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Sediment Composition (sediment + composition)
Selected AbstractsEffect of organic carbon content, clay type, and aging on the oral bioavailability of hexachlorobenzene in rats,ENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 11 2007Shakil A. Saghir Abstract Bioavailability of lipophilic chemicals is influenced by the physicochemical properties of soils/sediment such as particle size, pH, clay, and organic carbon content. The present study investigated the effects of sediment composition and aging on the oral bioavailability of hexachlorobenzene (HCB) in rats. Formulated sediments were prepared using various ratios of kaolinite and montmorillonite clay, sand, peat moss, and black carbon, spiked with 14C-HCB, and orally administered to rats prior to and after one year of aging in dark at 10°C. In the nonaged sediments there was a 21 to 45% reduction in the oral bioavailability of HCB when compared to the corn oil standard without any clear pattern of the impact of the sediment clay and/or organic carbon content. One year of aging resulted in statistically significant (p = 0.049) reduction in the oral bioavailability of HCB from the sediments compared to the corn oil standard and nonaged sediment indicating stronger interactions between HCB and sediment contents with aging. The mean reduction in oral bioavailability after one year of aging ranged from approximately 5 to 14% greater than that observed for nonaged sediments. The fecal elimination of the HCB-derived radioactivity from the one-year-aged sediments was much higher than the nonaged sediments, consistent with the lower absorption from the gastrointestinal tract due to lower desorption of HCB from the aged sediments. Increase in the fecal elimination and decrease in oral bioavailability of 14C-HCB was related to the increase in clay and black carbon. [source] Biodiversity and resource use of larval chironomids in relation to environmental factors in a large riverFRESHWATER BIOLOGY, Issue 6 2002CHRISTIAN FESL 1.,Larval chironomids were examined at four sites on a cross-section of the River Danube in Austria between September 1995 and August 1996. The sites differed in hydraulics, sediment composition and habitat stability. 2.,Species,accumulation curves, showing the increase in number of species with increasing sampling effort, from three main channel sites were best described by a logarithmic model, suggesting that most of the species occurring at these sites were found. Data from a site connected to a backwater fitted best to a power model, indicating a random assemblage with additional species immigrating from the backwater area. 3.,Properties of the community were estimated using Jackknife techniques: species richness (range of mean values at the four sites: 32,91), H, diversity (1.5,2.3), evenness (0.23,0.28), spatial resource width (0.01,0.06), spatial resource overlap (0.13,0.20), spatial species aggregation (0.60,0.77), temporal community persistence (Kendal's correlation coefficient: 0.47,0.60) and beta-diversity (6.2,9.7). 4.,Redundancy analysis (RDA) was used to relate the community properties and species abundance to environmental factors. Habitat stability was the major factor associated with community structure. Higher sediment turnover led to higher spatial aggregation and, consequently, a decrease in spatial resource width and overlap, and to a decline in larval density and species richness. 5.,Species-abundance patterns agreed well with the log-normal model. Moderate community persistence and stability of the streambed sediments suggest that the log-normal model may be a good descriptor for communities of intermediately disturbed habitats, like large rivers, rather than stable habitats. [source] Sandstone diagenesis of the Lower Cretaceous Sindong Group, Gyeongsang Basin, southeastern Korea: Implications for compositional and paleoenvironmental controlsISLAND ARC, Issue 1 2008Yong Il Lee Abstract The Gyeongsang Basin is a non-marine sedimentary basin formed by extensional tectonism during the Early Cretaceous in the southeastern Korean Peninsula. The sediment fill starts with the Sindong Group distributed along the western margin of the basin. It consists of three lithostratigraphic units: the Nakdong (alluvial fan), Hasandong (fluvial) and Jinju (lacustrine) formations with decreasing age. Sindong Group sandstones are classified into four petrofacies (PF) based on their detrital composition: PF-A consists of the lower Nakdong Formation with average Q73F12R15; PF-B the upper Nakdong and lower Hasandong formations with Q66F15R18; PF-C the middle Hasandong to middle Jinju formations with Q49F29R22; and PF-D the upper Jinju Formation with Q26F34R41. The variations of detrital composition influenced the diagenetic mineral assemblage in the Sindong Group sandstones. Illite and dolomite/ankerite are important diagenetic minerals in PF-A and PF-B, whereas calcite and chlorite are dominant diagenetic minerals in PF-C and PF-D. Most of the diagenetic minerals can be divided into early and late diagenetic stages of formation. Early diagenetic calcites occur mostly in PF-C, probably controlled by arid to semiarid climatic conditions during the sandstone deposition, no early calcite being found in PF-A and PF-B. Late-stage calcites are present in all Sindong Group sandstones. The calcium ions may have been derived from shale diagenesis and dissolution of early stage calcites in the Hasandong and Jinju sandstones. Illite, the only diagenetic clay mineral in PF-A and lower PF-B, is inferred to be a product of kaolinite transformation during deep burial, and the former presence of kaolinite is inferred from the humid paleoclimatic conditions during the deposition of the Nakdong Formation. Chlorites in PF-C and PF-D are interpreted to be the products of transformation of smectitic clay or of precipitation from alkaline pore water under arid to semiarid climatic conditions. The occurrence of late-stage diagenetic minerals largely depended on the distribution of early diagenetic minerals, which was controlled initially by the sediment composition and paleoclimate. [source] The potential role of plant oxygen and sulphide dynamics in die-off events of the tropical seagrass, Thalassia testudinumJOURNAL OF ECOLOGY, Issue 1 2005J. BORUM Summary 1Oxygen and sulphide dynamics were examined, using microelectrode techniques, in meristems and rhizomes of the seagrass Thalassia testudinum at three different sites in Florida Bay, and in the laboratory, to evaluate the potential role of internal oxygen variability and sulphide invasion in episodes of sudden die-off. The sites differed with respect to shoot density and sediment composition, with an active die-off occurring at only one of the sites. 2Meristematic oxygen content followed similar diel patterns at all sites with high oxygen content during the day and hyposaturation relative to the water column during the night. Minimum meristematic oxygen content was recorded around sunrise and varied among sites, with values close to zero at the die-off site. 3Gaseous sulphide was detected within the sediment at all sites but at different concentrations among sites and within the die-off site. Spontaneous invasion of sulphide into Thalassia rhizomes was recorded at low internal oxygen partial pressure during darkness at the die-off site. 4A laboratory experiment showed that the internal oxygen dynamics depended on light availability, and hence plant photosynthesis, and on the oxygen content of the water column controlling passive oxygen diffusion from water column to leaves and below-ground tissues in the dark. 5Sulphide invasion only occurred at low internal oxygen content, and the rate of invasion was highly dependent on the oxygen supply to roots and rhizomes. Sulphide was slowly depleted from the tissues when high oxygen partial pressures were re-established through leaf photosynthesis. Coexistence of sulphide and oxygen in the tissues and the slow rate of sulphide depletion suggest that sulphide reoxidation is not biologically mediated within the tissues of Thalassia. 6Our results support the hypothesis that internal oxygen stress, caused by low water column oxygen content or poor plant performance governed by other environmental factors, allows invasion of sulphide and that the internal plant oxygen and sulphide dynamics potentially are key factors in the episodes of sudden die-off in beds of Thalassia testudinum. Root anoxia followed by sulphide invasion may be a more general mechanism determining the growth and survival of other rooted plants in sulphate-rich aquatic environments. [source] | ||||||||||