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Quartz Reactor (quartz + reactor)

Distribution by Scientific Domains
Chemistry75%

Selected Abstracts

Gasification of char particles in packed beds: analysis and results

INTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 12 2001
S. Dasappa
Abstract In this paper a packed bed of char particles is considered for experimental study and analysis. The packed char bed is modelled by extending the single-particle analysis (Dasappa et al., 1994a, Chem. Eng. Sci.49,2:223,232. Dasappa et al., 1994b, Twenty-fifth Symposium (International) on Combustion, pp. 1619,1628. Dasappa et al., 1998, Twenty-seventh Symposium (International) on Combustion, pp. 1335,1342.). All the reactions related to gasification are introduced into the reaction system as in Dasappa et al. (1998). The propagation of the reaction front into the packed char bed against the air stream is modelled. The results are compared with the experimental data on a model quartz reactor using charcoal. Experimental data of propagation of the reaction front through the packed bed from the present study and of Groeneveld's charcoal gasifier are used for comparison. Using the analysis of Dosanjh et al. 1987 (Combust. Flame68:131,142), it is shown that heat loss dominates the heat generation at the quench condition. It is also shown that increasing the oxygen fraction in air has resulted in flame front to propagate into the char bed. The critical air mass flux for peak propagation rate in a bed of char is found to be 0.1 kg m,2 s. Copyright © 2001 John Wiley & Sons, Ltd. [source]

High-temperature kinetics of the homogeneous reverse water,gas shift reaction

AICHE JOURNAL, Issue 5 2004
F. Bustamante
Abstract The high-temperature rate of reaction of the homogeneous, reverse water,gas shift reaction (rWGSR) has been evaluated in quartz reactors with rapid feed preheating under both low- and high-pressure conditions. The form of the power-law rate expression was consistent with the Bradford mechanism. The Arrhenius expressions for the reaction rate constant, corresponding to the empty reactor, were in very good agreement with the low-pressure results of Graven and Long, but yielded rate constants roughly four times greater than those obtained in our packed reactor and those reported by Kochubei and Moin and by Tingey. Reactor geometry was not responsible for these differences because computational fluid dynamics simulations revealed similar residence time distributions and comparable conversions when the same kinetic expression was used to model the rWGSR in each reactor. Most likely, the empty NETL reactor and the Graven and Long reactor did not attain an invariant value of the concentration of the chain carrier (H) at low reaction times, which led to an overestimation of the rate constant. Conversions attained in an Inconel® 600 reactor operating at comparable conditions were approximately two orders of magnitude greater than those realized in the quartz reactor. This dramatic increase in conversion suggests that the Inconel® 600 surfaces, which were depleted of nickel during the reaction, catalyzed the rWGSR. © 2004 American Institute of Chemical Engineers AIChE J, 50: 1028,1041, 2004 [source]

Catalytic and Heating Behavior of Nanoscaled Perovskites under Microwave Radiation

CHEMICAL ENGINEERING & TECHNOLOGY (CET), Issue 7 2008
T. Krech
Abstract Perovskite powders of the types La0.5Ca0.5AlyM1,yO3,, (y = 0,0.8), M = Fe, Cr, Mn, Co and LaxSr1,xMnyCo1,y (x = 0.5,1, y = 0,1) were prepared via a sol-gel route according to the modified Pechini method. Incineration of the resins was performed before final sintering at 1000,°C for 6,h. The phase composition of the samples was established by X-ray powder diffraction analysis, and the lattice parameters were calculated using Rietveld analysis. The shape and size of the particles were determined via scanning electron microscopy and the specific surface area of the powder perovskites was established by the BET method. The principal particles were ca. 100,nm in size and formed agglomerates larger than 1.0,,m. The composition of the perovskites was established by EDX analysis. Following this, the catalytic behavior was tested by means of total oxidation of propane. The catalytic performance was measured at atmospheric pressure with 3,g of catalyst in a fixed-bed quartz reactor (i.d. = 18,mm) under thermal-assisted and microwave-assisted conditions. Initial results show a strong dependence of the catalytic and heating behavior on the nature of the M-atom and its number of unpaired d-electrons as well as on the particle size and its specific surface area. No significant difference in the results could be detected from comparison of the two heating methods. [source]

High-temperature kinetics of the homogeneous reverse water,gas shift reaction

AICHE JOURNAL, Issue 5 2004
F. Bustamante
Abstract The high-temperature rate of reaction of the homogeneous, reverse water,gas shift reaction (rWGSR) has been evaluated in quartz reactors with rapid feed preheating under both low- and high-pressure conditions. The form of the power-law rate expression was consistent with the Bradford mechanism. The Arrhenius expressions for the reaction rate constant, corresponding to the empty reactor, were in very good agreement with the low-pressure results of Graven and Long, but yielded rate constants roughly four times greater than those obtained in our packed reactor and those reported by Kochubei and Moin and by Tingey. Reactor geometry was not responsible for these differences because computational fluid dynamics simulations revealed similar residence time distributions and comparable conversions when the same kinetic expression was used to model the rWGSR in each reactor. Most likely, the empty NETL reactor and the Graven and Long reactor did not attain an invariant value of the concentration of the chain carrier (H) at low reaction times, which led to an overestimation of the rate constant. Conversions attained in an Inconel® 600 reactor operating at comparable conditions were approximately two orders of magnitude greater than those realized in the quartz reactor. This dramatic increase in conversion suggests that the Inconel® 600 surfaces, which were depleted of nickel during the reaction, catalyzed the rWGSR. © 2004 American Institute of Chemical Engineers AIChE J, 50: 1028,1041, 2004 [source]