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One-dimensional
Terms modified by One-dimensional Selected AbstractsPolymorphic One-Dimensional (N2H4)2ZnTe: Soluble Precursors for the Formation of Hexagonal or Cubic Zinc Telluride.CHEMINFORM, Issue 49 2005David B. Mitzi Abstract For Abstract see ChemInform Abstract in Full Text. [source] ChemInform Abstract: CuBi7I19 (C4H8O3H)3 (C4H8O3H2), a Novel Complex Bismuth Iodide Containing One-Dimensional [CuBi5I19]3- Chains.CHEMINFORM, Issue 19 2001Claus Feldmann Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source] Low-Temperature Synthesis of Phase-Pure 0D,1D BaTiO3 Nanostructures Using H2Ti3O7 TemplatesEUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 9 2010Duk Kyu Lee Abstract One-dimensional (1D) barium titanate (BaTiO3) nanowires, which were uniformly covered with 0D BaTiO3 nanocrystals, were synthesized by using a simple solvothermal reaction of protonated trititanate (H2Ti3O7) nanowires with barium hydroxide octahydrate [Ba(OH)2·8H2O] at 80 °C in ethanol/water mixed solvent systems. The compositions of the mixed solvents , the volume ratio of ethanol to deionized water , was a key controlling parameter in order to determine the phase formation and primary particle size of the 0D BaTiO3 nanocrystals. Single-phase cubic perovskite BaTiO3 started to form at 80 °C in a mixed solvent containing more than approximately 60,% by volume of ethanol. Field-emission scanning electron microscopy (FESEM) and high-resolution transmission electron microscopy (HRTEM) analysis revealed that the as-prepared BaTiO3 retained its wire-shaped morphology with nanocrystals on the surface. Furthermore, the synthetic mechanism of the 0D-1D BaTiO3 nanostructures was demonstrated in view of the dielectric tuning of the mixed solvent and the similarities between the crystal structures of BaTiO3 and H2Ti3O7. [source] Solar Cells by Design: Photoelectrochemistry of TiO2 Nanorod Arrays Decorated with CdSeADVANCED FUNCTIONAL MATERIALS, Issue 12 2010Jin Ho Bang Abstract One-dimensional (1D) nanostructures of TiO2 are grown directly on transparent, conductive glass substrate using hydrothermal/solvothermal methods. When employed as a photoanode in photoelectrochemical cells, the vertically aligned TiO2 nanorod array exhibits slower charge recombination at electrolyte interface as compared to mesoscopic TiO2 particulate film. Electrochemical deposition of CdSe onto TiO2 nanorod array is carried out to extend absorption into visible light region. The role of CdSe-sensitized, 1D rutile TiO2 architecture in the solar cell design is discussed. [source] A comparative proteome analysis of human metaphase chromosomes isolated from two different cell lines reveals a set of conserved chromosome-associated proteinsGENES TO CELLS, Issue 3 2007Hideaki Takata A comparative proteome analysis of human metaphase chromosomes between a typical epithelial-like cell, HeLa S3, and a lymphoma-type cell, BALL-1, was performed. One-dimensional (1-D) SDS-PAGE and radical-free and highly reducing two-dimensional electrophoresis (RFHR 2-DE) detected more than 200 proteins from chromosomes isolated from HeLa S3 cells, among which 189 proteins were identified by mass spectrometry (MS). Consistent with our recent four-layer structural model of a metaphase chromosome, all the identified proteins were grouped into four distinct levels of abundance. Both HeLa S3 and BALL-1 chromosomes contained specific sets of abundant chromosome structural and peripheral proteins in addition to less abundant chromosome coating proteins (CCPs). Furthermore, titin array analysis and a proteome analysis of the ultra-high molecular mass region indicated an absence of titin with their molecular weight (MW) more than 1000 kDa. Consequently, the present proteome analyses together with previous information on chromosome proteins provide the comprehensive list of proteins essential for the metaphase chromosome architecture. [source] Combining microwave and ultrasound irradiation for rapid synthesis of nanowires: a case study on Pb(OH)BrJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 12 2009Xiao-Fang Shen Abstract BACKGROUND: One-dimensional (1D) nanostructures such as wires, tubes and belts have attracted much attention in recent years because of their fascinating properties and promising applications, and various methods have been developed to prepare 1D nanostructures. Microwave and ultrasound, two methodologies for rapid synthesis, have both been applied to fabricate nanostructures. This paper reports on combining microwave and ultrasound irradiation as a new strategy for rapid synthesis of nanowires. Using Pb(OH)Br as a study case, nanowires were rapidly synthesized under the combined irradiation. The use of the ionic liquid 1-butyl-3-methylimidazolium bromide as a structure-directing agent and microwave absorbent significantly simplified the preparation procedure. RESULTS: Combined microwave,ultrasound irradiation at (50 W,50 W) greatly reduced the reaction