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Sakurai Reaction (sakurai + reaction)

Distribution by Scientific Domains
Chemistry100%

Selected Abstracts

ChemInform Abstract: Montmorillonite K10 Clay Catalyzed Synthesis of Homoallylic Silyl Ethers: An Efficient and Environmentally Friendly Hosomi,Sakurai Reaction.

CHEMINFORM, Issue 10 2010
Matthew R. Dintzner
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]

Diastereoselective Synthesis of 2-Aryl-3-vinyl-2,3-dihydrobenzo[b]furans Through a Sakurai Reaction: A Mechanistic Proposal.

CHEMINFORM, Issue 16 2007
Leticia Jimenez-Gonzalez
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF. [source]

Diastereoselective Synthesis of 2-Aryl-3-vinyl-2,3-dihydrobenzo[b]furans through a Sakurai Reaction: A Mechanistic Proposal

CHEMISTRY - A EUROPEAN JOURNAL, Issue 2 2007
Leticia Jiménez-González Dr.
Abstract The condensation of 2,3-dihydrobenzoxasilepins with aromatic aldehydes in the presence of boron trifluoride to form 2,3-dihydrobenzofurans shows a level of diastereoselection which is a function of the electronic nature of the aldehyde and the polarity of the solvent. The study of the mechanism of the reaction demonstrated that it proceeds through a ring-opened allylfluorosilane, which is stable enough to be isolated and characterized. [source]

ChemInform Abstract: Hosomi,Sakurai Reactions of Silacyclohexenes.

CHEMINFORM, Issue 1 2008
Nicholas J. Hughes
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]

Bismuth Triflate-Catalyzed Addition of Allylsilanes to N -Alkoxycarbonylamino Sulfones: Convenient Access to 3-Cbz-Protected Cyclohexenylamines

ADVANCED SYNTHESIS & CATALYSIS (PREVIOUSLY: JOURNAL FUER PRAKTISCHE CHEMIE), Issue 18 2009
Thierry Ollevier
Abstract Bismuth triflate was found to be an efficient catalyst in the Sakurai reaction of allyltrimethylsilanes with N -alkoxycarbonylamino sulfones. The reaction proceeded smoothly with a low catalyst loading of Bi(OTf)3,4,H2O (2,5,mol%) to afford the corresponding protected homoallylic amines in very good yields (up to 96%). A sequential allylation reaction followed by ring-closing metathesis delivers 6,8 membered 3-Cbz-protected cycloalkenylamines. [source]