Home About us Contact
|
Home About us Contact | ||
|
|
||
Major Elements (major + element)
Selected AbstractsMajor Elements in Lake Muhazi, Rwanda, East AfricaACTA GEOLOGICA SINICA (ENGLISH EDITION), Issue 5 2009Jean de la Paix MUPENZI Abstract: The aim of this study undertaken at Lake Muhazi in Rwanda was to determine and analyze the major elements present in water. The presence of many major elements (Al, As, Ba, C, Ca, Cu, Fe, H+, K, Mg, Mn, N, P, S, Si, and Zn) was determined by spectroscopic technique. The concentrations of the elements were measured in water samples taken from three different locations of the lake from May to August 2008. The lake is polluted by water flow from mountain sides surrounding the lake. Other causes of pollution could be the use of agrochemicals in the sugar land, which surrounds the lake, and human activities near the lake. Finally, we proposed the strategies that can be applied in order to ensure good conservation of the environment and to prevent augmentation of heavy materials into the lake. [source] Major element and primary sulfur concentrations in Apollo 12 mare basalts: The view from melt inclusionsMETEORITICS & PLANETARY SCIENCE, Issue 5 2005Daniel J. BOMBARDIERI These lunar basalts are likely to be genetically related by olivine accumulation (Walker et al. 1976a, b). Our results show that major element compositions of melt inclusions from samples 12009, 12075, and 12020 follow model crystallization trends from a parental liquid similar in composition to whole rock sample 12009, thereby partially confirming the olivine accumulation hypothesis. In contrast, the compositions of melt inclusions from samples 12018, 12040, and 12035 fall away from model crystallization trends, suggesting that these samples crystallized from melts compositionally distinct from the 12009 parent liquid and therefore may not be strictly cogenetic with other members of the Apollo 12 picritic basalt suite. Sulfur concentrations in melt inclusions hosted in early crystallized olivine (Fo75) are consistent with a primary magmatic composition of 1050 ppm S, or about a factor of 2 greater than whole rock compositions with 400,600 ppm S. The Apollo 12 picritic basalt parental magma apparently experienced outgassing and loss of S during transport and eruption on the lunar surface. Even with the higher estimates of primary magmatic sulfur concentrations provided by the melt inclusions, the Apollo 12 picritic basalt magmas would have been undersaturated in sulfide in their mantle source regions and capable of transporting chalcophile elements from the lunar mantle to the surface. Therefore, the measured low concentration of chalcophile elements (e.g., Cu, Au, PGEs) in these lavas must be a primary feature of the lunar mantle and is not related to residual sulfide remaining in the mantle during melting. We estimate the sulfur concentration of the Apollo 12 mare basalt source regions to be ,75 ppm, which is significantly lower than that of the terrestrial mantle. [source] The flora of the South Sandwich Islands, with particular reference to the influence of geothermal heatingJOURNAL OF BIOGEOGRAPHY, Issue 6 2000P. Convey Abstract Aim, To carry out as comprehensive a survey as practicable of the flora (higher plants, mosses, liverworts, lichens, basidiomycete fungi and diatoms) of the isolated, volcanically active, South Sandwich Islands archipelago in the southern South Atlantic. To relate the components of this flora to (1) the influence of local geothermal heating and (2) wider regional floras. Location, South Sandwich Islands, southern South Atlantic Ocean, maritime Antarctic (56,60° S, 26,28° W). Methods, Ice-free accessible sites on all 11 of the major islands in the archipelago were visited by helicopter in January 1997. During each visit, voucher specimens of each floral group were collected. The comprehensiveness of collections obtained at each site varied with the duration of each visit (a function of tight logistic constraints) and extent of site. Visit duration varied from 1 to 9 h at most sites, with longer periods spent on Bellingshausen Island (2 days) and Leskov Island (1 day). Candlemas Island was examined in greater detail over a 4-week period in February 1997. At all sites, particular attention was given to areas influenced by geothermal heating. Results, Data obtained in 1997 are combined with updated records from the only previous survey (in 1964) to provide a baseline description of the flora of the archipelago, which currently includes 1 phanerogam, 38 mosses, 11 liverworts, 5 basidiomycete fungi, 41 lichenised fungi and 16 diatoms with, additionally, several taxa identified only to genus. Major elements of the moss and liverwort floras are composed of South American taxa (32% and 73%, respectively), with a further 45% of mosses having bipolar or cosmopolitan distributions. These two groups show low levels of Antarctic endemicity (11% and 18%, respectively). In contrast, 52% of lichens and 80% of basidiomycete fungi are endemic to the Antarctic. A further 36% of lichens are bipolar/cosmopolitan, with only 5% of South American origin. Main Conclusions, The flora of the South Sandwich Islands is clearly derived from those of other Antarctic zones. The flora of unheated ground is closely related to that of the maritime Antarctic, although with a very limited number of species