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Particle Dispersion (particle + dispersion)

Distribution by Scientific Domains

Polymers and Materials Science	50%

Distribution within Polymers and Materials Science

General & Introductory Materials Science	42%
Polymer Science & Technology General	28%

Selected Abstracts

High Performance SiC Oxidation Protective Coating with ZrO2 Particle Dispersion for Carbon/Carbon Composites,

ADVANCED ENGINEERING MATERIALS, Issue 10 2008
Y.-L. Zhang
High performance SiC oxidation protective coating with ZrO2 particle dispersion for C/C composites was prepared by slurry and pack cementation. Isothermal oxidation tests at 1873,K in air showed that the as-prepared coating could effectively protect C/C composites from oxidation for 100,h. The excellent oxidation protective ability can be attributed to the introduction of ZrO2 particles in the SiC coating, which can baffle the enlargement of cracks and suppress the generation of the thermal stress. [source]

Lead Zirconate Titanate Particle Dispersion in Thick-Film Ink Formulations

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 6 2000
Erik S. Thiele
Diverse device applications for lead zirconate titanate (PZT) ceramics in thick-film form are currently in active development. In the present study, the particle dispersion properties of thick-film ink formulations containing PZT powder have been determined using rheological measurements. Although all of the eight commercially available dispersants tested are more effective than the terpineol solvent alone in decreasing attractive interparticle forces in suspensions, the best dispersant identified for hard and soft PZT powders is a phosphate ester oligomer. This dispersant is extremely efficient, and its use in thick-film ink formulations results in viscosity decreases of 50% at low shear rates (10 s,1) and 30% at high shear rates (100 s,1) compared with current ink formulations containing no dispersant. The effects upon rheology of the order of addition of components in the processing of inks have been studied, with the most effective processing route using a fugitive solvent that probably facilitates uniform coverage of the particle surfaces by the dispersant molecules. Modeling of the rheological profiles of inks indicates that the use of a dispersant decreases the depth of the primary minimum in the interparticle potential by a factor of 3. Demonstrated advantages of the use of a dispersant in PZT thick-film inks include improved microstructural homogeneity in the green body and the ability to formulate printable inks with higher solids loadings. No adverse effects of the dispersant upon the dielectric and piezoelectric properties of bulk PZT samples are found following burnout and sintering. [source]

Mechanisms of particle dispersion in a turbulent, square duct flow

AICHE JOURNAL, Issue 7 2009
Michael Fairweather
Abstract Particle dispersion in a square duct flow is studied using large eddy simulation combined with Lagrangian particle tracking under conditions of one-way coupling. The flow has a bulk Re = 250 k, with six particle sizes ranging from 5 to 1000 ,m. Results obtained for the fluid phase show good agreement with experimental data. For particles, predictions demonstrate that secondary flows within the duct dominate small particle dispersion and result in a uniform distribution, whereas gravity promotes the deposition of large particles on the duct floor. For the largest particles, the secondary flows contribute to particle concentration in corners on the duct floor, with these particles also clustering in low-velocity regions close to the floor. A detailed analysis of the influence of the flow on particle distribution is provided through consideration of the particle dispersion function, with the mechanisms of particle dispersion elucidated using a dynamical analysis. © 2009 American Institute of Chemical Engineers AIChE J, 2009 [source]

Experimental determination of saltating glass particle dispersion in a turbulent boundary layer

EARTH SURFACE PROCESSES AND LANDFORMS, Issue 14 2006
H. T. Wang
Abstract A horizontal saltation layer of glass particles in air is investigated experimentally over a flat bed and also over a triangular ridge in a wind tunnel. Particle concentrations are measured by light scattering diffusion (LSD) and digital image processing, and velocities using particle image velocimetry (PIV). All the statistical moments of the particle concentration are determined such as mean concentration, root mean square concentration fluctuations, skewness and flatness coefficients. Over the flat bed, it is confirmed that the mean concentration decreases exponentially with height, the mean dispersion height being a significant length scale. It is shown that the concentration distribution follows quite well a lognormal distribution. Over the ridge, measurements were made at the top of the ridge and in the cavity region and are compared with measurements without the ridge. On the hill crest, particles are retarded, the saltation layer decreases in thickness and concentration is increased. Downwind of the ridge, particle flow behaves like a jet, in particular no particle return flow is observed. Copyright © 2006 John Wiley & Sons, Ltd. [source]

High Performance SiC Oxidation Protective Coating with ZrO2 Particle Dispersion for Carbon/Carbon Composites,

A Lagrangian,Eulerian model of particle dispersion in a turbulent plane mixing layer

INTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS, Issue 5 2002
L.A. Oliveira
Abstract A Lagrangian,Eulerian model for the dispersion of solid particles in a two-dimensional, incompressible, turbulent flow is reported and validated. Prediction of the continuous phase is done by solving an Eulerian model using a control-volume finite element method (CVFEM). A Lagrangian model is also applied, using a Runge,Kutta method to obtain the particle trajectories. The effect of fluid turbulence upon particle dispersion is taken into consideration through a simple stochastic approach. Validation tests are performed by comparing predictions for both phases in a particle-laden, plane mixing layer airflow with corresponding measurements formerly reported by other authors. Even though some limitations are detected in the calculation of particle dispersion, on the whole the validation results are rather successful. Copyright © 2002 John Wiley & Sons, Ltd. [source]

