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Perpendicular
Kinds of Perpendicular Terms modified by Perpendicular Selected AbstractsEnergetic materials: variable-temperature crystal structure of ,-NTOJOURNAL OF APPLIED CRYSTALLOGRAPHY, Issue 2 2003Nadezhda B. Bolotina The crystal structure of the metastable , form of 5-nitro-2,4-dihydro-3H -1,2,4-triazol-3-one (,-NTO, monoclinic, P21/c) has been investigated at five temperatures in the range 100,298,K using single-crystal X-ray diffraction techniques. The second-rank thermal expansion tensor has been determined to describe thermal behavior of the crystal. The most significant thermal expansion is in a plane, which is almost perpendicular to the planes of all the NTO molecules. Perpendicular to the plane of maximal thermal expansion, a modest thermal contraction takes place. Both thermal expansion and contraction of the crystal lattice indicate anharmonicity of the atomic thermal motion. The experimental thermal variation of the unit-cell parameters is in qualitative agreement with that previously obtained from molecular dynamics calculations. Rigid-body analysis of the molecular thermal motion was performed using the libration and translation second-rank tensors. Although the translation part of the thermal motion is not strongly anisotropic, the largest displacements of the NTO molecules are oriented in the plane of maximal thermal expansion of the crystal and have significant anharmonic components. The libration motion is more anisotropic, and the largest libration as well as the largest translation principal axes are directed along the C5,N5 bond in each NTO molecule. [source] ChemInform Abstract: New Crystalline Layered Zinc Phosphate with 10-Membered-Ring Channels Perpendicular to Layers.CHEMINFORM, Issue 34 2009Zhi Lin Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source] ChemInform Abstract: Parallel (Face-to-Face) versus Perpendicular (Edge-to-Face) Alignment of Electron Donors and Acceptors in Fullerene Porphyrin Dyads: The Importance of Orientation in Electron Transfer.CHEMINFORM, Issue 3 2002Dirk M. Guldi Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source] Proposing magnetic nanoparticle hyperthermia in low-field MRICONCEPTS IN MAGNETIC RESONANCE, Issue 1 2010Pádraig Cantillon-Murphy Abstract This work examines feasibility, practical advantages, and disadvantages of a combined MRI/magnetic particle hyperthermia (MPH) system for cancerous tumor treatment in low perfusion tissue. Although combined MRI/hyperthermia systems have been proposed and constructed, the current proposal differs because the hyperthermia system would be specifically designed to interact with the magnetic nanoparticles injected at the tumor site. The proposal exploits the physical similarities between the magnetic nanoparticles currently employed for MPH and those used as superparamagnetic iron oxide (SPIO) contrast agents in MR imaging. The proposal involves the addition of a rotating magnetic field RF hyperthermia source perpendicular to the MRI B0 field which operates in a similar manner to the MRI RF excitation field, B1, but at significantly higher frequency and field strength such that the magnetic nanoparticles are forced to rotate in its presence. This rotation is the source of increases in temperature which are of therapeutic benefit in cancer therapy. For rotating magnetic fields with amplitudes much smaller than B0, the nanoparticles' suspension magnetization rapidly saturates with increasing B0. Therefore, the proposal is best suited to low-field MRI systems when magnetic saturation is incomplete. In addition, careful design of the RF hyperthermia source is required to ensure no physical or RF interference with the B1 field used for MRI excitation. Notwithstanding these caveats, the authors have shown that localized steady-state temperature rises in small spherical tumors of up to 10°C are conceivable with careful selection of the nanoparticle radius and concentration, RF hyperthermia field amplitude and frequency. © 2010 Wiley Periodicals, Inc. Concepts Magn Reson Part A 36A: 36,47, 2010. [source] The hydrogen atom, revisited: Parallel-field magnetic resonance,CONCEPTS IN MAGNETIC RESONANCE, Issue 5 2006John A. Weil Abstract Consideration of the magnetic resonance spectroscopy of the free hydrogen atom (1H0) reveals that, in addition to the well-known transitions (EPR and NMR) occurring between the four spin states when the excitation magnetic field B1 is perpendicular to the static external field B, there exists a combination line (simultaneous electronic and nuclear spin flips) when B1 , B, which becomes strong under some circumstances. The latter phenomenon is focused on and discussed herein, in some detail. © 2006 Wiley Periodicals, Inc. Concepts Magn Reson Part A 28A: 331,336, 2006 [source] ECCD Experiments Using the Upgraded Launching System in Heliotron JCONTRIBUTIONS TO PLASMA PHYSICS, Issue 6-7 2010K. Nagasaki Abstract Electron cyclotron current drive (ECCD) experiments have been made in Heliotron J by using an upgraded EC launching system. A focused Gaussian beam is injected with the parallel refractive index, N||, ranging from -0.05 to 0.6. Ray tracing calculation shows that the EC power is more localized than