represented. That of heated ground contains both maritime and sub-Antarctic elements, confirming the importance of geothermal heating for successful colonisation of the latter group. The occurrence of several maritime Antarctic species only on heated ground confirms the extreme severity of the archipelago's climate in comparison with well-studied sites much further south in this biogeographical zone. [source] Structural diversity of bacterial communities in a heavy metal mineralized granite outcropENVIRONMENTAL MICROBIOLOGY, Issue 3 2006Deirdre Gleeson Summary This laboratory study of a variably mineralized and hydrothermally altered granite outcrop investigated the influences of rock-surface chemistry and heavy metal content on resident bacterial populations. Results indicated that elevated heavy metal concentrations had a profound impact on bacterial community structure, with strong relationships found between certain ribotypes and particular chemical/heavy metal elements. Automated ribosomal intergenic sequence analysis (ARISA) was used to assess the nature and extent of bacterial diversity, and this was combined with chemical analysis and multivariate statistics to identify the main geochemical factors influencing bacterial community structure. A randomization test revealed significant changes in bacterial structure between samples, while canonical correspondence analysis (CCA) related each individual ARISA profile to linear combinations of the chemical variables (mineralogy, major element and heavy metal concentrations) revealing the geochemical factors that correlated with changes in the ARISA data. anova was performed to further explore interactions between individual ribotypes and chemical/heavy metal composition, and revealed that a high proportion of ribotypes correlated significantly with heavy metals. [source] New plant protection information system in Hungary,EPPO BULLETIN, Issue 1 2000A. Pákozdi Data on the occurrence and spread of pests has been supplied by the Hungarian Plant Protection Organization for over 40 years. Since the 1970s, this service has been operated by the central station and the 20 county stations of the Plant Protection Organization. Data recorded on pest occurrence and developmental stage of pests and plants has been used to run a forecasting system at local and national levels. However, because of significant staff reductions in the Plant Protection Organization and the disappearance of independent forecasting groups, the reliability of the system, which was based on very specific data, has decreased. It has become necessary to develop a more reliable and flexible computer-aided system (Plant Protection Information System, PPIS), better adjusted to the political and economic changes that have occurred. A major element of the new system, introduced in 1997, is that excessively detailed recording was replaced by a more practical general approach with fewer subjective errors. Specialists from the county stations of the Plant Protection Organization monitor infestation levels of 73 pests in 20 crops using five qualification categories. The results obtained are input into the PPIS program, which processes them into user-friendly charts and maps showing the plant health situation in each county and in the country as a whole, as a basis for taking decisions on plant protection measures. [source] Proportion in the Design of Women's Fashionable Clothing: A 50-Year RetrospectiveFAMILY & CONSUMER SCIENCES RESEARCH JOURNAL, Issue 2 2007Diana Saiki Proportion is a major element defining the appearance of apparel. This study identifies the proportions found in women's daywear. Data from 4,026 advertisement and main feature photographs in Vogue magazine from 1945 to 1995 are analyzed. Clothing ensembles are measured from left to right (horizontal proportion) and top to bottom (vertical proportion). The greatest number of observed horizontal proportions is in the 50/50 category, which is a proportion that is well balanced. The most frequent vertical proportion is 35/65, which is close to the golden section or ideal proportion. The proportion most equal to the golden section (40/60) is not the most frequent vertical proportion. In the 1960s, a time marked by social unrest and transition in women's roles in the United States, findings indicate that apparel meeting the guidelines of good proportion were not as common as other times. The study of proportion has application in teaching and critiquing design. [source] RNAi-mediated MEK1 knock-down prevents ERK1/2 activation and abolishes human hepatocarcinoma growth in vitro and in vivoINTERNATIONAL JOURNAL OF CANCER, Issue 6 2010Luc Gailhouste Abstract The mitogen-activated protein kinases MEK/ERK pathway regulates fundamental processes in malignant cells and represents an attractive target in the development of new cancer treatments especially for human hepatocarcinoma highly resistant to chemotherapy. Although gene extinction experiments have suggested distinct roles for these proteins, the MEK/ERK cascade remains widely considered as exhibiting an overlap of functions. To investigate the functionality of each kinase in tumorigenesis, we have generated stably knock-down clones for MEK1/2 and ERK1/2 isoforms in the human hepatocellular carcinoma line HuH7. Our results have shown that RNAi strategy allows a specific disruption of