time (10 min) and significantly increased the product yield (45.0%) in comparison with conventional heating (24 h reaction time, 23.0% yield). Combined microwave,ultrasound irradiation at (50 W,50 W) also changed the resultant wires from 20,30 µm diameter and 2,3 mm long to 80,800 nm and 50,100 µm, respectively. Further increase in power of the combined irradiation (250 W,50 W) led to a dramatic reduction in the reaction time (80 s) with a slightly increased yield of 48.2%. CONCLUSIONS: The obvious advantages of combined microwave,ultrasound irradiation are marked improvement of the product yield, significant enhancement of reaction rate and increased aspect ratio of the 1D structure. Copyright © 2009 Society of Chemical Industry [source] Pulsed field gradient (PFG) NMR spectroscopy: An effective tool for the analysis of mixtures of lubricating oil componentsLUBRICATION SCIENCE, Issue 4 2000G. S. Kapur Abstract In the presently reported work, the multinuclear two-dimensional (2D) diffusionordered nuclear magnetic resonance (NMR) spectroscopy (DOSY) technique based on the pulsed field gradient (PFG) has been used in experiments to analyse mixtures of lubricating oil components. One-dimensional (1D) PFG experiments have also been used to simplify and edit the NMR spectra of the mixtures. Such experiments provide a clean spectrum of the highest molecular weight (slower diffusing) component by eliminating the signals of lower molecular weight (faster diffusing) components, without any prior physical separation. These pulsed field gradient experiments not only facilitate the separation of resonance signals of different components, but also lead to their subsequent identification, and provide information about the number and structure of components in a mixture. Some examples of our initial efforts to establish 1D and 2D PFG-based NMR experiments for the analysis of mixtures of lubricating oil components are given and assessed to illustrate the potential applications of such techniques in the field of lubricating oils. [source] 1H and 13C NMR assignments for two new steroids from the coral Chromonephthea sp.MAGNETIC RESONANCE IN CHEMISTRY, Issue 4 2009Hua-Wei Geng Abstract Two new steroids isolated from EtOH extracts of the South China Sea soft coral Chromonephthea sp. were identified. One-dimensional (1D) and two-dimensional (2D) NMR experiments including COSY, HSQC, HMBC and NOESY were used for the determination of their structure. Copyright © 2008 John Wiley & Sons, Ltd. [source] Simulation and analysis of flow through microchannelASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 4 2009Madhusree Kundu Abstract One-dimensional and two-dimensional models for microchannel flow with noncontinuum (slip flow) boundary conditions have been presented here. This study presents an efficient numerical procedure using pressure-correction-based iterative SIMPLE algorithm with QUICK scheme in convective terms to simulate a steady incompressible two-dimensional flow through a microchannel. In the present work, the slip flow of liquid through a microchannel has been modeled using a slip length assumption instead of using conventional Maxwell's slip flow model, which essentially utilizes the molecular mean free path concept. The models developed, following this approach, lend an insight into the physics of liquid flow through microchannels. Copyright © 2009 Curtin University of Technology and John Wiley & Sons, Ltd. [source] Preparation, structure and photoluminescence properties of SiO2,coated ZnS nanowiresCRYSTAL RESEARCH AND TECHNOLOGY, Issue 10 2010Changhyun Jin Abstract It is essential to passivate one-dimensional (1D) nanostructures with insulating materials to avoid crosstalking as well as to protect them from contamination and oxidation. The structure and influence of thermal annealing on the photoluminescence properties of ZnS-core/SiO2 -shell nanowires synthesized by the thermal evaporation of ZnS powders followed by the sputter deposition of SiO2 were investigated. Transmission electron microscopy and X-ray diffraction analyses revealed that the cores and shells of the core-shell nanowires were single crystal zinc blende-type ZnO and amorphous SiO2, respectively. Photoluminescence (PL) measurement showed that the core-shell nanowires had a green emission band centered at around 525 nm with a shoulder at around 385 nm. The PL emission of the core-shell nanowires was enhanced in intensity by annealing in an oxidative atmosphere and further enhanced by subsequently annealing in a reducing atmosphere. Also the origin of the enhancement of the green emission by annealing is discussed based on the energy-dispersive X-ray spectroscopy analysis results. (© 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Nanowire-Based Electrochemical BiosensorsELECTROANALYSIS, Issue 6 2006Abstract We review recent advances in biosensors based on one-dimensional (1-D) nanostructure field-effect transistors (FET). Specifically, we address the