that in the previous launching system. In the initial ECCD experiment, the EC injection angle has been successfully scanned as designed. Comparison between perpendicular and oblique launching experiments shows that for standard configuration, the EC current of 1 kA is driven at N|| , 0.3 in the Fisch-Boozer direction, and the bootstrap current flows up to 1 kA. A large increase in electron cyclotron emission (ECE) signals has been observed when the EC current was driven (© 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Epitaxial Sn1-xPbxS nanorods on iso-compositional thin filmsCRYSTAL RESEARCH AND TECHNOLOGY, Issue 6 2010K. Bente Abstract Based on SnS (Herzenbergite) , SnPbS2 (Teallite) mixed crystals with orthorhombic layer structures, thin films and lawns of Sn1-xPbxS nanorods were produced using hot wall vacuum deposition method (HWVD). The lawn was formed onto the surface of an underlying thin Sn1-xPbxS film which is build by differently oriented blocks. The density of rods arranged like a lawn depends on the metal ratio and substrate temperature. X-ray and TEM analysis of the epitaxial material showed preferential (001) orientation perpendicular to the surface of the glass substrate. The roughness of the films measured by atomic force microscopy was in the range of Rq = 49.5,86.3 nm depending on lead concentration The rods were about 500 nm high and 300 nm in diameter. As revealed by TEM-EDX experiments the droplet at the tip of rods consists of tin. Therefore it is assumed the rods grew via a self-consuming vapor,liquid,solid (VLS) mechanism. (© 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Growth and optical characterization of Cd1- xBexSe and Cd1- xMgxSe crystalsCRYSTAL RESEARCH AND TECHNOLOGY, Issue 4-5 2005F. Firszt Abstract Cd1- xBexSe and Cd1- xMgxSe solid solutions were grown from the melt by the high pressure Bridgman method. Optical, luminescence and photothermal properties of these materials were investigated. Spectroscopic ellipsometry was applied for determination of the spectral dependence of the complex dielectric function (E) and refractive index n(E) at room temperature in the photon energy range 0.75-6.5 eV for samples with optic axis (c-axis) perpendicular to the air-sample interface. The critical point (CP) parameters for E0 and E1 transitions were determined using a standard excitonic CP function to fit the numerically calculated differential spectra ,2,2/,E2. The dispersion of the refractive index of the alloys was modelled using a Sellmeier-type relation. The values of fundamental and exciton band-gap energies were estimated from the ellipsometric and photoluminescence measurements. The origin of luminescence in Cd1- xBexSe and Cd1- xMgxSe was discussed. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Growth and characterization of LiCaGaF6CRYSTAL RESEARCH AND TECHNOLOGY, Issue 1-2 2005E. Sani Abstract Optically clear LiCaGaF6 (LiCGaF) single crystals up to 15 mm length were grown by the Czochralski method from CaF2 deficient melts. The substance melts incongruently at 751 °C. No significant deviations of the crystal composition from the nominal stoichiometry Li:Ca:Ga=1:1:1 could be found. X-ray structure analysis revealed that the substance crystallizes in the colquiriite type structure. LiCaGaF6 is transparent for optical wavelengths >140 , 150 nm. The thermal expansion of the trigonal crystals is ,11 = ,22 = 18.7×10 -6 K -1 perpendicular [001] and ,33 = 2.7×10 -6 K -1 parallel [001]. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Growth of bismuth tri-iodide platelets by the physical vapor deposition methodCRYSTAL RESEARCH AND TECHNOLOGY, Issue 10 2004A. Cuńa Abstract The work reports the growth of single BI3 crystals with platelets habit. Platelets were grown by physical vapor deposition (PVD) in a high vacuum atmosphere and with argon, polymer or iodine as additives. Crystals grew in the zone of maximum temperature gradient, perpendicular to the ampoule wall. Crystals grown with argon as additive show a very shining surface, have hexagonal (0 0 l) faces, sizes up to 20 x 10 mm2 and thicknesses up to 100 ,m. They were characterized by optical microscopy and scanning electron microscopy (SEM). Dendritic-like structures were found to be their main surface defect. SEM indicates that they grow from the staking of hexagonal unities. Electrical properties of the crystals grown under different growth conditions were determined. Resistivities up to 2 x 1012 ,cm (the best reported value for monocrystals of this material) were obtained. X-ray response was measured by irradiation of the platelets with a 241Am source of 3.5 mR/h. A comparison of results according to the growth conditions was made. Properties of the crystals grown by this method are compared with the ones measured for others previously grown from the melt. Also, results for bismuth tri-iodide platelets are compared with the ones obtained for mercuric and lead iodide platelets. (© 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] The geometry and motion of nematode sperm cellsCYTOSKELETON, Issue 6 2009Evgeny Demekhin Abstract The nematode sperm cell crawls by recycling major sperm protein (MSP) from dimers into subfilaments, filaments, and filament complexes, as a result