Home About us Contact
|
Home About us Contact | ||
|
|
||
Saturated Zone (saturated + zone)
Selected AbstractsInverse Modeling Approach to Allogenic Karst System CharacterizationGROUND WATER, Issue 3 2009N. Dörfliger Allogenic karst systems function in a particular way that is influenced by the type of water infiltrating through river water losses, by karstification processes, and by water quality. Management of this system requires a good knowledge of its structure and functioning, for which a new methodology based on an inverse modeling approach appears to be well suited. This approach requires both spring and river inflow discharge measurements and a continuous record of chemical parameters in the river and at the spring. The inverse model calculates unit hydrographs and the impulse responses of fluxes from rainfall hydraulic head at the spring or rainfall flux data, the purpose of which is hydrograph separation. Hydrograph reconstruction is done using rainfall and river inflow data as model input and enables definition at each time step of the ratio of each component. Using chemical data, representing event and pre-event water, as input, it is possible to determine the origin of spring water (either fast flow through the epikarstic zone or slow flow through the saturated zone). This study made it possible to improve a conceptual model of allogenic karst system functioning. The methodology is used to study the Bas-Agly and the Cent Font karst systems, two allogenic karst systems in Southern France. [source] Utilization of Decadal Tritium Variation for Assessing the Residence Time of Base FlowGROUND WATER, Issue 3 2007S. Rose An iterative algorithm is presented that allows the user to model the subsurface residence time of shallow ground water comprising stream base flow based on decadal scale variation of tritium concentrations. The algorithm accounts for the effects of radioactive decay, the shallow subsurface mixing of ground water with precipitation, and ground water flux. The inverse of the best-fitting modeled flux through the saturated zone is equivalent to the residence time. The data required for this model include at least two measurements of tritium in base flow for a given stream location made at least a decade apart and the long-term tritium input in precipitation for the region of interest. The model is sensitive to relatively small changes in tritium concentrations and is limited by analytic uncertainties to an accuracy of approximately ±5 years. The algorithm was applied to stream base flow for several basins in the Piedmont Province of Georgia in which tritium concentrations were measured during the early 1990s and again in the 2000s. The model results produced highly concordant residence times for three hydrogeologically similar basins in the Upper Ocmulgee Basin in North Central Georgia. The best estimate of the average residence time for ground water comprising base flow in this Piedmont basin using this new method is between approximately 14 and 18 years. These results are generally consistent with calculations made in previous studies, and these relatively long residence times can be attributed to the storage of water in the clay soils that dominate Piedmont Province watersheds. [source] Stochastic Study of Solute Transport in a Nonstationary MediumGROUND WATER, Issue 2 2006Bill X. Hu A Lagrangian stochastic approach is applied to develop a method of moment for solute transport in a physically and chemically nonstationary medium. Stochastic governing equations for mean solute flux and solute covariance are analytically obtained in the first-order accuracy of log conductivity and/or chemical sorption variances and solved numerically using the finite-difference method. The developed method, the numerical method of moments (NMM), is used to predict radionuclide solute transport processes in the saturated zone below the Yucca Mountain project area. The mean, variance, and upper bound of the radionuclide mass flux through a control plane 5 km downstream of the footprint of the repository are calculated. According to their chemical sorption capacities, the various radionuclear chemicals are grouped as nonreactive, weakly sorbing, and strongly sorbing chemicals. The NMM method is used to study their transport processes and influence factors. To verify the method of moments, a Monte Carlo simulation is conducted for nonreactive chemical transport. Results indicate the results from the two methods are consistent, but the NMM method is computationally more efficient than the Monte Carlo method. This study adds to the ongoing debate in the literature on the effect of heterogeneity on solute transport prediction, especially on prediction uncertainty, by showing that the standard derivation of solute flux is larger than the mean solute flux even when the hydraulic conductivity within each geological layer is mild. This study provides a method that may become an efficient calculation tool for many environmental projects. [source] A new saturated/unsaturated model for stormwater infiltration systemsHYDROLOGICAL PROCESSES, Issue 25 2008Dale Browne Abstract Infiltration systems are widely used as an effective urban stormwater control measure. Most design methods and models roughly approximate the complex physical flow processes in these systems using empirical equations and fixed infiltration rates to calculate emptying times from full. Sophisticated variably saturated flow models are available, but rarely applied owing to their complexity. This paper describes the development and testing of an integrated one-dimensional model of flow through the porous storage of a typical infiltration system and surrounding soils. The model accounts for the depth in the storage, surrounding soil moisture conditions and the interaction between the storage and surrounding soil. It is a front-tracking model that innovatively combines a soil-moisture-based solution of Richard's equation for unsaturated flow with piston flow through a saturated zone as well as a reservoir equation for flow through a porous storage. This allows the use of a simple non-iterative numerical solution that can handle ponded infiltration into dry soils. The model is more rigorous than approximate stormwater infiltration system models and could therefore be valuable in everyday practice. A range of test cases commonly