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Aryl Grignard Reagents (aryl + grignard_reagent)

Distribution by Scientific Domains
Chemistry100%
Distribution within Chemistry
Organic Chemistry60%
General & Introductory Chemistry40%

Selected Abstracts

Practical Iron-Catalyzed Allylations of Aryl Grignard Reagents

ADVANCED SYNTHESIS & CATALYSIS (PREVIOUSLY: JOURNAL FUER PRAKTISCHE CHEMIE), Issue 13 2010
Matthias Mayer
Abstract An operationally simple iron-catalyzed reductive cross-coupling reaction between aryl halides and allyl electrophiles has been developed. The underlying domino process exhibits high versatility with respect to the allylic leaving group (acetate, tosylate, diethyl phosphate, methyl carbonate, trimethylsilanolate, methanethiolate, chloride, bromide) and high economic and environmental sustainability with respect to the catalyst system (0.2,5 mol% tris(acetylacetonato)iron(III), ligand-free) and reaction conditions (tetrahydrofuran, 0,°C, 45,min). [source]

Direct Application of Phenolic Salts to Nickel-Catalyzed Cross-Coupling Reactions with Aryl Grignard Reagents,

ANGEWANDTE CHEMIE, Issue 27 2010
Da-Gang Yu
Nickel und Naphtholate: Der erfolgreiche Einsatz von Naphtholaten als Elektrophile (siehe Schema, X=Halogenid) in Kreuzkupplungen verbessert die Stufen- und Atomökonomie und senkt dadurch die Kosten, die entstehen, wenn komplizierte Gerüste aus leicht erhältlichen Phenolderivaten aufgebaut werden. [source]

Copper-Catalyzed Cross-Coupling of Alkyl and Aryl Grignard Reagents with Alkynyl Halides,

ANGEWANDTE CHEMIE, Issue 7 2010
Gérard Cahiez Dr.
Kupfer kann,s noch! Mit einer neuen, allgemein verwendbaren Strategie gelingt die Titelreaktion (siehe Schema; NMP=N -Methylpyrrolidinon). Die Reaktion ist chemoselektiv und ermöglicht die Synthese einer Vielzahl einfacher und funktionalisierter interner Alkine in hohen Ausbeuten. [source]

Efficient Chiral N-Heterocyclic Carbene/Copper(I)-Catalyzed Asymmetric Allylic Arylation with Aryl Grignard Reagents,

ANGEWANDTE CHEMIE, Issue 46 2009
Khalid
Gamma ist entscheidend: Die Titelreaktion gelang hoch regioselektiv mit Aryl-Grignard-Reagentien und einem Kupfer(I)-Katalysator mit einzähnigem chiralem N-heterocyclischem Carbenliganden und lieferte Diarylvinylmethane mit ausgezeichnetem Enantiomerenüberschuss und in hoher Ausbeute (siehe Schema). [source]

ChemInform Abstract: Transition-Metal-Free Electrophilic Amination Between Aryl Grignard Reagents and N-Chloroamines.

CHEMINFORM, Issue 33 2010
Takuji Hatakeyama
Abstract Various functional groups are tolerated under the mild conditions. [source]

ChemInform Abstract: Copper-Catalyzed Cross-Coupling of Alkyl and Aryl Grignard Reagents with Alkynyl Halides.

CHEMINFORM, Issue 24 2010
Gerard Cahiez
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]

ChemInform Abstract: Efficient Chiral N-Heterocyclic Carbene/Copper(I)-Catalyzed Asymmetric Allylic Arylation with Aryl Grignard Reagents.

CHEMINFORM, Issue 10 2010
Khalid B. Selim
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]

Transition Metal Catalyzed Cross-Coupling of Aryl Grignard Reagents with Aryl Fluorides via Pd- or Ni-Activation of the C,F Bond: An Efficient Synthesis of Unsymmetrical Biaryls , Application of Microwave Technology in Ligand and Catalyst Screening.

CHEMINFORM, Issue 27 2005
John W. Dankwardt
Abstract For Abstract see ChemInform Abstract in Full Text. [source]

Nickel(0)-Catalyzed Cross-Coupling of Alkyl Arenesulfonates with Aryl Grignard Reagents.

CHEMINFORM, Issue 36 2003
Chul-Hee Cho
Abstract For Abstract see ChemInform Abstract in Full Text. [source]

Nickel-Catalyzed Cross-Coupling of Non-Activated or Functionalized Aryl Halides with Aryl Grignard Reagents

CHEMISTRY - A EUROPEAN JOURNAL, Issue 34 2010
Lan-Gui Xie
New nickel complexes can efficiently catalyze cross-coupling of unactivated and deactivated aryl chlorides and fluorides with aryl Grignard reagents. The reaction can tolerate functional groups in aryl chlorides with or without the aid of additives, depending on the substrates (see scheme). [source]