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Rotor
Terms modified by Rotor Selected AbstractsA Molecular Double Ball Bearing: An AgI,PtII Dodecanuclear Quadruple-Decker Complex with Three Rotors,ANGEWANDTE CHEMIE, Issue 9 2010Shuichi Hiraoka Dr. Fabelhafte Maschine: Eine 2.5,nm große molekulare Maschine, die wie ein Doppelkugellager funktioniert, wurde aus zwei Arten von scheibenförmigen Liganden, AgI -Ionen und zweikernigen PtII -Brückenkomplexen konstruiert (siehe Struktur: C rot, N blau, O lila, S grün, Ag gelb, Pt braun). Die Bewegung der drei Rotoren hängt in erster Linie vom Grad der Verzahnung zwischen den beiden Liganden in Rotor 2 ab. [source] Controlling Molecular Rotary Motion with a Self-Complexing Lock,ANGEWANDTE CHEMIE, Issue 6 2010Da-Hui Qu Dr. Rotor mit Zündschlüssel: Ein molekularer Rotor, in dem ein DB24C8-Makrocyclus an der Unterseite und ein Dialkylammoniumion an die Oberseite der Achse angebracht sind, bildet in schwach polaren Lösungsmitteln wie CH2Cl2 ein [1]Pseudorotaxan. Dieses selbstkomplexierende System lässt sich mithilfe von Säuren und Basen auf- und abfädeln, um den molekularen Motor zu blockieren oder freizugeben (siehe Schema). [source] Mode-Selective Electrical Excitation of a Molecular RotorCHEMISTRY - A EUROPEAN JOURNAL, Issue 38 2009Heather Batteries not included: The rotation of individual molecular rotors can be driven electrically using electrons from a scanning tunneling microscope tip (see picture). Above the threshold energy of the CH stretch excitation, tunneling electrons are effective at selectively driving rotation, but not translation of the thioether rotors. The ability to rotate individual molecules on command will permit the interrogation of many important effects like rotational energy transfer along 1D molecular chains and rotational orientation switching in ordered arrays. [source] A Molecular Double Ball Bearing: An AgI,PtII Dodecanuclear Quadruple-Decker Complex with Three Rotors,ANGEWANDTE CHEMIE, Issue 9 2010Shuichi Hiraoka Dr. Fabelhafte Maschine: Eine 2.5,nm große molekulare Maschine, die wie ein Doppelkugellager funktioniert, wurde aus zwei Arten von scheibenförmigen Liganden, AgI -Ionen und zweikernigen PtII -Brückenkomplexen konstruiert (siehe Struktur: C rot, N blau, O lila, S grün, Ag gelb, Pt braun). Die Bewegung der drei Rotoren hängt in erster Linie vom Grad der Verzahnung zwischen den beiden Liganden in Rotor 2 ab. [source] Computational Design and In Vitro Characterization of an Integrated Maglev Pump-OxygenatorARTIFICIAL ORGANS, Issue 10 2009Juntao Zhang Abstract For the need for respiratory support for patients with acute or chronic lung diseases to be addressed, a novel integrated maglev pump-oxygenator (IMPO) is being developed as a respiratory assist device. IMPO was conceptualized to combine a magnetically levitated pump/rotor with uniquely configured hollow fiber membranes to create an assembly-free, ultracompact system. IMPO is a self-contained blood pump and oxygenator assembly to enable rapid deployment for patients requiring respiratory support or circulatory support. In this study, computational fluid dynamics (CFD) and computer-aided design were conducted to design and optimize the hemodynamics, gas transfer, and hemocompatibility performances of this novel device. In parallel, in vitro experiments including hydrodynamic, gas transfer, and hemolysis measurements were conducted to evaluate the performance of IMPO. Computational results from CFD analysis were compared with experimental data collected from in vitro evaluation of the IMPO. The CFD simulation demonstrated a well-behaved and streamlined flow field in the main components of this device. The results of hydrodynamic performance, oxygen transfer, and hemolysis predicted by computational simulation, along with the in vitro experimental data, indicate that this pump-lung device can provide the total respiratory need of an adult with lung failure, with a low hemolysis rate at the targeted operating condition. These detailed CFD designs and analyses can provide valuable guidance for further optimization of this IMPO for long-term use. [source] Functional and Biocompatibility Performances of an Integrated Maglev Pump-OxygenatorARTIFICIAL ORGANS, Issue 1 2009Tao Zhang Abstract To provide respiratory support for patients with lung failure, a novel compact integrated pump-oxygenator is being developed. The functional and biocompatibility performances of this device are presented. The pump-oxygenator is designed by combining a magnetically levitated pump/rotor with a uniquely configured hollow fiber membrane bundle to create an assembly free, ultracompact, all-in-one system. The hemodynamics, gas transfer and biocompatibility performances of this novel device were investigated