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Terms modified by Periodic Selected AbstractsSEASONAL VARIATIONS IN PHYTOPLANKTON COMMUNITIES OF AN EPHEMERAL POND SYSTEM IN SOUTHEASTERN VIRGINIAJOURNAL OF PHYCOLOGY, Issue 2000M.R. Kokolis The Grafton Ponds Natural Area is a 151 hectare preserve in York County, Virginia, approximately 56km north of the City of Norfolk. The preserve contains over 40 ephemeral ponds. These ponds which are filled seasonally by precipitation and groundwater discharge, are typically wet from late fall through late spring or early summer. Pond size varies from 0.1 to 2 ha, and depths range from 4 cm to 3 meters. The first phase of this study was to examine the physical and chemical characteristics of five of these ponds, including pond size and depth, inundation period, water temperature, pH, and phosphate and ammonium concentrations. The second phase, which is currently underway, is to examine the phytoplankton assemblages, relating differences in the phytoplankton populations to the varying physical and chemical characteristics of the ponds. To date, analysis indicates Chlorophytes and Cyanobacteria as dominant groups in the winter and spring with diatoms becoming more abundant in the late summer and fall. Periodic Dinoflagellate blooms also occur. Analysis also indicates rapid turnover of species from month to month. [source] Effect of Noise on T-Wave Alternans Measurement in Ambulatory ECGs Using Modified Moving Average versus Spectral MethodPACING AND CLINICAL ELECTROPHYSIOLOGY, Issue 5 2009RAJA J. SELVARAJ M.D. Background: The modified moving average (MMA) and spectral method (SM) are commonly used to measure T-wave alternans (TWA), but their accuracy has not been compared in ambulatory electrocardiograms (ECGs) where TWA signal-to-noise ratio is low. Our objective was to compare the effect of noise and signal nonstationarity on the accuracy of TWA measurement using MMA versus SM when applied to synthetic and ambulatory ECGs. Methods: Periodic and nonperiodic noise were added to noiseless synthetic ECGs. Simulated TWA (0,20 ,V) was added to synthetic ECGs and ambulatory ECG recordings. TWA was measured using SM and MMA, and the measurement error relative to added TWA was compared. An MMA ratio was used to discriminate TWA signal from noise. Signal nonstationarity was simulated by changing heart rate, TWA magnitude, and TWA phase. Results: With no added TWA, MMA falsely measured TWA in synthetic and ambulatory ECGs, while false measurement was not seen with SM. An MMA ratio > 1.2 eliminated false TWA detection. In the presence of low TWA magnitude (<10 ,V), TWA was overestimated by MMA and underestimated by SM in proportion to the noise level. In synthetic ECGs with periodic noise and 10-,V added TWA, MMA was less accurate than SM. The effects of simulated signal nonstationarity on the TWA magnitude measured with MMA versus SM were similar using a 64-beat analysis window. Conclusions: In the presence of noise, MMA falsely detects or overestimates simulated TWA in ambulatory ECG recordings. In this setting, the proposed MMA ratio improves the specificity of MMA. [source] Unexpected Deformations Induced by Surface Interaction and Chiral Self-Assembly of CoII -Tetraphenylporphyrin (Co-TPP) Adsorbed on Cu(110): A Combined STM and Periodic DFT StudyCHEMISTRY - A EUROPEAN JOURNAL, Issue 38 2010Philip Donovan Abstract In a combined scanning tunnelling microscopy (STM) and periodic density functional theory (DFT) study, we present the first comprehensive picture of the energy costs and gains that drive the adsorption and chiral self-assembly of highly distorted CoII -tetraphenylporphyrin (Co-TPP) conformers on the Cu(110) surface. Periodic, semi-local DFT calculations reveal a strong energetic preference for Co-TPP molecules to adsorb at the short-bridge site when organised within a domain. At this adsorption site, a substantial chemical interaction between the molecular core and the surface causes the porphyrin macrocycle to accommodate close to the surface and in a flat geometry, which induces considerable tilting distortions in the phenyl groups. Experimental STM images can be explained in terms of these conformational changes and adsorption-induced electronic effects. For the ordered structure we unambiguously show that the substantial energy gain from the molecule,surface interaction recuperates the high cost of the induced molecular and surface deformations as compared with gas phase molecules. Conversely, singly adsorbed molecules prefer a long-bridge adsorption site and adopt a non-planar, saddle-shape conformation. By using a van der Waals density functional correction scheme, we found that the intermolecular ,,, interactions make the distorted conformer more stable than the saddle conformer within the organic assembly. These interactions drive supramolecular assembly and also generate chiral expression in the system, pinning individual molecules in a propeller-like conformation and directing their assembly along non-symmetric directions that lead to the coexistence of mirror-image chiral domains. Our observations reveal that a strong macrocycle,surface interaction can trigger and stabilise highly unexpected deformations of the molecular structure and thus substantially extend the range of chemistries possible within these systems. [source] The embedded ion method: A new approach to the electrostatic description of crystal lattice effects in chemical shielding calculationsCONCEPTS IN MAGNETIC RESONANCE, Issue 5 2006Dirk Stueber Abstract The nuclear magnetic shielding anisotropy of NMR active nuclei is highly sensitive to the nuclear electronic