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Terms modified by Rigid Selected AbstractsFast and Scalable CPU/GPU Collision Detection for Rigid and Deformable SurfacesCOMPUTER GRAPHICS FORUM, Issue 5 2010Simon Pabst Abstract We present a new hybrid CPU/GPU collision detection technique for rigid and deformable objects based on spatial subdivision. Our approach efficiently exploits the massive computational capabilities of modern CPUs and GPUs commonly found in off-the-shelf computer systems. The algorithm is specifically tailored to be highly scalable on both the CPU and the GPU sides. We can compute discrete and continuous external and self-collisions of non-penetrating rigid and deformable objects consisting of many tens of thousands of triangles in a few milliseconds on a modern PC. Our approach is orders of magnitude faster than earlier CPU-based approaches and up to twice as fast as the most recent GPU-based techniques. [source] quart -Feproline: Synthesis of a Very Rigid [3]Ferrocenophane-Derived Artificial Amino AcidEUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 17 2008Ludger Tebben Abstract Starting from the ,-(dimethylamino)[3]ferrocenophane derivative 1, a short reaction sequence was developed to form a doubly anellated dihydropyrrole derivative 6 containing the ferrocenophane framework. Intermediate 6 was used for the synthesis of the (R,S,pS)-enantiomer of the rigid artificial amino acid "quart -Feproline". (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008) [source] Rigid, Self-Assembled Hydrogel Composed of a Modified Aromatic Dipeptide,ADVANCED MATERIALS, Issue 11 2006A. Mahler A simple dipeptide self-assembles into a biocompatible hydrogel (see figure and inside cover). This novel biomaterial is extremely simple to prepare and has a remarkable rigidity. It is very stable under extreme conditions, can be injected, and can be shaped according to the vessel it has been assembled in. The hydrogel allows a wide variety of possible biomedical applications including tissue engineering, axonal regeneration, and controlled drug release. [source] Lyotropic liquid-crystalline behavior of polyisocyanodipeptidesJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 6 2007Gerald A. Metselaar Abstract Rigid, helical polyisocyanodipeptides derived from alanine (PIAAs) that form lyotropic liquid-crystalline (LC) phases in tetrachloroethane are presented. An investigation by optical microscopy between crossed polarizers demonstrated that PIAAs prepared by the polymerization of isocyanodipeptide monomers with an activated tetrakis isocyanide nickel(II) catalyst could form cholesteric LC phases in tetrachloroethane in concentrations between 18 and 30 wt %. Cholesteric LC phases that were formed in solutions of greater than 25 wt % displayed a reversal of the cholesteric helix upon annealing at 50 °C. Diastereomeric PIAA mixtures displayed cholesteric LC behavior only when the PIAAs had the same helix screw sense. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 981,988, 2007 [source] Noncovalent Interactions in the Asymmetric Synthesis of Rigid, Conjugated Helical Structures,ANGEWANDTE CHEMIE, Issue 32 2009Makoto Miyasaka Dr. Von helicaler Faltung zu helicaler Fixierung: Das Tetrakis(,-trithiophen) 1 faltet sich in eine helicale Konformation (RRR), die eine doppelte Ringanellierung erleichtert und mit hoher Diastereoselektivität und mäßiger Enantioselektivität das Bis[7]helicen 2 (MRM) liefert. Diese starre, helical fixierte Struktur zeigt verbesserte chiroptische Eigenschaften, ähnlich denen des entsprechenden [15]Helicens. [source] ChemInform Abstract: Structure and Energetics of Ammonia Clusters (NH3)n (n = 3,20) Investigated Using a Rigid,Polarizable Model Derived from ab initio Calculations.CHEMINFORM, Issue 26 2008Paula E. Janeiro-Barral Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source] Highly Enantioselective Synthesis of Rigid, Quaternary 1,4-Benzodiazepine-2,5-diones Derived from Proline.CHEMINFORM, Issue 12 2006Stephanie MacQuarrie-Hunter Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF. [source] Rigid,Flexible Block Molecules Based on a Laterally Extended Aromatic Segment: Hierarchical Assembly into Single Fibers, Flat Ribbons, and Twisted RibbonsCHEMISTRY - A EUROPEAN JOURNAL, Issue 23 2008Eunji Lee Abstract Self-assembling rigid,flexible block molecules consisting of a laterally extended aromatic segment and different lengths of hydrophilic coils were synthesized and characterized. The block molecule based on a long poly(ethylene oxide) coil (1), in the melt state, shows an unidentified columnar structure, whereas the molecule with a shorter poly(ethylene oxide) coil (2) self-organizes into an oblique columnar structure. Further decrease in the poly(ethylene oxide) coil length as in the case of 3, on heating, induces a rectangular columnar structure in addition to an oblique columnar mesophase. In diethyl ether, 1 and 2 were observed to self-assemble into