both in vitro in a circulatory flow loop and in vivo in an ovine animal model. The in vitro results showed that the device was able to pump blood flow from 2 to 8 L/min against a wide range of pressures and to deliver an oxygen transfer rate more than 300 mL/min at a blood flow of 6 L/min. Blood damage tests demonstrated low hemolysis (normalized index of hemolysis [NIH],0.04) at a flow rate of 5 L/min against a 100-mm Hg afterload. The data from five animal experiments (4 h to 7 days) demonstrated that the device could bring the venous blood to near fully oxygen-saturated condition (98.6% ± 1.3%). The highest oxygen transfer rate reached 386 mL/min. The gas transfer performance was stable over the study duration for three 7-day animals. There was no indication of blood damage. The plasma free hemoglobin and platelet count were within the normal ranges. No gross thrombus is found on the explanted pump components and fiber surfaces. Both in vitro and in vivo results demonstrated that the newly developed pump-oxygenator can achieve sufficient blood flow and oxygen transfer with excellent biocompatibility. [source] A method to determine direct- and quadrature-axis inductances of permanent magnet synchronous motorsELECTRICAL ENGINEERING IN JAPAN, Issue 3 2010Shu Yamamoto Abstract The equivalent circuit constants of permanent magnet synchronous motors are needed in the calculation of operation characteristics, construction of a control system, etc. These constants can be computed from the data on structural form and materials. However, measurements are necessary to obtain highly precise values. Methods for measurement of the d- and q-axis inductances can be roughly divided into rotational and standstill methods. The standstill methods have the advantage that they are easy to carry out. However, it is difficult to consider magnetic saturation and distortion of the change in the armature winding inductance. The accuracy of the standstill method can be improved if these effects can be readily taken into account. This paper describes a standstill method for measuring accurate d- and q-axis synchronous inductances of permanent magnet synchronous motors. By utilizing the fact that the EMF interference terms in the motor voltage equation considering the distortion of the inductance change are equal to zero when the rotor is in a specific position, the proposed method determines the inductances considering both magnetic saturation and inductance distortion effects from simple off-line standstill testing. In addition, this method is capable of taking cross-magnetic saturation into account when used with the necessary testing equipment. The proposed method was implemented on a 0.4-kW interior permanent magnet synchronous motor with concentrated stator winding. The validity of the proposed method was demonstrated by comparing the measured and calculated results of the no-load and on-load characteristics. © 2010 Wiley Periodicals, Inc. Electr Eng Jpn, 171(3): 41,50, 2010; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/eej.20969 [source] Anodic Stripping Voltammetry Using a Vibrating ElectrodeELECTROANALYSIS, Issue 13 2007Conrad Abstract This work proposes a vibrating microwire electrode as working electrode in stripping voltammetry. The vibration was found to maintain a constant and thin (1,2,,m) diffusion layer during the deposition step. The electrode vibration eliminated the need for external stirring of the solution, thus facilitating in situ detection in the environment. The vibration was effected by fixing a low-voltage (3,V), asymmetric, electrical rotor to the working electrode (a gold microwire of either 5 or 25,,m). The sensitivity of the vibrated electrode was ca. 22×greater than stationary. Measurements of copper (4,nM) by anodic stripping voltammetry using the vibrating electrode had a low standard deviation (1% for n=6) indicating that the diffusion layer had only minor variability. The agitation mechanism was unaffected by water moving at >2,m s,1 and by water pressure equivalent to a depth of >40,m, indicating its suitability for in situ measurements. The vibrating probe was used for in situ detection of copper by anodic stripping voltammetry to a depth of 6,m. Using a 5,min deposition time, the limit of detection for labile copper was 38,pM. [source] Autonomous power system for island or grid-connected wind turbines in distributed generationEUROPEAN TRANSACTIONS ON ELECTRICAL POWER, Issue 7 2008Grzegorz Iwanski Abstract Modern power generation systems for wind turbines are often based on the rotor fed slip-ring machines. Power electronics converter provides the slip power, and also the reactive power for excitation of the generator during standalone operation. This way the isolated load can be supplied even