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Matrix Porosity (matrix + porosity)
Selected AbstractsSolute transport in sand and chalk: a probabilistic approachHYDROLOGICAL PROCESSES, Issue 5 2006E. Carlier Abstract A probabilistic approach is used to simulate particle tracking for two types of porous medium. The first is sand grains with a single intergranular porosity. Particle tracking is carried out by advection and dispersion. The second is chalk granulates with intergranular and matrix porosities. Sorption can occur with advection and dispersion during particle tracking. Particle tracking is modelled as the sum of elementary steps with independent random variables in the sand medium. An exponential distribution is obtained for each elementary step and shows that the whole process is Markovian. A Gamma distribution or probability density function is then deduced. The relationships between dispersivity and the elementary step are given using the central limit theorem. Particle tracking in the chalky medium is a non-Markovian process. The probability density function depends on a power of the distance. Experimental simulations by dye tracer tests on a column have been performed for different distances and discharges. The probabilistic approach computations are in good agreement with the experimental data. The probabilistic computation seems an interesting and complementary approach to simulate transfer phenomena in porous media with respect to the traditional numerical methods. Copyright © 2006 John Wiley & Sons, Ltd. [source] Hydraulic pathways in the crystalline rock of the KTBGEOPHYSICAL JOURNAL INTERNATIONAL, Issue 1 2000Günter Zimmermann Fracture systems and fluid pathways must be analysed in order to understand the dynamical processes in the upper crust. Various deterministic as well as stochastic fracture networks in the depth section of the Franconian Lineament (6900 to 7140 m), which appears as a brittle ductile shear zone and prominent seismic reflector, were modelled to simulate the hydraulic situation at the two boreholes of the Continental Deep Drilling Program (KTB). They led to estimations of the hydraulic permeability in crystalline rock. The geometrical parameters of the fractures, such as fracture locations and orientations, were determined from structural borehole measurements, which create an image of the borehole wall. The selection of potentially open fractures was decided according to the stress field. Only fractures with the dip direction (azimuth) of the fracture plane perpendicular to the maximum horizontal stress field were assumed to be open. The motivation for this assumption is the fact that the maximum horizontal stress is higher than the vertical stress from the formation, indicating that the state of stress is a strike-slip faulting. Therefore, the probability of open fractures due to this particular stress field at the KTB sites is enhanced. Length scales for fracture apertures and extensions were stochastically varied and calibrated by hydraulic experiments. The mean fracture aperture was estimated to be 25 ,m, assuming an exponential distribution, with corresponding permeability in the range of 10,16 m2. Similar results were also obtained for log-normal and normal distributions, with a variation of permeability of the order of a factor of 2. The influence of the fracture length on permeability of the stochastic networks was also studied. Decreasing the fracture length beyond a specific threshold of 10 m led to networks with vanishing connectivity and hence vanishing permeability. Therefore, we assume a mean fracture length exceeding the threshold of 10 m as a necessary assumption for a macroscopic hydraulically active fracture system at the KTB site. The calculated porosity due to the fracture network is of the order of 10,3 per cent, which at first sight contradicts the estimated matrix porosity of 1 to 2 per cent from borehole measurements and core measurements. It can be concluded from these results, however, that if the fluid transport is due to a macroscopic fracture system, only very low porosity is needed for hydraulic flow with permeabilities up to several 10,16 m2, and hence the contribution of matrix porosity to the hydraulic transport is of a subordinate nature. [source] Interpretation of the enhancement of field-scale effective matrix diffusion coefficient in a single fracture using a semi-analytical power series solutionHYDROLOGICAL PROCESSES, Issue 6 2009Tai-Sheng Liou Abstract A power series solution for convergent radial transport in a single fracture (PCRTSF) is developed. Transport processes considered in PCRTSF include advection and hydrodynamic dispersion in the fracture, molecular diffusion in the matrix, diffusive mass exchange across the fracture-matrix interface, and mixing effects in the injection and the extraction boreholes. An analytical solution in terms of a power series in Laplace domain is developed first, which is then numerically inverted by de-Hoog et al.'s algorithm. Four dimensionless parameters determine the behaviour of a breakthrough curve (BTC) calculated by PCRTSF, which are, in the order of decreasing sensitivity, the matrix diffusion factor, two mixing factors, and the Peclet number. The first parameter is lumped from matrix porosity, effective matrix diffusion coefficient, fracture aperture, and retardation factors. Its value increases as the matrix diffusion effect becomes significant. A non-zero matrix diffusion factor results in a , 3/2 slope of the tail of a log,log BTC, a common property for tracer diffusion into an infinite matrix. Both mixing factors have equal effects on BTC characteristics. However, the Peclet number has virtually no effect on BTC tail. PCRTSF is applied to re-analyse two published test results that were obtained from convergent radial tracer tests in a discrete, horizontal fracture in Silurian dolomite. PCRTSF is able to fit the field BTCs better than the original channel model does if a large matrix diffusion coefficient is used. Noticeably, the ratio of field-scale to lab-scale matrix diffusion coefficients can be as large as 378. This enhancement of the field-scale matrix