Home About us Contact | |||
Oxazoline Ligands (oxazoline + ligand)
Selected AbstractsPhospholane,Oxazoline Ligands for Ir-Catalyzed Asymmetric Hydrogenation.CHEMINFORM, Issue 25 2003Wenjun Tang Abstract For Abstract see ChemInform Abstract in Full Text. [source] Asymmetric Hydrogenation of Aromatic Olefins Catalyzed by Iridium Complexes of Proline-Derived Phosphine,Oxazoline Ligands.CHEMINFORM, Issue 18 2003Guopin Xu Abstract For Abstract see ChemInform Abstract in Full Text. [source] ChemInform Abstract: A New Class of Modular Phosphinite,Oxazoline Ligands: Ir-Catalyzed Enantioselective Hydrogenation of Alkenes.CHEMINFORM, Issue 18 2002Joerg Blankenstein Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source] Screening of a Modular Sugar-Based Phosphite,Oxazoline Ligand Library in Asymmetric Pd-Catalyzed Heck ReactionsCHEMISTRY - A EUROPEAN JOURNAL, Issue 12 2007Yvette Mata Abstract We have synthesised a library of phosphite,oxazoline ligands derived from readily available D -glucosamine. These ligands have been successfully screened in the palladium-catalysed Heck reaction of several substrates with high regio- (up to 99,%) and enantioselectivities (ee's up to 99,%) as well as with improved activities under standard thermal conditions. The results indicate that the catalytic performance is highly affected by the oxazoline and biarylphosphite substituents and the axial chirality of the biaryl moiety of the ligand. The Heck reactions were also performed under microwave irradiation conditions, allowing a considerably shorter reaction time (full conversion in minutes) maintaining the excellent regio- and enantioselectivities. [source] |