the targeted kinases and argued for the critical function of MEK1 in liver tumor growth. Transient and stable extinction experiments demonstrated that MEK1 isoform acts as a major element in the signal transduction by phosphorylating ERK1 and ERK2 after growth factors stimulation, whereas oncogenic level of ERK1/2 phosphorylation appears to be MEK1 and MEK2 dependent in basal condition. In addition, silencing of MEK1 or ERK2 abolished cell proliferation and DNA replication in vitro as well as tumor growth in vivo after injection in rodent. In contrast, targeting MEK2 or ERK1 had no effect on hepatocarcinoma progression. These results strongly corroborate the relevance of targeting the MEK cascade as attested by pharmacologic drugs and support the potential application of RNAi in future development of more effective cancer therapies. Our study emphasizes the importance of the MEK/ERK pathway in human hepatocarcinoma cell growth and argues for a crucial role of MEK1 and ERK2 in this regulation. [source] Transitory Sites: Mapping Dubai's ,Forgotten' Urban SpacesINTERNATIONAL JOURNAL OF URBAN AND REGIONAL RESEARCH, Issue 4 2008YASSER ELSHESHTAWY Abstract Seeking to uncover a hidden side of Dubai, this article investigates the city's ,forgotten' urban spaces. I use a theoretical framework that responds to a shift in global city research, emphasizing the everyday as well as transnational connections in which the local and the global are closely intertwined. I argue that such processes can be observed in these ,forgotten' settings, which, as well as being major gathering points, are utilized by Dubai's low-income migrant community for the exchange of information. Through an analysis of users and their activities as well as of the morphology of these spaces, I situate them within the overall development of Dubai. A key construct developed in this study and used as a unit of analysis is the notion of transitory sites , viewed as a major element in understanding migrant cities. The architectural and urban character of these sites is identified. A key finding is that low-income migrants resist globalizing influences by claiming these settings and establishing linkages through them to their home countries. Résumé En tentant de révéler la face cachée de Dubaï, cet article étudie les espaces urbains ,oubliés' des grandes villes. Son cadre théorique tient compte d'une transformation dans la recherche sur les villes planétaires, en soulignant les rapports, à la fois quotidiens et transnationaux, dans lesquels le local et le mondial sont liés de manière inextricable. Ce genre de processus est observable dans ces environnements ,oubliés' qui, en plus d'être des points de rassemblement importants, servent à la communauté des migrants à faible revenu de Dubaï pour échanger des informations. En analysant les usagers et leurs activités, ainsi que la morphologie de ces espaces, on peut les positionner dans le cadre de l'aménagement global de Dubaï. Cette étude produit un concept essentiel qui est utilisé comme unité d'analyse : la notion de sites transitoires, considérée comme un élément majeur pour comprendre les villes de migration. Le caractère architectural et urbain de ces sites est identifié. L'un des principaux résultats est le fait que les migrants à faible revenu résistent aux influences mondialisatrices en revendiquant ces espaces et en instaurant, grâce à eux, des liens avec leurs pays d'origine. [source] NMR structure of the pseudo -receiver domain of CikAPROTEIN SCIENCE, Issue 3 2007Tiyu Gao Abstract The circadian input kinase (CikA) is a major element of the pathway that provides environmental information to the circadian clock of the cyanobacterium Synechococcus elongatus. CikA is a polypeptide of 754 residues and has three recognizable domains: GAF, histidine protein kinase, and receiver-like. This latter domain of CikA lacks the conserved phospho-accepting aspartyl residue of bona fide receiver domains and is thus a pseudo -receiver (PsR). Recently, it was shown that the PsR domain (1) attenuates the autokinase activity of CikA, (2) is necessary to localize CikA to the cell pole, and (3) is necessary for the destabilization of CikA in the presence of the quinone analog 2,5-dibromo-3-methyl-6-isopropyl-p-benzoquinone (DBMIB). The solution structure of the PsR domain of CikA, CikAPsR, is presented here. A model of the interaction between the PsR domain and HPK portion of CikA provides a potential explanation for how the PsR domain attenuates the autokinase activity of CikA. Finally, a likely quinone-binding surface on CikAPsR is shown here. [source] Insect-symbiont systems: From complex relationships to biotechnological applicationsBIOTECHNOLOGY JOURNAL, Issue 12 2009Sandra Chaves Abstract Microbial symbiosis is a ubiquitous aspect of life and was a major element in the ability of insects to explore several adverse environments. To date, the study of symbiosis in insects has been impaired by the unculturability of most symbionts. However, some molecular methods represent powerful tools to help understand insect-microorganism associations and to disclose new symbiont-host systems. Beyond playing an essential role in nutrition and development of the insects, symbionts can produce bioactive compounds that protect the host against adverse environmental conditions, predators and/or direct competitors. Since the