyclic polyamine. Conditions such as reaction time and concentration of macrocyclic polyamine for the modification reaction were optimized to generate substantial EOF and enough chromatographic interactions. Anodic EOF was observed in the pH range of 2.0,8.0 studied due to the protonation of macrcyclic polyamine at the surface of the monolith. Morphology of the monolithic column was examined by SEM and the incorporation of macrocyclic polyamine to the poly(GMA- co -EDMA) monolith was characterized by infrared (IR) spectra. Successful separation of inorganic anions, isomeric benzenediols, and benzoic acid derivatives on the monolithic column was achieved for CEC. In addition to hydrophobic interaction, hydrogen bonding and electrostatic interaction played a significant role in the separation process. [source] An evaluation of continuous electrodeionization as an in-line process for plating rinsewater recoveryENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY, Issue 4 2001M. J. Semmens The objective of this project was to investigate the ability of continuous electrodeionization (CEDI) to be used in a copper electroplating line to recover copper sulfate and purified water from rinsewaters for reuse within the same process. Typically, these acidic rinsewaters contain approximately 10 to 50 mg/L of copper as copper sulfate. This range of copper is much higher than any used in previous applications of CEDI technology. Three bench-scale configurations of CEDI modules were evaluated under varying flow and voltage conditions to test the performance of the process in treating the rinsewater. The influence of different ion exchange packings on CEDI performance was examined to determine which module design worked best for this separation process. The bench-scale test results suggest that CEDI is a potentially viable technology for copper sulfate recovery from waste rinsewaters generated by a copper electroplating line. A single stage CEDI process was able to produce a pure water product containing non-detectable concentrations of copper, and an acidic copper sulfate concentrate with a copper concentration as high as 4,000 mg/L. [source] Supercritical fluid extraction of walnut kernel oilEUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY, Issue 7 2006Sema Salg Abstract The objective of this study was to investigate the effects of the main process parameters on supercritical fluid extraction of walnut (Juglans regia,L.) kernel oil. The recovery of walnut kernel oil was performed in a green and high-tech separation process. CO2 and CO2 +,ethanol mixtures were used as the supercritical solvent. The extraction was carried out at operating pressures of 30, 40 and 50,MPa, operating temperatures of 313, 323 and 333,K, mean particle sizes of 1.78×10,4, 3.03×10,4, 4.78×10,4, 7.00×10,4 and 9.00×10,4,m, supercritical CO2 (SC CO2) flow rates of 1.67×10,8, 3.33×10,8, 6.67×10,8 and 13.33×10,8,m3/s and entrainer (ethanol) concentrations of 2, 4, 8 and 12,vol-%. Maximum extraction yield and oil solubility in SC CO2 obtained at 50,MPa, 333,K, 9.00×10,4,m, 3.33×10,4,m3/h were 0.65,kg oil/kg of dry sample and 37.16,g oil/kg CO2, respectively. The results obtained in this study showed that the crossover pressure effect of walnut kernel oil was at 30,MPa. At 30,MPa and 313,K, the obtained extraction yields above 4,vol-% ethanol reached the organic solvent extraction yield of 68.5,kg oil/kg dry sample. Extraction time was decreased significantly because of the higher solubility of walnut kernel oil in SC CO2 +,ethanol mixtures. [source] Fabrication and Drug Delivery of Ultrathin Mesoporous Bioactive Glass Hollow FibersADVANCED FUNCTIONAL MATERIALS, Issue 9 2010Youliang Hong Abstract Ultrathin mesoporous bioactive glass hollow fibers (MBGHFs) fabricated using an electrospinning technique and combined with a phase-separation-induced agent, poly(ethylene oxide) (PEO), are described. The rapid solvent evaporation during electrospinning and the PEO-induced phase separation process demonstrated play vital roles in the formation of ultrathin bioactive glass fibers with hollow cores and mesoporous walls. Immersing the MBGHFs in simulated body fluid rapidly results in the development of a layer of enamel-like apatite mesocrystals at the fiber surfaces and apatite nanocrystals inside the hollow cores. Drug loading and release experiments indicate that the drug loading capacity and drug release behavior of the MBGHFs strongly depends on the fiber length. MBGHFs with fiber length >50,µm can become excellent carriers for drug delivery. The shortening of the fiber length reduces drug loading amounts and accelerates drug release. The MBGHFs reported here with sophisticated structure, high bioactivity, and good drug delivery capability can be a promising scaffold for hard tissue repair and wound healing when organized into 3D macroporous membranes. [source] Transmission Electron Microscopy and UV,vis,IR Spectroscopy Analysis of the Diameter Sorting of Carbon Nanotubes by Gradient Density UltracentrifugationADVANCED