if the grid has failed. Stator voltage in an autonomous operation is controlled using vectorial phase locked loop (PLL) structure; therefore the information about mechanical speed or angular position of the rotor is eliminated from the control method. The second PLL is also used for synchronization of the generated voltage with the grid voltage. Voltages synchronization is necessary for soft connection and protection of the supplied load from the rapid change of the supply voltage phase. The grid-connected doubly fed induction generator (DFIG) can be useful after grid fault; however, the mains outage detection methods are necessary for fast disconnection after grid failures. Copyright © 2008 John Wiley & Sons, Ltd. [source] Design and comparison of different flux-switch synchronous machines for an aircraft oil breather applicationEUROPEAN TRANSACTIONS ON ELECTRICAL POWER, Issue 6 2005Yacine Amara This paper presents a design procedure of a flux,switch synchronous machine for an aircraft oil breather application. This work is part of a European project called ,Power Optimised Aircraft'. The aim of this project is to replace some mechanical equipment by electromechanical devices to improve performance and reduce power consumption. The structure under study was developed at SATIE laboratory and it is based on the flux-switch principle. The permanent magnets are located in the stator, and the rotor is entirely passive. The study described in this paper is limited to the electromagnetic design. Copyright © 2005 John Wiley & Sons, Ltd. [source] Position-sensorless direct-torque-controlled synchronous motor drive for ship propulsionEUROPEAN TRANSACTIONS ON ELECTRICAL POWER, Issue 6 2000M. Niemelä A new concept is proposedfor position-sensorless Direct-Torque-Controlled (DTC) synchronous motor drives for ship propulsion. The principles of determination of the initial rotor position at standstill or the position of a rotating rotor, the operation at zero speed and at low rotational speeds in general are described. The study introduces also a flux linkage estimate correction method for the DTC. Some of the results of the numerous experiments performed with a laboratory prototype drive are given. [source] On computation of response of a rotor in deformed configuration using three-dimensional finite elementsINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN BIOMEDICAL ENGINEERING, Issue 3 2003A. Nandi Abstract The governing differential equations for a rotor are derived in a rotating reference, which rotates about the centre-line of the bearings with a speed equal to the shaft spin speed. The same equations of motion are once solved in the original configuration and once in the deformed configuration. It is observed that, though the analysis is based on small displacement elasticity, the difference in the above solutions is not negligible. It is shown that this can be attributed to the moment resultant caused by the centrifugal force in the deformed configuration. Copyright © 2003 John Wiley & Sons, Ltd. [source] Parallel simulation of unsteady hovering rotor wakesINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN ENGINEERING, Issue 6 2006C. B. Allen Abstract Numerical simulation using low diffusion schemes, for example free-vortex or vorticity transport methods, and theoretical stability analyses have shown the wakes of rotors in hover to be unsteady. This has also been observed in experiments, although the instabilities are not always repeatable. Hovering rotor wake stability is considered here using a finite-volume compressible CFD code. An implicit unsteady, multiblock, multigrid, upwind solver, and structured multiblock grid generator are presented, and applied to lifting rotors in hover. To allow the use of very fine meshes and, hence, better representation of the flow physics, a parallel version of the code has been developed, and parallel performance using upto 1024 CPUs is presented. A four-bladed rotor is considered, and it is demonstrated that once the grid density is sufficient to capture enough turns of the tip vortices, hover exhibits oscillatory behaviour of the wake, even using a steady formulation. An unsteady simulation is then performed, and also shows an unsteady wake. Detailed analysis of the time-accurate wake history shows that three dominant unsteady modes are captured, for this four-bladed case, with frequencies of one, four, and eight times the rotational frequency. A comparison with theoretical stability analysis is also presented. Copyright © 2006 John Wiley & Sons, Ltd. [source] Numerical investigation of the effect of inlet condition on self-excited oscillation of wet steam flow in a supersonic turbine cascade,INTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS, Issue 12 2009Wu