of thermal writhing in the presence of hydrophobic patches. Polymerization near leading edges of the cell intercolates MSP dimers onto the tips of growing filament complexes, forcing them against the cell boundary, and extending the cytoskeleton in the direction of motion. Strong adhesive forces attach the cell to the substrate in the forward part of the lamellipod, while depolymerization in the rearward part of the cell breaks down the cytoskeleton, contracting the lamellipod and pulling the cell body forward. The movement of these cells, then, is caused by coordinated protrusive, adhesive and contractile forces, spatially separated across the lamellipod. This paper considers a phenomenological model that tracks discrete elements of the cytoskeleton in curvilinear coordinates. The pseudo-two dimensional model primarily considers protrusion and rotation of the cell, along with the evolution of the cell boundary. General assumptions are that pH levels within the lamellipod regulate protrusion, contraction and adhesion, and that growth of the cytoskeleton, over time, is perpendicular to the evolving cell boundary. The model follows the growth and contraction of a discrete number of MSP fiber complexes, since they appear to be the principle contributors for force generation in cell boundary protrusion and contraction, and the backbone for the dynamic geometry and motion. Cell Motil. Cytoskeleton 2009. © 2009 Wiley-Liss, Inc. [source] Postembryonic development of the cranial lateral line canals and neuromasts in zebrafishDEVELOPMENTAL DYNAMICS, Issue 3 2003Jacqueline F. Webb Abstract The development of the cranial lateral line canals and neuromast organs are described in postembryonic zebrafish (0,80 days postfertilization). Cranial canal development commences several weeks after hatch, is initiated in the vicinity of individual neuromasts, and occurs in four discrete stages that are described histologically. Neuromasts remain in open canal grooves for several weeks during which they dramatically change shape and increase in size by adding hair cells at a rate one-tenth that in the zebrafish inner ear. Scanning electron microscopy demonstrates that neuromasts elongate perpendicular to the canal axis and the axis of hair cell polarization and that they lack a prominent nonsensory cell population surrounding the hair cells,features that make zebrafish neuromasts unusual among fishes. These results demand a reassessment of neuromast and lateral line canal diversity among fishes and highlight the utility of the lateral line system of postembryonic zebrafish for experimental and genetic studies of the development and growth of hair cell epithelia. Developmental Dynamics, 2003. © 2003 Wiley-Liss, Inc. [source] BIODIVERSITY RESEARCH: Population expansion in an invasive grass, Microstegium vimineum: a test of the channelled diffusion modelDIVERSITY AND DISTRIBUTIONS, Issue 5 2010Nathaniel P. Miller Abstract Aim, The greatest biodiversity impact of non-native plant species is caused by rapid expansion of colonist populations. Unfortunately, invasion has rarely been documented in real time at a population scale, and demographic mechanisms of invasion remain unclear. Our goal is to describe real-time expansion of populations, using channelled diffusion as a null model. Location, The study examined three populations of the invasive annual grass Microstegium vimineum in mature second-growth forests of south-eastern Ohio and nearby West Virginia, USA. Methods, Distributions were recorded in belt transects perpendicular to population edges over a period of 3 years. A second group of belt transects documented spread along five types of potential movement corridor. Observed changes in distribution were compared with predictions from a diffusion model. A seed-sowing experiment tested seed availability, microsite quality and proximity to potential movement corridors as factors controlling population spread. Results, Population boundaries showed little change over the study period. Colonization was limited by propagule availability over distances as little as 0.25 m, and to a lesser extent by litter cover. Populations did not advance along several potential movement corridors including unpaved roads, off-road vehicle trails and footpaths. Advance was observed along deer trails and stream courses but did not conform to the wave-form distribution predicted by diffusion theory. During the study, seeds were moved out of experimental plots by sheet flow and minor flooding events along small streams. Main conclusion, At a population level, invasion is driven by processes that are episodic in time and non-random in space , probably a common condition in non-native plant species. Spatially realistic models are likely to be more useful than diffusive models in managing invasions at these scales. [source] A new specimen of Baphetes from Ný,any, Czech Republic and the intrinsic relationships of the BaphetidaeACTA ZOOLOGICA, Issue 2009Angela C. Milner Abstract ,Loxomma'bohemicum from the Upper Carboniferous assemblage from Ný,any, Czech Republic, is a nomen dubium restricted to the type and only specimen. The new binomen Baphetes orientalis is created for a skull referred to Baphetes bohemicus by later authors. A previously