search for natural bioactive products and new enzymes is a developing area, understanding the diversity and nature of symbiont-host relationships paves the way for the exploitation of new resources in biotechnology. Furthermore, genetic transformation of the symbionts with genes that code for compounds that are toxic for pathogenic and phytopathogenic agents is also a promising area of application of the insect-symbiont relationships. The search for new bioactive compounds, the use of symbionts for pest and disease control and the molecular strategies applied for these purposes are issues of particular interest for innovative biotechnological applications and are addressed in the present review. [source] Corporate Governance in Germany and the German Corporate Governance CodeCORPORATE GOVERNANCE, Issue 3 2005Gerhard Cromme The term "corporate governance", and all that it implies, is now in everyday use in Germany. This is due to the enormous changes Germany has experienced in recent years, in international business, international finance and in German industrial structures. This contribution deals with recent changes in the German system of corporate governance. After a short historical review, the major elements of the international context that form the background for changes in Germany are discussed. This is followed by an explanation of the German Corporate Governance Code and its role, concluding with a prospectus for further possible developments and a summary of key points. [source] Nutrients, diversity, and community structure of two phytotelm systems in a lower montane forest, Puerto RicoECOLOGICAL ENTOMOLOGY, Issue 3 2000Barbara A. Richardson Summary 1. Bromeliad and heliconia phytotelmata in the same forest area were compared in terms of their animal assemblages, nutrient inputs, and plant architecture. 2. For all major elements, nutrient inputs from canopy-derived debris and rainfall in bromeliads were significantly lower than those derived from decaying flower parts and plant secretions in heliconia bracts. Bromeliads contained significantly fewer organisms per unit volume of water and unit dry weight of organic matter than did heliconia inflorescences. They also contained a significantly lower animal biomass (199 mg DW from 15 bromeliads, 527 mg DW from 15 heliconia inflorescences). 3. Species richness was independent of abundance, demonstrating that, at least for small container habitats, higher abundance does not necessarily lead to a greater species richness. Communities were remarkably similar in patterns of relative abundance and species richness (23 spp. in bromeliads, 21 spp. in heliconia), probably due to functional similarities in plant architecture, with the two most abundant species comprising 60,62% of the total community. Coefficients of similarity were low because of marked differences in species assemblages. 4. Some taxa were phytotelm generalists but most showed a preference for one particular habitat, indicating differential selection in the choice of oviposition sites and larval development within the forest ecosystem. In common with many island communities, species richness was lower than that reported for these phytotelm habitats in mainland central and south America. [source] REVIEW: Behavioural assessment of drug reinforcement and addictive features in rodents: an overviewADDICTION BIOLOGY, Issue 1 2006Carles Sanchis-Segura ABSTRACT Some psychoactive drugs are abused because of their ability to act as reinforcers. As a consequence behavioural patterns (such as drug-seeking/drug-taking behaviours) are promoted that ensure further drug consumption. After prolonged drug self-administration, some individuals lose control over their behaviour so that these drug-seeking/taking behaviours become compulsive, pervading almost all life activities and precipitating the loss of social compatibility. Thus, the syndrome of addictive behaviour is qualitatively different from controlled drug consumption. Drug-induced reinforcement can be assessed directly in laboratory animals by either operant or non-operant self-administration methods, by classical conditioning-based paradigms such as conditioned place preference or sign tracking, by facilitation of intracranial electric self-stimulation, or, alternatively by drug-induced memory enhancement. In contrast, addiction cannot be modelled in animals, at least as a whole, within the constraints of the laboratory. However, various procedures have been proposed as possible rodent analogues of addiction's major elements including compulsive drug seeking, relapse, loss of control/impulsivity, and continued drug consumption despite negative consequences. This review provides an extensive overview and a critical evaluation of the methods currently used for studying drug-induced reinforcement as well as specific features of addictive behaviour. In addition, comic strips that illustrate behavioural methods used in the drug abuse field are provided given for free download under http://www.zi-mannheim/psychopharmacology.de [source] Characterization of major and trace elements in sclerotium grainsEUROPEAN JOURNAL OF SOIL SCIENCE, Issue 3 2007M. Watanabe Summary Sclerotium grains in soil contain humus-metal complexes that are probably produced from fungal metabolites. The characterization of major elements in sclerotium grains collected from