environment. Hence, measurements of the nuclear magnetic shielding anisotropy represent a powerful tool in the elucidation of molecular structure for a wide variety of materials. Quantum mechanical ab initio nuclear magnetic shielding calculations effectively complement the experimental NMR data by revealing additional structural information. The accuracy and capacity of these calculations has been improved considerably in recent years. However, the inherent problem of the limitation in the size of the systems that may be studied due to the relatively demanding computational requirements largely remains. Accordingly, ab initio shielding calculations have been performed predominantly on isolated molecules, neglecting the molecular environment. This approach is sufficient for neutral nonpolar systems, but leads to serious errors in the shielding calculations on polar and ionic systems. Conducting ab initio shielding calculations on clusters of molecules (i.e., including the nearest neighbor interactions) has improved the accuracy of the calculations in many cases. Other methods of simulating crystal lattice effects in shielding calculations that have been developed include the electrostatic representation of the crystal lattice using point charge arrays, full ab initio methods, ab initio methods under periodic boundary conditions, and hybrid ab initio/molecular dynamics methods. The embedded ion method (EIM) discussed here follows the electrostatic approach. The method mimics the intermolecular and interionic interactions experienced by a subject molecule or cluster in a given crystal in quantum mechanical shielding calculations with a large finite, periodic, and self-consistent array of point charges. The point charge arrays in the EIM are generated using the Ewald summation method and embed the molecule or ion of interest for which the ab initio shielding calculations are performed. The accuracy with which the EIM reproduces experimental nuclear magnetic shift tensor principal values, the sensitivity of the EIM to the parameters defining the point charge arrays, as well as the strengths and limitations of the EIM in comparison with other methods that include crystal lattice effects in chemical shielding calculations, are presented. © 2006 Wiley Periodicals, Inc. Concepts Magn Reson Part A 28A: 347,368, 2006 [source] Axillary Basal Cell CarcinomaDERMATOLOGIC SURGERY, Issue 11 2003Benjamin W. LeSueur MD Background. Basal cell carcinoma (BCC) rarely occurs in the axilla. Only 18 cases have been reported in the world literature. Objectives. To report our institution's 11-year experience with axillary BCC. Methods. A review of patient charts and biopsy specimens is given. Results. We report 14 patients with 15 axillary BCCs. The average patient age was 65.6. The average lesion size was 10.8 mm. Nine patients had a personal history of skin cancer at sun-exposed sites. One patient had basal cell nevus syndrome. A history of ionizing radiation and severe sunburn involving the axilla was each seen in separate patients. No other predisposing factors for developing BCC were identified, such as immune suppression or a history of other malignancies. Histologic subtypes of all tumors were considered less aggressive, and only one tumor recurred. Conclusions. Axillary BCC is rare. Factors other than ultraviolet radiation likely contribute to the development of BCC, especially at sun-protected sites. Performing a periodic and complete cutaneous examination that includes sun-protected sites is important, especially in patients who have a history of skin cancer. [source] Soil creep and convex-upward velocity profiles: theoretical and experimental investigation of disturbance-driven sediment transport on hillslopesEARTH SURFACE PROCESSES AND LANDFORMS, Issue 13 2004Joshua J. Roering Abstract The movement of unconsolidated materials near the Earth's surface is often driven by disturbances that occur at a range of spatial and temporal scales. The nature of these disturbances ranges from highly variable, such as tree turnover, to periodic and predictable, such as frost heave or creep. To explore the effect of probabilistic disturbances on surface processes, we formulated a granular creep model with analogy to rate process theory (RPT) used for chemical reactions. According to the theory, individual particles must be energized to a height greater than adjacent particles in order for grain dilation and transport to occur. The height of neighbouring particles (which is akin to activation energy in chemical reactions) varies with slope angle such that energy barriers get smaller in the downslope direction as slopes steepen. When slopes approach the friction-limited angle of repose, the height of energy barriers approaches zero and grains ,ow in the absence of disturbance. An exponential function is used to describe the probability distribution of particle excitation height although alternative distributions are possible. We tested model predictions of granular dynamics in an experimental sandpile. In the sandpile, acoustic energy serves as the disturbance agent such that grains dilate and shear in response. Particle velocities are controlled by the frequency of energy pulses that result in grain displacement. Using tracer particles, we observed a convex-upward velocity pro,le near the surface of the sandpile, consistent with predictions of our RPT-based velocity model. In addition, we depth-integrated the velocity model to predict how ,ux rates vary with inclination of the sandpile and observed non-linear ,ux,gradient curves consistent with model predictions. By varying the acoustic energy level in the experimental sandpile, we