Xiaoming Abstract Self-excited oscillation can be induced due to the interaction between condensation process and local transonic condition in condensing flow, which is an important problem in wet steam turbine. With an Eulerian/Eulerian numerical model, the self-excited oscillation of wet steam flow is investigated in a supersonic turbine cascade. Owing to supercritical heat addition to the subsonic flow in the convergent part of the cascade, the oscillation frequency decreases with increased inlet supercooling. Mass flow rate increases in the oscillating flow due to the greater supersaturation in condensation process, while the increase will be suppressed with the flow oscillation. Higher inlet supercooling leads to the fact that the condensation process moves upstream and the loss increases. Moreover, some predictions of oscillation effects on outflow angle and aerodynamic force are also presented. Finally, heterogeneous condensations with inlet wetness and periodic inlet conditions, as a result of the interference between stator and rotor, are discussed. Copyright © 2008 John Wiley & Sons, Ltd. [source] Sliding mesh algorithm for CFD analysis of helicopter rotor,fuselage aerodynamicsINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS, Issue 5 2008R. Steijl Abstract The study of rotor,fuselage interactional aerodynamics is central to the design and performance analysis of helicopters. However, regardless of its significance, rotor,fuselage aerodynamics has so far been addressed by very few authors. This is mainly due to the difficulties associated with both experimental and computational techniques when such complex configurations, rich in flow physics, are considered. In view of the above, the objective of this study is to develop computational tools suitable for rotor,fuselage engineering analysis based on computational fluid dynamics (CFD). To account for the relative motion between the fuselage and the rotor blades, the concept of sliding meshes is introduced. A sliding surface forms a boundary between a CFD mesh around the fuselage and a rotor-fixed CFD mesh which rotates to account for the movement of the rotor. The sliding surface allows communication between meshes. Meshes adjacent to the sliding surface do not necessarily have matching nodes or even the same number of cell faces. This poses a problem of interpolation, which should not introduce numerical artefacts in the solution and should have minimal effects on the overall solution quality. As an additional objective, the employed sliding mesh algorithms should have small CPU overhead. The sliding mesh methods developed for this work are demonstrated for both simple and complex cases with emphasis placed on the presentation of the inner workings of the developed algorithms. Copyright © 2008 John Wiley & Sons, Ltd. [source] Multigrid convergence of inviscid fixed- and rotary-wing flowsINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS, Issue 2 2002C. B. Allen Abstract The affect of multigrid acceleration implemented within an upwind-biased Euler method is presented, and applied to fixed-wing and rotary-wing flows. The convergence of fixed- and rotary-wing computations is shown to be vastly different, and multigrid is shown to be less effective for rotary-wing flows. The flow about a hovering rotor suffers from very slow convergence of the inner blade region, where the flow is effectively incompressible. Furthermore, the vortical wake must develop over several turns before convergence is achieved, whereas for fixed-wing computations the far-field grid and solution have little significance. Results are presented for single mesh and two, three, four, and five level multigrid, and using five levels a reduction in required CPU time of over 80 per cent is demonstrated for rotary-wing computations, but 94 per cent for fixed-wing computations. It is found that a simple V-cycle is the most effective, smoothing in the decreasing mesh density direction only, with a relaxed trilinear prolongation operator. Copyright © 2002 John Wiley & Sons, Ltd. [source] Boundary control of a two-dimensional flexible rotorINTERNATIONAL JOURNAL OF ADAPTIVE CONTROL AND SIGNAL PROCESSING, Issue 6 2001S. P. Nagarkatti Abstract In this paper, we present the design of boundary controllers for a two-dimensional, spinning flexible rotor system. Specifically, we develop a model-based boundary controller which exponentially regulates the rotor's displacement and the angular velocity tracking error, and an adaptive boundary controller which asymptotically achieves the same control objective while compensating for parametric uncertainty. As opposed to previous boundary control work, which focused on the velocity setpoint problem and placed restrictions on the magnitude of the