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Mass Transfer Parameters (mass + transfer_parameter)
Selected AbstractsInfluence of temperature on mass transfer in an incomplete trapping supported liquid membrane extraction of triazole fungicidesJOURNAL OF SEPARATION SCIENCE, JSS, Issue 7 2009Luke Chimuka Abstract The influence of temperature in a supported liquid membrane (SLM) extraction of triazole fungicides was investigated. The mass transfer parameters such as diffusion coefficient, flux and apparent viscosity were determined at temperatures ranging from 5 to 40°C. Increase in temperature led to an increase in diffusion coefficient and flux with a flowing acceptor solution. The apparent viscosity also decreased with an increase in temperature. However, the increase in mass transfer parameters did not result in an overall increase in extraction efficiency with a stagnant or circulation acceptor phase. Stripping of the analytes from the membrane into the acceptor phase as well as the configuration of the extraction unit could have limited the influence of temperature on mass transfer. The partition coefficient of analytes from the acceptor solution to the membrane, KA, was found to be much higher than that from the donor solution to the membrane KD, thus triazole compounds preferred to remain in the membrane even with an increased extraction temperature. [source] Simulation and validation of ethanol removal from water in an adsorption packed bed: Isotherm and mass transfer parameter determination in batch studiesTHE CANADIAN JOURNAL OF CHEMICAL ENGINEERING, Issue 5 2010R. A. Jones Abstract Preferential adsorption of ethanol from ethanol/water mixtures in batch equilibrium and kinetic experiments were carried out on a commercially available activated carbon adsorbent Filtrasorb 600 (F-600). A model based on finite difference method was developed and employed to determine the mass transfer parameters and equilibrium behaviour for the adsorption of ethanol from simple batch systems. The estimates of the adsorption isotherm along with the mass transfer parameters were used to simulate the transient performance that could be expected in a packed bed under various operating conditions (feed flow rate, feed concentration, and particle size). The applicability of the simulation results were found to be a good match with experimental packed bed experiments over the entire range of operating conditions tested. La cinétique et l'isotherme d'adsorption de l'éthanol des mélanges eau/éthanol lors d'expériences en discontinus ont été déterminées pour un adsorbant au charbon activé disponible dans le commerce, le Filtrasorb 600 (F-600). Un modèle basé sur la méthode des différences finies a été développé et utilisé pour déterminer les paramètres de transfert de matière et étudier le comportement à l'équilibre pour l'adsorption préférentielle de l'éthanol en systèmes discontinus. Les estimations de l'isotherme d'adsorption aussi bien que les paramètres de transfert de matière ont été utilisées pour simuler la performance en régime transitoire d'un lit d'adsorbant sous diverses conditions de fonctionnement (taux d'écoulement du mélange, concentration du mélange et la taille des particules). L'applicabilité des résultats de simulation s'est avérée tout à fait concordante avec les données expérimentales sous toutes les conditions de fonctionnement examinées. [source] A multikinetic model approach to predict gluconic acid production in an airlift bioreactorBIOTECHNOLOGY JOURNAL, Issue 5 2007Mukesh Mayani Abstract This paper uses a multikinetic approach to predict gluconic acid (GA) production performance in a 4.5 L airlift bioreactor (ALBR). The mathematical model consists of a set of simultaneous firstorder ordinary differential equations obtained from material balances of cell biomass, GA, glucose, and dissolved oxygen. Multikinetic models, namely, logistic and contois equations constitute kinetic part of the main model. The main model also takes into account the hydrodynamic and mass transfer parameters. These equations were solved using ODE solver of MATLAB v6.5 software. The mathematical model was validated with the experimental data available in the literature and is used to predict the effect of change in initial biomass and air sparging rate on the GA production. It is concluded that the mathematical model incorporated with multikinetic approach would be more efficient to predict the change in operating parameters on overall bioprocess of GA production in an ALBR. [source] Activated Carbon Adsorbent for the Aqueous Phase Adsorption of Amoxicillin in a Fixed BedCHEMICAL ENGINEERING & TECHNOLOGY (CET), Issue 4 2010N. J. R. Ornelas Abstract Equilibrium constant and mass transfer parameters are needed for the study of amoxicillin separation in any process involving adsorption in fixed beds. In this work, the adsorption of amoxicillin and 6-aminopenillanic acid in aqueous solution on activated carbon were studied using static adsorption tests. The adsorption capacity was found to be strongly dependent on the pH of the aqueous phase. The adsorption constants, overall mass transfer coefficients, and axial dispersion coefficients for amoxicillin and 6-aminopenillanic acid were determined, by moment analysis, from a series of step tests in a fixed bed packed with activated carbon. The total bed voidage and axial dispersion coefficient were estimated from blue dextran pulse test data at different flow rates. The results show that adsorption intensity increased with increasing temperature. Furthermore, the increasing trend of HETP with velocity suggests that axial dispersion and mass transfer resistance control the column efficiency. [source] | ||||||||||