Outlet Concentration (outlet + concentration)

Distribution by Scientific Domains


Selected Abstracts


Eliminating a sulfuric acid mist plume from a wet caustic scrubber on a petroleum coke calciner

ENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY, Issue 3 2001
Charles A. Brown
Reducing sulfuric acid mist emissions and eliminating the visible plume that remained after steam dissipation were the objectives of a project recently completed for a petroleum coke calciner. The coke calciner produces flue gas containing SO2 that is treated with a wet caustic scrubber. The scrubber is extremely efficient at removing most of the SO2, but some oxidizes to SO3, catalyzed by vanadium in the coke dust that collects in the waste heat boiler. Submicron droplets of H2SO4 form when the flue gas is quenched by the scrubber liquor, and makes its way through the scrubber. This paper describes the installation of, and performance test results for, a wet electrostatic precipitator (WESP), as well as SO2 scrubber modifications that were re q u i red to make room for the WESP. The successful project significantly reduced sulfuric acid mist emissions, eliminating the visible plume while maintaining a very low SO2 outlet concentration, even after removing one of three gas-liquid contactors. [source]


Effect of CaO on NH3 + NO + O2 reaction system in the absence and presence of high concentration CO2

ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 2 2010
Tianjin Li
Abstract The effect of CaO on the NH3 + NO + O2 reaction system at 650,850 °C was investigated. High CO2 concentration was added to investigate the effect of CaCO3 on this reaction system also. Experimental results showed that CaO had a strong catalytic effect on NH3 decomposition, NH3 oxidation by O2 to NO, and NO reduction by NH3 in the absence of O2. The overall effect of CaO on the NO + NH3 + O2 reaction was to enhance NH3 oxidation by O2 to produce more NO. A small amount of NO2 and no N2O was detected in the outlet gas stream over CaO in the NH3 + NO + O2 reaction. NO2 formation decreased with temperature increase. NO2 formation in the NH3 + NO + O2 reaction over CaO was attributed to the oxidization of NH3 and NO by O2. The performance of CaCO3 was different from CaO. NH3 decomposition was promoted, but NH3 oxidation to NO was inhibited after CaO was converted to CaCO3. No catalytic activity for NO reduction was detected in NO + NH3 reaction over CaCO3, but strong activity for NH3 decomposition was observed. NO and NH3 outlet concentration over CaCO3 in the NH3 + NO + O2 reaction was lower and higher, respectively, than that of CaO, which was mainly due to the difference of CaO and CaCO3 for NH3 oxidation. NO2 formation was inhibited, but N2O was observed over CaCO3. N2O formation increased with temperature increase at 650,750 °C, and then decreased at 750,850 °C. Copyright © 2009 Curtin University of Technology and John Wiley & Sons, Ltd. [source]


Effect of Operating Parameters on the Condensation of Ammonium Sulfate by Electrodialysis

CHEMICAL ENGINEERING & TECHNOLOGY (CET), Issue 9 2008
H. Yang
Abstract The separation of ammonium sulfate from dilute solution by electrodialysis was investigated. From the results obtained, it is suggested that it is feasible to separate ammonium sulfate from aqueous solution by electrodialysis. The removal performance of ammonium sulfate obtained was very satisfactory. The optimal cation and anion membranes were found. The removal efficiencies were influenced by voltage, initial concentration, flow rate and temperature. High voltage and high temperature are beneficial to this separation process, but high fluid flow rate and concentrated initial concentration prolong the operation time required to achieve the target value. It was found that the optimal outlet concentration is 1,g/L, since the operation time is prolonged almost two-fold if the outlet concentration is decreased from 1,g/L to 0.5,g/L. [source]