documented changes in the rate of grain movement; similar changes in modelled velocities were achieved by varying the exponent of the particle excitation probability distribution. The general agreement between observed and modelled granular behaviour in our simple laboratory sandpile supports the utility of RPT-based methods for modelling transport processes (e.g. soil creep, frost heave, and till deformation), thus enabling us to account for the probabilistic nature of disturbances that liberate sediment in natural landscapes. Copyright © 2004 John Wiley & Sons, Ltd. [source] Experimental and theoretical simulations of seismic poundings between two adjacent structuresEARTHQUAKE ENGINEERING AND STRUCTURAL DYNAMICS, Issue 4 2003K. T. Chau Abstract Shaking table tests have been carried out to investigate the pounding phenomenon between two steel towers of different natural frequencies and damping ratios, subject to different combinations of stand-off distance and seismic excitations. Both harmonic waves and ground motions of the 1940 El Centro earthquake are used as input. Subjected to sinusoidal excitations, poundings between the two towers could appear as either periodic or chaotic. For periodic poundings, impact normally occurs once within each excitation cycle or within every other excitation cycle. A type of periodic group poundings was also observed for the first time (i.e. a group of non-periodic poundings repeating themselves periodically). Chaotic motions develop when the difference of the natural frequency of the two towers become larger. Under sinusoidal excitations, the maximum relative impact velocity always develops at an excitation frequency between the natural frequencies of the two towers. Both analytical and numerical predictions of the relative impact velocity, the maximum stand-off distance, and the excitation frequency range for pounding occurrences were made and found to be comparable with the experimental observations in most of the cases. The stand-off distance attains a maximum when the excitation frequency is close to that of the more flexible tower. Pounding appears to amplify the response of the stiffer structure but suppress that of the more flexible structure; and this agrees qualitatively with previous shaking table tests and theoretical studies. Copyright © 2003 John Wiley & Sons, Ltd. [source] Natural enemy specialization and the period of population cyclesECOLOGY LETTERS, Issue 5 2003P. Rohani Abstract The dynamical consequences of multiple-species interactions remain an elusive and fiercely debated topic. Recently, Murdoch and colleagues proposed a general rule for the dynamics of generalist natural enemies: when periodic, they exhibit single generation cycles (SGCs), similar to single species systems. This contrasts markedly with specialists, which tend to show classic (longer period) consumer,resource cycles. Using a well-studied laboratory system, we show that this general rule is contradicted when we consider resource age-structure. [source] Fabrication of Periodic Microstructures in Pentaerythritol Triacrylate Through Femtosecond Laser Interference Two-Photon Polymerization,ADVANCED ENGINEERING MATERIALS, Issue 7 2009Andrés Lasagni Fabrication of periodic, two-dimensional microstructures in pentaerythritol triacrylate (PETIA) is demonstrated through femtosecond laser interference patterning. Planar arrayed structures of different periodicities and geometries were fabricated using three, four, and five interfering beams from an 800,nm ultrafast femtosecond laser. The periodic topography can be varied from isolated conical pillars to interconnected cellular structures by simple control of the interference pattern in combination with energy dose. [source] Measurements on electrical power systems under bi-tone conditions by using the virtual time-domain approachEUROPEAN TRANSACTIONS ON ELECTRICAL POWER, Issue 1 2002L. Peretto The virtual time-domain approach is very convenient for the characterization of multi-tone signals, both quasiperiodic and periodic with very low fundamental frequency. Measurements on a three-phase load controlled by an inverter have been performed by means of a digital method implementing that approach. The results are reported and discussed also in comparison with those provided by a validation procedure. [source] Ecological effects of perturbation by drought in flowing watersFRESHWATER BIOLOGY, Issue 7 2003P. S. Lake SUMMARY 1Knowledge of the ecology of droughts in flowing waters is scattered and fragmentary, with much of the available information being gathered opportunistically. Studies on intermittent and arid-zone streams have provided most of the information. 2Drought in streams may be viewed as a disturbance in which water inflow, river flow and water availability fall to extremely low levels for extended periods of time. As an ecological perturbation, there is the disturbance of drought and the responses of the biota to the drought. 3Droughts can either be periodic, seasonal or supra-seasonal events. The types of disturbance for seasonal droughts are presses and for supra-seasonal droughts, ramps. 4In droughts, hydrological connectivity is disrupted. Such disruption range from flow reduction to complete loss of surface water and connectivity. The longitudinal patterns along streams as to where flow ceases and drying up occurs differs between streams. Three patterns are outlined: ,downstream drying', ,headwater drying' and ,mid-reach drying'. 5There are both direct and indirect effects of drought on stream ecosystems. Marked direct effects include loss of water, loss of habitat for aquatic organisms and loss of stream connectivity. Indirect effects include the deterioration of water quality, alteration of food resources, and changes in the strength and structure of interspecific interactions. 