fabrication, functionalization, assembly/alignment and sensing applications of FET based on carbon nanotubes, silicon nanowires and conducting polymer nanowires. The advantages and disadvantages of various fabrication, functionalization, and assembling procedures of these nanosensors are reviewed and discussed. We evaluate how they have been used for detection of various biological molecules and how such devices have enabled the achievement of high sensitivity and selectivity with low detection limits. Finally, we conclude by highlighting some of the challenges researchers face in the 1-D nanostructures research arena and also predict the direction toward which future research in this area might be directed. [source] Polyacrylamide gel electrophoresis followed by sodium dodecyl sulfate gradient polyacrylamide gel electrophoresis for the study of the dimer to monomer transition of human transthyretinELECTROPHORESIS, Issue 14 2003Klaus Altland Abstract Familial amyloidotic polyneuropathy (FAP) is caused by mutations which destabilize transthyretin (TTR) and facilitate the aggregation into extracellular amyloid fibrils preferentially in peripheral nerve and heart tissues. Therapeutic and preventive trials for FAP at the plasma TTR level require a careful study of the destabilization of TTR under variable conditions. We have developed a simple double one-dimensional (D1-D) electrophoretic procedure with polyacrylamide gel electrophoresis (PAGE) followed by sodium dodecylsulfate (SDS) gradient PAGE to study the dimer to monomer transition. TTR is first isolated by PAGE from other plasma proteins. The gel strip containing the TTR fraction is incubated in 2% SDS under varying conditions of temperature, buffer composition, pH, and additives like urea and/or a sulfhydryl-reactive agent, followed by SDS-gradient PAGE for the separation of TTR dimers and monomers. We demonstrate that an unidirectional dimer to monomer transition of normal TTR is achieved at 70,80°C in neutral to mild alkaline buffers or at 37°C and slightly acidic pH (6,7). Addition of urea favors the transition into monomers. Amyloidogenic mutations like amyloidogenic TTR (ATTR)-V30M or ATTR-I107V favor the transition into monomers in buffer systems close to the physiological pH of human plasma. We conclude that this finding has to be considered by any hypothesis on ATTR-derived amyloidogenesis. [source] Guest-Inclusion Behavior of Double-Strand 1D Coordination Polymers Based on N,N, -Type Schiff Base LigandsEUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 10 2008Qing Wang Abstract Four double-strand one-dimensional (1D) coordinationpolymers, namely, {[Ni(N3Py)2(NO3)2]·(C6H6)x·C2H5OH}n (1), [Cd(ImBNN)2(CH3C6H4SO3)2]n (2), {[Co(N3OPy)2(H2O)2](ClO4)2·C6H6·H2O}n (3), and {[Co(N3OPy)2(H2O)2](ClO4)2·(C8H10)x}n (4) were obtained from the assembly of three N,N, -type Schiff base ligands, 1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene (N3Py), 2,5-bis(4,-(imidazol-1-yl)benzyl)-3,4-diaza-2,4-hexadiene (ImBNN), and bis[4-(3-pyridylmethylenemino)phenoxy]methane (N3OPy), with transition-metal ions. All complexes were characterized by single-crystal X-ray diffraction, X-ray powder diffraction, and FTIR measurements. The guest-inclusion behavior of these complexes were investigated by thermogravimetric and X-ray powder diffraction analyses. The structural relationship between the ligands and the cavity sizes and packing fashions have been discussed to elucidate the distinctive guest-inclusion behavior of these complexes.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008) [source] Great Framework Variation of Polymers in the Manganese(II) Maleate/,,,,-Diimine System: Syntheses, Structures, and Magneto-Structural CorrelationEUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 15 2003Chengbing Ma Abstract Three novel manganese(II) coordination polymers, [Mn (maleate)(phen)]n (1; phen = 1,10-phenanthroline), [Mn(maleate)(phen)]n·nH2O (2), and [Mn(maleate)(bpy)]n (3; bpy = 2,2,-bipyridine), have been synthesized by treatment of Mn2+ with maleic acid with participation of chelate diimine ligands, and have been identified by single-crystal X-ray diffraction to have either one-dimensional (1D) zigzag chain structures (1 and 2) or a two-dimensional (2D) sinuous layer structure (3). Each maleate dianion coordinates to three Mn centers, in different bridging modes (syn - anti in 1 and 2, syn - syn and anti - anti in 3). These compounds represent an interesting example of structural topology variation from 1D to 2D mediated by chemically similar auxiliary chelate ligands. Variable-temperature magnetic susceptibility measurements show weak anti-ferromagnetic exchange interactions between the adjacent MnII ions, with J = ,0.06 cm,1 (2) and J = ,1.3 cm,1, zJ, = ,0.27 cm,1 (3). The differences in the magnitudes of these coupling interactions agree well with the nature of the carboxylate-bridging coordination of maleate. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003) [source] Synthesis and Microstructural Characterisation of Two New One-Dimensional Members of the (A3NiMnO6),(A3Mn3O9), Homologous Series (A = Ba, Sr)EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 13 2003Marķa Hernando Abstract Two new members of the one-dimensional (A3NiMnO6),(A3Mn3O9), homologous series, with the compositions (Sr0.75Ba0.25)5NiMn3O12 and Sr9Ni2Mn5O21, have been synthesised. Their structures can each be described as a hexagonal array of infinite one-dimensional chains of face-sharing polyhedra, running parallel to the c axis and separated by the Sr/Ba cations. The structure of (Sr0.75Ba0.25)5NiMn3O12, which constitutes the (, = 3, , = 2) member of the series, is made up of three face-sharing octahedra linked by one trigonal prism. For Sr9Ni2Mn5O21 (, = 2, , = 1) the sequence of polyhedra along the chains corresponds to a motif consisting of two octahedra,one trigonal prism,three octahedra,one trigonal prism. The manganese atoms occupy the octahedral sites in both phases, while the Ni2+ cations are distributed in the trigonal-prismatic sites in a disordered way. Only a small fraction of these (close to 20%) is located at the centres of the trigonal prisms, 80% being displaced towards the rectangular faces of the polyhedra and giving rise to a square-planar-like coordination. Both oxides present twinned microstructures, as evidenced by SAED and HREM. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003) [source] Enhanced Fluorescence Microscopic Imaging by Plasmonic Nanostructures: From a 1D Grating to a 2D Nanohole ArrayADVANCED FUNCTIONAL MATERIALS, Issue 6 2010Xiaoqiang Cui Abstract A two-dimensional (2D) plasmonic coupling nanostructure for enhanced fluorescence observation using a microscope is presented. The substrate contained periodically assembled nanohole arrays with a pitch of 400,nm and a depth of 25,nm. In comparison with one-dimensional (1D) gratings, this new substrate presented an excellent surface plasmon coupling ability to illuminate light from all directions. Under an optical microscope, an enhancement in the fluorescence intensity of up to 100 times compared with a plain glass slide was observed. The ability to markedly increase the fluorescence intensity means this technique has great potential for application in biodiagnostics, imaging, sensing, and photovoltaic cells. [source] Fabrication of CdSe-Nanofibers with Potential for Biomedical ApplicationsADVANCED FUNCTIONAL MATERIALS, Issue 6 2010Amir Fahmi Abstract The design and synthesis of nanostructured functional hybrid biomaterials are essential for the next generation of advanced diagnostics and the treatment of disease. A simple route to fabricate semiconductor nanofibers by self-assembled, elastin-like polymer (ELP)-templated semiconductor nanoparticles is reported. Core,shell nanostructures of CdSe nanoparticles with a shell of ELPs are used as building blocks to fabricate functional one-dimensional (1D) nanostructures. The CdSe particles are generated in situ within the ELP matrix at room temperature. The ELP controls the size and the size-distribution of the CdSe nanoparticles in an aqueous medium and simultaneously directs the self-assembly of core,shell building blocks into fibril architectures. It was found that the self-assembly of core,shell building blocks into nanofibers is strongly dependent on the pH value of the medium. Results of cytotoxicity and antiproliferation of the CdSe-ELP nanofibers demonstrate that the CdSe-ELP does not exhibit any toxicity towards B14 cells. Moreover, these are found to be markedly capable of crossing the cell membrane of B14. In contrast, unmodified CdSe nanoparticles with ELPs cause a strong toxic response and reduction in the cell proliferation. This concept is valid for the fabrication of a variety of metallic and semiconductor 1D-architectures. Therefore, it is believed that these could be used not only for biomedical purposes but for application in a wide range of advanced miniaturized devices. [source] The Influence of Mass Transfer on a Porous Fuel Cell ElectrodeFUEL CELLS, Issue 1-2 2004Y.-P. Sun Abstract A one-dimensional model for a porous fuel cell electrode using a liquid electrolyte with dissolved reactant is presented. The model consists of a Poisson, second-order ordinary differential equation, describing the effect of the electric field and a one-dimensional; Fickian diffusion, second-order ordinary differential equation describing the concentration variation associated with diffusion. The model accounts for mass transport and heterogeneous electrochemical reaction. The solution of this model is by the approximate Adomian polynomial method and is used to determine lateral distributions of concentration, overpotential and current density and overall cell polarisation. The model is used to simulate the effects of important system and operating parameters, i.e. local diffusion rates, and mass transport coefficients and electrode polarisation behaviour. [source] Communication between overpressured compartmentsGEOFLUIDS (ELECTRONIC), Issue 4 2001M. Wangen Abstract Overpressure build-up in compartments, and communication between overpressured compartments across faults are studied with simple analytical and numerical models. It is shown that the excess pressure in a (vertical) one-dimensional, one-compartment model can be written as the sum of the excess pressure generated in the seal above the compartment, and a second part, which is due to the expulsion of fluid from the compartment and the rocks below. The one-compartment model is generalized to a two-compartment model, which accounts for the fluid communication between the compartments through a fault zone. The volume rates of flow through the seals and the fault zone are shown to be the weighted mean of the volume rates of the one-dimensional, one-compartment model. The normalized weights are given by dimensionless numbers, called fault,seal numbers, which control the communication between the compartments. A fault,seal number much less than unity implies that the fault is a stronger barrier for the fluid flow than the seal. A fault,seal number larger than unity implies the opposite: that the seal is a stronger barrier than the fault. The conditions for isolated compartments and other regimes are identified in terms of the fault,seal numbers. It is discussed how the compartment fault,seal numbers can be computed when the permeability is given in the fault zone. The results given by the analytical compartment models are demonstrated and validated with two-dimensional numerical (finite element) simulations. [source] Spectral estimation on a sphere in geophysics and cosmologyGEOPHYSICAL JOURNAL INTERNATIONAL, Issue 3 2008F. A. Dahlen SUMMARY We address the problem of estimating the spherical-harmonic power spectrum of a statistically isotropic scalar signal from noise-contaminated data on a region of the unit sphere. Three different methods of spectral estimation are considered: (i) the spherical analogue of the one-dimensional (1-D) periodogram, (ii) the maximum-likelihood method and (iii) a spherical analogue of the 1-D multitaper method. The periodogram exhibits strong spectral leakage, especially for small regions of area A, 4,, and is generally unsuitable for spherical spectral analysis applications, just as it is in 1-D. The maximum-likelihood method is particularly useful in the case of nearly-whole-sphere coverage, A, 4,, and has been widely used in cosmology to estimate the spectrum of the cosmic microwave background radiation from spacecraft observations. The spherical multitaper method affords easy control over the fundamental trade-off between spectral resolution and variance, and is easily implemented regardless of the region size, requiring neither non-linear iteration nor large-scale matrix inversion. As a result, the method is ideally suited for most applications in geophysics, geodesy or planetary science, where the objective is to obtain a spatially localized estimate of the spectrum of a signal from noisy data within a pre-selected and typically small region. [source] Selective Atmospheric Pressure Chemical Vapor Deposition Route to CdS Arrays, Nanowires, and NanocombsADVANCED FUNCTIONAL MATERIALS, Issue 2 2004P. Ge Abstract CdS arrays, nanowires, and nanocombs were selectively prepared through an atmospheric pressure chemical vapor deposition (APCVD) process with CdCl2 and S as sources. The morphologies could be controlled by adjusting the deposition position, the temperature, and the flux of the carrier gas. The phase structure, morphologies, and photoluminescence properties of the CdS products were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and photoluminescence (PL) spectra. The formation mechanism of the nanowires is discussed on the basis of the experimental results. The adopted synthetic route is expected to be applied in the synthesis of other metal sulfide one-dimensional (1D) nanostructures. [source] The Stereostructure of Porphyra-334: An Experimental and Calculational NMR Investigation.HELVETICA CHIMICA ACTA, Issue 3 2007Evidence for an Efficient, Proton Sponge' Abstract The mycosporine-like amino acid (MAA) porphyra-334 (1) is subjected to extensive 1H- and 13C-NMR analysis as well as to density-functional-theory (DFT) calculations. All 1H- and 13C-NMR signals of 1 are assigned, as well as the resonances of prochiral proton pairs. This is achieved by 500-MHz standard COSY, HMQC, and HMBC experiments, as well as by one-dimensional (DPFGSE-NOE) and two-dimensional (NOESY) NOE experiments. Diffusion measurements (DOSY) confirm that 1 is monomeric in D2O solution. DFT Calculations yield 13C-NMR chemical shifts which are in good agreement for species 6 which is the imino N-protonated form of 1. An exceptionally high proton affinity of 265.7,kcal/mol is calculated for 1, indicating that 1 may behave as a very powerful ,proton sponge' of comparable strength as synthetic systems studied so far. Predictions of 13C-NMR chemical shifts by the ,NMRPredict' software are in agreement