undescribed baphetid specimen from Ný,any is referred to B. orientalis despite differences in skull proportions. It comprises a skull in dorsal aspect, mandibles and some associated postcranial elements. The skull possesses sclerotic ring elements within the orbital region of the dorsal fenestration of the skull, confirming the eye location. The elongate gastralia are arranged perpendicular to the interclavicle edge in contrast to the condition in temnospondyls and colosteids. Cladistic analysis of 24 characters of 11 baphetoids was carried out using Acanthostega and Crassigyrinus as outgroups. Eucritta was the most primitive baphetoid, with Spathicephalus being the sister-taxon to the remaining taxa, justifying a monotypic Spathicephalidae as a sister-taxon to the Baphetidae. The Baphetidae are divided into a subfamily Baphetinae nom.nov. containing two Baphetes species; and a subfamily Loxommatinae with Loxomma as a paraphyletic grade leading to a Megalocephalus +Kyrinion clade. The Linton taxon ,Baphetes' lintonensis is transferred to the genus Loxomma to give the new combination Loxomma lintonensis. [source] Organization and mode of secretion of the granular prismatic microstructure of Entodesma navicula (Bivalvia: Mollusca)ACTA ZOOLOGICA, Issue 2 2009Elizabeth M. Harper The term homogeneous has been applied to molluscan microstructures that lack a readily discernible microstructure and as a result, it has become rather a ,dustbin' term, covering a multitude of unrelated finely crystalline textures. Here we investigate in detail the outer ,homogeneous' layer of the lyonsiid bivalve Entodesma navicula. The apparently equigranular crystals (up to 10 µm) are, in fact, short prisms which grow in a dense organic matrix with their c -axes and fibre axes coincident, perpendicular to the growth surface. These prisms are distinct from the aragonitic prisms grown by other bivalves in both their morphology and their mode of growth and so we propose the term granular prismatic microstructure. The organic content of granular prisms (7.4%) is the highest yet recorded for any molluscan microstructure and it is apparent that the short prisms have grown within a gel-filled space. Although this high organic content is likely to make the microstructure metabolically expensive to produce, it has the benefit of making the valves very flexible. This may be advantageous in the intertidal zone inhabited by E. navicula by allowing a tight seal between the valves. [source] Flume experiments on the horizontal stream offset by strike-slip faultsEARTH SURFACE PROCESSES AND LANDFORMS, Issue 2 2004Shunji OuchiArticle first published online: 4 FEB 200 Abstract Flume experiments, in which the middle section of an erosion channel is displaced horizontally, have been conducted to assess the response of streams to horizontal displacement by a strike-slip fault. The experimental erosion channel was developed in a mixture of sand and clay, which provided relatively stable banks with its cohesiveness. Horizontal displacement of a strike-slip fault perpendicular to the channel is expected to add a ,at section to its longitudinal pro,le along the fault line. The experimental stream eliminated this ,at section with downstream degradation, upstream aggradation, and lateral channel shift. As a result, a roughly continuous longitudinal pro,le was maintained. This maintenance of a continuous longitudinal pro,le along channel is considered to be the principle of stream response to horizontal displacement by a strike-slip fault. Downstream degradation was the dominant process of this stream response in the overall tendency of erosion without sand supply. When the rate of fault displacement was low (long recurrence interval), the experimental stream eroded the fault surface, jutting laterally into the channel like a scarp, and de,ected the channel within the recurrence interval. This lateral channel shift gave some gradient to the reach created by fault displacement (offset reach), and the downstream degradation occurred as much as completing the remaining longitudinal pro,le adjustment. When the rate of fault displacement was high (short recurrence interval), the lateral erosion on the ,rst fault surface was interrupted by the next fault displacement. The displacement was then added incrementally to the existing channel offset making channel shift by lateral erosion increasingly dif,cult. The channel offset with sharp bends persisted without much modi,cation, and downstream degradation and upstream aggradation became evident with the effect of the offset channel course, which worked like a dam. In this case, a slight local convexity, which was incidentally formed by downstream degradation and upstream aggradation, tended to remain in the roughly continuous longitudinal pro,le, as long as the horizontal channel offset persisted. In either case, once the experimental stream obtained a roughly continuous gradient, further channel adjustment seemed to halt. Horizontal channel offset remained to a greater or lesser extent at the end of each run long after the last fault displacement. Copyright © 2004 John Wiley & Sons, Ltd. [source] Behavior of moment-resisting frame structures subjected to near-fault ground motionsEARTHQUAKE