uniform nanofibers with bilayer packing. Remarkably, these elementary fibers were observed to further aggregate in a lateral way to form well-defined flat ribbons (1) and twisted ribbons (2) with solvent exchange of diethyl ether into methanol. Furthermore, the ribbons formed in methanol dissociated into elementary fibers in response to the addition of aromatic guest molecules. This transformation between ribbons and single fibers in response to the addition of guest molecules is attributed to the intercalation of aromatic substrates within the rigid segments and subsequent loosening of the aromatic stacking interactions. These results demonstrate that the introduction of a laterally extended aromatic segment into an amphiphilic molecular architecture can lead to the hierarchical formation from elementary fibers of nanoribbons with a tunable twist through controlled lateral interactions between aromatic segments. [source] Oily calcium hydroxide suspension (Osteoinductal) used as an adjunct to guided bone regeneration: an experimental study in ratsCLINICAL ORAL IMPLANTS RESEARCH, Issue 6 2007Andreas Stavropoulos Abstract Objectives: To evaluate whether an oily calcium hydroxide suspension (OCHS) promotes bone healing when used as an adjunct to guided bone regeneration (GBR). Material and methods: Rigid, hemispherical, teflon capsules were placed with their open part facing the lateral surface of the ramus on both sides of the mandible in 10 adult Wistar rats. In each animal, one capsule was filled out with an OCHS (test) before placement, while the capsule on the other side was left empty (control). After 4 months of healing, the animals were sacrificed and histological sections containing the capsules and the neighboring soft and hard tissues were prepared. On three to four sections taken by uniformly random sampling from each specimen, the relative volumes of (1) the newly formed bone (mineralized bone and marrow), (2) the soft connective tissue, (3) the residual OCHS, and (4) the acellular (empty) space inside the capsule were estimated by a point-counting technique, and expressed as percentage of the space originally created by the capsule. Results: There was no new bone formation inside the capsules in all but one test specimen, where only a minimal amount of newly formed bone could be observed in continuation with the lateral surface of the ramus. OCHS had a homogenous appearance and occupied the major portion (79.4%) of the space created by the capsule. No signs of active resorption of the material could be observed. On the contrary, 31.5% of the space provided by the capsule was filled out with newly formed bone in the control group. The new bone had a trabecular appearance with large marrow spaces filled with hematopoietic and fatty marrow. The rest of the capsule space in the controls appeared empty. Conclusion: OCHS may hamper bone healing when used as an adjunct to GBR. [source] Fast and Scalable CPU/GPU Collision Detection for Rigid and Deformable SurfacesCOMPUTER GRAPHICS FORUM, Issue 5 2010Simon Pabst Abstract We present a new hybrid CPU/GPU collision detection technique for rigid and deformable objects based on spatial subdivision. Our approach efficiently exploits the massive computational capabilities of modern CPUs and GPUs commonly found in off-the-shelf computer systems. The algorithm is specifically tailored to be highly scalable on both the CPU and the GPU sides. We can compute discrete and continuous external and self-collisions of non-penetrating rigid and deformable objects consisting of many tens of thousands of triangles in a few milliseconds on a modern PC. Our approach is orders of magnitude faster than earlier CPU-based approaches and up to twice as fast as the most recent GPU-based techniques. [source] Cross-correlated and conventional dipolar carbon-13 relaxation in methylene groups in small, symmetric moleculesCONCEPTS IN MAGNETIC RESONANCE, Issue 2 2007Leila Ghalebani Abstract A theory for dipolar cross-correlated relaxation processes in AMX or AX2 spin system, with special reference to 13C-methylene groups, is reviewed briefly. Simple experiments and protocols for measuring the transfer rates between the carbon-13 Zeeman order and the three-spin order, and for their analogues in the transverse plane, are discussed using a concentrated solution of the disaccharide trehalose as a model system. Experimental data sets consisting of conventional carbon-13 relaxation parameters (T1, T2, and NOE), along with the cross-correlated relaxation rates, are also presented for some small, rigid, polycyclic molecules. These data are interpreted using spectral density functions appropriate to spherical or symmetric tops reorienting according to small-step rotational diffusion model. The analysis results in a consistent picture of the auto- and cross-correlated spin relaxation processes. © 2007 Wiley Periodicals, Inc. Concepts Magn Reson Part A 30A: 100,115, 2007. [source] Sensitivity of