desired angular velocity setpoint, the proposed control architecture achieves angular velocity tracking with no restrictions on the magnitude of the desired velocity trajectory. Experimental results conducted on a flexible rotor tested are presented to illustrate the feasibility of implementing the proposed boundary control laws. Copyright © 2001 John Wiley & Sons, Ltd. [source] Simplified models for the performance evaluation of desiccant wheel dehumidificationINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 1 2003M. Beccali Abstract In the present communication, simple models have been presented to evaluate the performance of rotary desiccant wheels based on different kind of solid desiccants e.g. silica gel and LiCl. The first part of the paper presents ,Model 54' which is developed for silica gel desiccant rotor. The model has been derived from the interpolation of experimental data obtained from the industry and the correlations have been developed for predicting outlet temperature and absolute humidity. The ,Model 54' consists of 54 coefficients corresponding to each correlation for outlet absolute humidity and temperature and it is found that the model predicts very well the performance of silica gel desiccant rotor (Type-I). In the second part of the paper, a psychrometric model has been presented to obtain relatively simple correlations for outlet temperature and absolute humidity. The developed psychometric model is based on the correlations between the relative humidity and enthalpy of supply and regeneration air streams. The model is used to predict the performance of three type of desiccant rotors manufactured by using different kind of solid desiccants (Type I, II and III). The model is tested corresponding to a wide range of measurement data. The developed psychometric model is simple in nature and able to predict very well the performance of different kind of desiccant rotors. Copyright © 2002 John Wiley & Sons, Ltd. [source] Thermodynamic calculations for molecules with asymmetric internal rotors.JOURNAL OF COMPUTATIONAL CHEMISTRY, Issue 3 2008Abstract The thermodynamic properties of three halocarbon molecules relevant in atmospheric and public health applications are presented from ab initio calculations. Our technique makes use of a reaction path-like Hamiltonian to couple all the vibrational modes to a large-amplitude torsion for 1,2-difluoroethane, 1,2-dichloroethane, and 1,2-dibromoethane, each of which possesses a heavy asymmetric rotor. Optimized ab initio energies and Hessians were calculated at the CCSD(T) and MP2 levels of theory, respectively. In addition, to investigate the contribution of electronically excited states to thermodynamic properties, several excited singlet and triplet states for each of the halocarbons were computed at the CASSCF/MRCI level. Using the resulting potentials and projected frequencies, the couplings of all the vibrational modes to the large-amplitude torsion are calculated using the new STAR-P 2.4.0 software platform that automatically parallelizes our codes with distributed memory via a familiar MATLAB interface. Utilizing the efficient parallelization scheme of STAR-P, we obtain thermodynamic properties for each of the halocarbons, with temperatures ranging from 298.15 to 1000 K. We propose that the free energies, entropies, and heat capacities obtained from our methods be used to supplement theoretical and experimental values found in current thermodynamic tables. © 2007 Wiley Periodicals, Inc. J Comput Chem, 2008 [source] Vibration and stability control of robotic manipulator systems consisting of a thin-walled beam and a spinning tip rotorJOURNAL OF FIELD ROBOTICS (FORMERLY JOURNAL OF ROBOTIC SYSTEMS), Issue 10 2002Ohseop Song Vibration and stability feedback control of a robotic manipulator modeled as a cantilevered thin-walled beam carrying a spinning rotor at its tip is investigated. The control is achieved via incorporation of adaptive capabilities that are provided by a system of piezoactuators, bonded or embedded into the host structure. Based on converse piezoelectric effect, the piezoactuators produce a localized strain field in response to an applied voltage, and as a result, an adaptive change of vibrational and stability response characteristics is obtained. A feedback control law relating the piezoelectrically induced bending moments at the beam tip with the appropriately selected kinematical response quantities is used, and the beneficial effects of this control methodology upon the closed-loop eigenvibration characteristics and stability boundaries are highlighted. The cantilevered structure modeled as a thin-walled beam, and built from a composite material, encompasses non-classical features, such as anisotropy, transverse shear, and