volcanic ash soils in Mt Myoko was examined by X-ray photoelectron spectroscopy, FT-IR spectrometry and CHN analysis, and the concentration of trace elements was determined by PIXE (particle induced X-ray emission spectrometer) analysis. The content of major elements, C, H, N, O and Al, was approximately 47.6, 3.32, 0.78, 30.2 and 1.4% by mass, respectively. Trace elements such as Ti, Cr, Mn, Cu, Zn, Br and Pb were detected in the grains at concentrations between 10 and 100 ,g g,1. Functional carbon groups for the whole grain were characterized by the dominance of O-alkyl C associated with aromatic C. The comparison between the surface and subsurface (matrix) of the grain showed that the concentrations of O, C and N were relatively greater on the surface of sclerotium grains than in the matrix. The proportion of carbon having C,O, C=O, and O,C=O bonds, O and N showed a tendency to decrease from the surface towards the matrix. The proportion of C assigned as C,C and/or C,H bonds had a tendency to increase towards the matrix associated with Al. [source] THE IMPORTANCE OF PREADAPTED GENOMES IN THE ORIGIN OF THE ANIMAL BODYPLANS AND THE CAMBRIAN EXPLOSIONEVOLUTION, Issue 5 2010Charles R. Marshall The genomes of taxa whose stem lineages branched early in metazoan history, and of allied protistan groups, provide a tantalizing outline of the morphological and genomic changes that accompanied the origin and early diversifications of animals. Genome comparisons show that the early clades increasingly contain genes that mediate development of complex features only seen in later metazoan branches. Peak additions of protein-coding regulatory genes occurred deep in the metazoan tree, evidently within stem groups of metazoans and eumetazoans. However, the bodyplans of these early-branching clades are relatively simple. The existence of major elements of the bilaterian developmental toolkit in these simpler organisms implies that these components evolved for functions other than the production of complex morphology, preadapting the genome for the morphological differentiation that occurred higher in metazoan phylogeny. Stem lineages of the bilaterian phyla apparently required few additional genes beyond their diploblastic ancestors. As disparate bodyplans appeared and diversified during the Cambrian explosion, increasing complexity was accommodated largely through changes in cis -regulatory networks, accompanied by some additional gene novelties. Subsequently, protein-coding genic richness appears to have essentially plateaued. Some genomic evidence suggests that similar stages of genomic evolution may have accompanied the rise of land plants. [source] Inhibition of ,-synuclein fibrillization by dopamine analogs via reaction with the amino groups of ,-synucleinFEBS JOURNAL, Issue 14 2005Implication for dopaminergic neurodegeneration Fibrillization of ,-synuclein (,-Syn) is closely associated with the formation of Lewy bodies in neurons and dopamine (DA) is a potent inhibitor for the process, which is implicated in the causative pathogenesis of Parkinson's disease (PD). To elucidate any molecular mechanism that may have biological relevance, we tested the inhibitory abilities of DA and several analogs including chemically synthetic and natural polyphenols in vitro. The MS and NMR characterizations strongly demonstrate that DA and its analogs inhibit ,-Syn fibrillization by a mechanism where the oxidation products (quinones) of DA analogs react with the amino groups of ,-Syn chain, generating ,-Syn,quinone adducts. It is likely that the amino groups of ,-Syn undergo nucleophilic attack on the quinone moiety of DA analogs to form imino bonds. The covalently cross-linked ,-Syn adducts by DA are primarily large molecular mass oligomers, while those by catechol and p -benzoquinone (or hydroquinone) are largely monomers or dimers. The DA quinoprotein retains the same cytotoxicity as the intact ,-Syn, suggesting that the oligomeric intermediates are the major elements that are toxic to the neuronal cells. This finding implies that the reaction of ,-Syn with DA is relevant to the selective dopaminergic loss in PD. [source] The major- and trace-element whole-rock fingerprints of Egyptian basalts and the provenance of Egyptian artefactsGEOARCHAEOLOGY: AN INTERNATIONAL JOURNAL, Issue 7 2001John D. Greenough Discrimination diagrams have been developed that source Egyptian basaltic artefacts using whole-rock major element geochemistry. These include K2O versus SiO2, TiO2 and P2O5 against MgO/Fe2O3t (total Fe as Fe2O3), and a discriminant analysis diagram using SiO2, Fe2O3t, CaO, and MnO. A complementary set of diagrams uses easily obtained trace element data (Nb/Y versus Zr/Nb; Zr [ppm] versus Rb/Sr; TiO2 [wt % volatile free] versus V; and Cr [ppm] versus Zr/Y) to determine the bedrock sources. These diagrams have been applied to seven First Dynasty basalt vessels (Abydos), two Fourth Dynasty basalt paving stones (Khufu's funerary temple, Giza), and two Fifth Dynasty paving stones (Sahure's complex, Abu Sir). They show that the bedrock source for all the artefacts was the Haddadin flow in northern Egypt. Multidimensional scaling and cluster analysis applied to the whole-rock data (major elements and trace elements together) and previously published mineral fingerprinting studies confirm these results. Comparing mineral versus