alveolar macrophages to substrate mechanical and adhesive propertiesCYTOSKELETON, Issue 6 2006Sophie Féréol Abstract In order to understand the sensitivity of alveolar macrophages (AMs) to substrate properties, we have developed a new model of macrophages cultured on substrates of increasing Young's modulus: (i) a monolayer of alveolar epithelial cells representing the supple (,0.1 kPa) physiological substrate, (ii) polyacrylamide gels with two concentrations of bis-acrylamide representing low and high intermediate stiffness (respectively 40 kPa and 160 kPa) and, (iii) a highly rigid surface of plastic or glass (respectively 3 MPa and 70 MPa), the two latter being or not functionalized with type I-collagen. The macrophage response was studied through their shape (characterized by 3D-reconstructions of F-actin structure) and their cytoskeletal stiffness (estimated by transient twisting of magnetic RGD-coated beads and corrected for actual bead immersion). Macrophage shape dramatically changed from rounded to flattened as substrate stiffness increased from soft ((i) and (ii)) to rigid (iii) substrates, indicating a net sensitivity of alveolar macrophages to substrate stiffness but without generating F-actin stress fibers. Macrophage stiffness was also increased by large substrate stiffness increase but this increase was not due to an increase in internal tension assessed by the negligible effect of a F-actin depolymerizing drug (cytochalasine D) on bead twisting. The mechanical sensitivity of AMs could be partly explained by an idealized numerical model describing how low cell height enhances the substrate-stiffness-dependence of the apparent (measured) AM stiffness. Altogether, these results suggest that macrophages are able to probe their physical environment but the mechanosensitive mechanism behind appears quite different from tissue cells, since it occurs at no significant cell-scale prestress, shape changes through minimal actin remodeling and finally an AMs stiffness not affected by the loss in F-actin integrity. Cell Motil. Cytoskeleton 2006. © 2006 Wiley-Liss, Inc. [source] Gadolinium, a mechano-sensitive channel blocker, inhibits osmosis-initiated motility of sea- and freshwater fish sperm, but does not affect human or ascidian sperm motilityCYTOSKELETON, Issue 4 2003Zoltán Krasznai Abstract Exposure to hypo-osmotic or hyperosmotic environment triggers the initiation of fish sperm motility. In this article, we report that calcium and potassium channel blockers do not influence motility of puffer fish sperm but calmodulin antagonists reversibly decrease it, suggesting that calmodulin,Ca2+ interactions are prerequisite for the initiation of sperm motility in this species. Gadolinium (a stretch activated ion channel blocker) decreased the motility of puffer fish sperm from 92 ± 3% to 6 ± 3% and that of carp sperm from 91 ± 7% to 3.5 ± 4.3% in a dose-dependent manner (10,40 ,M). The effect of gadolinium was reversible, suggesting that stretch activated ion channels participate in the initiation of sperm motility of the two species. Gadolinium inhibits changes in the isoelectric point of certain proteins of puffer fish sperm, which occur when sperm motility is initiated in a hypertonic solution. Anisotropy measurements showed that hypo-osmotic treatment, which initiates carp sperm motility, increased membrane fluidity. When hypo-osmotic treatment was given in the presence of gadolinium, the sperm membrane remained as rigid as in quiescent cells, while motility was blocked. By contrast, gadolinium did not influence the motility parameters of Ciona or human sperm. Based on these lines of evidence, we suggest that conformational changes of mechanosensitive membrane proteins are involved in osmolality-dependent but not osmolality-independent sperm. Cell Motil. Cytoskeleton 55:232,243, 2003. © 2003 Wiley-Liss, Inc. [source] An evidence-based appraisal of splinting luxated, avulsed and root-fractured teethDENTAL TRAUMATOLOGY, Issue 1 2008Bill Kahler For this systematic review of splinting of teeth that have been luxated, avulsed or root-fractured, the clinical PICO question is (P) what are splinting intervention decisions for luxated, avulsed and root-fractured teeth (I) considering that the splinting intervention choice may include (i) no splinting, (ii) rigid or functional splinting for the different types of trauma and (iii) different durations of the splinting period (C) when comparing these splinting choices for the different types of trauma and their effect on (O) healing outcomes for the teeth. A keyword search of PubMed was used. Reference lists from identified articles and dental traumatology texts were also appraised. The inclusion criterion for this review was either a multivariate analysis or controlled stratified analyses as many variables have the potential to confound the assessment and evaluation of healing outcomes for teeth that have been luxated, avulsed or root-fractured. A positive statistical