secondary warping, and in this context, a special ply-angle configuration inducing a structural coupling between flapping-lagging and transverse shear is implemented. It is also shown that the directionality property of the material of the host structure used in conjunction with piezoelectric strain actuation capability, yields a dramatic enhancement of both the vibrational and stability behavior of the considered structural system. © 2002 Wiley Periodicals, Inc. [source] Hydrodynamic Cavitation to Improve Bulk Fluid to Surface Mass Transfer in a Nonimmersed Ultraviolet System for Minimal Processing of Opaque and Transparent Fluid FoodsJOURNAL OF FOOD SCIENCE, Issue 9 2007P.J. Milly ABSTRACT:, Ultraviolet (UV)-induced chemical reactions and inactivation of microorganisms in transparent and opaque fluids are strongly dependent upon the homogenous exposure of the target species to the UV irradiation. Current UV technologies used in water disinfection and food preservation applications have limited efficacy due to suspended particles shading target species. An Ultraviolet-Shockwave PowerÔ Reactor (UV-SPR) consisting of an inner rotating rotor and a stationary quartz housing and 2 end plates was used to induce ,controlled cavitation.' Eight UV low-pressure mercury lamps spaced uniformly were installed lengthwise around the quartz housing periphery. A KI to I3,chemical dosimeter for UV was used to quantify photons received by fluid in the annular space of the SPR. UV dose (J/m2) increased from 97 J/m2 at 0 rpm to over 700 J/m2 for SPR speeds above 2400 rpm. Inactivation of E. coli 25922 in apple juice and skim milk in the UV-SPR at exit temperatures below 45 °C was greater than 4.5 and 3 logs, respectively. The UV-SPR system proved successful in increasing the mass transfer of transparent and opaque fluid to the UV irradiated surface. [source] Experimental and numerical investigation of the precipitation of barium sulfate in a rotating liquid film reactorAICHE JOURNAL, Issue 8 2009Shengchang Guo Abstract Precipitation of nanosized barium sulfate in a rotating liquid film reactor (RLFR) has been investigated experimentally and through simulations based on the computational fluid dynamics technique including the population balance equation coupled with the Navier,Stokes equations, renormalization group k,, model equations, and species transport equations. A comparative experiment was carried out involving conventional precipitation in a flask. The structure of the precipitate was identified by powder X-ray diffraction (PXRD), which showed that the crystals obtained using the RLFR were smaller in size than those obtained in the flask. Transmission electron microscopy (TEM) images demonstrated that the crystals produced by the two different processes had different morphologies. Further detailed experiments involving varying the operating parameters of the RLFR were performed to investigate the effects on crystal size distribution (CSD). Increasing the speed of the rotor in the RLFR in the range 1000,5000 rpm or increasing the rotor-stator gap in the range 0.1,0.5 mm resulted in a decrease in particle size and narrower particle size distributions. The simulation results suggested that turbulent effects and reaction processes in the effective reactor space were directly related to rotor speed and rotor-stator gap. The simulated volume weighted mean diameter and CSD of particles of barium sulfate were almost identical to the corresponding experimental results obtained using TEM and laser particle size analyzer. The effects of other parameters such as the Kolmogorov scale and competition between induction time and mixing time are also discussed. © 2009 American Institute of Chemical Engineers AIChE J, 2009 [source] A disc brake test stand for measurement of airborne wear particlesLUBRICATION SCIENCE, Issue 6 2009Jens Wahlström Abstract During braking, there is wear on both the rotor and the pads. This process generates particles that may become airborne. In field tests, it is difficult to distinguish these particles from others in the surrounding environment. Therefore, a laboratory test stand has been designed which allows control of the cleanliness of the surrounding air. The test stand consists of a front right brake assembly mounted in a sealed chamber. A braking load is applied by a pneumatic system and the rotor, which has been pre-conditioned with a rust layer to simulate a car standing parked overnight in a wet environment, is driven by an electric motor. The number and size of airborne wear particles are then measured. This experimental set-up has been verified by an initial test series performed at low braking loads. The results suggest that this test stand can be used to study rust layer removal from the