Product Composition (product + composition)

Distribution by Scientific Domains
Distribution within Chemistry


Selected Abstracts


ASSOCIATION OF STRAWBERRY YOGURT SENSORY PROPERTIES WITH PRODUCT COMPOSITION BY PROCRUSTES ANALYSIS

JOURNAL OF SENSORY STUDIES, Issue 4 2004
ADRIANA GÁMBARO
ABSTRACT The flavor of eight samples of commercial strawberry yogurt was studied by Free-Choice Profile analysis (FCP). Generalized Procrustes Analysis (GPA) applied to FCP allowed differentiation between samples and highlighted flavor attributes responsible for the observed differences. The relation between sensory and physicochemical datasets was studied by means of GPA. Those samples with higher carbohydrate content were perceived as sweeter, having stronger strawberry flavor, and with more dairy and yogurt flavors. Samples with higher titratable acidity, ash and protein content were perceived as more acidic and higher in intensity of "faulty" or "defective" flavors. Higher moisture content was associated with lower intensity of "dairy" flavors (creamy, dairy, and yogurt) and greater intensity of rancid flavor. It is concluded that, though not often used to this end, GPA is a suitable method to study the relationship of sensory and instrumental measurements. [source]


Numerical studies on the reaction of carbon particles in a vacuum residue,air flame

INTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 9 2006
Ho Young Park
Abstract A computational work was carried out for the study of one-dimensional, laminar, premixed, flat, atomized vacuum residue (VR) particle,air flames. The mathematical model includes the specified pyrolysis scheme, soot and char oxidation scheme. With some experimental works, the product composition and kinetic parameters of VR pyrolysis were determined and used for the present computational work. The computed results show that the oxidation of VR carbon char and soot occurs mainly in the reaction zone and the oxidation rate of soot is much higher than that of VR carbon char. The oxidation rates of carbon char and soot can be increased with the decrease in particle diameter, and it might be accomplished by the more effective atomization and mixing of solid particles with combustion air. Copyright © 2005 John Wiley & Sons, Ltd. [source]


Survival of Salmonella in peanut butter and peanut butter spread

JOURNAL OF APPLIED MICROBIOLOGY, Issue 3 2000
S.L. Burnett
In 1996, the first documented outbreak of salmonellosis associated with the consumption of peanut butter was reported. This study was undertaken to determine survival characteristics of high (5·68 log10 cfu g,1) and low (1·51 log10 cfu g,1) inocula of a five-serotype mixture of Salmonella in five commercial peanut butters and two commercial peanut butter spreads. Populations in samples inoculated with 5·68 log10 cfu g,1 and stored for 24 weeks at 21 or 5 °C decreased 4·14,4·50 log10 cfu g,1 and 2·86,4·28 log10 cfu g,1, respectively, depending on the formulation. The order of retention of viability was: peanut butter spreads > traditional (regular) and reduced sugar, low-sodium peanut butters > natural peanut butter. Differences in rates of inactivation are attributed to variation in product composition as well as size and stability of water droplets in the colloidal matrix, which may influence nutrient availability. With the exception of natural peanut butter, products initially inoculated with 1·51 log10 cfu of Salmonella g,1 (32 cfu g,1) were positive for the pathogen after storage for 24 weeks at 5 °C. At 21 °C, however, with the exception of one peanut butter spread, all products were negative for Salmonella after storage for 24 weeks. Post-process contamination of peanut butters and spreads with Salmonella may to result in survival in these products for the duration of their shelf life at 5 °C and possibly 21 °C, depending on the formulation. [source]


Temperature-related reaction kinetics and product composition of ethoxylated fatty acid methyl esters

JOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 5 2002
aw Hreczuch
Abstract The work investigates the influence of temperature on the reaction kinetics and the consequent change in the distribution of homologues during ethoxylation of fatty acid methyl esters. It was found that temperature-related kinetics of ethoxylation significantly affects the composition of the products and more narrow distributions of homologues are found with an increase in the reaction temperature from 135,°C to 185,°C. It is suggested that intermolecular complexation of the catalyst cation takes place, thus broadening the distribution of the homologues produced at the lower temperature range and the effect decays with increases in the reaction temperature. The substantial influence of the distribution of homologues on the products' viscosity and solubility is revealed. © 2002 Society of Chemical Industry [source]


KINETICS OF OSMOTIC DEHYDRATION IN ORANGE AND MANDARIN PEELS

JOURNAL OF FOOD PROCESS ENGINEERING, Issue 4 2001
M. CHÁFER
ABSTRACT The nutritional and health properties of some citrus peel components such as pectin, flavonoids, carotenoids or limonene make interesting developing processing methods to obtain peel stable products, maintaining its quality attributes, increasing its sweetness and improving its sensory acceptability. In this sense, osmotic dehydration represents a useful alternative by using sugar solutions at mild temperature. Kinetics of osmotic treatments of orange and mandarin peels carried out at atmospheric pressure and by applying a vacuum pulse at the beginning of the process were analysed at 30, 40 and 50C, in 65 °Brix sucrose, 55 °Brix glucose and 60 °Brix rectified grape must. Vacuum pulse greatly affected mass transfer behavior of peels due to the greatly porous structure of albedo. So, PVOD treatments greatly accelerate the changes in the product composition in line with an increase in the peel sample thickness. In osmotic processes at atmospheric pressure, sample impregnation occurs coupled with osmotic process, but much longer treatments are required to achieve a reasonable concentration degree which assures sample stability. Low viscosity osmotic solutions seems recommendable in order to promote both diffusional and hydrodynamic transport, in vacuum pulsed pretreatments at mild temperatures. [source]


Quality Attributes and Microbial Storage Stability of Caviar from Cultivated White Sturgeon (Acipenser transmontanus)

JOURNAL OF FOOD SCIENCE, Issue 1 2010
Joong-Han Shin
ABSTRACT:, Caviar was prepared from white sturgeon (Acipenser transmontanus) roe by adjusting the water phase salt (WPS) to 4.0% to 6.3% by adding food grade NaCl. Fish were obtained from 2 different farms from the Inland Northwest (N,= 5). Salt was absorbed at a different rate and to a different extent by roe from different fish. The lipid content in the fish roe varied from 10.2% to 14.4% (w/w), with palmitic acid and oleic acid being the most abundant saturated and monounsaturated fatty acids present, respectively. The caviar contained high levels of polyunsaturated fatty acids (PUFA) (35% to 37%) with docosahexanoic acid being the most abundant ,-3 long chain fatty acid. There were no significant differences in microbial storage stability for caviars from different fish stored at 3 °C. However, for caviar stored at 7 °C, there was less growth of,Listeria monocytogenes,(using a cocktail of ATCC 19114, 7644, 19113 strains) in 2 samples (2B46 and 0F05) until day 20. In 2 other samples (453F and 2519), which had lower initial microbial loads, less overall microbial growth was observed, indicating that culture and harvest practices result in compositional differences between fish, which may impact both product composition and storage stability. [source]


Plasma Synthesis of Tungsten Carbide Nanopowder from Ammonium Paratungstate

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 3 2009
Taegong Ryu
A thermal plasma process has been applied to the synthesis of nanosized tungsten carbide powder with ammonium paratungstate (APT) as the precursor. The reduction and carburization of vaporized APT produced nanosized tungsten carbide (WC1,x) powder, which sometimes contained a small amount of W2C phase. The effects of reactant gas composition, plasma torch power, the flow rate of plasma gas, and the addition of secondary plasma gas (H2) on the product composition and particle size were investigated. The produced tungsten carbide (WC1,x) powder was <20 nm in particle size. The synthesized powders were also subjected to a hydrogen heat treatment to fully carburize the WC1,x and W2C phases to the WC phase as well as to remove excess carbon. Finally, WC powder of particle size <100 nm was obtained. [source]