used to test soil water flow models for infiltration in unsaturated conditions, drainage from saturation and infiltration under ponded conditions were used to test the model along with an experiment with variable depth in a porous storage over saturated conditions. Results show that the model produces a good fit to the observed data, analytical solutions and Hydrus. Copyright © 2008 John Wiley & Sons, Ltd. [source] Estimation of mean residence times of subsurface waters using seasonal variation in deuterium excess in a small headwater catchment in JapanHYDROLOGICAL PROCESSES, Issue 3 2007Naoki Kabeya Abstract We measured deuterium excess (d = ,D , 8,18O) in throughfall, groundwater, soil water, spring water, and stream water for 3 years in a small headwater catchment (Matsuzawa, 0·68 ha) in the Kiryu Experimental Watershed in Japan. The d value represents a kinetic effect produced when water evaporates. The d value of the throughfall showed a sinusoidal change (amplitude: 6·9, relative to Vienna standard mean ocean water (V-SMOW)) derived from seasonal changes in the source of water vapour. The amplitude of this sinusoidal change was attenuated to 1·3,6·9, V-SMOW in soil water, groundwater, spring water, and stream water. It is thought that these attenuations derive from hydrodynamic transport processes in the subsurface and mixing processes at an outflow point (stream or spring) or a well. The mean residence time (MRT) of water was estimated from d value variations using an exponential-piston flow model and a dispersion model. MRTs for soil water were 0,5 months and were not necessarily proportional to the depth. This may imply the existence of bypass flow in the soil. Groundwater in the hillslope zone had short residence times, similar to those of the soil water. For groundwater in the saturated zone near the spring outflow point, the MRTs differed between shallow and deeper groundwater; shallow groundwater had a shorter residence time (5,8 months) than deeper groundwater (more than 9 months). The MRT of stream water (8,9 months) was between that of shallow groundwater near the spring and deeper groundwater near the spring. The seasonal variation in the d value of precipitation arises from changes in isotopic water vapour composition associated with seasonal activity of the Asian monsoon mechanism. The d value is probably an effective tracer for estimating the MRT of subsurface water not only in Japan, but also in other East Asian countries influenced by the Asian monsoon. Copyright © 2006 John Wiley & Sons, Ltd. [source] Successful unsaturated zone treatment of PCE with sodium permanganateREMEDIATION, Issue 2 2009John R. Hesemann In situ chemical oxidation (ISCO) with permanganate has been widely used for soil and groundwater treatment in the saturated zone. Due to the challenges associated with achieving effective distribution and retention in the unsaturated zone, there is a great interest in developing alternative injection technologies that increase the success of vadose-zone treatment. The subject site is an active dry cleaner located in Topeka, Kansas. A relatively small area of residual contamination adjacent to the active facility building has been identified as the source of a large sitewide groundwater contamination plume with off-site receptors. The Kansas Department of Health and Environment (KDHE) currently manages site remedial efforts and chose to pilot-test ISCO with permanganate for the reduction of perchloroethene (PCE) soil concentrations within the source area. KDHE subsequently contracted Burns & McDonnell to design and implement an ISCO pilot test. A treatability study was performed by Carus Corporation to determine permanganate-soil-oxidant-demand (PSOD) and the required oxidant dosing for the site. The pilot-test design included an ISCO injection approach that consisted of injecting aqueous sodium permanganate using direct-push technology with a sealed borehole. During the pilot test, approximately 12,500 pounds of sodium permanganate were injected at a concentration of approximately 3 percent (by weight) using the methods described above. Confirmation soil sampling conducted after the injection event indicated PCE reductions ranging from approximately 79 to more than 99 percent. A follow-up treatment, consisting of the injection of an additional 6,200 pounds of sodium permanganate, was implemented to address residual soil impacts remaining in the soil source zone. Confirmation soil sampling conducted after the treatment indicated a PCE reduction of greater than 90 percent at the most heavily impacted sample location and additional reductions in four of the six samples collected. © 2009 Wiley Periodicals, Inc. [source] Field and laboratory evaluation of the treatment of DNAPL source zones using emulsified zero-valent ironREMEDIATION, Issue 2 2006Suzanne O' Hara Emulsified zero-valent iron (EZVI) is a surfactant-stabilized, biodegradable emulsion that forms droplets consisting of a liquid-oil membrane surrounding zero-valent iron (ZVI) particles in water. This article summarizes the results obtained during the first field-scale deployment of EZVI at NASA's Launch Complex 34 (LC34) located on Cape Canaveral Air Force Station, Florida, in August 2002 and presents the results of recent follow-on laboratory tests evaluating the mechanisms, which contribute to the performance of the technology. The field-scale demonstration evaluated the performance of EZVI containing nanoscale zero-valent iron (NZVI) when applied to dense, nonaqueous phase liquid (DNAPL) trichloroethylene (TCE) in the saturated zone. Results of the field demonstration indicate substantial reductions in TCE soil concentrations (greater than 80 percent) at all but two soil boring locations and significant reductions in TCE groundwater concentrations (e.g., 60 percent to 100 percent) at all depths targeted with EZVI. Laboratory tests conducted in 2005 suggest that both NZVI particles and EZVI containing NZVI can provide significant reductions in TCE mass when used to treat TCE DNAPL in small test reactors. However, EZVI was able to reduce TCE concentrations to lower levels than were obtained with NZVI alone, likely as a result of the combined impact of sequestration of the TCE into the oil phase and degradation of the TCE with the NZVI. © 2006 Wiley Periodicals, Inc. [source] | ||||||||||