rotor. Copyright © 2009 John Wiley & Sons, Ltd. [source] Fabrication of Aligned Poly(L -lactide) Fibers by Electrospinning and DrawingMACROMOLECULAR MATERIALS & ENGINEERING, Issue 10 2009Amalina M. Afifi Abstract A new target collector was designed for taking up aligned nanofibers by electrospinning. The collector consists of a rotor around which several fins were attached for winding electrospun filaments continuously in large amounts. The alignment of the nanofibers wound on the collector was affected by the electrospinning conditions, such as the needle-to-collector distance and the applied voltage, but not by the rotation speed of the collector. At a voltage of 0.5,kV,·,cm,1, about 60% of the fibers were found to be aligned within an angle of,±,5° relative to the rotational direction of the collector. The fiber alignment was improved to 90% by drawing the fiber bundle 2,3 times at 110,°C. The drawing was also effective for crystal orientation of the fibers as revealed by WAXD. The drawn fibers show improved mechanical properties. [source] High-resolution magic-angle spinning NMR for the identification of reaction products directly from thin-layer chromatography spotsMAGNETIC RESONANCE IN CHEMISTRY, Issue 10 2007Scott A. Bradley Abstract We have investigated the prospect of identifying organic reaction products directly from separated thin-layer chromatography (TLC) spots with high-resolution magic-angle spinning (HRMAS) NMR. The concept is to use the TLC spots for NMR analysis so that spectra can be obtained before the reaction is worked up, but without having to elute the product from the TLC stationary phase. Thus, the separated spot is scraped from the plate, transferred to an HRMAS sample rotor, and suspended with a deuterated solvent. Herein, we describe the effects of having the stationary phase present during NMR acquisition. Using a Varian 4 mm gHX Nanoprobe and rotenone as a test compound, we found that the presence of the stationary phase during NMR acquisition resulted in (i) a large, broad ,background' signal near 4.6 ppm and (ii) a decrease in the signal-to-noise ratio due to the adsorption of the product molecules to the adsorbent. However, both effects could be adequately and conveniently eliminated. The background signal was removed by using either a CPMG pulse sequence or chemical exchange. The adsorption was avoided by using a more polar solvent system. Finally, we found that spectra with good signal-to-noise ratio and resolution could be acquired in a matter of minutes even for cases of limited product concentration. Therefore, we believe the technique has value and provides the organic chemist with another option to obtain NMR data critical for structural elucidation or verification. Copyright © 2007 John Wiley & Sons, Ltd. [source] Shear stress nucleation in microcellular foaming processPOLYMER ENGINEERING & SCIENCE, Issue 6 2002Lee Chen The effect of shear stress on the foaming process has been studied using the Foaming Process Simulator developed previously. The polymer samples were saturated with gas in the test chamber. A rotor was used to apply shear stress to the polymer samples. Foams were obtained by releasing the pressure quickly. Polystyrene, filled and unfilled, was used as the material. The cell density was analyzed with a scanning electron microscope. It was found that the cell density was significantly increased by introducing shear stress. The higher the shear stress, the more significant the effect. A cell stretch model has been developed to explain the cell nucleation enhancement with shear stress. The nucleation sites are stretched under the shear stress. The stretched nuclei are much easier to expand for cell formation owing to their larger surface areas and non-spherical shapes. The model prediction shows the same tendency of the effect of shear stress observed in the experiment. The key issue with shear stress nucleation is the transformation of mechanical shear energy into surface energy. [source] A comparison of algebraic Reynolds stress models for the prediction of the turbulent flow inside a turbomachine rotorPROCEEDINGS IN APPLIED MATHEMATICS & MECHANICS, Issue 1 2003Marco Antonello Dr. An algebraic Reynolds stress model has been developed and tested simulating the turbulent flow inside a centrifugal impeller. The prediction of the model are compared with those of other algebraic turbulent stress models, in order to analyse the capability of properly account for effects such as flow curvature, flow separation, and solid wall rotation. [source] Prevent major failures and accidents with well-trained and empowered operatorsPROCESS SAFETY PROGRESS, Issue 2 2010Muhammad Idrees Abstract This article shares Engro's experience at its ammonia plant involving the prevention of