whole-rock fingerprinting techniques, a major advantage of the former is the small sample size required (0.001 g compared to , 0.1 g). Analytical costs are similar for both methods assuming that a comparison (bedrock) database can be assembled from the literature. For most archaeological problems, a whole-rock bedrock database is more likely to exist than a mineral database, and whole-rock analyses on artefacts will generally be easier to obtain than mineral analyses. Whole-rock fingerprinting may be more sensitive than mineral-based fingerprinting. Thus, if sample quantity is not an issue, whole-rock analysis may have a slight cost, convenience, and technical advantage over mineral-based methods. Our results also emphasize that the Egyptians cherished their Haddadin basalt flow and used it extensively and exclusively for manufacturing basalt vessels and paving stones for at least 600 years (,3150 B.C. to 2500 B.C., approximate ages of the vessels and Abu Sir paving stones, respectively). © 2001 John Wiley & Sons, Inc. [source] An experimental and modeling study of Na-rich hydrothermal alterationGEOFLUIDS (ELECTRONIC), Issue 4 2005J. HARA Abstract Sodic alteration assemblages including clinoptilolite, mordenite, analcime and Na-montmorillonite were locally observed in sediments in the eastern part of the Hachimantai geothermal region, northeast Japan. This study investigated the mechanisms of sodic enrichment in the sediments during alteration. Kinetic results for water/rock interaction experiments are reported here. Batch-type experiments were conducted at 150,250°C under saturated vapor pressure. Pyroclastic rocks dissolved incongruently in these experiments, and the solubility and dissolution rates among elements varied as follows: the apparent steady-state concentrations of major elements are Si > Na , K > Ca > Al and the order of the dissolution rates is Si > Al > Na , K > Ca. Na had the highest steady-state concentration and fastest dissolution rate of the alkali and alkali earth metal ions. Based on surface analysis of plagioclase, dissolution was effected via a reaction layer of Na-montmorillonite on the mineral surface. Additionally, a reaction model constructed based on the experimentally observed reaction mechanism quantitatively explains the dissolution behavior. These results show that Na-montmorillonite can be precipitated by pyroclastic rock/meteoric water interactions without seawater involvement: the Na is derived from the host rocks. [source] Comparison of Linear Regression Models for Quantitative Geochemical Analysis: An Example Using X-Ray Fluorescence SpectrometryGEOSTANDARDS & GEOANALYTICAL RESEARCH, Issue 3 2005Mirna Guevara calibration analytique; régression linéaire; matériaux de référence en géochimie; géochimie analytique; loi de propagation d'erreurs This paper presents statistical aspects related to the calibration process and a comparison of different regression approaches of relevance to almost all analytical techniques. The models for ordinary least-squares (OLS), weighted least-squares (WLS), and maximum likelihood fitting (MLF) were evaluated and, as a case study, X-ray fluorescence (XRF) calibration curves for major elements in geochemical reference materials were used. The results showed that WLS and MLF models were statistically more consistent in comparison with the usually applied OLS approach. The use of uncertainty on independent and dependent variables during the calibration process and the calculation of final uncertainty on individual results using error propagation equations are the novel aspects of our work. Cet article présente les aspects statistiques liés au processus de calibration et fait une comparaison des différents calculs de régression utilisés dans pratiquement toutes les techniques analytiques. Les modèles des moindres carrés ordinaires (MCO) et pondérés (MCP), et d'ajustement de maximum de vraisemblance (AMV) ont étéévalués et appliqués aux courbes de calibration d'éléments majeurs obtenues en analyse par fluorescence X (XRF) de matériaux certifiés de référence. Les résultats obtenus avec les modèles MCP et AMV sont plus cohérents statistiquement que ceux obtenus la méthode classique des MCO. L'utilisation de l'incertitudes sur des variables indépendantes ou dépendantes durant la procédure de calibration et le calcul de l'incertitude finale sur chaque résultat à partir des lois de propagation d'erreur sont des aspects novateurs de ce travail. [source] Stack unit mapping of coastal aquifer to predict and control sea water intrusion using remote sensing and a geographical information systemHYDROLOGICAL PROCESSES, Issue 17 2003J. Moses Edwin Abstract Aquifers are inherently susceptible to contamination and coastal aquifers in specific are highly vulnerable to sea water intrusion. For efficient planning and management of coastal aquifers in Kayalpattu and Tiruchopuram villages, which extend over 4·05 km2, it is essential to delineate and predict the extent of intrusion into the shallow aquifer. Management of ground water in coastal aquifers is composed of major elements that should be properly evaluated, and special attention is given to the sea water intrusion problem. Different data, like hydro-geomorphological and depth-wise iso-apparent resistivity, are integrated spatially using a geographical information system. The stack-unit mapping approach