FUNCTIONAL MATERIALS, Issue 14 2009Romain Fleurier Abstract Diameter separation of single-walled carbon nanotubes is achieved via the density gradient ultracentrifugation process. Statistical analysis of the separated samples is performed using high-resolution transmission electron microscopy (HRTEM). The evolution of the diameter distribution with respect to the gradient density is extracted by analyzing hundreds of HRTEM images, and the results are found to be consistent with those estimated by UV,vis,IR spectroscopy. The efficiency of the separation process can be quantitatively characterized by the standard deviation of the diameter distribution, which is determined from the TEM analyses. This particular study indicated that for electric arc nanotubes dispersed in sodium cholate, diameter sorting is more efficient in the upper part of the gradient. [source] A study on membrane distillation by a solar thermal-driven systemHEAT TRANSFER - ASIAN RESEARCH (FORMERLY HEAT TRANSFER-JAPANESE RESEARCH), Issue 7 2007Tsung-Ching Chen Abstract Membrane distillation (MD) is a membrane separation process that has long been investigated in small scale laboratory studies and has the potential to become a viable tool for water desalination. MD is a separation process that combines simultaneous mass and heat transfer through a hydrophobic microporous membrane. A solar collector is used in direct contact membrane distillation (DCMD) to heat seawater as a temperature driving force in heat transfer to establish seawater desalting systems. The effect of the temperature difference makes the brine vaporize in the hot fluid side and condense in the cold fluid side. The optimal operating parameters on the pure water production rate will also be examined in this study. The purposes of this study are to develop the theoretical heat and mass transfer formulations, simulate heat transfer rate of solar collector with internal fins in membrane distillation, and investigate the mass-transfer efficiency improvement in membrane distillation with the brine flow rate, solar collector efficiency, and temperature difference between both sides of membrane as parameters. © 2007 Wiley Periodicals, Inc. Heat Trans Asian Res, 36(7): 417,428, 2007; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/htj.20172 [source] Theoretical investigation of charge transfer excitation and charge recombination in acenaphthylene,tetracyanoethylene complexINTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, Issue 1 2003Hai-Bo Yi Abstract Ab initio calculations were performed to investigate the charge separation and charge recombination processes in the photoinduced electron transfer reaction between tetracyanoethylene and acenaphthylene. The excited states of the charge-balanced electron donor,acceptor complex and the singlet state of ion pair complex were studied by employing configuration interaction singles method. The equilibrium geometry of electron donor,acceptor complex was obtained by the second-order Møller,Plesset method, with the interaction energy corrected by the counterpoise method. The theoretical study of ground state and excited states of electron donor,acceptor complex in this work reveals that the S1 and S2 states of the electron donor,acceptor complexes are excited charge transfer states, and charge transfer absorptions that corresponds to the S0 , S1 and S0 , S2 transitions arise from ,,,* excitations. The charge recombination in the ion pair complex will produce the charge-balanced ground state or excited triplet state. According to the generalized Mulliken,Hush model, the electron coupling matrix elements of the charge separation process and the charge recombination process were obtained. Based on the continuum model, charge transfer absorption and charge transfer emission in the polar solvent of 1,2-dichloroethane were investigated. © 2003 Wiley Periodicals, Inc. Int J Quantum Chem 94: 23,35, 2003 [source] Processing of ethanol fermentation broths by Candida krusei to separate bioethanol by pervaporation using silicone rubber-coated silicalite membranesJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 8 2009Toru Ikegami Abstract BACKGROUND: Pervaporation employing ethanol-permselective silicalite membranes as an alternative to distillation is a promising approach for refining low-concentration bioethanol solutions. However, to make the separation process practicable, it is extremely important to avoid the problems caused by the adsorption of succinate on the membrane during the separation process. In this work, the pervaporation of an ethanol fermentation broth without succinate was investigated, as well as the influence of several fermentation broth nutrient components. RESULTS:Candida krusei IA-1 produces an extremely low level of succinate. The decrease in permeate ethanol concentration through a silicone rubber-coated silicalite membrane during the separation of low-succinate C. krusei IA-1 fermentation broth was significantly improved when compared with that obtained using