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Qualitative Trends (qualitative + trend)
Selected AbstractsNumerical investigation of gas mixing in gas-solid fluidized bedsAICHE JOURNAL, Issue 9 2010Tingwen Li Abstract Gas mixing in a tall narrow fluidized bed operated in the slugging fluidization regime is simulated with the aid of computational fluid dynamics. In the first part, a parametric study is conducted to investigate the influence of various parameters on the gas mixing. Among the parameters studied, the specularity coefficient for the partial-slip solid-phase wall boundary condition had the most significant effect on gas mixing. It was found that the solid-phase wall boundary condition needs to be specified with great care when gas mixing is modeled, with free slip, partial slip and no-slip wall boundary conditions giving substantial differences in the extent of gas back mixing. Axial and radial tracer concentration profiles for different operating conditions are generally in good agreement with experimental data from the literature. Detailed analyses of tracer back mixing are carried out in the second part. Two parameters, the tracer backflow fraction and overall gas backflow fraction, in addition to axial profiles of cross-sectional averaged tracer concentrations, are evaluated for different flow conditions. Qualitative trends are consistent with reported experimental findings. © 2010 American Institute of Chemical Engineers AIChE J, 2010 [source] Vapor phase transport of unexploded ordnance compounds through soilsENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 10 2002Raghunathan Ravikrishna Abstract Unexploded ordnance(UXO) is a source of concern at several U.S. Department of Defense(DOD) sites. Localization of munitions and fate and transport of the explosive compounds from these munitions are a major issue of concern. A set of laboratory experiments were conducted in specially designed flux chambers to measure the evaporative flux of three explosive compounds (2,4-dinitrotoluene, 2,6-dinitrotoluene, and 1,3-dinitrobenzene) from three different soils. The effect of different soil moisture contents, the relative humidity of air contacting the soil surface, and soil temperature on the chemical fluxes were evaluated. A diffusion model was used to describe the chemical transport mechanism in the soil pore air. The soil-air partition constant was treated as a fit parameter in the model because of the uncertainty in the a priori estimation. The model predicts the qualitative trends of the experimental fluxes satisfactorily. Under extremely dry conditions, the flux decreased more rapidly than that predicted by the model. The fluxes from soils at 24°C were higher than those at 14°C, indicating a larger volatilization driving force at the higher temperature. [source] Problems in evaluating regional and local trends in temperature: an example from eastern Colorado, USAINTERNATIONAL JOURNAL OF CLIMATOLOGY, Issue 4 2002R. A. Pielke SR Abstract We evaluated long-term trends in average maximum and minimum temperatures, threshold temperatures, and growing season in eastern Colorado, USA, to explore the potential shortcomings of many climate-change studies that either: (1) generalize regional patterns from single stations, single seasons, or a few parameters over short duration from averaging dissimilar stations; or (2) generalize an average regional pattern from coarse-scale general circulation models. Based on 11 weather stations, some trends were weakly regionally consistent with previous studies of night-time temperature warming. Long-term (80 + years) mean minimum temperatures increased significantly (P < 0.2) in about half the stations in winter, spring, and autumn and six stations had significant decreases in the number of days per year with temperatures , , 17.8 °C (,0 °F). However, spatial and temporal variation in the direction of change was enormous for all the other weather parameters tested, and, in the majority of tests, few stations showed significant trends (even at P < 0.2). In summer, four stations had significant increases and three stations had significant decreases in minimum temperatures, producing a strongly mixed regional signal. Trends in maximum temperature varied seasonally and geographically, as did trends in threshold temperature days ,32.2 °C (,90 °F) or days ,37.8 °C (,100 °F). There was evidence of a sub-regional cooling in autumn's maximum temperatures, with five stations showing significant decreasing trends. There were many geographic anomalies where neighbouring weather stations differed greatly in the magnitude of change or where they had significant and opposite trends. We conclude that sub-regional spatial and seasonal variation cannot be ignored when evaluating the direction and magnitude of climate change. It is unlikely that one or a few weather stations are representative of regional climate trends, and equally unlikely that regionally projected climate change from coarse-scale general circulation models will accurately portray trends at sub-regional scales. However, the assessment of a group of stations for consistent more qualitative trends (such as the number of days less than ,17.8 °C, such as we found) provides a reasonably robust procedure to evaluate climate trends and variability. Copyright © 2002 Royal Meteorological Society [source] Operating windows of slot die coating: Comparison of theoretical predictions with experimental observationsADVANCES IN POLYMER TECHNOLOGY, Issue 1 2010Chi-Feng Lin Abstract The objective of the present study is to examine the validity of the theoretical predictions on the operating windows of slot die coating. The operating window is defined as a domain inside which stable and uniform coating is possible; different types of coating defects are found outside the window. A flow visualization technique was applied to observe the coating bead, particularly the positions and shapes of the downstream and upstream menisci, just before and after coating defects appear at high coating speeds. Special features of coating bead shapes, which lead to onsets of ribbing and air entrainment, were identified. The two-dimensional flow in the coating bead region was computed by the commercial software package FLOW-3D®. Critical features observed experimentally for the onset of coating defects were used to judge whether the coating flow was within the operating window. The theoretically evaluated operating windows were found to be much larger than those determined experimentally in terms of coating speeds. However, the qualitative trends of theoretical predictions agree with experimental observations. © 2010 Wiley Periodicals, Inc. Adv Polym Techn 29:31,44, 2010; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/adv.20173 [source] Solvent models for protein,ligand binding: Comparison of implicit solvent poisson and surface generalized born models with explicit solvent simulationsJOURNAL OF COMPUTATIONAL CHEMISTRY, Issue 6 2001Linda Yu Zhang Abstract Solvent effects play a crucial role in mediating the interactions between proteins and their ligands. Implicit solvent models offer some advantages for modeling these interactions, but they have not been parameterized on such complex problems, and therefore, it is not clear how reliable they are. We have studied the binding of an octapeptide ligand to the murine MHC class I protein using both explicit solvent and implicit solvent models. The solvation free energy calculations are more than 103 faster using the Surface Generalized Born implicit solvent model compared to FEP simulations with explicit solvent. For some of the electrostatic calculations needed to estimate the binding free energy, there is near quantitative agreement between the explicit and implicit solvent model results; overall, the qualitative trends in the binding predicted by the explicit solvent FEP simulations are reproduced by the implicit solvent model. With an appropriate choice of reference system based on the binding of the discharged ligand, electrostatic interactions are found to enhance the binding affinity because the favorable Coulomb interaction energy between the ligand and protein more than compensates for the unfavorable free energy cost of partially desolvating the ligand upon binding. Some of the effects of protein flexibility and thermal motions on charging the peptide in the solvated complex are also considered. © 2001 John Wiley & Sons, Inc. J Comput Chem 22: 591,607, 2001 [source] | ||||||||||