ENGINEERING AND STRUCTURAL DYNAMICS, Issue 6 2004Babak Alavi Abstract Near-fault ground motions impose large demands on structures compared to ,ordinary' ground motions. Recordings suggest that near-fault ground motions with ,forward' directivity are characterized by a large pulse, which is mostly orientated perpendicular to the fault. This study is intended to provide quantitative knowledge on important response characteristics of elastic and inelastic frame structures subjected to near-fault ground motions. Generic frame models are used to represent MDOF structures. Near-fault ground motions are represented by equivalent pulses, which have a comparable effect on structural response, but whose characteristics are defined by a small number of parameters. The results demonstrate that structures with a period longer than the pulse period respond very differently from structures with a shorter period. For the former, early yielding occurs in higher stories but the high ductility demands migrate to the bottom stories as the ground motion becomes more severe. For the latter, the maximum demand always occurs in the bottom stories. Preliminary regression equations are proposed that relate the parameters of the equivalent pulse to magnitude and distance. The equivalent pulse concept is used to estimate the base shear strength required to limit story ductility demands to specific target values. Copyright © 2004 John Wiley & Sons, Ltd. [source] Assessment of the Tilting Properties of the Human Mitral Valve during Three Main Phases of the Heart Cycle: An Echocardiographic StudyECHOCARDIOGRAPHY, Issue 4 2006Daniel Vanhercke B.N., N.F.E.S.C., R.D.C.S. Rationale and Objectives: In experimental models of the left heart, the mitral valve (MV) is commonly implanted perpendicular to a central axis of the apex/MV. To adapt this to a more correct anatomical model, as well as for further studies of the left ventricle, we created a database of implantation angles of the MV and annulus during three main phases of the heart cycle, based on standard cardiac ultrasound measurements. Materials and Methods: Twenty-eight patients were studied with the standard cardiac ultrasound equipment. From the apical echo window, an anteroposterior (AP) plane and a perpendicular commisure-commisure (CC) plane were generated during three critical moments in the heart cycle: systole (S); diastole early filling (E); and diastole late filling (A). In both planes, the angles between the annular plane and each mitral leaflet, as well as the angle between a theoretical longitudinal axis through the apex and center of the MV orifice and the mitral annulus plane, were measured with a custom-made application of Matlab R14. Results: We observed an inclination of the angle mitral annulus/central left ventricle axis, with its lowest point in the direction of the aortic valve (AP plane) of 85°± 7° in systole (S), 88°± 8° in early diastole (E), and 88°± 7° in late diastole (A). In the CC plane, we observed an almost horizontal implantation of 91°± 5° in systole (S), 91°± 8° in early diastole (E), and 91°± 7° in late diastole (A). [source] Vegetation impacts on near bank flowECOHYDROLOGY, Issue 4 2009Leslie Hopkinson Abstract Vegetation is an important component of stream restoration designs used to control streambank retreat, but vegetation effects on near bank flows need to be quantified. The goal of this research was to evaluate how three-dimensional velocity structure and turbulence characteristics vary with three vegetation treatments: tree, shrub and grass. A second order prototype stream (Tom's Creek in Blacksburg, Virginia, USA) with individual reaches dominated by each vegetation treatment was modelled in a research flume using a fixed-bed Froude-scale modelling technique. One model streambank of the prototype stream was constructed for each vegetation type and compared to a bare control (only grain roughness). Velocity profiles perpendicular to the flume model boundary were measured using a three-dimensional acoustic Doppler velocimeter. Three-dimensional velocity records, turbulent kinetic energy characteristics, and Reynolds stresses were analysed. The addition of vegetation on a sloping streambank increased the free stream streamwise velocity as compared to a bare streambank. Velocity in the downstream direction decreased in the area close to the streambank boundary for all vegetation treatments. Tree turbulence intensity and Reynolds stress distributions were similar to the bare condition due to the sparse tree placement characteristic of mature forests. The turbulence caused by the upright shrub treatment increased turbulent kinetic energy and Reynolds stresses near the streambank, particularly at the toe. The flexible grass vegetation folded and protected the streambank, reducing shear stress near the boundary. Copyright © 2009 John Wiley & Sons, Ltd. [source] Slit effect of common ground patterns in affecting crosstalk noise between two parallel signal traces on printed circuit boardsELECTRONICS & COMMUNICATIONS IN JAPAN, Issue 10 2010Tsuyoshi Maeno Abstract It is well known that electromagnetic (EM) disturbances in vehicle-mounted radios are mainly caused by conducted noise currents flowing through wiring harnesses from