Saccharomyces cerevisiae broth. By treating the fermentation broth with activated carbon, bioethanol was concentrated as efficiently as with binary mixtures of ethanol/water. The total flux was improved upto 56% of that obtained from the separation of binary mixtures, compared with 43% before the addition of activated carbon. Nutrients such as peptone, yeast extract and corn steep liquor had a negative effect on pervaporation, but this response was distinct from that caused by succinate. CONCLUSION: For consistent separation of bioethanol from C. krusei IA-1 fermentation broth by pervaporation, it is useful to treat the low nutrient broth with activated carbon. To further improve pervaporation performance, it will be necessary to suppress the accumulation of glycerol. Copyright © 2009 Society of Chemical Industry [source] Recovery of lipase by adsorption at the n -hexadecane,water interfaceJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 11 2003Hui-Min Wang Abstract A novel separation process based on the hydrophobic adsorption at the n -hexadecane,water interface was developed for the recovery of Acinetobacter radioresistens lipase from a pre-treated fermentation broth. In a mixture containing water, lipase and n -hexadecane, a water-in-oil emulsion was formed when the n -hexadecane-to-water ratio (o/w ratio) was larger than 3, and a large amount of lipase was found to be adsorbed at the interface. Compared with the oil-in-water emulsion (occurring when o/w ratio < 3), the water-in-oil emulsion generated smaller droplets and larger interfacial area, and was more stable. The harvested emulsion phase could be centrifuged to give an aqueous, concentrated lipase solution. Adsorption of lipase at the interface could be described by the Langmuir isotherm. For lipase concentrations ranging from 8.4 to 87.2 U cm,3, a single-stage adsorption resulted in a six- to four-fold concentration and 16,45% activity recovery, where lipase concentration was the dominant factor. A method using data from a single-stage adsorption to predict multiple-stage operation was described, and the agreement between the experimental and the predicted results was good. To improve the enzyme recovery, a multiple-run adsorption process was proposed. The use of salts enhanced the hydrophobic interaction between lipase and n -hexadecane. Advantages of the proposed process include simple operation, low operational cost, environmentally friendly, no requirement for pre-concentration of the enzyme solution, and negligible enzyme denaturation. Copyright © 2003 Society of Chemical Industry [source] CLARIFICATION AND PURIFICATION OF AQUEOUS STEVIA EXTRACT USING MEMBRANE SEPARATION PROCESSJOURNAL OF FOOD PROCESS ENGINEERING, Issue 3 2009M.H.M. REIS ABSTRACT Stevia rebaudiana Bertoni is a native plant from South America and its active constituents have been considered the "sweeteners of the future."Stevia is a natural diet-sweetening source, safe to health and without calories. However, the obtained raw extract is foul smelling, bitter tasting, dark brown colored, and presents suspension matter due to organic and inorganic compounds. Therefore, further purification/clarification is essential in order to get a product of commercial quality. In this work ceramic membranes were applied in the stevia extract clarification process. The process was carried out under different membrane pore sizes and at different pressure values. The best clarification result was obtained with the membrane of 0.1 µm at 4 bar. On the other hand, the best condition for the flux was obtained with the membrane of 0.2 µm at 6 bar. The process with all the tested membranes and conditions achieved recovery of sweeteners higher than 90%. Finally, a filtration mathematical model was applied to describe the flux behavior, showing that the main fouling phenomenon during the process occurred because of the complete blocking of pores. PRACTICAL APPLICATION Stevia is the world's only all-natural sweetener with zero calories, zero carbohydrates and a zero glycemic index. However, the obtained stevia extract has a dark brown appearance, mainly because of the presence of impurities. In this work the membrane separation process was studied for stevia extract clarification and purification in order to get a product with higher commercial acceptability. The obtained results showed that total clarification and recuperation of sweeteners was almost achieved. Nonetheless, membrane fouling is an inevitable problem during membrane filtration. The mathematical analysis of the fouling occurrences showed that the complete blocking of pores is the main cause for the membrane permeability decrease. [source] Modeling the mass transfers during the elaboration of chitosan-activated carbon composites for medical applicationsAICHE JOURNAL, Issue 6 2010A. Venault Abstract Hydrogels composites composed of chitosan and activated carbon were prepared for medical applications using the vapor-induced phase separation process. Since the gelation process involves mass exchanges