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Quartz Sand (quartz + sand)
Selected AbstractsEvaluating the transport and removal of chromate using pyrite and biotite columnsHYDROLOGICAL PROCESSES, Issue 14 2007Chul-Min Chon Abstract To remove chromate from a wastewater, a porous permeable reactive barrier system (PRBS), using pyrite and biotite, was adapted. This study included bench-scale column experiments to evaluate the efficiency of the PRBS and investigate the reaction process. The total chromium concentration of the effluent from the biotite and pyrite columns reached the influent concentration of 0·10 mM after passing through more than 150 pore volumes (PVs) and 27 PVs respectively, and remained constant thereafter. The CrVI concentration in the effluent from the biotite column became constant at about 0·08 mM, accounting for approximately 80% of the influent concentration, after passing through 200 PVs. Moreover, in the pyrite column, the CrVI concentration remained at about 0·01 mM, 10% of the input level, after passing through 116 PVs. This shows that both columns maintained their levels of chromate reduction once the CrVI breakthrough curves (BTCs) had reached the steady state, though the steady-state output concentration of total chromium had reached the influent level. The variances of the iron concentration closely followed those of the chromium. The observed data for both columns were fitted to the predicted BTCs calculated by CXTFIT, a program for estimating the solute transport parameters from experimental data. The degradation coefficient µ of the total chromium BTCs for both columns was zero, suggesting the mechanisms for the removal of chromate limit the µ of the CrVI BTCs. The CrVI degradation of the pyrite column (6·60) was much greater than that of the biotite column (0·27). In addition, the CrVI retardation coefficient R of the pyrite column (253) was also larger than that of the biotite column (125). The R values for the total chromium BTCs from both columns were smaller than those of the CrVI BTC. Whereas the total chromium BTC for the pyrite column showed little retardation (1·5), the biotite column showed considerable retardation (80). The results for the 900 °C heat-treated biotite column were analogous to those of the control column (quartz sand). This suggests that the heat-treated biotite played no role in the retardation and removal of hexavalent chromium. The parameters of the heat-treated biotite were calculated to an R of 1·2 and µ of 0·01, and these values confirmed quantitatively that the heated biotite had little effect on the transport of CrVI. These solute transport parameters, calculated by CXTFIT from the data obtained from the column tests, can provide quantitative information for the evaluation of bench- or field-scale columns as a removal technology for CrVI in wastewater or contaminated groundwater. Copyright © 2006 John Wiley & Sons, Ltd. [source] An enhanced constitutive model for crushable granular materialsINTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS, Issue 6 2010Ali Daouadji Abstract Studies in the past have tried to reproduce the mechanical behaviour of granular materials by proposing constitutive relations based on a common assumption that model parameters and parameters describing the properties, including gradation of individual grains are inevitably linked. However successful these models have proved to be, they cannot account for the changes in granular assembly behaviour if the grains start to break during mechanical loading. This paper proposes to analyse the relation between grading change and the mechanical behaviour of granular assembly. A way to model the influence of grain breakage is to use a critical state-based model. The influence of the amount of grain breakage during loading, depending on the individual grain strength and size distribution, can be introduced into constitutive relations by means of a new parameter that controls the evolution of critical state with changes in grain size distribution. Experimental data from a calcareous sand, a quartz sand, and a rockfill material were compared with numerical results and good-quality simulations were obtained. The main consequences of grain breakage are increased compressibility and a gradual dilatancy disappearance in the granular material. The critical state concept is also enriched by considering its overall relation to the evolution of the granular material. Copyright © 2009 John Wiley & Sons, Ltd. [source] Reduced-bore monolithic silica column modified with C8 -TEOS for reversed-phase electrochromatographyJOURNAL OF SEPARATION SCIENCE, JSS, Issue 9 2004Qishu Qu Abstract Monolithic silica columns of 2.7 mm ID were prepared and derivatized with C8 -TEOS and TEOS by on-column sol-gel reaction. These C8 large diameter monolithic silica columns gave 21 000 theoretical plates for aromatic hydrocarbons in 60% acetonitrile and 40% Tris-HCl buffer. The surface areas as well as the separation reproducibility were improved on coating by the sol-gel approach. Joule heating was greatly reduced by using monolithic columns to which fine quartz sand had been added during column preparation. Since this is a preliminary investigation on a monolithic column with such a large inner diameter, the separation efficiency was not so high as that presently achieved in normal capillary electrochromatography (CEC). However, use of the columns improved sample loadability and concentration detectability of electrochromatography, and semi-preparative separations could be performed. [source] Mixing Deposition of Upper Carboniferous in Jiangshan, Zhejiang Province and its Tectonic SignificanceACTA GEOLOGICA SINICA (ENGLISH