diffusion coefficient may be ascribed to the presence of a degraded zone at the fracture-matrix interface because of karstic effects, or to flow channeling as a result of aperture heterogeneity. Copyright © 2009 John Wiley & Sons, Ltd. [source] Influence of the matrix porosity on the synthesis and adsorption behavior of dithiocarbamate styrenic resins toward zinc(II) and cadmium(II) ionsJOURNAL OF APPLIED POLYMER SCIENCE, Issue 5 2010Priscila A. da Costa Abstract The dependence of the adsorption behavior toward Zn2+ and Cd2+ on the synthesis conditions of dithiocarbamate styrenic resins was investigated. We synthesized styrene,divinylbenzene copolymers with different kinds of porous structures by varying the divinylbenzene (DVB)-to-styrene ratio and the dilution degree of the monomers with n -heptane. The porous structure of these materials was characterized. The introduction of the dithiocarbamate moiety on the copolymers followed a synthetic pathway based on the nitration reaction, reduction of the nitro group to the amino one, and finally, the addition of the amino group to CS2. All of the synthesis steps were monitored by Fourier transform infrared spectroscopy. Only the addition reaction to CS2 was greatly influenced by the copolymer porosity. The effect of the dilution degree on the reaction extension was more pronounced than the effect of the DVB content. The more porous materials with higher dithiocarbamate contents adsorbed a higher amount of ions in a faster way, with Zn2+ being preferable over Cd2+ ions. The difference between the Zn2+ and Cd2+ adsorption rates was enhanced with the copolymer porosity, and also enhanced was the difference between the amounts of ions adsorbed by the copolymer; this suggested that the selectivity toward these ions could be controlled by the copolymer porous structure. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 [source] Processing and Properties of a Porous Oxide Matrix Composite Reinforced with Continuous Oxide FibersJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 10 2003Magnus G. Holmquist A process to manufacture porous oxide matrix/polycrystalline oxide fiber composites was developed and evaluated. The method uses infiltration of fiber cloths with an aqueous slurry of mullite/alumina powders to make prepregs. By careful manipulation of the interparticle pair potential in the slurry, a consolidated slurry with a high particle density is produced with a sufficiently low viscosity to allow efficient infiltration of the fiber tows. Vibration-assisted infiltration of stacked, cloth prepregs in combination with a simple vacuum bag technique produced composites with homogeneous microstructures. The method has the additional advantage of allowing complex shapes to be made. Subsequent infiltration of the powder mixture with an alumina precursor was made to strengthen the matrix. The porous matrix, without fibers, possessed good thermal stability and showed linear shrinkage of 0.9% on heat treatment at 1200°C. Mechanical properties were evaluated in flexural testing in a manner that precluded interlaminar shear failure before failure via the tensile stresses. It was shown that the composite produced by this method was comparable to porous oxide matrix composites manufactured by other processes using the same fibers (N610 and N720). The ratio of notch strength to unnotch strength for a crack to width ratio of 0.5 was 0.7,0.9, indicating moderate notch sensitivity. Interlaminar shear strength, which is dominated by matrix strength, changed from 7 to 12 MPa for matrix porosity ranging from 38% to 43%, respectively. The porous microstructure did not change after aging at 1200°C for 100 h. Heat treatment at 1300°C for 100 h reduced the strength for the N610 and N720 composites by 35% and 20%, respectively, and increased their brittle nature. [source] Hydrocarbon Accumulation Conditions of Ordovician Carbonate in Tarim BasinACTA GEOLOGICA SINICA (ENGLISH EDITION), Issue 5 2010LI Qiming Abstract: Based on comprehensive analysis of reservoir-forming conditions, the diversity of reservoir and the difference of multistage hydrocarbon charge are the key factors for the carbonate hydrocarbon accumulation of the Ordovician in the Tarim Basin. Undergone four major deposition-tectonic cycles, the Ordovician carbonate formed a stable structural framework with huge uplifts, in which are developed reservoirs of the reef-bank type and unconformity type, and resulted in multistage hydrocarbon charge and accumulation during the Caledonian, Late Hercynian and Late Himalayan. With low matrix porosity and permeability of the Ordovician carbonate, the secondary solution pores and caverns serve as the main reservoir space. The polyphase tectonic movements formed unconformity reservoirs widely distributed around the paleo-uplifts; and the reef-bank reservoir is controlled by two kinds of sedimentary facies belts, namely the steep slope and gentle slope. The unconventional carbonate pool is characterized by extensive distribution, no obvious edge water or bottom water, complicated oil/gas/water relations and severe heterogeneity controlled by reservoirs. The low porosity and low permeability reservoir together with multi-period hydrocarbon accumulation resulted in the difference and complex of the distribution and production of oil/gas/water. The distribution of hydrocarbon is controlled by the temporal-spatial relation between revolution of source rocks and paleo-uplifts. The heterogenetic carbonate reservoir and late-stage gas charge are the main factors making the oil/ gas phase complicated. The slope areas of the paleo-uplifts formed in the Paleozoic are the main carbonate exploration directions based on comprehensive evaluation. The Ordovician of the northern slope of the Tazhong uplift, Lunnan and its periphery areas are practical exploration fields. The Yengimahalla-Hanikatam and Markit slopes are the important replacement targets for carbonate exploration. Gucheng, Tadong, the deep layers of Cambrian dolomite in the Lunnan and Tazhong-Bachu areas are favorable directions for research and risk exploration. 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