between the polymer solution and the air, the kinetics of mass transfer were investigated through experimental and modeling approaches. Among the formulation and process parameters, gravimetric measurements exhibited that mass transfers were mostly controlled by the initial ammonia partial pressure. A nonisotherm mass-transfer model was developed to predict the nonsolvent and solvent exchange rates, therefore, the water and ammonia concentration profiles within the sample during the process. The numerical results were successively validated with gravimetrical kinetic curves obtained in a chamber where the process parameters were controlled. The model aimed also at predicting the pH moving front along the film thickness. The gelation time could also be predicted for different operating conditions (formulation and process parameters). © 2009 American Institute of Chemical Engineers AIChE J, 2009 [source] Simulation and optimal design of multiple-bed pressure swing adsorption systemsAICHE JOURNAL, Issue 11 2004Ling Jiang Abstract Pressure swing adsorption (PSA) is a very versatile technology for gas separation and purification. The widespread industrial application of PSA has called for an efficient set of simulation, design, and optimization methodologies. In previous work by Jiang and co-workers, we used a Newton-based approach to quickly converge the cyclic steady state and design constraints, and a simultaneous tailored approach with the state-of-art nonlinear optimization strategy to design optimal PSA processes. In this work we extend the simulation and optimization strategies to multiple bed systems. Both unibed and multibed frameworks are adopted to describe bed behaviors. The unibed framework models only one bed over a cycle and uses storage buffers to mimic the bed interactions. The multibed framework simultaneously solves all beds but only for a portion of the cycle. Challenges and implementation details of both frameworks are discussed. A five-bed, 11-step hydrocarbon separation process, which separates H2 from a mixture of H2, N2, CO2, CO, and CH4, is used for illustration. By manipulating valve constants, step times, flow rates, and bed geometry, the optimizer successfully maximizes H2 recovery, while meeting product purity and pressure specifications. © 2004 American Institute of Chemical Engineers AIChE J, 50: 2904,2917, 2004 [source] Mass transport and flow regimes in centrifugal partition chromatographyAICHE JOURNAL, Issue 8 2002L. Marchal Centrifugal partition chromatography (CPC) is a support-free liquid,liquid separation process that depends for efficiency on the behavior of the two liquid phases. Hydrodynamics of phases was studied according to flow rate and centrifugal acceleration, using a transparent column and a stroboscopic video system. For the heptane-methanol two-phase system, three main flow regimes,stuck film, oscillating sheet, and atomization,are observed, highlighting the coriolis acceleration effect as well as the influence of the column shape. Mass transport in the CPC column is modeled by a plug flow with axial dispersion and mass transfer with a stagnant volume. Model parameters (residence time, Péclet number, partition ratio, and mass-transfer coefficient) are fitted on solute residence-time distribution. Off-column dispersion is an important source of peak broadening in CPC, whereas its irregular geometry provides a plug flow for mobile phase. Importance of flow pattern on mass transfer is demonstrated. CPC interest for preparative applications is confirmed. [source] Detection system for electro-separation analytical methodsJOURNAL OF SEPARATION SCIENCE, JSS, Issue 12 2005Radek Abstract The paper provides information about the on-line monitoring of components analysed by capillary electrophoresis. For this purposes we developed a whole-capillary transverse scanning detection system, which helps to improve and control the separation processes. A picture from a colour line scanner was used as a source of basic information for autonomous control of the separation process by regulation of the high voltage source. The application and algorithms for machine vision were designed in the progressive graphic development system LabVIEW. Real-time control of the separation process was implemented in a compact control process logic controller. The performance of the detection system was evaluated and the function of the overall system was tested by performing isotachophoretic analysis of a model mixture. [source] Separation of a sphere from a flat in the presence of couple stress fluidsLUBRICATION SCIENCE, Issue 1 2008Abdallah A. Elsharkawy Abstract A mathematical model for couple stress fluid is presented to analyse the separation flow of a fully flooded sphere from a flat under the condition of constant load. Assuming the lubricant between the sphere and the flat to contain additives, the couple stress effect, presented by the characteristic length of the additives, has been considered to account for the non-Newtonian behaviour. In addition, the