is used to delineate the zones with iso-apparent resistivity of less than 10 , m have been found to be increasing in areal extent with reference to depth. Copyright © 2003 John Wiley & Sons, Ltd. [source] Interferons, interferon-like cytokines, and their receptorsIMMUNOLOGICAL REVIEWS, Issue 1 2004Sidney Pestka Summary:, Recombinant interferon-, (IFN-,) was approved by regulatory agencies in many countries in 1986. As the first biotherapeutic approved, IFN-, paved the way for the development of many other cytokines and growth factors. Nevertheless, understanding the functions of the multitude of human IFNs and IFN-like cytokines has just touched the surface. This review summarizes the history of the purification of human IFNs and the key aspects of our current state of knowledge of human IFN genes, proteins, and receptors. All the known IFNs and IFN-like cytokines are described [IFN-,, IFN-,, IFN-,, IFN-,, IFN-,, IFN-,, IFN-,, IFN-,, limitin, interleukin-28A (IL-28A), IL-28B, and IL-29] as well as their receptors and signal transduction pathways. The biological activities and clinical applications of the proteins are discussed. An extensive section on the evolution of these molecules provides some new insights into the development of these proteins as major elements of innate immunity. The overall structure of the IFNs is put into perspective in relation to their receptors and functions. [source] Major and trace element provenance signatures in stream sediments from the Kando River, San'in district, southwest JapanISLAND ARC, Issue 2 2006Edwin Ortiz Abstract Basement rocks in the catchment of the Kando River in southwest Japan can be divided into two main groups. Paleogene to Cretaceous felsic granitoids and volcanic rocks dominate in the upstream section, and more mafic, mostly Miocene volcanic and volcaniclastic rocks occur in the downstream reaches. Geochemically distinctive Mount Sambe adakitic volcanic products also crop out in the west. X-ray fluorescence analyses of major elements and 14 trace elements were made of two size fractions (<180 and 180,2000 µm) from 86 stream sediments collected within the catchment, to examine contrasts in composition between the fractions as a result of sorting and varying source lithotype. The <180 µm fractions are depleted in SiO2 and enriched in most other major and trace elements relative to the 180,2000 µm fractions. Na2O, K2O, Ba, Rb and Sr are either depleted relative to the 180,2000 µm fractions, or show little contrast in abundance. Sediments from granitoid-dominated catchments are distinguished by greater K2O, Th, Rb, Ba and Nb than those derived from the Miocene volcanic rocks. Granitoid-derived <180 µm fractions are also enriched in Zr, Ce and Y. Sediments derived from the Miocene volcanic rocks generally contain greater TiO2, Fe2O3*, Sc, V, MgO and P2O5, reflecting their more mafic source. Sediments containing Sambe volcanic rocks in their source are marked by higher Sr, CaO, Na2O and lower Y, reflecting an adakitic signature that persists into the lower main channel, where compositions become less variable as the bedload is homogenized. Normalization against source averages shows that compositions of the 180,2000 µm fractions are less fractionated from their parents than are the <180 µm fractions, which are enriched for some elements. Contrast between the size fractions is greatest for the granitoid-derived sediments. Weathering indices of the sediments are relatively low, indicating source weathering is moderate, and typical of temperate climates. Some zircon concentration has occurred in granitoid-derived <180 µm fractions relative to 180,2000 µm counterparts, but Th/Sc and Zr/Sc ratios overall closely reflect both provenance and homogenization in the lower reaches. [source] Perspectives of ammonite paleobiology from shell abnormalities in the genus BaculitesLETHAIA, Issue 3 2002R.A. HENDERSON Many Baculites specimens from the Upper Cretaceous of the United States Western Interior show exceptional preservation of the original aragonitic shell and its fine-scale surface ornamentation. Growth lines are ubiquitous, with two orders of these structures represented on some shells, and reflect the incremental addition of new shell at the apertural margin. Growth line interruption in the form of repair of minor shell damage at the aperture, commonplace in contemporary Nautilus, is essentially absent in Baculites, suggesting that its members fed on small prey in the water column. As typical of Mesozoic ammonites in general, and in striking contrast to contemporary Nautilus, no in vivo epizoans have been recognized on specimens of Baculites. It is inferred that the shell of Baculites was covered in periostracum to eliminate epizoic colonization. By analogy with Nautilus, a distinctive micro-ornament oriented at right angles to growth lines and visible on parts of some specimens was probably associated with periostracal attachment. A small proportion of Baculites specimens show abnormalities in shell growth categorized as v-shaped indentations of growth lines, shell grooves, fine-scale folds on the surface of growth lines and feather structures. We view this entire set of structures as due to abnormalities in mantle growth induced at the leading edge, impressed into the periostracum during its fabrication, and then in turn into the shell surface. As many