Feasible compositions for random copolymerizations,

POLYMER ENGINEERING & SCIENCE, Issue 2 2001
Raymond L. Smith
Using the attainable region approach, feasible compositions and conversions for random copolymers are determined, along with altermatives for the related reactor configurations. This analysis attempts to find all of the possible compositions that can be produced by any system of reactros and mixing. The average copolymer compositions are bounded by the feed composition and the instantaneous copolymer composition produced at the initial conditions. Since the instantaneous copolymer composition can be found through the Mayo-Lewis equation, that case and the feed composition mark the limiting feasible compositions. The results can also be used to determine the range of feed compositions for which a specific copolymer product composition is possible. If the addition of monomer at any point in the reactor system is possible, e.g., by side-feeding, the analysis indicates that any desired copolymer composition can be obtained. [source]


A two-level distillation design method

AICHE JOURNAL, Issue 11 2008
Amit Amale
Abstract Recently, Lucia et al. have used a distillation line method to develop the concept of shortest stripping line distance approach to minimum energy designs of distillation columns and multiunit processes. It is well known that distillation line methods can be very sensitive to specified product compositions. A two-level distillation design procedure is proposed for finding portfolios of minimum energy designs when specifications are given in terms of key component recoveries. Thus, product compositions are not specified but calculated. It is shown that the proposed two-level design procedure is flexible and can find minimum energy designs for both zeotropic and azeotropic distillations. It is also shown that the two-level design method encompasses Underwood's solution but can find minimum energy designs when Underwood's method fails. Numerical results for several distillation examples involving ternary and quaternary mixtures are presented to support these claims, and geometric illustrations are used to elucidate key points. © 2008 American Institute of Chemical Engineers AIChE J, 2008 [source]


Experimental study of feasibility in kinetically-controlled reactive distillation

AICHE JOURNAL, Issue 2 2005
Madhura Chiplunkar
Abstract Bifurcation studies predict limited ranges of feasibility for products in certain reactive distillations. These are closely related to the bifurcations in the singular points of dynamic models for simple reactive distillation (isobaric open evaporation with liquid phase reaction). A new dynamic model is described with constant vapor rate together with an experimental study for the reactive distillation of acetic acid with isopropanol to produce isopropyl acetate, catalyzed by Amberlyst-15 ion-exchange resin. An experimental apparatus with real-time measurement of liquid compositions based on Fourier transform infrared (FTIR) spectroscopy is described, and used to follow the composition dynamics at several initial conditions and Damköhler numbers (Da). The experimental results match model predictions that show four regions of behavior. For Da , 1, these show a stable node at acetic acid and several other fixed points as saddles. However, near Da , 2, both isopropanol and acetic acid are stable nodes and a quaternary singular point appears. The presence of two stable nodes requires the presence of a distillation boundary and, therefore, a limited feasibility for the bottom product compositions from continuous reactive distillation. For the reaction rates studied, the model predictions are closely consistent with the experimental findings, and are robust to variations in the vapor rate. These experiments are among the first to analyze the dynamics and feasibility in a kinetically-controlled reactive distillation and are consistent with previous studies for the reaction equilibrium limit, indicating the formation of a reactive azeotrope. © 2005 American Institute of Chemical Engineers AIChE J, 51: 464,479, 2005 [source]


Experimental validation of a high-gain observer for composition estimation in an ethanol,water distillation column

ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 6 2009
A. C. Téllez-Anguiano
Abstract In this paper a high-gain observer used to estimate the product compositions in a distillation column for a non-ideal mixture (ethanol,water) through the tray temperature measurements is presented. The design of this observer is based on a simplified mathematical model. One of the main advantages of this observer is its constant gain, therefore its tuning depends only on choosing a few constant parameters satisfying some simple algebraic inequalities. The effectiveness of the proposed method is demonstrated through on-line experiments in a distillation pilot plant. Copyright © 2009 Curtin University of Technology and John Wiley & Sons, Ltd. [source]