with the DFT data. The absolute configuration at the ring stereogenic center of 1 is concluded to be (S) from NOE data as well as from similarities with the absolute configuration (S) found in mycosporine-glycine 16. This supports the assumption that 1 is biochemically derived from 3,3- O -didehydroquinic acid (17). The data obtained question the results recently published by a different research group claiming that the configuration at the imino moiety of 1 is (Z), rather than (E) as established by the here presented study. [source] Credits, Qualifications and the Fluttering StandardHIGHER EDUCATION QUARTERLY, Issue 3 2001Paul H. Bridges The primary function of credit is to help assess the equivalence of learning and to facilitate student transfer within and between institutions. Recently, attention has focused on the role credit may have in defining the academic standards of qualifications. Some recently proposed qualifications frameworks are one-dimensional in that they have levels as the only measurable parameter. Such 'frameworks, are not true frameworks because there is no basis for differentiating the qualifications at each level. Other frameworks are two-dimensional, using credits and levels as the two parameters. Where the award of credit for a module reflects the satisfactory completion of all the designated learning outcomes at a specified level, there is a clear basis for relating credit to academic standards. In this situation, plotting the credit requirements for qualifications onto a framework that comprises levels and credits makes an important contribution towards understanding the relative standards of the qualifications. [source] Subglacial modulation of the hydrograph from glacierized basinsHYDROLOGICAL PROCESSES, Issue 19 2008Gwenn E. Flowers Abstract The extent of basin glacierization has important implications for the hydrograph in part, because snow, firn and ice impart different delays in water transport through the system. Here, the significance of subglacial drainage morphology in modulating the hydrograph is examined with a one-dimensional physically based model. The conceptual model of subglacial drainage comprises both ,fast' and ,slow' elements, respectively associated with summer and winter drainage regimes. The additional possibility of a permeable glacier substrate is taken into account by allowing water transport in a subglacial aquifer. Forced by prescribed rates of melt-water delivery to the glacier bed, the model predicts glacier discharge by drainage system provenance. The effects of (1) ,hard' versus ,soft' glacier beds, (2) subsurface permeability and groundwater flow, and (3) glacier geometry are then investigated. Hydrograph character, in the form of peak timing and amplitude, symmetry with respect to the forcing, and the amplitude of diurnal fluctuations, is affected by the partitioning of water through the various flow elements. Hard beds and impermeable substrates maximize the discharge routed through the fast-drainage system in the simulations, generally resulting in higher seasonal discharge maxima and stronger diurnal variations in discharge. High hydraulic transmissivities, either at the glacier bed or in underlying strata, hinder the development of the fast-drainage system in the simulations, producing hydrographs of lower amplitude. Glacier geometry has a modest effect, with adverse bed slopes, very thick or very thin ice and short glacier lengths favouring prolonged drainage through the slow system. These results suggest that the morphology and evolution of the subglacial drainage system may play a significant role in determining the character of the hydrograph from glacierized basins. Copyright © 2008 John Wiley & Sons, Ltd. [source] Hydrodynamics and geomorphic work of jökulhlaups (glacial outburst floods) from Kverkfjöll volcano, IcelandHYDROLOGICAL PROCESSES, Issue 6 2007Jonathan L. Carrivick Abstract Jökulhlaups (glacial outburst floods) occur frequently within most glaciated regions of the world and cause rapid landscape change, infrastructure damage, and human disturbance. The largest jökulhlaups known to have occurred during the Holocene within Iceland drained from the northern margin of Vatnajökull and along the Jökulsį į Fjöllum. Some of these jökulhlaups originated from Kverkfjöll volcano and were routed through anastomosing, high gradient and hydraulically rough channels. Landforms and sediments preserved within these channels permit palaeoflow reconstructions. Kverkfjöll jökulhlaups were reconstructed using palaeocompetence (point measurements), slope,area (one-dimensional), and depth-averaged two-dimensional (2D) hydrodynamic modelling techniques. The increasing complexity of 2D modelling required a range of assumptions, but produced information on both spatial and temporal variations in jökulhlaup characteristics. The jökulhlaups were volcanically triggered, had a linear-rise hydrograph and a peak discharge of 50 000,100 000 m3 s,1, which attenuated by 50,75% within 25 