Regular Array (regular + array)

Distribution by Scientific Domains


Selected Abstracts


Widening the Voltammetric Window Using Regular Arrays of Microdisk Electrodes

ELECTROANALYSIS, Issue 16 2007
Francois
Abstract This work explores, through mathematical modeling and numerical simulation, the use of regular arrays of microdisk electrodes wired in parallel as a means to increase the width of the electrochemical window in which one can carry out electrochemical experiments. [source]


Regular Arrays of Microdisk Electrodes: Numerical Simulation as an Optimizing Tool to Maximize the Current Response and Minimize the Electrode Area Used

ELECTROANALYSIS, Issue 23 2006
Francois
Abstract Microdisk electrode arrays constitute an interesting tool for electroanalysis and electrocatalysis due to their increased sensitivity and excellent limits of detection. We first demonstrate that a 2-dimensional simulation based on the diffusion domain approximation can be used to simulate the response of such electrochemical systems and therefore improve their design and fabrication process. Second, we report data showing the peak current response for arrays at three typically employed voltage scan rate as a function of the number of disks per unit area and their radii. [source]


Plasmonic modes of gold nano-particle arrays on thin gold films

PHYSICA STATUS SOLIDI - RAPID RESEARCH LETTERS, Issue 10 2010
A. Hohenau
Abstract Regular arrays of metal nanoparticles on metal films have tuneable optical resonances that can be applied for surface enhanced Raman scattering or biosensing. With the aim of developing more surface selective geometries we investigate regular gold nanoparticle arrays on 25 nm thick gold films, which allow to excite asymmetric surface plasmon modes featuring a much better field confinement compared to the symmetric modes used in conventional surface plasmon resonance setups. By optical extinction spectroscopy we identify the plasmonic modes sustained by our structures. Furthermore, the role of thermal treatment of the metal structures is investigated, revealing the role of modifications in the crystalline structure of gold on the optical properties. (© 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


Nanocarving of Titania as a Diffusion-Driven Morphological Instability,

ADVANCED FUNCTIONAL MATERIALS, Issue 3 2008
Doh-Kwon Lee
Abstract Under strongly reducing conditions at high temperatures titania develops a specific surface morphology, comprising a regular array of fibers with a diameter in the sub-micrometer range. By a chemical diffusion experiment in a defined oxygen potential gradient it is shown that this surface structuring is caused by a diffusion-driven morphological instability of an advancing reaction front (surface). The kinetics of the process is analyzed in terms of linear transport equations. The conditions for the occurrence of the surface instability are discussed and the required materials properties are analyzed. The observed surface structuring is not restricted to titania, rather it has to occur in all nonstoichiometric compounds with predominant cation mobility. [source]


Evidence for Band-Like Transport in Graphene-Based Organic Monolayers

ADVANCED MATERIALS, Issue 3 2010
Daniel Käfer
Evidence for a band-like, lateral transport of electrons through the cores of HBC-thiolates, forming a highly ordered self-assembled monolayer (SAM) containing a very regular array of HBC-cores, is provided based on a detailed analysis of temperature-dependent scanning tunneling microscopy (STM) data recorded for islands of aromatic SAMs immersed in an insulating matrix. [source]


Multiscale approach to geo-composite cellular structures subjected to rock impacts

INTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS, Issue 13 2007
François Nicot
Abstract Geo-composite cellular structures are an efficient technological solution for various applications in civil engineering. This type of structure is particularly well adapted to resisting rockfalls and can act as a defensive structure. However, the design of such structures is for the most part empirically based; this lack of research-based design stagnates optimization and advanced development. In this paper, the mechanical behaviour of a geo-composite cellular structure is investigated using a multi-scale approach, from the individual cell made up of an assembly of rocky particles contained in a wire netting cage to the entire structure composed of a regular array of cells. Based on discrete modelling of both the cell and structure scales, a computational tool has been developed for design purposes. Copyright © 2007 John Wiley & Sons, Ltd. [source]


Effect of Cloud Cover on UVB Exposure Under Tree Canopies: Will Climate Change Affect UVB Exposure?

PHOTOCHEMISTRY & PHOTOBIOLOGY, Issue 2 2006
Richard H. Grant
ABSTRACT The effect of cloud cover on the amount of solar UV radiation that reaches pedestrians under tree cover was evaluated with a three-dimensional canopy radiation transport model. The spatial distribution of UVB irradiance at the base of a regular array of spherical tree crowns was modeled under the full range of sky conditions. The spatial mean relative irradiance (I), and erythemal irradiance of the entire below-canopy domain and the spatial mean relative irradiance and erythemal irradiance in the shaded regions of the domain were determined for solar zenith angles from 15° to 60°. The erythemal UV irradiance under skies with 50% or less cloud cover was not remarkably different from that under clear skies. In the shade, the actual irradiance was greater under partly cloudy than under clear skies. The mean ultraviolet protection factor for tree canopies under skies with 50% or less cloud cover was nearly equivalent to that for clear sky days. Regression equations of spatially averaged Ir. as a function of cloud cover fraction, solar zenith angle and canopy cover were used to predict the variation in erythemal irradiance in different land uses across Baltimore, MD. [source]


Widening the Voltammetric Window Using Regular Arrays of Microdisk Electrodes

ELECTROANALYSIS, Issue 16 2007
Francois
Abstract This work explores, through mathematical modeling and numerical simulation, the use of regular arrays of microdisk electrodes wired in parallel as a means to increase the width of the electrochemical window in which one can carry out electrochemical experiments. [source]


Thin absorbing structure for all incidence angles based on the use of a high-impedance surface

MICROWAVE AND OPTICAL TECHNOLOGY LETTERS, Issue 3 2003
S. A. Tretyakov
Abstract It is shown that thin mushroom layers (high-impedance surfaces realized as regular arrays of small patches at a small distance from a metal surface) can be used as radar-absorbing structures whose performance does not change with the incidence angle for TM-polarized waves. The key role of the vias connectors between the patches and the ground plane is explained, and potential performance demonstrated in examples. © 2003 Wiley Periodicals, Inc. Microwave Opt Technol Lett 38: 175,178, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/mop.11006 [source]


Diffractive imaging for periodic samples: retrieving one-dimensional concentration profiles across microfluidic channels

ACTA CRYSTALLOGRAPHICA SECTION A, Issue 4 2007
Oliver Bunk
A technique has been developed that allows determination of the concentration profiles of colloidal solutions or any kind of fluid under confinement. Currently, submicrometre-wide channels are sampled with a resolution in the 10,nm range. The method comprises regular arrays of microfluidic channels and one-dimensional X-ray phase-retrieval techniques for the analysis of small-angle X-ray diffraction from the array structures. Recording the X-ray diffraction data requires a low dose on each individual channel since the sum of the signals from all channels is detected. The determined concentration profiles represent the ensemble average rather than individual entities and are obtained in a model-independent way. As an example, amplitude and phase of the exit field and concentration profiles for a colloidal fluid within confining channels of different widths are shown. [source]