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Precipitation Mechanism (precipitation + mechanism)

Distribution by Scientific Domains
Earth and Environmental Science75%

Selected Abstracts

Precipitation of lead,zinc ores in the Mississippi Valley-type deposit at Trèves, Cévennes region of southern France

GEOFLUIDS (ELECTRONIC), Issue 1 2006
D. LEACH
Abstract The Trèves zinc,lead deposit is one of several Mississippi Valley-type (MVT) deposits in the Cévennes region of southern France. Fluid inclusion studies show that the ore was deposited at temperatures between approximately 80 and 150°C from a brine that derived its salinity mainly from the evaporation of seawater past halite saturation. Lead isotope studies suggest that the metals were extracted from local basement rocks. Sulfur isotope data and studies of organic matter indicate that the reduced sulfur in the ores was derived from the reduction of Mesozoic marine sulfate by thermochemical sulfate reduction or bacterially mediated processes at a different time or place from ore deposition. The large range of ,34S values determined for the minerals in the deposit (12.2,19.2, for barite, 3.8,13.8, for sphalerite and galena, and 8.7 to ,21.2, for pyrite), are best explained by the mixing of fluids containing different sources of sulfur. Geochemical reaction path calculations, based on quantitative fluid inclusion data and constrained by field observations, were used to evaluate possible precipitation mechanisms. The most important precipitation mechanism was probably the mixing of fluids containing different metal and reduced sulfur contents. Cooling, dilution, and changes in pH of the ore fluid probably played a minor role in the precipitation of ores. The optimum results that produced the most metal sulfide deposition with the least amount of fluid was the mixing of a fluid containing low amounts of reduced sulfur with a sulfur-rich, metal poor fluid. In this scenario, large amounts of sphalerite and galena are precipitated, together with smaller quantities of pyrite precipitated and dolomite dissolved. The relative amounts of metal precipitated and dolomite dissolved in this scenario agree with field observations that show only minor dolomite dissolution during ore deposition. The modeling results demonstrate the important control of the reduced sulfur concentration on the Zn and Pb transport capacity of the ore fluid and the volumes of fluid required to form the deposit. The studies of the Trèves ores provide insights into the ore-forming processes of a typical MVT deposit in the Cévennes region. However, the extent to which these processes can be extrapolated to other MVT deposits in the Cévennes region is problematic. Nevertheless, the evidence for the extensive migration of fluids in the basement and sedimentary cover rocks in the Cévennes region suggests that the ore forming processes for the Trèves deposit must be considered equally viable possibilities for the numerous fault-controlled and mineralogically similar MVT deposits in the Cévennes region. [source]

Liquid Chromatographic Separation of Olefin Oligomers and its Relation to Separation of Polyolefins , an Overview

MACROMOLECULAR SYMPOSIA, Issue 1 2009
Tibor Macko
Abstract Summary: Linear and branched alkanes are oligomers of polyethylene. Alkanes with higher molar masses are called waxes. These substances are widely used as fuels, oils, lubricants, etc. and for these reasons many groups have tried to analyse, separate and characterise alkanes by various methods, including liquid chromatography. Alkanes may be separated according to their size in solution by SEC. In addition to chromatographic systems separating in the SEC mode, various sorbent-solvent systems have been published, where alkanes have been separated one from another by adsorption and/or precipitation mechanism. The mobile phase is either a non-polar solvent or a polar solvent or a mixture of a solvent and a non-solvent for alkanes. Even near critical conditions, which have several advantages for applications of HPLC in polymer analysis, have been identified for alkanes. Moreover, selective separations of branched alkanes according to their structure have been published. In the majority of these published studies, solvents with low boiling points have been used as the mobile phases, which do not allow dissolution of crystalline polyolefins at atmospheric pressure. However, taking into account experiences with the separation of alkanes, new HPLC systems for the separation of polyolefins may be developed. This is a major challenge and first results are presented in this contribution. [source]

Precipitation of lead,zinc ores in the Mississippi Valley-type deposit at Trèves, Cévennes region of southern France