vehicle-mounted printed circuit boards (PCBs) having common ground patterns with slits. To evaluate the noise current outflows from PCBs of this kind, we previously measured noise current outflows from four types of simple three-layer PCBs having two perpendicular signal traces and different ground patterns with or without slits, and showed that slits on a ground pattern allow conducted noise currents to flow out from PCBs, while the levels for the symmetric slit ground type are smaller than in the case of two asymmetric slit ground types. In the present study, to further investigate the above finding, we fabricated six types of simple two-layer PCBs having two parallel signal traces and different ground patterns with and without slits, and measured the crosstalk noise between the traces. We found that the ground patterns with the slits perpendicular to the traces increased the crosstalk noise levels, which were 19 to 42 dB larger than those for the ground pattern with no slits, while the ground patterns with the slits parallel to the traces were able to reduce the noise levels, which were slightly smaller (by 2.5 to 4.5 dB) than in the case of the no-slit ground pattern. These results were confirmed by FDTD simulation, and were also qualitatively explained by means of an equivalent bridge circuit model that we previously proposed. © 2010 Wiley Periodicals, Inc. Electron Comm Jpn, 93(10): 19,24, 2010; Published online in Wiley Online Library (wileyonlinelibrary.com). DOI 10.1002/ecj.10287 [source] Behaviour of male pine sawflies, Neodiprion sertifer, released downwind from pheromone sourcesENTOMOLOGIA EXPERIMENTALIS ET APPLICATA, Issue 2 2000Fredrik Östrand Abstract This study investigated the behaviour of male European pine sawflies, Neodiprion sertifer Geoffroy (Hym., Diprionidae), that were released and observed downwind from pheromone traps baited with 100 ,g of the sex pheromone, (2S,3S,7S)-3,7-dimethyl-2-pentadecyl acetate. Releases were done at three distances; either at 5 m from one trap, or at 50 or 200 m from five traps, placed in a line perpendicular to the current wind direction. As control, males were released identically but without any pheromone source present. The behaviour of the males prior to take-off was studied. A total of 1729 males were released, and 80% of them took flight. Males took off significantly faster in the presence of pheromone. Grooming was significantly more frequent in presence of pheromone compared with control. In all pheromone experiments significantly more males displayed grooming, wing fanning and take-off towards the wind compared with the control. Weather data was simultaneously collected at the study site. Wing fanning was negatively correlated with wind speed. Grooming was not influenced by wind speed. Reduced levels of incoming short-wave radiation lowered the take-off frequency significantly. Pheromone-induced behaviour in diprionids seems to be less distinct than in other insects, e.g., Lepidoptera. [source] Risk Assessment and Withdrawal Behavior by Two Species of Aposematic Poison Frogs, Dendrobates auratus and Oophaga pumilio, on Forest TrailsETHOLOGY, Issue 4 2009William E. Cooper Jr Many chemically defended prey advertize toxicity to predators by aposematic coloration. When aposematic prey are approached, they often move slowly or not at all, allowing predators to evaluate their unprofitability. Poison frogs (Dendrobatidae) are toxic, aposematically colored, forage openly and diurnally, and are much easier to capture than many palatable frogs. Although protected against diverse predators, they are sometimes attacked and are subjected to injury by large animals without predatory intent. We predicted that they have limited escape behavior, but retain ability to assess and respond to risk. When we approached Dendrobates auratus and Oophaga pumilio on forest trails, both species hopped by the shortest route to the nearer forest edge and stopped there. When approached, D. auratus moved after shorter latency at an angle closer to perpendicular to the forest edge, were more likely to leave the trail, and left the trail sooner with fewer changes in direction after moving a shorter distance than when not approached. In agreement with predictions of optimal escape theory based on risk, flight initiation distance by D. auratus was greater when approached directly than indirectly and rapidly than slowly, and was greater when frogs were in the open than partially concealed. Frogs neither attempted rapid escape nor entered refuges. Both species hopped leisurely and remained visible after stopping. They exhibit the diminished escape behavior of aposematic prey, yet retain the capacity to assess risk and adjust behavior accordingly. Their behavior demonstrates continued need for escape behavior by highly toxic aposematic prey. [source] O -Acylated 2-Phosphanylphenol Derivatives , Useful Ligands in the Nickel-Catalyzed Polymerization of EthyleneEUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 9 2009Dmitry G. Yakhvarov Abstract The title ligands were prepared by O -acylation of 2-diphenylphosphanyl-4-methylphenol (1) or directly by double lithiation of 2-bromo-4-methylphenol and stepwise coupling with ClPPh2 and ClP(O)Ph2 or RC(O)Cl (R = Me, tBu, Ph, 