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Polymer Science (polymer + science)
Selected AbstractsEditorial announcement: The 2007 SPSJ International Award of the Society of Polymer Science, Japan for Virgil PercecJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 17 2008Craig J. Hawker No abstract is available for this article. [source] Missions and Challenges of Polymer Science and TechnologyMACROMOLECULAR CHEMISTRY AND PHYSICS, Issue 8 2003Kazuyuki Horie This section contains reports on topical conferences. Reports are usually written at the request of the editorial office, but unsolicited contributions are also welcome. Suggestions should be sent to the editorial office of the Macromolecular journals, preferably by E-mail to macromol@wiley-vch.de. [source] 5rd DPI Workshop on Combinatorial and High-Throughput Experimentation in Polymer Science , Special Focus on Microwave Synthesis,MACROMOLECULAR RAPID COMMUNICATIONS, Issue 4 2007Richard Hoogenboom First page of article [source] Glossar zu Begriffen mit Bezug zu Kinetik, Thermodynamik und Mechanismen von Polymerisationen,ANGEWANDTE CHEMIE, Issue 50 2009Ulrich Jonas Dr. Abstract Im Folgenden werden empfohlene Definitionen von grundlegenden Begriffen mit Bezug zu Polymerisationsprozessen vorgestellt. Neuere Entwicklungen im Hinblick auf die Kinetik, die Thermodynamik und die Mechanismen von Polymerisationen machen die Einführung neuer Begriffe und einige Revisionen oder Erweiterungen von Begriffen notwendig, die zuvor im "Compendium of Chemical Terminology" oder im "Glossary of Basic Terms in Polymer Science" definiert wurden. [source] Titanosilsesquioxanes Embedded in Synthetic Clay as a Hybrid Material for Polymer Science,ANGEWANDTE CHEMIE, Issue 33 2009Fabio Carniato Dr. Zwischen den Schichten: Ein neuartiges Hybridmaterial (siehe Bild) wurde durch die Interkalation eines difunktionellen Titanosilsesquioxans in synthetisches Natriumsaponit erhalten. Ein Nanokomposit aus einer Polystyrolmatrix und dem Hybrid als Additiv weist verbesserte thermooxidative Eigenschaften auf. [source] Poly(glycoamidoamine)s: Cationic glycopolymers for DNA deliveryJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 24 2006Theresa M. Reineke Abstract Polymer science is playing an exciting role in inspiring and advancing novel discoveries in the area of genetic drug delivery. Polymeric materials can be synthesized and chemically tailored to bind and compact nucleic acids into viral-like nanoparticles termed polyplexes that can deliver genetic materials into cells. This article highlights our work in this area to synthesize and study a novel class of cationic glycopolymers that we have termed poly(glycoamidoamine)s (PGAAs). The design of these materials has been inspired by many previous works in the literature. Carbohydrate comonomers have been incorporated into these structures to lower the toxicity of the delivery vehicle, and oligoamine moieties have been added to yield a cationic backbone that facilitates strong DNA binding, compaction, cellular uptake, and delivery of genetic material. PGAAs have been designed to vary in the carbohydrate size, the hydroxyl number and stereochemistry, the amine number, and the presence or absence of heterocyclic groups. Through structure,bioactivity studies, we have discovered that these materials are highly biocompatible, and each specific feature plays a large role in the observed delivery efficacy. Such structure,property studies are important for increasing our understanding of how the polymer chemistry affects the biological activity for the clinical development of polymer-based therapeutics. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 6895,6908, 2006 [source] Going Ultra: How We Can Increase the Length Scales Studied in Small-Angle Neutron Scattering,ADVANCED ENGINEERING MATERIALS, Issue 6 2009Melissa A. Sharp Abstract Small-angle neutron scattering (SANS) has over the years proved to be a popular technique to investigate a variety of problems in materials science, since the length scales probed by this technique (1,100,nm) are ideal for many systems. However, there are a number of problems where the length scale of interest is larger. In order to study such systems it is possible to combine SANS with ultra-small-angle neutron scattering (USANS). This allows the study of structures from a few nanometers up to 50,µm. Here it is shown how the combination of SANS and USANS has allowed for a wider range of problems within materials science and polymer science to be solved. [source] Synthesis of well-defined polymeric activated estersJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 20 2008Patrick Theato Abstract Monomers bearing an activated ester group can be polymerized under various controlled polymerization techniques, such as ATRP, NMP, RAFT polymerization, or ROMP. Combining the functionalization of polymers via polymeric activated esters with these controlled polymerization techniques generate possibilities to realize highly functionalized polymer architectures. Within this highlight two different research areas of activated esters in polymer science will be discussed: (i) the preparation of defined reactive polymer architectures by controlled polymerization techniques and (ii) the preparation of defined reactive thin films. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 6677,6687, 2008 [source] Polymer chemistry in flow: New polymers, beads, capsules, and fibersJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 22 2006Jeremy L. Steinbacher Abstract The union between polymer science and microfluidics is reviewed. Fluids in microreactors allow the synthesis of a wide range of polymeric materials with unique properties. We begin by discussing the important fluid dynamics that dominate the behavior of fluids on the micrometer scale. We then progress through a comprehensive analysis of the polymeric materials synthesized to date. This highlight concludes with an overview of the methods used to make microreactors. We enthusiastically endorse microreactors as a powerful approach to making materials with controlled properties, although we have tried to provide a critical eye to help the nonexpert enter the field. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 6505,6533, 2006 [source] Advanced solid-state nuclear magnetic resonance for polymer scienceJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 20 2004Hans Wolfgang Spiess Abstract Today, solid-state nuclear magnetic resonance (NMR) is one of the most powerful and versatile tools for elucidating the structures and dynamics of molecular, macromolecular, and supramolecular systems. It provides information on molecular and collective phenomena over large length scales and timescales and is particularly suited to handle noncrystalline materials. This report describes how developments in solid-state NMR were triggered by the possibilities that became available about 30 years ago by neutron scattering and synchrotron radiation. Close analogies between NMR spectroscopy and scattering are pointed out to emphasize that the two approaches nicely complement each other. Specific examples applying the new NMR techniques to amorphous polymers and supramolecular systems are described. The findings are related to the mechanical properties of polymers as well as specific functions such as photoconductivity and proton conductivity. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5031,5044, 2004 [source] Hydrogen bond-mediated self-assembly and supramolecular structures of diblock copolymer mixturesPOLYMER INTERNATIONAL, Issue 5 2009Shiao-Wei Kuo Abstract This review summarizes recent advances in the preparation of hydrogen bonding block copolymer mixtures and the supramolecular structures they form through multiple hydrogen bonding interactions. Hydrogen bonding in block copolymer mixtures that form nanostructures and have unusual electronic, photonic and magnetic properties is a topic of great interest in polymer science. Combining the self-assembly of block copolymers with supramolecular structures offers unique possibilities to create new materials with tunable and responsive properties. The self-assembly of structures from diblock copolymer mixtures in the bulk state is readily controlled by varying the weight fraction of the block copolymer mixture and the copolymer composition; in solution, the morphologies are dependent on the copolymer composition, the copolymer concentration, the nature of the common solvent, the amount of the selective solvent and, most importantly, the hydrogen bonding strength. Copyright © 2008 Society of Chemical Industry [source] Contribution of polymer chemistry to dentistry: development of an impermeable interpenetrating polymer network to protect teeth from acid demineralizationPOLYMER INTERNATIONAL, Issue 2 2008Nobuo Nakabayashi The purpose of this review article is to show how polymer science can contribute to the further improvement of modern dentistry. It has long been believed that the development of strong dental materials is essential to improve dentistry, and polymeric materials might not be reliable compared to metals and ceramics. It was hypothesized that the bonding of restoration materials to the tooth structure is required in order to inhibit the detachment of prostheses. However, bonding of artificial materials to natural tissues is difficult. It has been found that a polymer network interpenetrated with dental hard tissues resolves this problem, that formal bonding is not required and that protection of prepared dentin against lactic acid demineralization with an impermeable barrier is a requisite for prevention of caries. Copyright © 2007 Society of Chemical Industry [source] Foreword: polymer science in Queensland,celebrating forty years of researchPOLYMER INTERNATIONAL, Issue 11 2003Professor Franēois Schue Editor-in-Chief No abstract is available for this article. [source] Fluorophores as Optical Sensors for Local Forces,CHEMPHYSCHEM, Issue 12 2009Stefan Marawske Abstract The main aim of this study is to investigate correlations between the impact of an external mechanical force on the molecular framework of fluorophores and the resultant changes in their fluorescence properties. Taking into account previous theoretical studies, we designed a suitable custom-tailored oligoparaphenylenevinylene derivative (OPV5) with a twisted molecular backbone. Thin foils made of PVC doped with 100 nM OPV were prepared. By applying uniaxial force, the foils were stretched and three major optical effects were observed simultaneously. First, the fluorescence anisotropy increased, which indicates a reorientation of the fluorophores within the matrix. Second, the fluorescence lifetime decreased by approximately 2.5,% (25 ps). Finally, we observed an increase in the emission energy of about 0.2,% (corresponding to a blue-shift of 1.2 nm). In addition, analogous measurements with Rhodamine 123 as an inert reference dye showed only minor effects, which can be attributed to matrix effects due to refractive index changes. To relate the observed spectroscopic changes to the underlying changes in molecular properties, quantum-chemical calculations were also performed. Semiempirical methods had to be used because of the size of the OPV5 chromophore. Two conformers of OPV5 (C2 and Cisymmetry) were considered and both gave very similar results. Both the observed blue-shift of fluorescence and the reduced lifetime of OPV5 under tensile stress are consistent with the results of the semiempirical calculations. Our study proves the feasibility of fluorescence-based local force probes for polymers under tension. Improved optical sensors of this type should in principle be able to monitor local mechanical stress in transparent samples down to the single-molecule level, which harbors promising applications in polymer science and nanotechnology. [source] Design of Gold Nanoparticle-Based Colorimetric Biosensing AssaysCHEMBIOCHEM, Issue 15 2008Weian Zhao Abstract Gold nanoparticle (AuNP)-based colorimetric biosensing assays have recently attracted considerable attention in diagnostic applications due to their simplicity and versatility. This Minireview summarizes recent advances in this field and attempts to provide general guidance on how to design such assays. The key to the AuNP-based colorimetric sensing platform is the control of colloidal AuNP dispersion and aggregation stages by using biological processes (or analytes) of interest. The ability to balance interparticle attractive and repulsive forces, which determine whether AuNPs are stabilized or aggregated and, consequently, the color of the solution, is central in the design of such systems. AuNP aggregation in these assays can be induced by an "interparticle-crosslinking" mechanism in which the enthalpic benefits of interparticle bonding formation overcome interparticle repulsive forces. Alternatively, AuNP aggregation can be guided by the controlled loss of colloidal stability in a "noncrosslinking-aggregation" mechanism. In this case, as a consequence of changes in surface properties, the van der Waals attractive forces overcome interparticle repulsive forces. Using representative examples we illustrate the general strategies that are commonly used to control AuNP aggregation and dispersion in AuNP-based colorimetric assays. Understanding the factors that play important roles in such systems will not only provide guidance in designing AuNP-based colorimetric assays, but also facilitate research that exploits these principles in such areas as nanoassembly, biosciences and colloid and polymer sciences. [source] | |||||||||||||