EDITION), Issue 2 2010Fusheng GUO Abstract: The Outangdi Formation in Jiangshan, Zhejiang, is the mixing deposit of terrigenous clastics and carbonates in Weiningian of the late Carboniferous. The mixing deposits include interbeddings, which constitute a series of alternated clastic and carbonate beds and mixing within the same bed which forms "hunji rock". The Outangdi Formation has the features of intercalated marine and terrestrial deposits with the progradational sequences, which are lower fine and upper coarse sedimentary granularity in the section. Hunji rock is formed in a seashore environment. It is a mixed carbonate sediment found in beaches or tideland facies with quartz sand taken from a bayou or beach by coastwise flow and circumfluence. There are two kinds of hunji sequences: (1) interbeds of sandstone and carbonate rock in seashore environments; and (2) interbeds of clastics in river facies and carbonate rock in ocean facies. It is indicated that mixing depositions belong to "facies mixing", affected mainly by regional tectonic uplift, rise of the global sea level, and the dynamics of water medium in the basin. Regional sea level periodic changes and progradational sequences probably resulted from the intense uplift of the old land called Cathaysia. The classification and name of mixed sediments are also discussed in the present study. Interbeds and alternated beds of clastic and carbonate beds are named "hunji sequence", a new genetic term. It is suggested that hunji rock means a special sediment event of mixing terrigenous clastics and carbonates instead of a name of a specific rock. [source] Stratigraphy, sedimentology, age and palaeoenvironment of marine varved clay in the Middle Swedish end-moraine zoneBOREAS, Issue 2 2010MARK D. JOHNSON Johnson, M. D. & Ståhl, Y. 2009: Stratigraphy, sedimentology, age and palaeoenvironment of marine varved clay in the Middle Swedish end-moraine zone. Boreas, 10.1111/j.1502-3885.2009.00124.x. ISSN 0300-9483 Deglaciation of the Middle Swedish end-moraine zone and age of the sediment in and between the moraines have been discussed for about a hundred years. The goal of this project was to determine the stratigraphy and age of the sediment in and between the moraines. Inter-moraine flats are underlain by clay, 10,25 m thick, overlying thin sand and gravel or till on bedrock. The clay is overlain by a few metres of sand and gravel. Much of the clay beneath the flats consists of rhythmites that grade from grey to red and are 2,74 cm thick. Our interpretation of these rhythmites as being varves is supported by grain size and mineralogical and elemental variations. Foraminifera and ostracods show that the clay was deposited in an arctic marine environment, while radiocarbon dating of the microfossils indicates that the clay was deposited 12 150 cal. 14C years ago, during the Younger Dryas chronozone (YD). Most of the optical stimulated luminescence dates on the clay are much older, containing quartz sand that was insufficiently bleached. The stratigraphy indicates that the moraines are composed of YD clay pushed into ridge forms during ice-front oscillations. It is not possible to determine how far north the Scandinavian Ice Sheet retreated prior to the YD advance. We neither support nor reject the suggestion that the ice margin retreated to the northern edge of Mt. Billingen during the Allerųd, causing the Baltic Ice Lake to drain. [source] Formation of Furfural in Catalytic Transformation of Levoglucosan over Mesoporous MaterialsCHEMCATCHEM, Issue 5 2010M. Käldström Abstract Catalytic transformations of levoglucosan (1-6-anhydro-,- D -glucopyranose) and furfural were carried out in a fixed-bed reactor at 573,K over mesoporous materials. Proton forms of MCM-41, MCM-48, SBA-15, and platinum form of MCM-48 catalysts were tested in the reaction, whereas H-Beta and quartz sand were used as reference materials. The yield of the transformation products was substantially influenced by the catalyst structures. Oxygenated species were the main liquid products, consisting mainly of aldehydes and furfural. The formation of furfural was the highest over MCM-41 catalyst followed by SBA-15, MCM-48, and H-Beta catalyst. All catalysts were to some extent deactivated due to coke formation. However, it was possible to successfully regenerate the spent catalysts without changing the structure. [source] Mapping the geochemistry of the northern Rub' Al Khali using multispectral remote sensing techniquesEARTH SURFACE PROCESSES AND LANDFORMS, Issue 7 2001Kevin White Abstract Spatial variations in sand sea geochemistry relate to mixing of different sediment sources and to variations in weathering. Due to problems of accessibility, adequate spatial coverage cannot be achieved using field surveys alone. However, maps of geochemical composition produced from remotely sensed data can be calibrated against limited field data and the results extrapolated over large, inaccessible areas. This technique is applied to part of the Rub' Al Khali in the northern United Arab Emirates. Trend surface analysis of the results suggests that the sand sea at this location can be modelled as an east,west mixing zone of two spectral components: terrestrial reddened quartz sands and marine carbonate sands. Optical dating of these sediments suggests that dune emplacement occurred rapidly around 10 ka BP, when sea level was rising rapidly. The spatial distribution of mineralogical components suggests that this phase of dune emplacement resulted from coastal dune sands being driven inland during marine transgression, thereby becoming mixed with rubified terrestrial sands. Copyright © 2001 John Wiley & Sons, Ltd. [source] | ||||||||||||||||