test is not proof of a causal conclusion, as a positive statistical relationship can arise by chance, and so this review also appraises animal studies that reportedly explain biological mechanisms that relate to healing outcomes of splinted teeth. The clinical studies were ranked using the ,Centre of Evidence-based Medicine' categorization (levels 1,5). All 12 clinical studies selected were ranked as level 4. The studies generally indicate that the prognosis is determined by the type of injury rather than factors associated with splinting. The results indicate that the types of splint and the fixation period are generally not significant variables when related to healing outcomes. This appraisal identified difficulties in the design of animal experimentation to correctly simulate some dental injuries. Some of the studies employed rigid splinting techniques, which are not representative of current recommendations. Recommended splinting treatment protocols for teeth that have been luxated, avulsed or root-fractured teeth are formulated on the strength of research evidence. Despite the ranking of these studies in this appraisal as low levels of evidence, these recommendations should be considered ,best practice', a core philosophy of evidence-based dentistry. [source] Response analysis of rigid structures rocking on viscoelastic foundationEARTHQUAKE ENGINEERING AND STRUCTURAL DYNAMICS, Issue 7 2008Alessandro Palmeri Abstract In this paper the rocking response of slender/rigid structures stepping on a viscoelastic foundation is revisited. The study examines in depth the motion of the system with a non-linear analysis that complements the linear analysis presented in the past by other investigators. The non-linear formulation combines the fully non-linear equations of motion together with the impulse-momentum equations during impacts. The study shows that the response of the rocking block depends on the size, shape and slenderness of the block, the stiffness and damping of the foundation and the energy loss during impact. The effect of the stiffness and damping of the foundation system along with the influence of the coefficient of restitution during impact is presented in rocking spectra in which the peak values of the response are compared with those of the rigid block rocking on a monolithic base. Various trends of the response are identified. For instance, less slender and smaller blocks have a tendency to separate easier, whereas the smaller the angle of slenderness, the less sensitive the response to the flexibility, damping and coefficient of restitution of the foundation. Copyright © 2008 John Wiley & Sons, Ltd. [source] Influence of dynamic soil,structure interaction on the nonlinear response and seismic reliability of multistorey systemsEARTHQUAKE ENGINEERING AND STRUCTURAL DYNAMICS, Issue 3 2007Armando Bárcena Abstract A set of reinforced concrete structures with gravitational loads and mechanical properties (strength and stiffness) representative of systems designed for earthquake resistance in accordance with current criteria and methods is selected to study the influence of dynamic soil,structure interaction on seismic response, ductility demands and reliability levels. The buildings are considered located at soft soil sites in the Valley of Mexico and subjected to ground motion time histories simulated in accordance with characteristic parameters of the maximum probable earthquake likely to occur during the system's expected life. For the near-resonance condition the effects of soil,structure interaction on the ductility demands depend mainly on radiation damping. According to the geometry of the structures studied this damping is strongly correlated with the aspect ratio, obtained by dividing the building height by its width. In this way, for structures with aspect ratio greater than 1.4 the storey and global ductility demands increase with respect to those obtained with the same structures but on rigid base, while for structures with aspect ratio less than 1.4 the ductility demands decrease with respect to those for the structures on rigid base. For the cases when the fundamental period of the structure has values very different from the dominant ground period, soil,structure interaction leads in all cases to a reduction of the ductility demands, independently of the aspect ratio. The reliability index , is obtained as a function of the base shear ratio and of the seismic intensity acting on the nonlinear systems subjected to the simulated motions. The resulting reliability functions are very similar for systems on rigid or on flexible foundation, provided that in the latter case the base rotation and the lateral displacement are removed from the total response of the system. Copyright © 2006 John Wiley & Sons, Ltd. [source] Seismic interaction in electrical substation equipment connected by non-linear rigid bus conductorsEARTHQUAKE ENGINEERING AND STRUCTURAL DYNAMICS, Issue 2 2007Junho Song