major failures of the synthesis gas compressor turbine by taking prompt action to shutdown the compressor. Engro's strategy of providing operations training to enable and empower its people to make the right decisions at right time is the major learning of this article, whereby a manual shutdown before the automatic instrumentation trip of the machine was initiated. This article also describes the techniques used by the operations team to train and empower their people. Despite a plant outage of more than 10 days to replace the rotor, we believe the manual shutdown averted a more disastrous situation. Continuing to run the turbine may have resulted in a safety incident or an even longer plant shutdown for significant repairs. A well-trained and empowered operator is always helpful by making prompt decisions to shut down equipment, rather than relying solely on instrumentation to protect equipment. The following is a discussion of the training program which enables and empowers the operator to make correct decisions and take the correct action at the right time. © 2009 American Institute of Chemical Engineers Process Saf Prog, 2010 [source] Deterministic random walks on regular treesRANDOM STRUCTURES AND ALGORITHMS, Issue 3 2010Joshua Cooper Abstract Jim Propp's rotor,router model is a deterministic analog of a random walk on a graph. Instead of distributing chips randomly, each vertex serves its neighbors in a fixed order. Cooper and Spencer (Comb Probab Comput 15 (2006) 815,822) show a remarkable similarity of both models. If an (almost) arbitrary population of chips is placed on the vertices of a grid ,d and does a simultaneous walk in the Propp model, then at all times and on each vertex, the number of chips on this vertex deviates from the expected number the random walk would have gotten there by at most a constant. This constant is independent of the starting configuration and the order in which each vertex serves its neighbors. This result raises the question if all graphs do have this property. With quite some effort, we are now able to answer this question negatively. For the graph being an infinite k -ary tree (k , 3), we show that for any deviation D there is an initial configuration of chips such that after running the Propp model for a certain time there is a vertex with at least D more chips than expected in the random walk model. However, to achieve a deviation of D it is necessary that at least exp(,(D2)) vertices contribute by being occupied by a number of chips not divisible by k at a certain time. © 2010 Wiley Periodicals, Inc. Random Struct. Alg., 2010 [source] Sea-land breeze development during a summer bora event along the north-eastern Adriatic coastTHE QUARTERLY JOURNAL OF THE ROYAL METEOROLOGICAL SOCIETY, Issue 651 2010Maja Teli, man Prtenjak Abstract The interaction of a summer frontal bora and the sea-land breeze along the north-eastern Adriatic coast was investigated by means of numerical simulations and available observations. Available measurements (in situ, radiosonde, satellite images) provided model validation. The modelled wind field revealed several regions where the summer bora (weaker than 6 m s,1) allowed sea-breeze development: in the western parts of the Istrian peninsula and Rijeka Bay and along the north-western coast of the island of Rab. Along the western Istrian coast, the position of the narrow convergence zone that formed depended greatly on the balance between the bora jets northward and southward of Istria. In the case of a strong northern (Trieste) bora jet, the westerly Istrian onshore flow presented the superposition of the dominant swirled bora flow and local weak thermal flow. It collided then with the easterly bora flow within the zone. With weakening of the Trieste bora jet, the convergence zone was a result of the pure westerly sea breeze and the easterly bora wind. In general, during a bora event, sea breezes were somewhat later and shorter, with limited horizontal extent. The spatial position of the convergence zone caused by the bora and sea-breeze collision was strongly curved. The orientation of the head (of the thermally-induced flow) was more in the vertical causing larger horizontal pressure gradients and stronger daytime maximum wind speed than in undisturbed conditions. Except for the island of Rab, other lee-side islands in the area investigated did not provide favourable conditions for the sea-breeze formation. Within a bora wake near the island of Krk, onshore flow occurred as well, although not as a sea-breeze flow, but as the bottom branch of the lee rotor that was associated with the hydraulic jump-like feature in the lee of the Velika Kapela Mountain. Copyright © 2010 Royal Meteorological Society [source] | ||||||||||||||||||||||||||||||||||