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Average Particle Diameter (average + particle_diameter)
Selected AbstractsEffect of the carboxylic acid monomer type on the emulsifier-free emulsion copolymerization of styrene and butadieneJOURNAL OF APPLIED POLYMER SCIENCE, Issue 2 2007Mahdi Abdollahi Abstract Carboxylated styrene,butadiene rubber latexes were prepared through the emulsifier-free emulsion copolymerization of styrene and butadiene with various carboxylic acid monomers. The effects of various carboxylic acid monomers on the particle formation process were investigated. The type of carboxylic acid monomer strongly affected the particle nucleation. The number of particles and thus the polymerization rate increased with the increasing hydrophobicity of the carboxylic acid monomers. There was a significant difference in the polymerization rate per particle. The results showed that particle nucleation and growth were dependent on the hydrophilic nature of the carboxylic acid monomers. The average particle diameter of the carboxylated styrene,butadiene rubber latexes in the dry state was obtained through some calculations using direct measurements of the average particle diameter in the monomer-swollen state by a dynamic light scattering technique. Several parameters, such as the polymerization rate, number of latex particles per unit of volume of the aqueous phase, and polymerization rate per particle, were calculated. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 [source] Supercritical CO2 extraction of accumulated capsidiol from biotic elicitor-activated Capsicum annuum L fruit tissuesJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 2 2005ur Salg Abstract This work investigates the supercritical CO2 extraction of capsidiol from pepper fruit tissues activated with Alternaria alternate (Fr) Keissler suspension culture as a biotic elicitor. Capsidiol production in the fruit tissue was markedly increased by the treatment with a biotic elicitor and reached its maximum level after 4 days of elicitation. The effects of separation parameters such as temperature, pressure, supercritical solvent flow rate, particle diameter and also initial capsidiol concentration were investigated on solubility, initial extraction rate and extraction yield. The optimal extraction conditions were obtained at the temperature of 40 °C, the pressure of 400 bar, the supercritical CO2 flow rate of 2 cm3 min,1, and the average particle diameter of 116 µm. The results showed that the ratio of the supercritical CO2 extraction yield to the organic solvent extraction yield was changed from 84 to 97 wt-% depending on the initial capsidiol concentration. Copyright © 2004 Society of Chemical Industry [source] Calcium- and Lanthanum-Modified Lead Titanate (PCLT) Ceramic and PCLT/Vinylidene Fluoride-Trifluoroethylene 0-3 NanocompositesJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 9 2000Q. Q. Zhang Calcium- and lanthanum-modified lead titanate (PCLT) powders with size in the nanometer range were prepared by a sol,gel process. The PCLT gel was annealed at 850°C to produce powder with an average particle diameter of 80 nm. A dense and fine-grained PCLT ceramic, with grain size of ,0.7 ,m, was prepared by sintering the sol,gel-derived powder at 1150°C. The piezoelectric and pyroelectric properties of the PCLT ceramic varied linearly with the degree of poling in the ceramic. PCLT/vinylidene fluoride-trifluoroethylene (P(VDF-TrFE)) 0-3 nanocomposites with PCLT volume fractions of 0.1,0.5 were fabricated, using PCLT powders imbedded in a P(VDF-TrFE) matrix. The ceramic data were used to model the piezoelectric and pyroelectric properties of the PCLT/P(VDF-TrFE) composites, and good agreements were obtained. [source] RHEOLOGICAL PROPERTIES OF NONCOHESIVE APPLE DISPERSION WITH HELICAL AND VANE IMPELLERS: EFFECT OF CONCENTRATION AND PARTICLE SIZEJOURNAL OF FOOD PROCESS ENGINEERING, Issue 5 2000DENIS CANTÚ-LOZANO ABSTRACT The proportionality constant, ks, between shear rate, ,, and agitation velocity, N, for a helical ribbon-screw (HRS) agitator was 17.8. Using the HRS agitator, values of consistency index K and the flow behavior index n of 14 apple pulp suspensions at seven different solids concentrations and two average particle diameters 0.71 mm and 1.21 mm were determined; in addition, values of the Casson viscosity ,c and yield stress ,OC were also calculated. The magnitudes of K increased and of n decreased with increase in pulp concentration. Experimental values of the vane yield stress, ,O,, measured with a six-blade vane increased with increase in pulp content. The values of ,OC obtained using the Casson model were close to the experimental values ,O,. The effect of particle size on the relative viscosity, ,r, was correlated with Peclet number. [source] Rate constants of mass transfer kinetics in reversed phase liquid chromatographyAICHE JOURNAL, Issue 12 2005Lan Hong Abstract The parameters of the kinetics of mass transfer of several n -alkylbenzenes were measured by the method of moments on a series of columns prepared with different samples of the same RPLC packing material having widely different average particle diameters, from 3 to 50 ,m. These data were analyzed using the available models, and correlations. The best agreement between experimental and theoretical data was obtained under the assumption that the rate constant for the external mass transfer increases with increasing average particle size, an unexpected conclusion. It was also shown that the interpretation of the relative importance of the roles of pore diffusivity and surface diffusivity in the internal mass transfer kinetics is somewhat ambiguous and that the conclusion to be drawn from experimental results depends on the assumptions made regarding the tortuosity model and the relationship between kext and the average particle size. © 2005 American Institute of Chemical Engineers AIChE J, 2005 [source] Random lasing in nanocrystalline ZnO powdersPHYSICA STATUS SOLIDI (B) BASIC SOLID STATE PHYSICS, Issue 6 2010Heinz Kalt Abstract We investigate the properties of random lasing in nanocrystalline ZnO powders. The lowest threshold for lasing occurs for average particle diameters of about 260,nm. Reproducible lasing features are achieved for reduced ensemble sizes. Spatially resolved luminescence spectroscopy is used to probe directly the degree of localization of random laser mode. We find that strongly confined and extended modes can co-exist in the same spatial area. However, localized modes appear for small optical gain while extended modes are only supported in the presence of large optical gain, as is expected from theory. Localized and extended random-laser modes co-exist in space but appear in spectral regions of low and high optical gain, respectively. [source] | |||||||||||||