Abstract An important element within the power transmission lifeline is the electrical substation that typically consists of a complex set of equipment items interconnected through conductor buses or cables. If the connections are not sufficiently flexible, significant dynamic interaction may occur between the connected equipment items during a seismic event, which may result in damage and loss of the equipment. This paper investigates the interaction effect between electrical substation equipment items connected by non-linear rigid bus conductors. The equipment items are modelled as single-degree-of-freedom oscillators by use of appropriate shape functions. The hysteretic behaviours of rigid bus connectors are described by differential equation models fitted to experimental data. An efficient non-linear random vibration method is used to quantify the seismic interaction effect of the connected equipment items. Based on the developed analytical models and method, the effect of interaction in the connected equipment system is investigated through extensive parametric studies. The results lead to practical charts and guidelines for the seismic design of interconnected electrical substation equipment. Copyright © 2006 John Wiley & Sons, Ltd. [source] Asymmetric one-storey elastic systems with non-linear viscous and viscoelastic dampers: Earthquake responseEARTHQUAKE ENGINEERING AND STRUCTURAL DYNAMICS, Issue 4 2003Wen-Hsiung Lin Abstract Investigated are earthquake responses of one-way symmetric-plan, one-storey systems with non-linear fluid viscous dampers (FVDs) attached in series to a linear brace (i.e. Chevron or inverted V-shape braces).Thus, the non-linear damper is viscous when the brace is considered rigid or viscoelastic (VE) when the brace is flexible. The energy dissipation capacity of a non-linear FVD is characterized by an amplitude-dependent damping ratio for an energy-equivalent linear FVD, which is determined assuming the damper undergoes harmonic motion. Although this formulation is shown to be advantageous for single-degree-of-freedom (SDF) systems, it is difficult to extend its application to multi-degree-of-freedom (MDF) systems for two reasons: (1) the assumption that dampers undergo harmonic motion in parameterizing the non-linear damper is not valid for its earthquake-induced motion of an MDF system; and (2) ensuring simultaneous convergence of all unknown amplitudes of dampers is difficult in an iterative solution of the non-linear system. To date, these limitations have precluded the parametric study of the dynamics of MDF systems with non-linear viscous or VE dampers. However, they are overcome in this investigation using concepts of modal analysis because the system is weakly non-linear due to supplemental damping. It is found that structural response is only weakly affected by damper non-linearity and is increased by a small amount due to bracing flexibility. Thus, the effectiveness of supplemental damping in reducing structural responses and its dependence on the planwise distribution of non-linear VE dampers were found to be similar to that of linear FVDs documented elsewhere. As expected, non-linear viscous and VE dampers achieve essentially the same reduction in response but with much smaller damper force compared to linear dampers. Finally, the findings in this investigation indicate that the earthquake response of the asymmetric systems with non-linear viscous or VE dampers can be estimated with sufficient accuracy for design applications by analysing the same asymmetric systems with all non-linear dampers replaced by energy-equivalent linear viscous dampers. Copyright © 2003 John Wiley & Sons, Ltd. [source] A matching method using edges with the rigid body assumptionELECTRONICS & COMMUNICATIONS IN JAPAN, Issue 11 2009Shiho Tanaka Abstract In this paper, we propose the matching method using the edge image with the rigid-body assumption. We introduce the virtual intensity added to the edge image and regard it as the energy function. It is assumed that the objects to match each other are rigid. The edges are repeatedly moved to the direction which the energy function is reduced by parallel translation and rotation. The corresponding point between two images can be found when the function is minimum. Real images include the areas which have no or extreme intensity change. The proposed method is available in those cases since it uses features of the image, that is, the edges. We showed this advantage by experiments on motion estimation. © 2009 Wiley Periodicals, Inc. Electron Comm Jpn, 92(11): 28,33, 2009; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/ecj.10148 [source] Writing Fables: Genre and CreativityENGLISH IN EDUCATION, Issue 1 2002David Whitley Abstract This article explores the relationship between genre and creativity with particular reference to children's writing. It is argued that, although the programme may have been implemented too rigidly, a key emphasis on genre