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Removal Mechanisms (removal + mechanism)

Distribution by Scientific Domains

Life Sciences	41%
Chemistry	25%
Polymers and Materials Science	16%

Selected Abstracts

UNSTEADY STATE DISPERSION OF AIR POLLUTANTS UNDER THE EFFECTS OF DELAYED AND NONDELAYED REMOVAL MECHANISMS

NATURAL RESOURCE MODELING, Issue 4 2009
MANJU AGARWAL
Abstract In this paper, we present a two-dimensional time-dependent mathematical model for studying the unsteady state dispersion of air pollutants emitted from an elevated line source in the atmosphere under the simultaneous effects of delayed (slow) and nondelayed (instantaneous) removal mechanisms. The wind speed and coefficient of diffusion are taken as functions of the vertical height above the ground. The deposition of pollutants on the absorptive ground and leakage into the atmosphere at the inversion layer are also included in the model by applying appropriate boundary conditions. The model is solved numerically by the fractional step method. The Lagrangian approach is used to solve the advection part, whereas the Eulerian finite difference scheme is applied to solve the part with the diffusion and removal processes. The solutions are analyzed to observe the effects of coexisting delayed and nondelayed removal mechanisms on overall dispersion. Comparison of delayed and nondelayed removal processes of equal capacity shows that the latter (nondelayed) process is more effective than the former (delayed removal) in the removal of pollutants from the atmosphere. [source]

Fate and effects of triclosan in activated sludge

ENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 7 2002
Thomas W. Federle
Abstract Triclosan (TCS; 5-chloro-2-[2,4-dichloro-phenoxy]-phenol) is a widely used antimicrobial agent. To understand its fate during sewage treatment, the biodegradation and removal of TCS were determined in activated sludge. In addition, the effects of TCS on treatment processes were assessed. Fate was determined by examining the biodegradation and removal of TCS radiolabeled with 14C in the 2,4-dichlorphenoxy ring in laboratory batch mineralization experiments and bench-top continuous activated-sludge (CAS) systems. In batch experiments with unacclimated sludge, TCS was mineralized to 14CO2, but the total yield varied as a function of test concentration. Systems that were redosed with TCS exhibited more extensive and faster mineralization, indicating that adaptation was a critical factor determining the rate and extent of biodegradation. In a CAS study in which the influent level of TCS was incrementally increased from 40 ,g/L to 2,000 ,g/L, removal of the parent compound exceeded 98.5% and removal of total radioactivity (parent and metabolites) exceeded 85%. Between 1.5 and 4.5% of TCS in the influent was sorbed to the wasted solids, whereas >94% underwent primary biodegradation and 81 to 92% was mineralized to CO2 or incorporated in biomass. Increasing levels of TCS in the influent had no major adverse effects on any wastewater treatment process, including chemical oxygen demand, biological oxygen demand, and ammonia removal. In a subsequent experiment, a CAS system, acclimated to TCS at 35 ,g/L, received two separate 4-h shock loads of 750 ,g/L TCS. Neither removal of TCS nor treatment processes exhibited major adverse effects. An additional CAS study was conducted to examine the removal of a low level (10 ,g/L) of TCS. Removal of parent equaled 94.7%, and biodegradation remained the dominant removal mechanism. A subsequent series of CAS experiments examined removal at four influent concentrations (7.5, 11, 20, and 50 ,g/L) of TCS and demonstrated that removal of parent ranged from 98.2 to 99.3% and was independent of concentration. Although TCS removal across all experiments appeared unrelated to influent concentration, removal was significantly correlated (r2 = 0.87) with chemical oxygen demand removal, indicating that TCS removal was related to overall treatment efficiency of specific CAS units. In conclusion, the experiments show that TCS is extensively biodegraded and removed in activated-sludge systems and is unlikely to upset sewage treatment processes at levels expected in household and manufacturing wastewaters. [source]

Preparation and characterization of UV-grafted ion-exchange textiles in continuous electrodeionization

JOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 12 2004
Kyeong-Ho Yeon
Abstract Ion-exchange textiles (IETs) suitable for use in continuous electrodeionization (CEDI) stacks were prepared using the ultraviolet (UV)-induced grafting of acrylic acid and sodium styrene sulfonate for cation-exchange textiles, or 2-hydroxyethyl methacrylate and vinylbenzyl trimethyl ammonium chloride for anion-exchange textiles, onto nonwoven polypropylene fabric using benzophenone as photoinitiator. Although the ion-exchange capacity (2.2 meq g,1) of the prepared strong acid cation-exchange textile was lower than that of IRN77 strong acid cation-exchange resin (4.2 meq g,1), the overall rate constant of IET was very high due to its low crosslinking and high specific surface area. There was no significant difference between the two different media in terms of the Co(II) removal rate. Furthermore, the current efficiency for IETs was higher than that of IRN77 cation-exchange resin during a CEDI operation, with efficiencies of 60% and 20%, respectively. The IET also showed the faster exchange kinetics. Therefore, IETs prepared in this study proved to have desirable ion-conducting characteristics within the CEDI systems. Also this study revealed that the primary removal mechanism in CEDI is the transport of ions through a medium and not the ionic capacity of a medium. Copyright © 2004 Society of Chemical Industry [source]

Stress-Corrosion Cracking of Silicon Carbide Fiber/Silicon Carbide Composites

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 8 2000
Russell H. Jones
Ceramic-matrix composites are being developed to operate at elevated temperatures and in oxidizing environments. Considerable improvements have been made in the creep resistance of SiC fibers and, hence, in the high-temperature properties of SiC fiber/SiC (SiCf/SiC) composites; however, more must be known about the stability of these materials in oxidizing environments before they are widely accepted. Experimental weight change and crack growth data support the conclusion that the oxygen-enhanced crack growth of SiCf/SiC occurs by more than one mechanism, depending on the experimental conditions. These data suggest an oxidation embrittlement mechanism (OEM) at temperatures <1373 K and high oxygen pressures and an interphase removal mechanism (IRM) at temperatures of ,700 K and low oxygen pressures. The OEM results from the reaction of oxygen with SiC to form a glass layer on the fiber or within the fiber,matrix interphase region. The fracture stress of the fiber is decreased if this layer is thicker than a critical value (d > dc) and the temperature below a critical value (T < Tg), such that a sharp crack can be sustained in the layer. The IRM results from the oxidation of the interfacial layer and the resulting decrease of stress that is carried by the bridging fibers. Interphase removal contributes to subcritical crack growth by decreasing the fiber-bridging stresses and, hence, increasing the crack-tip stress. The IRM occurs over a wide range of temperatures for d < dc and may occur at T > Tg for d > dc. This paper summarizes the evidence for the existence of these two mechanisms and attempts to define the conditions for their operation. [source]

H i content in galaxies in loose groups

MONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, Issue 1 2006
Chandreyee Sengupta
ABSTRACT Gas deficiency in cluster spirals is well known and ram-pressure stripping is considered the main gas removal mechanism. In some compact groups too gas deficiency is reported. However, gas deficiency in loose groups is not yet well established. Lower dispersion of the member velocities and the lower density of the intragroup medium in small loose groups favour tidal stripping as the main gas removal process in them. Recent releases of data from the H i Parkes All-Sky Survey (HIPASS) and catalogues of nearby loose groups with associated diffuse X-ray emission have allowed us to test this notion. In this paper, we address the following questions: (i) do galaxies in groups with diffuse X-ray emission statistically have lower gas content compared to the ones in groups without diffuse X-ray emission? (ii) does H i deficiency vary with the X-ray luminosity, LX, of the loose group in a systematic way? We find that (i) galaxies in groups with diffuse X-ray emission, on average, are H i deficient, and have lost more gas compared to those in groups without X-ray emission; the latter are found not to have significant H i deficiency; (ii) no systematic dependence of the H i deficiency with LX is found. Ram-pressure-assisted tidal stripping and evaporation by thermal conduction are the two possible mechanisms to account for this excess gas loss. [source]

Speciation and Environmental Fate of Chromium in Rivers Contaminated with Tannery Effluents