6Droughts have marked effects on the densities and size- or age-structure of populations, on community composition and diversity, and on ecosystem processes. 7Organisms can resist the effects of drought by the use of refugia. Survival in refugia may strongly influence the capacity of the biota to recover from droughts once they break. 8Recovery by biota varies markedly between seasonal and supra-seasonal droughts. Faunal recovery from seasonal droughts follows predictable sequences, whilst recovery from supra-seasonal droughts varies from one case to another and may be marked by dense populations of transient species and the depletion of biota that normally occur in the streams. 9The restoration of streams must include the provision of drought refugia and the inclusion of drought in the long-term flow regime. [source] Linking return visits and return migration among Commonwealth Eastern Caribbean migrants in TorontoGLOBAL NETWORKS, Issue 1 2004David Timothy Duval Return visits are periodic but temporary sojourns made by members of migrant communities to their external homeland or another location where strong social ties exist. As a result, the conceptual framework in this article revolves around transnationalism as the return visit is shown to be a transnational exercise that may facilitate return. Using data from ethnographic fieldwork, three themes highlight the link between return visits and return migration: (1) the need to facilitate ties such that relationships are meaningful upon permanent return; (2) the functional nature of the return visit, such that changes are measured and benchmarked against what is remembered and internalized by the migration after the migration episode; and (3) the knowledge that return visits aid in reintegration. [source] A comprehensive approach to characterization of the nonlinearity of runoff in the headwaters of the Tarim River, western ChinaHYDROLOGICAL PROCESSES, Issue 2 2010Jianhua Xu Abstract Nonlinear characteristics of the runoff processes in the headwaters of the Tarim River were identified and evaluated using several selected methods, including wavelet analysis, correlation dimension, and R/S analysis. Time-series of annual data describing runoff, average temperature, and precipitation from 1957 to 2005 were used to construct and test empirical models. The primary findings of this study were as follows: (1) The annual runoff of the headwaters are complex and nonlinear in nature, and they each presented periodic, nonlinear trends at the chosen time scales, chaotic dynamics, and long-memory characteristics. (2) These nonlinear trends appeared to have resulted from the regional climatic changes that occurred during the study period. The periodicity of changes in runoff occurred on an approximately 25-year cycle, which appeared to be correlated with temperature and precipitation cycles. In addition, the annual runoff exhibited a significant, positive correlation with the temperature and precipitation factors at the 4-, 8-, 16-, and 32-year temporal scales. (3) The correlation dimensions of the attractor derived from the runoff time series for the Hotan, Yarkand, and Aksu rivers were all greater than 3·0 and non-integral, implying that all three rivers are dynamic chaotic systems that are sensitive to initial conditions, and that the dynamic modelling of their annual runoff requires at least four independent variables. (4) The computed Hurst exponents indicate that a long-term memory characteristic exists in the annual runoff processes. However, there were some differences observed, with the Aksu and Yarkand rivers demonstrating a persistent trait, and the Hotan River exhibiting an anti-persistent feature. Copyright © 2009 John Wiley & Sons, Ltd. [source] Energy-Absorbing Hybrid Composites Based on Alternate Carbon-Nanotube and Inorganic LayersADVANCED MATERIALS, Issue 28 2009Qiang Zhang Hybrid materials with aligned carbon nanotubes intercalating naturally layered compounds (see upper figures) are fabricated using general metal-ion intercalation and in situ growth. As indicated by SEM images (lower figures), they exhibit periodic and hierarchical structures. The ability to control their composition resulted in some samples possessing excellent mechanical properties, such as high energy absorption during compression. [source] Semi-discretization method for delayed systemsINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN ENGINEERING, Issue 5 2002Tamás Insperger Abstract The paper presents an efficient numerical method for the stability analysis of linear delayed systems. The method is based on a special kind of discretization technique with respect to the past effect only. The resulting approximate system is delayed and also time periodic, but still, it can be transformed analytically into a high-dimensional linear discrete system. The method is applied to determine the stability charts of the Mathieu equation with continuous time delay. Copyright © 2002 John Wiley & Sons, Ltd. [source] Two-dimensional prediction of time dependent, turbulent flow around a square cylinder confined in a channelINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS, Issue 11 2010M. Raisee Abstract This paper presents two-dimensional and unsteady RANS computations of time dependent, periodic, turbulent flow around a square block. Two turbulence models are used: the Launder,Sharma low-Reynolds number k,, model and a non-linear extension sensitive to the anisotropy of turbulence. The