within the National Literacy Strategy is potentially positive. The fable is offered as a particular example, demonstrating that, although too rigid a conception of a genre's formal characteristics may inhibit children's creative engagement, an understanding in depth of the range of purposes to which a particular form may be put is helpful both in providing a good range of models and in responding sensitively to children's writing. [source] Long-Lived Luminescent Dendrimers with a [Ru(dpp)3]2+ -Type Core: Synthesis and Photophysical PropertiesEUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 18 2009Uwe Hahn Abstract Metallodendrimers built around a [Ru(dpp)3]2+ -type core (dpp = 4,7-diphenyl-1,10-phenanthroline) were prepared containing peripheral phenyl moieties. The convergent synthesis of the ligands was accomplished by coupling dendritic branches with a focal amino function to the chelating phenanthroline precursor under the formation of sulfonamide linkages. Complexation of ruthenium ions afforded the corresponding metallodendrimers with up to 24 peripheral phenyl units in the case of the largest dendritic structure. The absorption spectra and luminescence properties of the four new dendrimers are reported. The dendritic effect is clearly visible, going from zero to second generation, as demonstrated by an elongation in the excited-state lifetime in aerated acetonitrile and improved emission quantum yields relative to the reference complex containing a [Ru(dpp)3]2+ core. Interestingly, the use of rigid and conjugated ruthenium-based cores results, for all dendritic structures, in luminescence lifetimes that are several microseconds long in deaerated solutions, even at room temperature.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009) [source] Complexation and Dynamic Switching Properties of Fluorophore-Appended Resorcin[4]arene CavitandsEUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Issue 5 2010Laura D. Shirtcliff Abstract Fluorophore-appended resorcin[4]arene-based cavitands having pyrene (2) and anthracene (3) moieties attached to the rims were prepared by short synthetic routes. Both undergo reversible temperature- and acid- (CF3COOD) induced vase,,,kite switching as evidenced by 1H NMR spectroscopy. The 1H NMR spectra also suggest that suitably sized solvents, such as [D8]toluene, efficiently solvate the cavity, reducing the conformational flexibility. In [D12]mesitylene, both cavitands undergo remarkably stable host-guest inclusion complexation with cycloalkanes. The larger cavity of 3 preferentially hosts cyclohexane, whereas the smaller cavity of 2 forms the most stable complex with cyclopentane. The propensity for the cavitands to facilitate ,,, stacking between the chromophores was confirmed by both 1H NMR and fluorescence spectroscopy. The interchromophoric interaction is strongly solvent-dependent: ,,, stacking between the pyrene moieties of 2 is not as efficient in [D8]toluene, as it solvates the inner cavity and prevents the two chromophores from approaching each other. Fluorescence studies revealed an unexpectedly large conformational flexibility of the cavitand structures both in the vase and kite forms, which was further confirmed by molecular dynamics simulations. Excimer formation is most preferred in [D12]mesitylene when the cavities are empty, whereas efficient solvation or guest binding in the interior spaces reduces the propensity for excimer formation. The observed high conformational flexibility of the cavitands in solution explains previous differences from the behavior of related systems in the solid state. This study shows that the rigid, perfect vase and kite geometries found for bridged resorcin[4]arene cavitands in the solid state are largely a result of crystal packing effects and that the conformational flexibility of the structures in solution is rather high. [source] Proximate, "Parallel-In-Plane" Preoriented Bis(diazenes) , In-Plane Delocalized Bis(homoconjugated) 4N/5(6)e AnionsEUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Issue 21 2003Eberhard Beckmann Abstract Synthetic details are presented for a series of more or less rigid, "parallel-in-plane" preoriented bis(diazenes), with N=N/N=N distances (d) of 3.3,2.9 Å and interorbital angles (,) of 142,164° (X-ray crystal structures). DFT calculations (B3LYP/6,31G*) and one-/two-electron reduction experiments with the two least preoriented, most "distant" bis(diazenes) (dN=N/N=N ca. 3.3 Å; , 142,146°) provide more insight into the structural prerequisites for bis(homoconjugative) in-plane electron delocalization in 4N/5e radical anions and 4N/6e dianions. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003) [source] Civil Society and the Re-imagination of European ConstitutionalismEUROPEAN LAW JOURNAL, Issue 4 2003Michael A. Wilkinson Recognising this necessarily dynamic relationship, an essentialist reading of a constitutionalisation of the demos is abandoned, and an examination of the extent to which the dialectic can credibly or legitimately be played out in a supranational ,community' and in the context of an emerging transnational civil society can be undertaken. Rather than seeking credibility or legitimacy through the rationalisation of a community by an ethical consensus as in some forms of republicanism and communitarianism, the dialectic opens up the norms and boundaries of the polity and leads to an understanding of the ,community' in less rigid and more diffuse, even plural, terms. Once understood in this way the possibility emerges for legitimacy to be pursued through a public sphere enlarged by a context-transcending constitutional discourse mediated by transnational civil society. Alternatively the normative ,openness' of the polity might be prioritised and with it the uncertainty/fluidity of the constitutional arrangement itself; in this way the legitimate pursuit of constitutionalism is understood in terms of a never-ending agonistic struggle or experimental practice. [source] An Alternative Approach to Constructing Solution Processable Multifunctional Materials: Their Structure, Properties, and Application in High-Performance Organic Light-Emitting DiodesADVANCED FUNCTIONAL MATERIALS, Issue 18 2010Shanghui Ye Abstract A new series of full hydrocarbons, namely 4,4,-(9,9,-(1,3-phenylene)bis(9H -fluorene-9,9-diyl))bis(N,N -diphenylaniline) (DTPAFB), N,N,-(4,4,-(9,9,-(1,3-phenylene)bis(9H -fluorene-9,9-diyl))bis(4,1-phenylene))bis(N -phenylnaphthalen-1-amine) (DNPAFB), 1,3-bis(9-(4-(9H -carbazol-9-yl)phenyl)-9H -fluoren-9-yl)benzene, and 1,3-bis(9-(4-(3,6-di- tert -butyl-9H -carbazol-9-yl)phenyl)-9H -fluoren-9-yl)benzene, featuring a highly twisted tetrahedral conformation, are designed and synthesized. Organic light-emitting diodes (OLEDs) comprising DNPAFB and DTPAFB as hole transporting layers and tris(quinolin-8-yloxy)aluminum as an emitter are made either by vacuum deposition or by solution processing, and show much higher maximum efficiencies than the commonly used N,N,-di(naphthalen-1-yl)- N,N,-diphenylbiphenyl-4,4,-diamine device (3.6 cd A,1) of 7.0 cd A,1 and 6.9 cd A,1, respectively. In addition, the solution processed blue phosphorescent OLEDs employing the synthesized materials as hosts and iridium (III) bis[(4,6-di-fluorophenyl)-pyridinato-N, C2] picolinate (FIrpic) phosphor as an emitter present exciting results. For example, the DTPAFB device exhibits a brightness of 47 902 cd m,2, a maximum luminescent efficiency of 24.3 cd A,1, and a power efficiency of 13.0 lm W,1. These results show that the devices are among the best solution processable blue phosphorescent OLEDs based on small molecules. Moreover, a new approach to constructing solution processable small molecules is proposed based on rigid and bulky fluorene and carbazole moieties combined in a highly twisted configuration, resulting in excellent solubility as well as chemical miscibility, without the need to introduce any solubilizing group such as an alkyl or alkoxy chain. [source] Solid-State NMR Investigations of the Unusual Effects Resulting from the Nanoconfinement of Water within Amphiphilic Crosslinked Polymer NetworksADVANCED FUNCTIONAL MATERIALS, Issue 21 2009Ryutaro Ohashi Abstract Two types of solid-state 19F NMR spectroscopy experiments are used to characterize phase-separated hyperbranched fluoropolymer,poly(ethylene glycol) (HBFP,PEG) crosslinked networks. Mobile (soft) domains are detected in the HBFP phase by a rotor-synchronized Hahn echo under magic-angle spinning conditions, and rigid (hard) domains by a solid echo with no magic-angle spinning. The mobility of chains is detected in the PEG phase by 1H,,,13C cross-polarization transfers with 1H spin-lock filters with and without magic-angle spinning. The interface between HBFP and PEG phases is detected by a third experiment, which utilized a 19F,,,1H,(spin diffusion),1H,,,13C double transfer with 13C solid-echo detection. The results of these experiments show that composition-dependent PEG inclusions in the HBFP glass rigidify on hydration, consistent with an increase in macroscopic tensile strength. [source] ,Selbstgefühl, Todesschicksal', and the end of ,Parteidichtung': Herybert Menzel's Anders kehren wir wieder (1943)GERMAN LIFE AND LETTERS, Issue 4 2001Martin Travers The ,Parteidichtung' published in the Third Reich is commonly viewed as formally rigid and thematically trite political propaganda. Such a judgement accurately describes the work produced by poets such as Heinrich Anacker, Baldur von Schirach and Hans Baumann, a group of writers known as the ,Junge Mannschaft'. Theirs was a functional poetry, written to be narrated, sung, or chanted on private and public occasions, with the aim of mobilising readers and performers alike in the direction of the ,national revolution' and, later, in support for Germany's efforts in the Second World War. Viewed within this context, Herybert Menzel's volume of poetry, Anders kehren wir