Mechanisms of particle dispersion in a turbulent, square duct flow

Effect of Ultrasonication on the Microstructure and Tensile Elongation of Zirconia-Dispersed Alumina Ceramics Prepared by Colloidal Processing

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 9 2001
Tohru S. Suzuki
To obtain dense, fine-grained ceramics, fine particles and advanced powder processing, such as colloidal processing, are needed. Al2O3 and ZrO2 particles are dispersed in colloidal suspensions by electrosteric repulsion because of polyelectrolyte absorbed on their surfaces. However, additional redispersion treatment such as ultrasonication is required to obtain dispersed suspensions because fine particles tend to agglomerate. The results demonstrate that ultrasonication is effective in improving particle dispersion in suspensions and producing a homogeneous fine microstructure of sintered materials. Superplastic tensile ductility is improved by ultrasonication in preparing suspensions because of the dense and homogeneous fine microstructure. [source]

Effect of an organic dicarboxylic acid salt on fractionated crystallization of polypropylene droplets

JOURNAL OF APPLIED POLYMER SCIENCE, Issue 6 2007
Y. Jin
Abstract The effect of a particulate nucleating agent on fractionated crystallization of polypropylene (PP) was studied. A novel method utilizing breakup of PP nanolayers was used to obtain a dispersion of PP droplets in a polystyrene (PS) matrix. An assembly with hundreds of PP nanolayers alternating with thicker PS layers was fabricated by layer-multiplying coextusion. The concentration of an organic dicarboxylic acid salt (HPN) nucleating agent in the coextruded PP nanolayers was varied up to 2 wt %. When the assembly was heated into the melt, interfacial driven breakup of the thin PP layers produced a dispersion of PP particles in a PS matrix. Analysis of optical microscope images and atomic force microscope images indicated that layer breakup produced a bimodal particle size distribution of submicron particles and large, micron-sized particles. Almost entirely submicron particles were obtained from breakup of 12 nm PP layers. The fraction of PP as submicron particles dropped dramatically as the PP nanolayer thickness increased to 40 nm. Only large, micron-sized particles were obtained from 200 nm PP nanolayers. The crystallization behavior of the particle dispersions was characterized by thermal analysis and wide angle X-ray diffraction. Only part of the PP was nucleated by HPN. It was found that HPN was not effective in nucleating the population of submicron particles. The particulate HPN was too large to be accommodated in the submicron PP particles. On the other hand, the amount of nucleated crystallization qualitatively paralleled the fraction of PP in the form of large, micron-sized particles. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 [source]

Restoration of PSD from Chord Length Distribution Data using the Method of Projections onto Convex Sets

PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION, Issue 2 2005
Jörg Worlitschek
Abstract The interpretation of chord length distributions (CLDs) is essential in many fields and has been discussed by various authors. Here, the technique of the Focused Beam Reflectance Measurement (FBRM) is considered as on-line and in-situ measurement device of the CLD of particle dispersions and emulsions. Though useful in general, this measurement cannot be converted directly into a particle size distribution (PSD), unless the physics of the measurement method is described and accounted for. In this work we present a new tool to carry out such a conversion once the particle shape is known a priori and can be fixed, which is based on a two step procedure: (1) the computation of a matrix that converts the PSD of a population of particles with given shape into the corresponding CLD using a 3-dimensional geometric model; (2) the calculation of the PSD from the resulting linear matrix equation for the measured CLD. Here, the method of Projections onto Convex Sets (POCS) is applied to solve the PSD restoration problem, which is a mathematically ill-posed inverse problem. We study the effect of particle shape and matrix dimension on the ill-posed character of the inverse problem. A detailed error analysis of the CLD allows for a predictive description of a posteriori constraints in the POCS framework. We discuss the application of this method to the characterization of simulated test cases and experimentally obtained data. [source]

Selective migration in polyethylene/rubbery particles blends during capillary flow

POLYMER ENGINEERING & SCIENCE, Issue 4 2010
C. Chartier
Adding elastomeric particles (Sunigum®) into a polyethylene (PE) matrix leads to an increase of both viscosity and dynamic moduli in the molten state. This suspension effect is more pronounced if the particle's dispersion is improved with a compatibilizing agent. However, under capillary flow, the blends exhibit a more complex behavior with a strong violation of a viscosity mixing rule. To elucidate the origin of this observation, an analysis of extrudates by confocal micro Raman spectrometry has been carried out. A selective migration of the lowest viscosity component (at a given shear rate) toward the wall of the capillary die has been noted. This migration is inhibited by the addition of a compatibilizer. POLYM. ENG. SCI., 2010. © 2009 Society of Plastics Engineers [source]