ENGINEERING IN LIFE SCIENCES (ELECTRONIC), Issue 2 2007
J. Dominik
Abstract Redox and size speciation of chromium in rivers contaminated with tannery wastewater was carried out to provide insight into its transport and removal mechanisms. Total chromium was determined with Inductively Coupled Plasma-Mass Spectrometry and Cr,(VI) with Catalytic Adsorption Stripping Voltammetry. For the size speciation, particles were retained with a cartridge filter (cut-off 1.2,,m) and the total filterable fraction was further fractionated with Tangential Flow Filtration to determine the concentrations of chromium associated with the High Molecular Weight Colloidal (HMWC), Low Molecular Weight Colloidal (LMWC) and Truly Dissolved (TD) fractions. Two fluvial systems of similar sizes, but located in contrasting climatic zones, were selected for comparison: the Sebou-Fez system in Morocco and Dunajec River-Czorsztyn Reservoir system in Poland. Particulate Cr dominated in the Sebou-Fez system (about 90,%); while in the Dunajec-Czorsztyn system, it represented only 17,53,% of the total chromium in raw water. Still, the partition coefficients [Kd] were of the same magnitude. Chromium,(III) was the only form detected in Sebou-Fez, whereas in Dunajec-Czorsztyn Cr,(VI) was also present with its proportion increasing downstream from the input of tannery wastewater due to the preferential removal of Cr,(III). In the filtered water in Morocco a large fraction of Cr occurred in the HMWC fraction (50,70,%) at the two most contaminated sites, while the LMWC and TD forms prevailed at the non-contaminated sites in the Sebou River. At a very high concentration, in the water in the proximity of tanneries (well above the theoretical saturation level) Cr precipitated as polynuclear Cr-hydroxide. In Dunajec-Czorsztyn, the partition of Cr,(III) was approximately equal between the HMWC, LMWC and TD fractions, in contrast to Cr,(VI) which occurred almost exclusively in the TD fraction. In both systems, Cr,(III) was rapidly removed from the water to the sediments. The confluence of the Sebou with the Fez and the Czorsztyn reservoir trapped efficiently Cr,(III) preventing its spreading over long distances. Cr,(VI) showed conservative behavior and bypassed the Czorsztyn Reservoir. This study provides a first set of data on the partitioning of Cr,(III) and Cr,(VI) between the particulate, the colloidal and truly dissolved fractions in fluvial systems contaminated with tannery effluents. It also suggests that, in these systems, truly dissolved Cr,(III) can be adequately modeled from the total filterable concentrations. [source]

Investigation of an onsite wastewater treatment system in sandy soil: Site characterization and fate of anionic and nonionic surfactants

ENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 12 2002
Allen M. Nielsen
Abstract This study reports on the fate of linear alkylbenzene sulfonate (LAS), alcohol ethoxylate (AE), and alcohol ether sulfate (AES) surfactants in a home septic system near Jacksonville (FL, USA) that has been used since 1976. The drainfield at this site resides in fine sand (<6% silt and clay) with an unsaturated zone that ranges from 0 to 1.3 m. During the wettest times of the year, it is likely that effluent from the septic system passes directly into the groundwater without exposure to an unsaturated zone of soil. Groundwater was collected during two sampling events, representing seasonal high and low groundwater table levels, and analyzed for the surfactants LAS, AES, and AE. During the wet season, the unsaturated zone was approximately 0.01 m beneath the drainfield. During the dry season, the unsaturated zone was about 0.4 m below the drainfield. Alcohol ethoxylate was not detected in any groundwater samples during either sampling. Alcohol ether sulfate was not found in the dry season sampling, but traces of AES had migrated downgradient about 4.7 m horizontally and 1.8 m vertically in the wet season. Linear alkylbenzene sulfonate was detected in some dry season samples and had moved downgradient some 11.7 m horizontally and 3.7 m vertically in the wet season. These observations demonstrate that these surfactants were removed to a great extent; otherwise, they would have traveled more than 260 m downgradient, which is the calculated distance that a conservative tracer like bromide would have moved downgradient over the life of the system. The most likely removal mechanisms for these surfactants were biodegradation and sorption. Therefore, this study indicates that LAS, AE, and AES are readily removed from groundwater in soils below septic system drainfields even in situations with minimal unsaturated soil zones. [source]