Reynolds number based on the free stream velocity and obstacle side is Re=2.2×104. The present numerical results have been obtained using a finite volume code that solves the governing equations in a vertical plane, located at the lateral mid-point of the channel. The pressure field is obtained with the SIMPLE algorithm. A bounded version of the third-order QUICK scheme is used for the convective terms. Comparisons of the numerical results with the experimental data indicate that a preliminary steady solution of the governing equations using the linear k,, does not lead to correct flow field predictions in the wake region downstream of the square cylinder. Consequently, the time derivatives of dependent variables are included in the transport equations and are discretized using the second-order Crank,Nicolson scheme. The unsteady computations using the linear and non-linear k,, models significantly improve the velocity field predictions. However, the linear k,, shows a number of predictive deficiencies, even in unsteady flow computations, especially in the prediction of the turbulence field. The introduction of a non-linear k,, model brings the two-dimensional unsteady predictions of the time-averaged velocity and turbulence fields and also the predicted values of the global parameters such as the Strouhal number and the drag coefficient to close agreement with the data. Copyright © 2009 John Wiley & Sons, Ltd. [source] A streamfunction,velocity approach for 2D transient incompressible viscous flowsINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS, Issue 3 2010Jiten C. Kalita Abstract We recently proposed (J. Comput. Phys. 2005; 207(1):52,68) a new paradigm for solving the steady-state two-dimensional (2D) Navier,Stokes (N,S) equations using a streamfunction,velocity (,,v) formulation. This formulation was shown to avoid the difficulties associated with the traditional formulations (primitive variables and streamfunction-vorticity formulations). The new formulation was found to be second-order accurate and was found to yield accurate solutions of a number of fluid flow problems. In this paper, we extend the ideas and propose a second-order implicit, unconditionally stable ,,v formulation for the unsteady incompressible N,S equations. The method is used to solve several 2D time-dependent fluid flow problems, including the flow decayed by viscosity problem with analytical solution, the lid-driven square cavity problem, the backward-facing step problem and the flow past a square prism problem. For the problems with known exact solutions, our coarse grid transient solutions are extremely close to the analytical ones even for high Reynolds numbers (Re). For the driven cavity problem, our time-marching steady-state solutions up to Re=7500 provide excellent matches with established numerical results, and for Re=10000, our study concludes that the asymptotic stable solution is periodic as has been found by other authors in recent studies. For the backward step problem, our numerical results are in excellent agreement with established numerical and experimental results. Finally, for the flow past a square prism, we have very successfully simulated the von Kármán vortex street for Re=200. Copyright © 2009 John Wiley & Sons, Ltd. [source] Near optimal LQR performance for uncertain first order systemsINTERNATIONAL JOURNAL OF ADAPTIVE CONTROL AND SIGNAL PROCESSING, Issue 4 2004L. Luo Abstract In adaptive control, the objective is to provide stability and acceptable performance in the face of significant plant uncertainty. However, often there are large transients in the plant output and the control signal can become excessively large. Here, we consider the first order case with the plant parameters restricted to a compact set; we show how to design a (linear time-varying) adaptive controller which provides near optimal LQR performance. This controller is periodic with each period split into two parts: during the Estimation Phase, an estimate of the optimal control signal is formed; during the Control Phase, a suitably scaled estimate of this signal is applied to the system. We demonstrate the technique with a simulation and discuss the benefits and limitations of the approach. Copyright © 2004 John Wiley & Sons, Ltd. [source] Thinking inside the box: Novel linear scaling algorithm for Coulomb potential evaluationINTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, Issue 4 2006David C. Thompson Abstract Beginning with the Poisson equation, and expanding the electronic potential in terms of sine functions, the natural orbitals for describing the particle-in-a-box problem, we find that simple analytic forms can be found for the evaluation of the Coulomb energy for both the interacting and non-interacting system of N -electrons in a box. This method is reminiscent of fast-Fourier transform and scales linearly. To improve the usefulness of this result, we generalize the idea by considering a molecular system, embedded in a box, within which we determine the electrostatic potential, in the same manner as that described for our model systems. Within this general formalism, we consider both periodic and aperiodic recipes with specific application to systems described using Gaussian orbitals; although in principle the method is seen to be completely general. © 2005 Wiley Periodicals, Inc. Int J Quantum Chem, 2006 [source] Predictor-based repetitive learning control for a class of remote control nonlinear systemsINTERNATIONAL JOURNAL OF ROBUST AND NONLINEAR CONTROL, Issue 16 2007Ya-Jun Pan Abstract In this paper, a repetitive learning control (RLC) approach is proposed for a class of remote control