effect of the sphere inertia on accelerating the separation process has been considered. Compared with the Newtonian fluid case, the results of the numerical solution indicated that the separation time increases with increasing the characteristic length of the additives. It was also found that the additive characteristic length has negligible effect on the thickness of the lubricant film at the separation point. Copyright © 2007 John Wiley & Sons, Ltd. [source] Pressure-Sensitive Adhesive Blend Films for Low-Tack ApplicationsMACROMOLECULAR MATERIALS & ENGINEERING, Issue 7 2007Peter Müller-Buschbaum Abstract Polymer blend films consisting of a tacky and a nonadhesive component are promising candidates for low-tack applications. Immiscibility of both components results in a phase separation process yielding a tacky matrix with glassy objects embedded. The influence of the blending ratio of the components poly(n -butyl acrylate) (PnBA) and polystyrene (PS) is addressed. The mechanical information resulting from the tack test shows the possibility of varying the bonding strength of the PSA blend over a wide range. The macroscopic and microscopic structural characterization with optical microscopy and ultrasmall angle X-ray scattering (USAXS) shows that the blend PnBA/PS exhibits similarities to common filler systems as well as deviates regarding installed structures. Due to the large domain size on a microscopic level, only the tacky component, PnBA, defines the adhesive behavior. The nonadhesive component limits the contact area between the adhesive and the substrate. [source] Sequential Polymer Precipitation of Core,Shell Microstructured Composites with Giant PermittivityMACROMOLECULAR RAPID COMMUNICATIONS, Issue 5 2010Tingyang Dai Abstract Polymeric core,shell microstructures have been constructed through a new method, namely sequential precipitation, which is intrinsically a self-assembly and phase separation process. High-quality poly(vinyldene fluoride),polycarbonate,lithium perchlorate composite films with spherical core,shell microstructures have been prepared and determined to consist of conducting cores and insulating shells. Because of the percolation effect, the resulting materials present a dielectric constant as high as 104,107 at the threshold. [source] Reactive processing of syndiotactic polystyrene with an epoxy/amine solvent systemMACROMOLECULAR SYMPOSIA, Issue 1 2003Jaap Schut Abstract Syndiotactic polystyrene (sPS) is a new semi-crystalline thermoplastic which is believed to fill the price-performance gap between engineering and commodity plastics. In order to reduce the high processing temperature of sPS (>290°C), an epoxy-amine model system was used as a reactive solvent. Such a processing aid can be used to achieve a 50 to 500 fold lowering of the melt viscosity. When initially homogeneous solutions of sPS in a stoechiometric epoxy-amine mixture are thermally cured, Reaction Induced Phase Separation (RIPS) takes place, leading to phase separated thermoplastic-thermoset polymer blends. We focus our study on low (wt% sPS < 20%) and high concentration blends (wt% sPS > 60%) prepared by two processing techniques (mechanical stirring in a laboratory reactor or internal mixer/ reactive extrusion respectively). These blends have different potential interests. Low concentration blends (sPS domains in an epoxy-amine matrix) are prepared to create new, tunable blend morphologies by choosing the nature of the phase separation process, i.e. either crystallisation followed by polymerization or polymerization followed crystallisation. High concentration blends (sPS matrix containing dispersed epoxy-amine particles after RIPS) are prepared to facilitate the extrusion of sPS. In this case, the epoxy amine model system served as a reactive solvent. The time to the onset of RIPS is in the order of 7-9 min for low concentration blends, while it increases to 20-45 min for high concentration samples, as the reaction rates are substantially slowed down due to lower epoxy and amine concentrations. During the curing reaction the melting temperature of sPS in the reactive solvent mixture evolves back from a depressed value to the level of pure sPS. This indicates a change in the composition of the sPS phase, caused by (complete) phase separation upon reaction. We conclude that our epoxy amine system is suited for reactive processing of sPS, where final properties depend strongly on composition and processing conditions. [source] Dielectric in situ sensor monitoring of phase separation and changes in the state of each phaseMACROMOLECULAR SYMPOSIA, Issue 1 2003D. Kranbuehl Abstract Frequency dependent dielectric measurements have been used to monitor and characterize the phase separation process and changes in state of each phase. The measurements are made in situ using a micro planar sensor. They can be made both in the laboratory as well as in an industrial production or use environment. Two examples are presented. The first is monitoring the onset of phase separation, the