GEOFLUIDS (ELECTRONIC), Issue 1 2006
D. LEACH
Abstract The Trèves zinc,lead deposit is one of several Mississippi Valley-type (MVT) deposits in the Cévennes region of southern France. Fluid inclusion studies show that the ore was deposited at temperatures between approximately 80 and 150°C from a brine that derived its salinity mainly from the evaporation of seawater past halite saturation. Lead isotope studies suggest that the metals were extracted from local basement rocks. Sulfur isotope data and studies of organic matter indicate that the reduced sulfur in the ores was derived from the reduction of Mesozoic marine sulfate by thermochemical sulfate reduction or bacterially mediated processes at a different time or place from ore deposition. The large range of ,34S values determined for the minerals in the deposit (12.2,19.2, for barite, 3.8,13.8, for sphalerite and galena, and 8.7 to ,21.2, for pyrite), are best explained by the mixing of fluids containing different sources of sulfur. Geochemical reaction path calculations, based on quantitative fluid inclusion data and constrained by field observations, were used to evaluate possible precipitation mechanisms. The most important precipitation mechanism was probably the mixing of fluids containing different metal and reduced sulfur contents. Cooling, dilution, and changes in pH of the ore fluid probably played a minor role in the precipitation of ores. The optimum results that produced the most metal sulfide deposition with the least amount of fluid was the mixing of a fluid containing low amounts of reduced sulfur with a sulfur-rich, metal poor fluid. In this scenario, large amounts of sphalerite and galena are precipitated, together with smaller quantities of pyrite precipitated and dolomite dissolved. The relative amounts of metal precipitated and dolomite dissolved in this scenario agree with field observations that show only minor dolomite dissolution during ore deposition. The modeling results demonstrate the important control of the reduced sulfur concentration on the Zn and Pb transport capacity of the ore fluid and the volumes of fluid required to form the deposit. The studies of the Trèves ores provide insights into the ore-forming processes of a typical MVT deposit in the Cévennes region. However, the extent to which these processes can be extrapolated to other MVT deposits in the Cévennes region is problematic. Nevertheless, the evidence for the extensive migration of fluids in the basement and sedimentary cover rocks in the Cévennes region suggests that the ore forming processes for the Trèves deposit must be considered equally viable possibilities for the numerous fault-controlled and mineralogically similar MVT deposits in the Cévennes region. [source]

Precipitation characteristics of the Eurasian Arctic drainage system

INTERNATIONAL JOURNAL OF CLIMATOLOGY, Issue 11 2003
Mark C. Serreze
Abstract This study examines characteristics of precipitation over the major watersheds of the Eurasian Arctic drainage system over the period 1960,92. In addition to the Ob, Yenisey and Lena (the three largest drainage systems), we examine the combined Kolyma,Indigirka in eastern Eurasia. Each basin exhibits approximately symmetric mean annual cycles of monthly total precipitation and daily event size, with winter minima and July maxima. These are strikingly similar to the annual cycles of total column water vapour (precipitable water), which fundamentally reflects the control on saturation vapour pressure by temperature. Effective precipitation mechanisms exist in all seasons. However, because of the long distance from strong moisture sources (continentality), precipitation tends to follow the seasonality in column water vapour. An effective contrast is presented for the Iceland sector. Here, the annual cycle of precipitation is tied not to the seasonality in column water vapour, but to the stronger precipitation-generating mechanisms in winter. Hence, the annual cycles of precipitation and column water vapour in this region oppose each other. Mean winter precipitation over the Eurasian watersheds is primarily driven by a modest convergence of water vapour. Whereas precipitation peaks in summer, the mean flux convergence exhibits a general minimum (negative in the Ob). Summer precipitation is hence primarily associated with surface evaporation. A strong role of convection is supported from consideration of static stability, the fairly weak spatial organization of precipitation totals and results from prior studies. On daily time scales, the largest basin-averaged precipitation events, for both summer and winter, are allied with synoptic-scale forcing. This is seen in relationships with cyclone frequency, and patterns of 500 hPa height, vertical motion and the 700 hPa vapour flux. The relative frequency of four 500 hPa synoptic types captures the basic time series structures of precipitation. Copyright © 2003 Royal Meteorological Society [source]