nonlinear systems satisfying the global Lipschitz condition. The proposed approach is to deal with the remote tracking control problem when the environment is periodic or repeatable over infinite time domain. Since there exist time delays in the two transmission channels: from the controller to the actuator and from the sensor to the controller, tracking a desired trajectory through a remote controller is not an easy task. In order to solve the problem caused by time delays, a predictor is designed on the controller side to predict the future state of the nonlinear system based on the delayed measurements from the sensor. The convergence of the estimation error of the predictor is ensured. The gain design of the predictor applies linear matrix inequality (LMI) techniques developed by Lyapunov Kravoskii method for time delay systems. The RLC law is constructed based on the feedback error from the predicted state. The overall tracking error tends to zero asymptotically over iterations. The proof of the stability is based on a constructed Lyapunov function related to the Lyapunov Kravoskii functional used for the proof of the predictor's convergence. By well incorporating the predictor and the RLC controller, the system state tracks the desired trajectory independent of the influence of time delays. A numerical simulation example is shown to verify the effectiveness of the proposed approach. Copyright © 2007 John Wiley & Sons, Ltd. [source] Intelligent control of DC motor driven mechanical systems: a robust learning control approachINTERNATIONAL JOURNAL OF ROBUST AND NONLINEAR CONTROL, Issue 1 2003Tae-Yong Kuc Abstract A robust learning controller is presented for DC motor driven mechanical systems with friction. The proposed controller takes advantage of both robust and learning control approaches to learn and compensate periodic and non-periodic uncertain dynamics. In the learning controller, a set of learning rules is implemented in which three types of learnings occur: one is direct learning of desired inverse dynamics input and the other two learning of unknown linear parameters and nonlinear bounding functions in the models of system dynamics and friction. The global asymptotic stability of learning control system is shown by using the Lyapunov stability theory. Experimental data demonstrate the effectiveness of developed learning approach to tracking of DC motor driven mechanical systems. Copyright © 2002 John Wiley & Sons, Ltd. [source] Spatial abundance structures in an assemblage of gall-forming sawfliesJOURNAL OF ANIMAL ECOLOGY, Issue 3 2004M. A. McGeoch Summary 1Examination of the fine-scale internal structure of species geographical ranges, and interspecific variation therein across landscapes, contributes to a more comprehensive understanding of the structure of geographical ranges. Two components of this internal structure that require further examination are the occurrence, extent and position of spatial autocorrelation, and relationships between the spatial abundance structures of closely related, ecologically similar species. 2Here we compare the abundance structures of an assemblage of gall-forming sawflies (Tenthredinidae) across a landscape. We identify the relative roles of spatial and non-spatial factors in explaining their abundance structures and test the hypothesis that sawfly density is explained by host plant quality, as has been demonstrated repeatedly at finer scales. We use these results to distinguish between alternative sets of mechanisms that may be operating at the landscape scale. 3Species densities were mainly multimodal across the landscape and significantly spatially structured, with patch, periodic and trend components. The abundance structures thus mimic those found generally for species across the full extent of their geographical ranges. 4Many abundance structure characteristics were unique to species, with differences in their correlogram profiles, distances over which densities were positively autocorrelated, and the absence of significant spatial structure in one species. 5In contrast to previous, fine-scale studies, host plant quality explained little of the variation in sawfly gall density across the landscape, whereas unexplained spatial structure contributed between 30% and 50%. Based on knowledge of the biology of these species and the absence of competitive interactions, species dispersal characteristics and the Moran effect are suggested as probable alternative hypotheses at this scale. 6Therefore, a spatial approach has identified the hierarchical nature of mechanisms underlying the population dynamics of this sawfly assemblage for the first time. Furthermore, it has highlighted the importance of spatial processes in explaining the densities of species at the landscape scale, as well as the individualistic nature of their abundance structures. [source] The Bravais polar lattice as a didactic tool for diffraction beginnersJOURNAL OF APPLIED CRYSTALLOGRAPHY, Issue 5-2 2010Massimo Nespolo When undergraduate students discover crystallography for the first time, they are usually already familiar with the phenomenon of diffraction as the `bending' of waves around small obstacles. The special (periodic) nature of crystals acting as `diffraction gratings' that produce interference of diffracted waves is typically rationalized in terms of the reciprocal lattice of the crystal. The concept of the reciprocal lattice, however, remains somewhat abstract for beginners, until they perform a diffraction experiment. It can be made more easily understandable through an intermediate step, namely its ancestor, the Bravais polar lattice. By means of a short historical