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Primary Aromatic Amines (primary + aromatic_amine)

Distribution by Scientific Domains
Chemistry100%

Selected Abstracts

ChemInform Abstract: Structural Revision in the Reactions of 3-Cyanochromones with Primary Aromatic Amines.

CHEMINFORM, Issue 10 2010
Improved Synthesis of 2-Amino-3-(aryliminomethyl)chromones.
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]

Nuclear Amination Catalyzed by Fungal Laccases: Reaction Products of p-Hydroquinones and Primary Aromatic Amines.

CHEMINFORM, Issue 32 2005
Timo H. J. Niedermeyer
Abstract For Abstract see ChemInform Abstract in Full Text. [source]

Well-Defined Regioselective Iminopyridine Rhodium Catalysts for Anti-Markovnikov Addition of Aromatic Primary Amines to 1-Octyne

ADVANCED SYNTHESIS & CATALYSIS (PREVIOUSLY: JOURNAL FUER PRAKTISCHE CHEMIE), Issue 6 2009
Carlos Alonso-Moreno
Abstract A series of cationic rhodium(I) complexes of the type [Rh(N-N)(COD)][BPh4], containing the following iminopyridine-based bidentate nitrogen donor ligands (N-N): 2,6-diisopropyl- N -[1-(pyridin-2-yl)ethylidene]aniline (dipea, 1), 2,6-dimethyl- N -[1-(pyridin-2-yl)ethylidene]aniline (dmpea, 2), 2,4,6-trimethyl- N -[1-(pyridin-2-yl)ethylidene]aniline (tmpea, 3) and 2,6-diisopropyl- N -[1-(4-methylpyridin-2-yl)ethylidene]aniline] (dipmpea, 4), were synthesized and fully characterized. The intermolecular hydroamination of a terminal alkyne, such as 1-octyne, with primary aromatic amines in the presence of these cationic rhodium(I) catalysts occurred in an anti-Markovnikov fashion. The rhodium complexes catalyzed the regioselective formation of the E- isomer of the corresponding imine, without the formation of the Z -isomer or the Markovnikov product. These compounds are also presented as efficient regioselective catalysts for the hydroamination of anilines in the presence of air and/or water. [source]

Hemilabile-coordinated copper promoted amination of aryl halides with ammonia in aqueous ethylene glycol under atmosphere pressure

APPLIED ORGANOMETALLIC CHEMISTRY, Issue 4 2009
Zhennü Guo
Abstract Direct amination of aryl iodides and bromides with ammonia under 1 atm pressure has been effected using in situ -generated hemilabile coordinated copper(I) species from copper(I) halides or copper metal in aqueous ethylene glycol, producing primary aromatic amines in good yields. Ammonia pressure and water were found to accelerate the copper-mediated reaction while strong chelating ligands showed a suppression effect. A rationale for the copper-mediated amination of aryl halides with ammonia is given based on a double-face role of chelating effect. Copyright © 2009 John Wiley & Sons, Ltd. [source]