4-MeOC6H4) to afford diphenylphosphinate 2 and carboxylic esters 3a,d. X-ray crystal structure analyses of 3b,d show conformations in which the P -phenyl substituents are rotated away from the ester group and the C(O)O , planes are nearly perpendicular to the phenol ring , plane. O -Acylated phosphanylphenols 2 and 3a,d form highly active catalysts with Ni(1,5-cod)2 (as does 1) for polymerization of ethylene, whereas phosphanylphenyl ethers do not give catalysts under the same conditions. The reason is the cleavage of the O -acyl bond upon heating with nickel(0) precursor compounds in the presence of ethylene. The precursors are P-coordinated Ni0 complexes, which are formed at room temperature, such as 4d obtained from 3d and Ni(cod)2 (in a 2:1 molar ratio), and characterized by multinuclear NMR spectroscopy. Upon heating in the presence of ethylene, the precatalysts are activated. Catalysts 2Ni and 3a,dNi convert ethylene nearly quantitatively, 2Ni slowly, and 3a,dNi rapidly, into linear polyethylene with vinyl and methyl end groups, and in the latter case, C(O)R end groups are also detectable. This proves insertion of Ni0 into the O,C(O)R bond of 3a,d ligands for formation of the primary catalyst. Termination of the first chain growing cycle by ,-hydride elimination changes the mechanism to the phosphanylphenolate,NiH initiated polymerization providing the main body of the polymer. A small retardation in the ethylene consumption rate with 3a,dNi catalysts relative to that observed for 1Ni and stabilization of the catalyst, which gives rise to reproducibly high ethylene conversion, is observed. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009) [source] NMR Study of L-Shaped (Quinoxaline)platinum(II) Complexes , Crystal Structure of [Pt(DMeDPQ)(bipy)](PF6)2EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 23 2004Enrico Rotondo Abstract A 1H and 13C NMR study of nine PtII complexes of DMeDPQ [6,7-dimethyl-2,3-bis(2-pyridyl)quinoxaline] and BDPQ [2,3-bis(2-pyridyl)benzo[g]quinoxaline], and the crystal structure of one of them, are reported. The results are consistent with Cs symmetry of "L-shaped square-planar complexes". The rigid seven-membered chelated quinoxaline ligand holds the fused aromatic rings nearly perpendicular to the PtII coordination plane, generating the peculiar L-shaped structure. Ancillary ligands in the residual coordination sites are: a) bidentate flexible-planar 2,2,-bipyridine (bipy; complexes 1 and 2); b) bidentate rigid-planar dipyrido[3,2- a:2,3,- c]phenazine (dppz) or benzo[b]dipyrido[3,2- h:2,,3,- j]phenazine (bdppz; complexes 3,6); or c) 3-substituted monodentate pyridines (3-Rpy; complexes 7,9). The L-shaped geometry has been exploited to gain insight into the steric and dynamic features that regulate the noncovalent interactions of these square-planar complexes with DNA. We have shown previously, for [Pt(bipy)(n -Rpy)2]2+, that bipy twisting can be frozen out on the NMR timescale below 260 K. Preservation of the Cs symmetry at low temperature indicates a lack of bipy fluxionality within these L-shaped structures. The static butterfly-like symmetric orientation of the quinoxaline pyridyl rings accounts for the hampered twisting of Pt(bipy), which is otherwise assisted by the synchronous "windscreen wiper" conrotatory rocking of the ancillary pyridine rings. The L-geometry can also be used to monitor the ancillary n -Rpy rotation by NMR spectroscopy. The quasi-vertical quinoxaline pyridyl rings alignment leave room in the coordination plane for the crossing of the opposite pyridine rings, thereby reducing their rotational barriers about the Pt,N bond. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004) [source] Reactivity of Organoelement Subhalides of Gallium and Indium , Ga,Ga and In,In Bonds Bridged by Carboxylato LigandsEUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 5 2004Werner Uhl Abstract The organoelement subhalides R2Ga2I2 (5) and R3In3I2 [6; R = C(SiMe3)3] reacted with silver benzoate AgOOCC6H5 to yield the dicarboxylato dielement compounds R2E2(µ-OOCC6H5 - O,O,)2 (7, E = Ga; 8, E = In). Both compounds possess E,E single bonds bridged by the chelating carboxylato ligands. The chelating groups are arranged perpendicular to one another. Owing to the small bite of the carboxylato group very short E,E bond lengths of 240.5 pm (Ga,Ga) and 265.4 pm (In,In) were observed. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004) [source] Ferromagnetism in [Mn(Cp*)2]+ -Derived Complexes: the "Miraculous" Stacking in [Mn(Cp*)2][Ni(dmit)2]EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 15 2003Christophe Faulmann Abstract The synthesis and characterisation (X-ray structure and magnetism) of metal complexes (Ni, Au) with the [Mn(Cp*)2]+ cation and the dmit2, and dmid2, ligands are reported. [Mn(Cp*)2][Ni(dmit)2] (1) and [Mn(Cp*)2][Au(dmit)2] (2) exhibit the same structural arrangement, built on stacks of [Ni(dmit)2], pairs separated by two [Mn(Cp*)2]+ cations, showing a ···D+D+A,A,D+D+A,A,··· motif. On the contrary, the dmid2, derivative [Mn(Cp*)2][Ni(dmid)2]·CH3CN (3) exhibits a totally different structure, built on mixed layers composed of one [Ni(dmid)2], unit separated by two [Mn(Cp*)2]+ cations, showing a ···D+D+A,D+D+A,···motif. The layers are separated from each other by perpendicular [Ni(dmid)2], units and solvent molecules. Compound 2 exhibits antiferromagnetic interactions, whereas 1 and 3 exhibit ferromagnetic interactions at low temperature. Moreover, as confirmed by AC and DC magnetic susceptibility measurements, 1 is a ferrimagnet, the first ever derived from a 1,2-bis-dithiolene ligand. The ferromagnetic interactions in 1 and 3 are explained using the McConnell I mechanism. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003) [source] Study on Crack-like Pores of Al Foams Made via the Powder-Metallurgy Route,ADVANCED ENGINEERING MATERIALS, Issue 1-2 2010Lei Wang Mechanisms for the formation and disappearance of the crack-like pores generated during the early stage of Al foaming are investigated. A model for their disappearance process is proposed for the first time. The stress, perpendicular to the compaction direction in uniaxial cold compaction, is caused by the interaction of the Al powder under a high compaction pressure and is the main reason for the formation of the crack-like pores. The results of the model analysis and theoretical calculations suggest that the pressure difference ,P between the initial, round bubbles and the crack-like pores is the driving force for their disappearance. The rapid reduction of ,P is attributed to the decomposition characteristics of the TiH2 powder. [source] Two-dimensional finite element thermal modeling of an oil-immersed transformerEUROPEAN TRANSACTIONS ON ELECTRICAL POWER, Issue 6 2008Jawad Faiz Abstract Finite element (FE) modeling of a typical transformer indicates that the hot spot position is always on the top most part of the transformer. The hot spot temperature of winding depends on the load and the type of loading and is changed by loading. A number of the generated magnetic flux lines of windings close to their paths perpendicular to the internal channel of the windings and therefore the flux density in the middle of the channel is considerably larger than the beginning and ending of the winding. Two models of windings are employed and different temperature distributions are obtained. The computation results show that the time constant of high voltage (HV) winding is lower than that of the low voltage (LV) winding. A good agreement between the test and computed results has been achieved. Copyright © 2007 John Wiley & Sons, Ltd. [source] Hierarchical ZnS-In2S3 -CuS Nanospheres with Nanoporous Structure: Facile Synthesis, Growth Mechanism, and Excellent Photocatalytic ActivityADVANCED FUNCTIONAL MATERIALS, Issue 19 2010Yingxuan Li Abstract Without using any templates or surfactants, hierarchical ZnS-In2S3 -CuS nanospheres with nanoporous structure are successfully synthesized via a simple and convenient process. The nanospheres are aggregations of densely packed nanoparticles and nanorods. Different to the oriented attachment (OA) mechanism reported in the literature, the formation of these nanorods is believed to follow a lateral OA mechanism (nanoparticles attach along the direction perpendicular to the crystallographic axes with lateral planes as the juncture) based on the experimental data. This process could be a general phenomenon and would provide a new insight into the OA mechanism. A detailed time-resolved TEM kinetic study of the formation of the complex structure is shown. The dipole mechanism and electric field-induced growth are found to be responsible for the final architecture. Photocatalytic activities for water splitting are investigated under visible-light irradiation (, > 400 nm) and an especially high photocatalytic activity (apparent yield of 22.6% at 420 nm) is achieved by unloaded ZnIn0.25Cu0.02S1.395 prepared at 180 °C for 18 h because of their high crystallinity, large pore volume, and the presence of nanorods with special microstructures. [source] Standing contact fatigue with a cylindrical indenterFATIGUE & FRACTURE OF ENGINEERING MATERIALS AND STRUCTURES, Issue 7 2005J. DAHLBERG ABSTRACT A hardened steel cylinder was repeatedly pressed against a flat case-hardened steel specimen that was equally wide as the cylinder was long. Some contact end effects were noted as a result of limited plastic deformation. A strain gauge on the contact surface, just outside the contact and oriented perpendicular to the cylinder detected a surface strain when the cylinder was loaded. The non-zero surface strain was the result of boundary effects of the finite specimen. Four different types of contact fatigue cracks developed in and below the specimen contact surface. The cracks were named lateral, median, contact end and edge cracks. Changes in the measured surface strain values could be used to determine when the lateral and edge cracks developed. The order in which all four crack types typically developed was determined from optical crack observation at test termination, strain measurements and stress computations. Numerical computations using finite-element (FE) analyses were used to verify the surface strain behaviour due to loading and cracking; to verify contact end effects; crack locations and crack orientation by aid of the Findley multi-axial fatigue criterion. [source] | ||||||||||||||||||||||||||||||||||||||||||||||