buildup in Tg and change in composition of each phase during "reactive processing" of a high performance thermoplastic (TP) PPI, thermoset precursors (TS) DGEBA-MCDEA intially homogeneous blend. The second example involves monitoring the stability, onset of phase separation, as a function of temperature on a mineral oil, stearyl alcohol, water, sufactant emulsion used in the cosmetic industry. [source] The Ludwig-Soret Effect on the Thermally Induced Phase Separation Process in Polymer Solutions: A Computational StudyMACROMOLECULAR THEORY AND SIMULATIONS, Issue 2 2009Sureshkumar B. Kukadiya Abstract The Ludwig-Soret effect was investigated in the thermally induced phase separation process via SD in polymer solutions under an externally imposed spatial linear temperature gradient using mathematical modeling and computer simulation. The mathematical model incorporated non-linear Cahn-Hilliard theory for SD, Flory-Huggins theory for thermodynamics, and the Ludwig-Soret effect for thermal diffusion. 2D simulation results revealed that the Ludwig-Soret effect had negligible impact on the phase separation mechanism in binary polymer solutions under a non-uniform temperature field, as reflected by the time evolution of the dimensionless structure factor and the transition time from the early to the intermediate stages of SD. [source] Verallgemeinerungsfähige Merkmale und Besonderheiten des SprühkompaktierensMATERIALWISSENSCHAFT UND WERKSTOFFTECHNIK, Issue 1 2003K. Bauckhage Sprayforming; Modelling Microstructure; Geometry Abstract Dadurch, daß beim Sprühkompaktieren die schnelle Erstarrung und Abkühlung des Materials das Ausmaß von Entmischungen eindämmen, können Makroseigerungen unterbunden und Anreicherungen an den Korngrenzen deutlich verringert werden. Ferner wird das Risiko der Lunker- und Warmrißbildung durch den Impuls des Massetransportes während des Kompaktiervorganges stark reduziert. Dies bedeutet, daß solche Materialien, die bspw. beim Gießen zu starker Seigerung neigen und besonders anfällig für die Lunkerbildung und/oder Warmrißbildung sind sowie bei Umformverfahren zur Zeilenbildung von Carbiden, Nitriden oder Sulfiden neigen, mit Hilfe des Sprühkompaktierens im Freiformverfahren mit großen Abmaßen chemisch homogen und fehlerfrei herstellbar werden. Ein besonderes Merkmal sprühkompaktierter Deposits ist ihr feines Gefüge und ihre vergleichsweise hohe Duktilität. Die Besonderheiten des neuartigen Urformverfahrens werden anhand von Beispielen erläutert. Characteristic Features and Specific Qualifications of the Sprayforming Process to be Generalized The solidification and cooling process of spray formed materials predominates the extent of any segregation and separation process, which is conducive to avoid macro-segregation and to diminish concentration of alloying components at the grain boundaries. The risk of coarse porosity or of hot cracking is reduced significantly by the momentum of the mass flow during spray deposition. This means that those materials which e.g. during the casting process tend to establish strong segregation effects and cavities and/or hot cracks as well as those which tend to create filaments of carbides, nitrides or sulphides during rolling can be generated by the spray forming process in large dimensions with chemical homogeneity and without any of those defects. A characteristic feature of spray formed materials is the fine equiaxed grain structure and the high ductility. Specific features of this new free forming process will be discussed. [source] Global regular solutions to Cahn,Hilliard system coupled with viscoelasticityMATHEMATICAL METHODS IN THE APPLIED SCIENCES, Issue 17 2009Irena Paw Abstract In this paper we prove the existence and uniqueness of a global in time, regular solution to the Cahn,Hilliard system coupled with viscoelasticity. The system arises as a model, regularized by a viscous damping, of phase separation process in a binary deformable alloy quenched below a critical temperature. The key tools in the analysis are estimates of absorbing type with the property of exponentially time-decreasing contribution of the initial data. Such estimates allow not only to prolong the solution step by step on the infinite time interval but also to conclude the existence of an absorbing set. Copyright © 2009 John Wiley & Sons, Ltd. [source] HVPE GaN substrates: growth and characterizationPHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 7-8 2010D. Gogova Abstract GaN substrates with low dislocation densities were prepared by halide vapor-phase epitaxy (HVPE) on c-plane sapphire and by means of a post-growth laser-induced lift-off or natural stress-induced (self-) separation process. The HVPE growth on InGaN/GaN buffer layers and subsequent self-separation method was seen as advantageous, in comparison with the laser-induced lift-off one, in terms of lower cost and better crystalline quality of the GaN material obtained. (© 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] | ||||||||||||||||||||||||||||||||||||||||