km. Frontal flow velocities were ,2 m s,1; but, as stage increased, velocities reached 5,15m s,1. Peak instantaneous shear stress and stream power reached 1 × 104 N m,2 and 1 × 105 W m,2 respectively. Hydraulic parameters can be related to landform groups. A hierarchy of landforms is proposed, ranging from the highest energy zones (erosional gorges, scoured bedrock, cataracts, and spillways) to the lowest energy zones (of valley fills, bars, and slackwater deposits). Fluvial erosion of bedrock occurred in Kverkfjallarani above ,3 m flow depth, ,7m s,1 flow velocity, ,1 × 102 N m,2 shear stress, and 3 × 102 W m,2 stream power. Fluvial deposition occurred in Kverkfjallarani below ,8 m flow depth, 11 m s,1 flow velocity, 5 × 102 N m,2 shear stress, and 3 × 103 W m,2 stream power. Hence, erosional and depositional ,envelopes' have considerable overlap, probably due to transitional flow phenomena and the influence of upstream effects, such as hydraulic ponding and topographic constrictions, for example. Holocene Kverkfjöll jökulhlaups achieved geomorphic work comparable to that of other late Pleistocene ,megafloods'. This work was a result of steep channel gradients, topographic channel constrictions, and high hydraulic roughness, rather than to extreme peak discharges. The Kverkfjöll jökulhlaups have implications for landscape evolution in north-central Iceland, for water-sediment inputs into the North Atlantic, and for recognizing jökulhlaups in the rock record. 2D hydrodynamic modelling is likely to be important for hazard mitigation in similar landscapes and upon other glaciated volcanoes, because it only requires an input hydrograph and a digital elevation model to run a model, rather than suites of geomorphological evidence and field-surveyed valley cross-sections, for example. Copyright © 2006 John Wiley & Sons, Ltd. [source] One- and two-dimensional modelling of overland flow in semiarid shrubland, Jornada basin, New MexicoHYDROLOGICAL PROCESSES, Issue 5 2006David A. Howes Abstract Two distributed parameter models, a one-dimensional (1D) model and a two-dimensional (2D) model, are developed to simulate overland flow in two small semiarid shrubland watersheds in the Jornada basin, southern New Mexico. The models are event-based and represent each watershed by an array of 1-m2 cells, in which the cell size is approximately equal to the average area of the shrubs. Each model uses only six parameters, for which values are obtained from field surveys and rainfall simulation experiments. In the 1D model, flow volumes through a fixed network are computed by a simple finite-difference solution to the 1D kinematic wave equation. In the 2D model, flow directions and volumes are computed by a second-order predictor,corrector finite-difference solution to the 2D kinematic wave equation, in which flow routing is implicit and may vary in response to flow conditions. The models are compared in terms of the runoff hydrograph and the spatial distribution of runoff. The simulation results suggest that both the 1D and the 2D models have much to offer as tools for the large-scale study of overland flow. Because it is based on a fixed flow network, the 1D model is better suited to the study of runoff due to individual rainfall events, whereas the 2D model may, with further development, be used to study both runoff and erosion during multiple rainfall events in which the dynamic nature of the terrain becomes an important consideration. Copyright © 2006 John Wiley & Sons, Ltd. [source] Advances in river ice hydrology 1999,2003HYDROLOGICAL PROCESSES, Issue 1 2005Brian Morse Abstract In the period 1999 to 2003, river ice has continued to have important socio-economic impacts in Canada and other Nordic countries. Concurrently, there have been many important advances in all areas of Canadian research into river ice engineering and hydrology. For example: (1) River ice processes were highlighted in two special journal issues (Canadian Journal of Civil Engineering in 2003 and Hydrological Processes in 2002) and at five conferences (Canadian Committee on River Ice Processes and the Environment in 1999, 2001 and 2003, and International Association of Hydraulic Research in 2000 and 2002). (2) A number of workers have clearly advanced our understanding of river ice processes by bringing together disparate information in comprehensive review articles. (3) There have been significant advances in river ice modelling. For example, both one-dimensional (e.g. RIVICE, RIVJAM, ICEJAM, HEC-RAS, etc.) and two-dimensional (2-D; www.river2d.ca) public-domain ice-jam models are now available. Work is ongoing to improve RIVER2D, and a commercial 2-D ice-process model is being developed. (4) The 1999,2003 period is notable for the number of distinctly hydrological and ecological studies. On the quantitative side, many are making efforts to determine streamflow during the winter period. On the ecological side, some new publications have addressed the link to water quality (temperature, dissolved