wieder (1943), is a remarkable achievement: written by one of the leading voices within the ,Junge Mannschaft', this is a book that speaks not of self-confident bravura and unshakeable faith in the mission of National Socialist Germany, but of personal loss, doubt, and of the travails and insecurities brought about by war, sentiments made even more effective by being framed in the near-Expressionist style used by the author. The very existence of Menzel's Anders kehren wir wieder seems to suggest that even within the genre of officially sanctioned National Socialist literature important idiosyncratic voices could be heard. [source] The uses and abuses of time: globalization and time arbitrage in India's outsourcing industriesGLOBAL NETWORKS, Issue 1 2009SHEHZAD NADEEM Abstract Globalization has undoubtedly altered our conceptions and experience of time. It has sped up the pace of life and some scholars even suggest that a new temporal order is supplanting ,natural' and pre-existing cycles and rhythms. Yet time is not dissolved in the global circuits of capital. Rather, globalization has brought about a complex mixture of temporal orientations; the workplaces of ,new economy', for example, are traversed by novel and retrograde modes of work pace, rhythm and time-discipline. In this article, I explore the temporal implications of the outsourcing of information technology-based service work to India. Drawing on fieldwork and interviews with workers, managers and executives in the Indian IT and Business Processing Outsourcing industries, I address the following questions: (1) How are corporations using time arbitrage to reap the full benefits of a globally dispersed labour pool? (2) What impacts are these temporal changes having on the health and social lives of Indian workers? For corporations, time arbitrage means increased efficiency and cost-savings. But for workers, it results in long hours, an intense work pace, and temporal displacement. Night-shift employees, such as call centre workers, are particularly vulnerable to such displacement, as manifested in health and safety problems and social alienation. Globalization therefore does not entail the loosening of temporal chains, but their reconfiguration: a combination both rigid and flexible that binds even as it liberates. [source] Highly Fluorinated Comb-Shaped Copolymers as Proton Exchange Membranes (PEMs): Improving PEM Properties Through Rational Design,ADVANCED FUNCTIONAL MATERIALS, Issue 14 2006B. Norsten Abstract A new class of comb-shaped polymers for use as a proton conducting membrane is presented. The polymer is designed to combine the beneficial physical, chemical, and structural attributes of fluorinated Nafion-like materials with higher-temperature, polyaromatic-based polymer backbones. The comb-shaped polymer unites a rigid, polyaromatic, hydrophobic backbone with lengthy hydrophilic polymer side chains; this combination affords direct control over the polymer nanostructure within the membrane and results in distinct microphase separation between the opposing domains. The microphase separation serves to compartmentalize water into the hydrophilic polymer side chain domains, resulting in effective membrane water management and excellent proton conductivities. [source] Exploiting Chemical Switching in a Diels,Alder Polymer for Nanoscale Probe Lithography and Data Storage,ADVANCED FUNCTIONAL MATERIALS, Issue 11 2006B. Gotsmann Abstract Reversibly crosslinked polymer films have properties that are beneficial to scanned-probe data storage and lithographic applications that use thermomechanical nanoindentation as a write or expose mechanism. The novel polymer under study contains linkages based on thermally reversible Diels,Alder crosslinking. Thermomechanical properties on the nanometer scale are analyzed by indentation experiments on polymer thin films using heated tips. The underlying indentation mechanism is studied at varying tip temperatures and indentation times, revealing Arrhenius kinetics. This is in contrast to the Williams,Landau,Ferry kinetics usually observed for polymer systems. The discrepancy is explained by the reversible crosslinking incorporated into the structure of the polymer that allows switching between two different states: a rigid, highly crosslinked, low-temperature state, and a deformable, fragmented, high-temperature state. An individual indentation volume of less than 10,20,L (10,000,molecule pairs) is estimated. These kinetics experiments demonstrate that a chemical reaction of only a few thousand molecules can be transduced into a mechanically measurable action. The ability to cycle between two sets of properties in these materials opens up new perspectives in lithography and data storage. Examples of data storage with densities up to 1,Tb,in.,2 and maskless lithography with resolution below 20,nm are demonstrated at writing times of 10,,s per bit/pixel. [source] | ||||||||||||||||||||||||||||||||||||||||||||||||||||