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Relaxation Strength (relaxation + strength)

Distribution by Scientific Domains

Polymers and Materials Science	83%

Selected Abstracts

Local dynamics in epoxy coatings containing iron oxide nanoparticles by dielectric relaxation spectroscopy

JOURNAL OF APPLIED POLYMER SCIENCE, Issue 5 2008
G. Kortaberria
Abstract Nanocomposites of photocurable epoxy resin and epoxy-modified iron oxide magnetic nanoparticles were analyzed by dielectric relaxation spectroscopy to study the local dynamics at temperatures well below the glass-transition temperature. Two secondary processes were detected, , and , processes, but the second one was just detected at lower temperatures in the high-frequency part of the spectra and moved out of the frequency range at higher temperatures. Data were fitted to the Havriliak,Negami and Arrhenius models, and the obtained parameters were analyzed. Relaxation times of the , secondary relaxation did not change with the nanoparticle content, but the relaxation strength increased. The increase could not be explained when we took into account the molecular origin of the relaxation. The presence of ferromagnetic nanoparticles enhanced the internal field and increased the relaxation strengths. Transmission electron microscopy images showed that the nanoparticles were well dispersed in the matrix, without magnetic agglomerates. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci 2008 [source]

Influence of the cross-linking density on the main dielectric relaxation of poly(methyl acrylate) networks

POLYMER ENGINEERING & SCIENCE, Issue 10 2005
J.M. Meseguer Dueñas
A series of polymer networks of varying cross-linking density was prepared by copolymerization of methyl acrylate and ethyleneglycol dimethacrylate. The aim of this work is to study the influence of cross-linking on the conformational mobility of the polymer chains using dielectric relaxation spectroscopy (DRS) in the temperature range of the main dielectric relaxation. As expected, the temperature range in which glass transition takes place became wider with increasing crosslinking density. DRS results were analyzed using the Havriliak-Negami equation. Master Cole-Cole arcs could be drawn for all the networks. The arcs become more symmetric as cross-linking density increases, as a consequence of the different effect of cross-links on large and small scale mobility. The conformational mobility that produces the main relaxation is drastically reduced when the cross-linking density increases what reduces the relaxation strength, but it also gives a qualitative change of behavior, as shown by the temperature dependence of the relaxation strength. In the loosely cross-linked networks the relaxation strength decreases monotonously as temperature increases, as in the main dielectric relaxation of linear polymers. Nevertheless, in highly cross-linked networks the curve of relaxation strength against temperature presents a maximum. POLYM. ENG. SCI., 45:1336,1342, 2005. © 2005 Society of Plastics Engineers [source]

Morphology and mechanical properties of blends of polycarbonate and segmented copolyetherester

POLYMER ENGINEERING & SCIENCE, Issue 2 2000
M. Gaztelumendi
The solid state features and the mechanical properties of melt mixed polycarbonate (PC)/segmented copolyetherester (CPEE) blends were investigated over the full composition range. The partially crystallized blends were composed of two amorphous phases but with only small composition differences in most blend compositions. The specific interactions, and the free volume decreases observed, gave rise to a decrease in the , relaxation strength. The dependence on composition of both the decreases in the , relaxation strength and in the free volume, as well as that of the modulus of elasticity and yield stress, were very similar to those of miscible blends. The nature of the amorphous phases of the blends at room temperature, changed from glassy to partially rubbery as the CPEE content was increased. As a consequence, to discuss the plots of the properties against composition at room temperature, the properties of the rubbery materials in the glassy state had to be determined. The synergistic modulus and yield stress behaviors appeared to be mainly determined by the , relaxation strength and specific volume decrease, and that of ductility additionally by the Tg change. [source]

The effect of crystallinity and water absorption on the dynamic mechanical relaxation behaviour of polycaprolactone

POLYMER INTERNATIONAL, Issue 9 2004
Kate L Harrison
Abstract The effect of the degree of crystallinity on the dynamic mechanical relaxation behaviour (flexural storage modulus and loss tangent) of polycaprolactone has been investigated. The degree of crystallinity was found to determine the temperature of the ,-relaxation process and the relaxation strength of the ,-relaxation. The increase in temperature of the ,-process has been ascribed to constrainment of the amorphous regions of the sample by the crystallites. In accordance with the observed effect of the degree of crystallinity, the origin of the dynamic mechanical ,-relaxation has been ascribed to the amorphous regions of the material. The intensity of the ,-process has also been found to depend on the moisture content, becoming more prominent when moisture is present. In addition, moisture has been shown to penetrate the crystalline regions of the sample over a relatively short timescale, as shown by infrared spectroscopy. Copyright © 2004 Society of Chemical Industry [source]

Analytical approach for the toroidal relaxation of viscoelastic earth

GEOPHYSICAL JOURNAL INTERNATIONAL, Issue 1 2006
Hansheng Wang
SUMMARY This paper is concerned with post-seismic toroidal deformation in a spherically symmetric, non-rotating, linear-viscoelastic, isotropic Maxwell earth model. Analytical expressions for characteristic relaxation times and relaxation strengths are found for viscoelastic toroidal deformation, associated with surface tangential stress, when there are two to five layers between the core,mantle boundary and Earth's surface. The multilayered models can include lithosphere, asthenosphere, upper and lower mantles and even low-viscosity ductile layer in the lithosphere. The analytical approach is self-consistent in that the Heaviside isostatic solution agrees with fluid limit. The analytical solution can be used for high-precision simulation of the toroidal relaxation in five-layer earths and the results can also be considered as a benchmark for numerical methods. Analytical solution gives only stable decaying modes,unstable mode, conjugate complex mode and modes of relevant poles with orders larger than 1, are all excluded, and the total number of modes is found to be just the number of viscoelastic layers between the core,mantle boundary and Earth's surface,however, any elastic layer between two viscoelastic layers is also counted. This confirms previous finding where numerical method (i.e. propagator matrix method) is used. We have studied the relaxation times of a lot of models and found the propagator matrix method to agree very well with those from analytical results. In addition, the asthenosphere and lithospheric ductile layer are found to have large effects on the amplitude of post-seismic deformation. This also confirms the findings of previous works. [source]