oxygen, nutrients and pollutants), and others have dealt with sediment transport and geomorphology (particularly as it relates to break-up), stream ecology (plants, food cycle, etc.) and fish habitat. There is the growing recognition, that these types of study require collaborative efforts. In our view, the main areas requiring further work are: (1) to interface geomorphological and habitat models with quantitative river ice hydrodynamic models; (2) to develop a manager's toolbox (database management, remote sensing, forecasting, intervention methodologies, etc.) to enable agencies to intervene better at the time of ice-jam-induced floods; and (3) finalize ice-jam prevention methods on the St Lawrence River to safeguard its $2 billion commercial navigation industry. Copyright © 2005 John Wiley & Sons, Ltd. [source] One-Dimensional Conducting Polymer Nanostructures: Bulk Synthesis and ApplicationsADVANCED MATERIALS, Issue 14-15 2009Henry D. Tran Abstract This Progress Report provides a brief overview of current research activities in the field of one-dimensional (1D) conducting polymer nanostructures. The synthesis, properties, and applications of these materials are outlined with a strong emphasis on recent literature examples. Chemical methods that can produce 1D nanostructures in bulk quantities are discussed in the context of two different strategies: 1) procedures that rely on a nanoscale template or additive not inherent to the polymer and 2) those that do not. The different sub-classifications of these two strategies are delineated and the virtues and vices of each area are discussed. Following this discussion is an outline of the properties and applications of 1D conducting polymer nanostructures. This section focuses on applications in which nanostructured conducting polymers are clearly advantageous over their conventional counterparts. We conclude with our perspective on the main challenges and future research directions for this new class of nanomaterials. This Progress Report is not intended as a comprehensive review of the field, but rather a summary of select contributions that we feel will provide the reader with a strong basis for further investigation into this fast emerging field. [source] Ultrathin Nanowires,A Materials Chemistry Perspective,ADVANCED MATERIALS, Issue 9 2009Ludovico Cademartiri Abstract The recent years have seen an explosive interest in one-dimensional nanostructures1, as testified by the number of citations this field has accrued; as customary, its blossoming was enabled by chemical breakthroughs that allowed the reproducible and affordable synthesis of such structures.2, 3 The limitations of those syntheses was in the diameter of the nanowires that it could produce (hardly,<,10,nm), and in the use of expensive and low-yield techniques, such as chemical vapor deposition (CVD). This paper attempts to summarize the very recent chemical breakthroughs that have allowed the production of ultrathin nanowires, often in solution, and often in gram-scale quantities. By no means is this a comprehensive coverage of the field, which can in part be found in other excellent reviews1, 2, 4,6 but a selection of those contributions that we feel would most help put this emerging field in perspective. We will review the various synthetic strategies, their pros and cons, and we will give our best guesses as to the future directions of the field and what we can expect from it. [source] Wave propagation velocity under a vertically vibrated surface foundationINTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS, Issue 9 2009Jaehun Ahn Abstract The ultimate objective of the research conducted by the authors is to explore the feasibility of determining reliable in situ values of soil modulus as a function of strain. In field experiments, an excitation is applied on the ground surface using large-scale shakers, and the response of the soil deposit is recorded through receivers embedded in the soil. The focus of this paper is on the simulation and observation of signals that would be recorded at the receiver locations under idealized conditions to provide guidelines on the interpretation of the field measurements. Discrete models are used to reproduce one-dimensional and three-dimensional geometries. When the first times of arrival are detected by receivers under the vertical impulse, they coincide with the arrival of the P wave; therefore related to the constrained modulus of the material. If one considers, on the other hand, phase differences between the motions at two receivers, the picture is far more complicated and one would obtain propagation velocities, function of frequency and measuring location, which do not correspond to either the constrained modulus or Young's modulus. It is necessary then to conduct more rigorous and complicated analyses in order to interpret the data. This paper discusses and illustrates these points. Copyright © 2008 John Wiley & Sons, Ltd. 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