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SEM Measurements (sem + measurement)
Selected AbstractsModeling the dynamics of reactive foaming and film thinning in polyurethane foamsAICHE JOURNAL, Issue 2 2010G. Harikrishnan Abstract Flexible polyurethane foams are widely used in cushioning and packaging applications. A model for the dynamics of formation of polyurethane foams is presented, which includes thinning of foam lamellae. Experimental measurements for water blown flexible foam formulations at different water concentrations are presented to validate the model. Adiabatic temperature rise measurements during foaming are used to obtain the kinetic parameters of the reactions of isocyanate with polyol and water. The variation of foam density during foaming is studied by weight loss and video shooting methods and both are compared to estimate the amount of blowing gas lost during foaming. The average thickness of the foam lamellae of the solid foam is obtained by SEM measurements. The predictions of the model show good agreement with the experimental measurements of temperature and density with time and the final lamellar thickness. The results are important for understanding the cell opening process. © 2009 American Institute of Chemical Engineers AIChE J, 2010 [source] Deagglomeration of nanoparticle aggregates via rapid expansion of supercritical or high-pressure suspensionsAICHE JOURNAL, Issue 11 2009Daniel To Abstract Deagglomeration of suspensions of alumina and titania nanopowders (i.e., nanoparticle aggregates) via rapid expansion of supercritical suspensions (RESS) or high-pressure suspensions (REHPS) was studied. The size distribution of fragmented nanopowders was characterized by online Scanning Mobility Particle Spectrometer (SMPS) and Aerodynamic Particle Sizer (APS), and by offline Scanning Electron Microscopy (SEM). SMPS and SEM measurements indicate that the average agglomerate sizes were well below 1 ,m, consistent with the length scales observed in our complementary RESS/REHPS mixing experiments using alumina and silica nanopowders. The APS measurements, on the other hand, were affected by reagglomeration during sampling and yielded an agglomerate size range of 1 to 3 ,m. Analysis of the RESS/REHPS process through compressible flow models revealed that both the shear stress in the nozzle and the subsequent impact of the agglomerates with the Mach disc in the free expansion region can lead to micron or sub-micron level deagglomeration. © 2009 American Institute of Chemical Engineers AIChE J, 2009 [source] Marginal Adaptation of Cerec 3 CAD/CAM Composite Crowns Using Two Different Finish Line Preparation DesignsJOURNAL OF PROSTHODONTICS, Issue 3 2006Jaber Hussain Akbar DDS Purpose: The purpose of this study was to compare marginal discrepancies of Cerec 3 CAD/CAM composite crowns, fabricated on human prepared teeth with two different finish line designs, chamfer and shoulder. Materials and Methods: Sixteen human molar teeth were used to prepare full crowns. Eight teeth were prepared with a 1-mm-wide chamfer finish line and the other eight with a 1.2- to 1.5-mm circumferential shoulder. Cerec 3 crowns were fabricated from optical impressions using Paradigm MZ100 composite polymer. Marginal adaptation was evaluated in two ways: (1) using modified United States Public Health Service (USPHS) criteria to evaluate eight preselected sites on each crown margin, and (2) using scanning electron microscopy (SEM) to measure marginal gaps on all four axial walls with 15 measurements on each wall (60 measurements per crown). An evaluation of the number of acceptable crowns, determined by having all measured sites per tooth with margin gap size less than 100 ,m, as a function of finish line design was also conducted. Results: In both chamfer and shoulder groups, there were only two crowns (out of eight) with clinically acceptable ratings for all eight measurement sites according to USPHS criteria. Fisher's chi-square analysis showed that there was no statistically significant difference in marginal adaptability as a function of finish line design ( p > 0.05). With SEM imaging, overall mean marginal gaps for the chamfer group were 65.9 ± 38.7 ,m (range 35.0 to 130.0 ,m), and for the shoulder group were 46.0 ± 9.2 ,m (range 26.3 to 55.6 ,m); this difference was not found to be statistically significant ( p > 0.05). While crown assessment based on mean marginal discrepancy measurements indicated that both the chamfer and shoulder groups were considered clinically acceptable (<100 ,m); crown acceptability based on all measurement sites being less than 100 ,m indicated that in the chamfer and shoulder groups there were four and three acceptable crowns out of eight, respectively. The Fisher's chi-square test indicated no statistically significant difference between the groups ( p > 0.05). An agreement rate of 81.2% was calculated between the two evaluation methods, modified USPHS criteria and SEM measurements. Conclusions: Based on mean marginal discrepancy measurements, the typical marginal assessment technique, Cerec 3 Paradigm MZ100 crown restorations appear to have acceptable marginal adaptability (mean discrepancies <100 ,m). Thus, the evidence from this investigation would suggest that the finish line preparation design had no effect on marginal adaptation for Cerec 3 composite crowns. [source] Melt Crystallization and Morphology of Poly(p -phenylene sulfide) under High PressureMACROMOLECULAR CHEMISTRY AND PHYSICS, Issue 4 2007Jun Lu Abstract The high-pressure melt-crystallization behaviors of poly(p -phenylene sulfide) (PPS) were investigated using WAXD, DSC, TEM and SEM. PPS extended-chain crystals with c -axis thickness exceeding 4.5 µm were formed at high pressure. The DSC results showed that the melting temperature and melting enthalpy of high-pressure crystallized PPS samples were up to 327.53,°C and 94.96 J,·,g,1, respectively, which were higher than the values of ideal PPS perfect crystals used by some researchers, and the melting enthalpy of the samples fluctuated regularly during the thickening growth of the PPS crystals. Other characteristic morphologies obtained at high pressure, i.e. spherulites and rod-like crystals, were also presented with the SEM measurements. [source] Preparation and characterization of nylon 6/organoclay nanocomposite filament fibersPOLYMER COMPOSITES, Issue 3 2009Kap Jin Kim A series of nylon 6 (NY6)/organoclay nanocomposites were prepared via in situ polymerization of ,-caprolactam in the presence of 1,2-aminododecanoic acid-intercalated montmorillonite (ADA-MMT) organoclay (1,5 wt%) using 6-aminocaproic acid as polymerization catalyst. The extent of organoclay dispersion in NY6 matrix was analyzed using WAXD and SEM measurements. DSC studies revealed marginal shift in melting and melt-crystallization peaks toward lower temperature with increasing clay content. Melt viscosity studies for NY6/ADA-MMT exhibited higher shear-thinning behavior than neat NY6 probably due to the slip between NY6 matrix and exfoliated organoclay platelets during shear flow. The prepared nanocomposites were melt-spun and studied for their property improvements against varying clay content, draw ratios, and annealing conditions. Birefringence and sonic velocity values increased initially at lower draw ratios (,2.5) due to increased orientation of molecular chains along the drawing direction but saturated at higher draw ratio (3.0) for all the samples. At the same draw ratio; compared to neat NY6, NY6/organoclay fibers showed increased chain orientation along the drawing direction which can be attributed to the "tethering effect" of organoclay on NY6 matrix. The initial modulus and stress at break were sensitive to factors such as draw ratio, clay content, and annealing conditions. POLYM. COMPOS., 2009. © 2008 Society of Plastics Engineers [source] | ||||||||||