trip through pre-X-ray crystallography, a generalized introduction to the notion of the dual lattice is given, of which the reciprocal lattice is the most common but by no means the only example, and it is shown how the use of the Bravais polar lattice can ease the introduction of the reciprocal lattice. [source] Automatic indexing of area-detector data of periodic and aperiodic crystalsJOURNAL OF APPLIED CRYSTALLOGRAPHY, Issue 2 2002Katrin Pilz An autoindexing procedure is described that produces the indexing of diffraction data of aperiodic crystals. The procedure has been designed for indexing the data obtained with an area detector, but it can also be applied to data obtained with a single-point detector. The essential step in the indexing process is the ability to discriminate between reflections that fit to a reciprocal lattice, the satellite reflections and possible reflections that do not belong to this indexing. To achieve this goal, the refinement of the orientation matrix and the diffractometer parameters is made an intrinsic part of the process of indexing. The proposed autoindexing procedure has been implemented in a computer program called BAYINDEX. Successful application to data sets of three different one-dimensionally modulated structures, one two-dimensionally modulated structure and a periodic crystal is presented. Very good agreement between experimental and theoretical reflection positions is found. The indexing produced by BAYINDEX can serve as the basis for integration routines. [source] Refinement of modulated structures against X-ray powder diffraction data with JANA2000JOURNAL OF APPLIED CRYSTALLOGRAPHY, Issue 3 2001M. Du JANA is a computer program for the refinement and analysis of periodic and aperiodic (incommensurately modulated structures and composite crystals) crystal structures. Here a new module is introduced that allows Rietveld refinements against powder diffraction data. It is shown that JANA2000 provides a state-of-the-art description of the peak profiles. A re-analysis of the low-temperature structure of (CO)xC60 showed that the application of icosahedral symmetry restrictions to the C60 molecule leads to a better description of the electron density and to a corrected position of the CO molecule as compared with a rigid-body refinement. The incommensurately modulated structure of NbTe4 has been successfully refined against X-ray powder diffraction data. The structural parameters are equal to, but less accurate, than the parameters obtained from a single-crystal study. [source] Influence of nitrogen on the degradation of toluene in a compost-based biofilterJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 9 2001Marie-Caroline Delhoménie Abstract Two identical laboratory-scale bioreactors were operated simultaneously, each treating an input air flow rate of 1,m3,h,1. The biofilters consisted of multi-stage columns, each stage packed with a compost-based filtering material, which was not previously inoculated. The toluene inlet concentration was fixed at 1.5,g,m,3 of air. Apart from the necessary carbon, the elements nitrogen, phosphorus, sulfur, potassium and other micro-elements are also essential for microbial metabolism. These were distributed throughout the filter bed material by periodic ,irrigations' with various test nutrient solutions. The performance of each biofilter was quantified by determining its toluene removal efficiency, and elimination capacity. Nutrient solution nitrogen levels were varied from 0 to 6.0,g,dm,3, which led to elimination capacities of up to 50,g,m,3,h,1 being obtained for a toluene inlet load of 80,g,m,3,h,1. A theoretical analysis also confirmed that the optimum nitrogen solution concentration lays in the range 4.0,6.0,g,dm,3. Validation of the irrigation mode was achieved by watering each biofilter stage individually. Vertical stage-by-stage stratification of the biofilter performance was not detected, ie each filter bed section removed the same amount of pollutant, the elimination capacity per stage being about 16,g,m,3,h,1 per section of column. © 2001 Society of Chemical Industry [source] Models for the treatment of crystalline solids and surfacesJOURNAL OF COMPUTATIONAL CHEMISTRY, Issue 13 2004Karl Jug Abstract Crystalline solids and surfaces have become a subject of growing interest. The difficulty of a comprehensive description of a variety of phenomena by a single method has led to the development of many models. These models can be classified as nonperiodic and periodic models. The former include free clusters, saturated clusters, and embedded clusters. The latter two models serve to remove the boundary effects of the free clusters. No perfect avoidance of such effects can be achieved in this way. The cyclic cluster model overcomes this difficulty in a natural way. It is periodic with a finite periodicity. An embedding can take into account a long-range effect in ionic crystals. Previous periodic approaches relied on the large unit cell model, which is related to the supercell approach. For perfect crystals the conventional unit cell approach is a well-known standard. However, its disadvantage is the unphysical periodicity of defects, which is avoided in the cyclic cluster model. The present article presents a description of these models together with selective applications to solid-state systems and surfaces. © 2004 Wiley Periodicals, Inc. J Comput Chem 13: 1551,1567, 2004 [source] Abiotic and biotic drivers of seedling survival in a hurricane-impacted tropical forestJOURNAL OF ECOLOGY, Issue 6 2009Liza S. Comita Summary 1. ,Many forests experience periodic, large-scale disturbances, such as hurricanes and cyclones, which open the forest canopy, causing dramatic changes in understorey light conditions and seedling densities. Thus, in hurricane-impacted forests, large variations in abiotic and biotic conditions likely shape seedling dynamics, which in turn will contribute to patterns of forest recovery. 