Visualising Liquid Water in PEM Fuel Cells Using Neutron Imaging,

FUEL CELLS, Issue 5 2009
R. Mukundan
Abstract In this article, we review the neutron imaging techniques that have been used to visualise liquid water in PEM fuel cells. A list of the various facilities engaged in this research is provided and the published literature in this field reviewed. Neutron imaging has been successfully used to visualise water dynamics in the flow channels of operating fuel cells. This technique has also been used to understand water removal mechanisms and the importance of membrane hydration and GDL flooding to optimal fuel cell performance. More recently this technique has been applied to imaging the water in fuel cell cross-sections in order to quantify the water contents in the different components of an operating fuel cell. Finally, this technique has also been utilised to examine ice formation during sub-zero operation of single fuel cells. With ongoing improvements in spatial and temporal resolution, neutron imaging can be expected to play a greater role in any fuel cell development related to water transport. [source]

Evaluation of the environmental implications to include structural changes in a wastewater treatment plant

JOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 11 2002
Núria Vidal
Abstract The environmental implications of including structural changes in a wastewater treatment plant to decrease effluent concentrations of nitrogen were evaluated in this study. Environmental effects from these structural changes were assessed by using the Life Cycle Assessment theoretical framework. The wastewater treatment plant selected as a reference scenario had an activated sludge configuration. The Ludzack,Ettinger and Oxidation Ditch configurations were selected as modifications of the reference scenario. Results from this study show that the inclusion of nitrogen removal mechanisms in the configuration of the plant reduces the effect of the plant on the eutrophication, but simultaneously increases the effect on the consumption of abiotic resources, global warming, acidification and human toxicity. These general trends, however, vary depending on the configuration selected to remove nitrogen. Taking all the impacts together, the Oxidation Ditch configuration would cause less environmental impact than the Ludzack,Ettinger configuration, given the characteristics of the selected scenarios. © 2002 Society of Chemical Industry [source]

Effect of mating surface on the high temperature wear of 253 MA alloy

MATERIALS AND CORROSION/WERKSTOFFE UND KORROSION, Issue 4 2004
M. Roy
Abstract The wear behaviour of metallic material is influenced by the friction force, which in turn, is governed by the hardness and oxidation kinetics of the mating surface. In view of this, present investigation is undertaken to find the influence of mating surface on the high temperature wear of 253 MA alloy. This alloy is developed for high temperature application. In this work 253 MA alloy is made to slide against two different types of counter face material, namely 100Cr6 steel and PM 1000 alloy, at five different temperatures. 100Cr6 steel gets soften with increase of temperature whereas PM 1000 alloy retains its strength even at high temperature. The friction coefficient and the thickness loss of 253 MA alloy is measured and compared against both variety of mating surfaces as function of temperatures. The morphology of the worn surfaces and the transverse section of the worn surfaces are examined under scanning electron microscope (SEM) to identify the material removal mechanisms. The results showed that the friction coefficient of test material against PM 1000 alloy is around 40% higher than the friction coefficient against 100Cr6 steel. The transverse section of the worn surface showed presence of a transfer layer, mechanically mixed layer and composite layer, which govern the wear behaviour particularly at elevated temperature. The chemical characteristics of these layers are dependent on the test temperature and the counter face material. [source]

UNSTEADY STATE DISPERSION OF AIR POLLUTANTS UNDER THE EFFECTS OF DELAYED AND NONDELAYED REMOVAL MECHANISMS

Performing contaminant mass balances for remedy assessments

REMEDIATION, Issue 2 2009
James T. Gibbs
Contaminant mass-balance assessments are useful tools to help quantify various mass transport and removal mechanisms that may be active in a remedial system setting. This article presents the basics of performing a mass balance and illustrates the utility of using the information derived to support project management decisions. It is important to understand the partitioning of contaminant mass into various environmental media and physical forms, as well as the relationships among the partitions. Contaminant partitioning tends toward an equilibrium state, so natural or engineered mass transfer into or out of one partition will affect the others. Mass balances are exercises that quantify, to the extent possible, the contaminant mass in the various environmental partitions and the transfer and transformation processes that affect contaminant distribution. Understanding mass partitioning and transfer mechanisms helps remediation practitioners to engineer and optimize those mechanisms that contribute to risk reduction at a contaminated site. Such knowledge can inform risk managers when natural mechanisms may dominate engineered approaches and help identify uncertainties in contaminant fate and transport. © 2009 Wiley Periodicals, Inc. [source]