2. ,We monitored 13 836 seedlings of 82 tree and shrub species over 10 years following Hurricane Georges in 1998 in a subtropical, montane forest in Puerto Rico. We quantified changes in the biotic and abiotic environment of the understorey and linked seedling dynamics to changes in canopy openness and seedling density, and to spatial variation in soil type, topography and tree density. 3. ,Canopy openness was highest when first measured after Hurricane Georges and dropped significantly within c. 3 years, while seedling densities remained high for c. 5 years post-hurricane. When all species and census intervals were analysed together, generalized linear mixed effects models revealed that canopy openness, seedling and adult tree densities were significant drivers of seedling survival. 4. ,The relative importance of abiotic and biotic factors changed over time. Separate analyses for each census interval revealed that canopy openness was a significant predictor of survival only for the first census interval, with lower survival at the highest levels of canopy openness. The effect of conspecific seedling density was significant in all intervals except the first, and soil type only in the final census interval. 5. ,When grouping species into life-history guilds based on adult tree susceptibility to hurricane damage, we found clear differences among guilds in the effects of biotic and abiotic factors on seedling survival. Seedlings of hurricane-susceptible and intermediate guilds were more strongly influenced by canopy openness, while seedlings of the hurricane-resistant group were less affected by conspecific seedling density. Individual species-level analyses for 12 common species, however, showed considerable variation among species within guilds. 6. ,Synthesis. Our results suggest that hurricanes shape species composition by altering understorey conditions that differentially influence the success of seedlings. Thus, predicted increases in the intensity and frequency of hurricanes in the Caribbean will likely alter seedling dynamics and ultimately the species composition in hurricane-impacted forests. [source] Periodic spotted patterns in semi-arid vegetation explained by a propagation-inhibition modelJOURNAL OF ECOLOGY, Issue 4 2001P. Couteron Summary 1,Vegetation cover regularly punctuated by spots of bare soil is a frequent feature of certain semi-arid African landscapes, which are also characterized by banded vegetation patterns (i.e. tiger bush). 2,The propagation-inhibition (PI) model suggests that a periodic pattern characterized by a dominant wavelength can theoretically establish itself through a Turing-like spatial instability depending only on a trade-off between facilitative and competitive interactions among plants. Under strictly isotropic conditions, spotted and banded patterns are distinct outcomes of a unique process, whereas anisotropy leads to a banded structure. The model predicts that spotted patterns will have a lower dominant wavelength than bands. 3,We test some outcomes of the PI model against vegetation patterns observable in aerial photographs from West Africa. Two sites with rainfall of c. 500,600 mm year,1 were studied: a 525-ha plain in north-west Burkina Faso and a 300-ha plateau in southern Niger. Digitized photographs were subjected to spectral analysis by Fourier transform in order to quantify vegetation patterns in terms of dominant wavelengths and orientations. 4,Spotted vegetation proved highly periodic. The characteristic range of dominant wavelengths (30,50 m) was similar at two sites more than 500 km apart. The PI model suggests that spots may occur as a hexagonal lattice but there is little evidence of such patterning in the field. A dominant wavelength was far quicker to establish in simulations (c. 102,103 years for annual grasses) than a hexagonal symmetry (c. 105 years), and observed patterns are therefore likely to be far from the asymptotic structure. 5,Elongated and smudged spots that locally became flexuous bands have been observed in southern Niger. This pattern that had a dominant wavelength of 50 m but lacked any dominant orientation can be interpreted as a transition from spots to bands under fairly isotropic conditions. 6,The PI model provides a framework for further investigation of patterns in semi-arid vegetation and may be of a broader ecological application. [source] ORDINARY LEAST SQUARES LEARNING AND NONLINEARITIES IN MACROECONOMICSJOURNAL OF ECONOMIC SURVEYS, Issue 1 2010Orlando Gomes Abstract The paper reviews the literature on adaptive learning in macroeconomic settings where the formation of expectations is particularly relevant. Special attention will be given to simple two-period overlapping generations models with a unique fixed point perfect foresight equilibrium; in this kind of scenario, eventual long-term periodic and a-periodic cycles are exclusively the result of the process of learning. The outcome that high rates of money growth have a potentially destabilizing effect generating periodic fluctuations and chaos is emphasized. The persistence of systematic forecast errors in a scenario where agents are supposed to act rationally is relevant in this context and it will be thoroughly discussed resorting to the notions of self-fulfilling mistakes, consistent expectations equilibria and beliefs equilibria. [source] |