of the Baculites with shell abnormalities are smooth, the proposal by Checa linking homologous structures recognized on other ammonites to the formation of comarginal ribs is rejected. A case of sutural inversion, in which the form of minor divisions of the major saddles and lobes are transposed, is recognized in a specimen of Baculites codyensis Reeside. We consider sutural pattern in ammonites, an expression of septal fluting, as replicating the genetically specified standing form of an elastic adapical visceral mass. The inverted sutural pattern, and by implication the style of septal fluting, was transcribed exactly in the three successive septa preserved on the specimen. The abnormality appears to be a case of homeotic mutation in which the plan for one body region becomes translocated to another. The conservatism of major elements of sutural (=septal) patterns for Mesozoic ammonites in their evolutionary spectrum suggests that a homeobox of conserved DNA sequence, with the transcription factors encoded in homeotic genes, is likely to have been involved. [source] Chemical variation within fragments of Australasian tektitesMETEORITICS & PLANETARY SCIENCE, Issue 6 2005Trinh Hai SON No data for intra-sample trace element variations existed. Thus, we sectioned a Muong Nong-type tektite fragment from Vietnam and a splash-form tektite fragment from the Philippines into eleven and six pieces, respectively, and analyzed the individual fragments for major and trace element contents. The compositions obtained agree well with those found in previous studies, supporting argument that tektites have been derived from terrestrial upper crustal sediments. Chemical variations within the tektite fragments are present, but do not show any systematic trends, probably reflecting incomplete mixing of parent rocks. The intra-sample heterogeneity of the Muong Nong-type tektite is more pronounced than that in the philippinite. For the Muong Nong-type tektite, the intra-sample variation in the trace element contents is higher than that for the major elements, again reflecting target rock properties. For the philippinite the intra-sample variations mostly do not exceed the limits imposed by the precision of the analytical data, confirming that the splash form tektites are indeed well homogenized. [source] Petrology and chemistry of the new shergottite Dar al Gani 476METEORITICS & PLANETARY SCIENCE, Issue 1 2000J. ZIPFEL The meteorite is classified as a basaltic shergottite and is only the 13th martian meteorite known to date. It has a porphyritic texture consisting of a fine-grained groundmass and larger olivines. The groundmass consists of pyroxene and feldspathic glass. Minor phases are oxides and sulfides as well as phosphates. The presence of olivine, orthopyroxene, and chromite is a feature that DaG 476 has in common with lithology A of Elephant Moraine (EET) A79001. However, in DaG 476, these phases appear to be early phenocrysts rather than xenocrysts. Shock features, such as twinning, mosaicism, and impact-melt pockets, are ubiquitous. Terrestrial weathering was severe and led to formation of carbonate veins following grain boundaries and cracks. With a molar MgO/(MgO + FeO) of 0.68, DaG 476 is the most magnesian member among the basaltic shergottites. Compositions of augite and pigeonite and some of the bulk element concentrations are intermediate between those of lherzolitic and basaltic shergottites. However, major elements, such as Fe and Ti, as well as LREE concentrations are considerably lower than in other shergottites. Noble gas concentrations are low and dominated by the mantle component previously found in Chassigny. A component, similar to that representing martian atmosphere, is virtually absent. The ejection age of 1.35 ± 0.10 Ma is older than that of EETA79001 and could possibly mark a distinct ejection. Dar al Gani 476 is classified as a basaltic shergottite based on its mineralogy. It has a fine-grained groundmass consisting of clinopyroxene, pigeonite and augite, feldspathic glass and chromite, Ti-chromite, ilmenite, sulfides, and whitlockite. Isolated olivine and single chromite grains occur in the groundmass. Orthopyroxene forms cores of some pigeonite grains. Shock-features, such as shock-twinning, mosaicism, cracks, and impact-melt pockets, are abundant. Severe weathering in the Sahara led to significant formation of carbonate veins crosscutting the entire meteorite. Dar al Gani 476 is distinct from other known shergottites. Chemically, it is the most magnesian member among known basaltic shergottites and intermediate in composition for most trace and major elements between Iherzolitic and basaltic shergottites. Unique are the very low bulk REE element abundances. The CI-normalized abundances of LREEs are even lower than those of Iherzolitic shergottites. The overall abundance pattern, however, is similar to that of QUE 94201. Textural evidence indicates that orthopyroxene, as well as olivine and chromite, crystallized as phenocrysts from a magma similar in composition to that of bulk DaG 476. Whether such a magma composition can be a shergottite parent melt or was formed by impact melting needs to be explored further. At this time, it cannot entirely be ruled out that these phases represent relics of disaggregated xenoliths that were incorporated and partially assimilated by a basaltic melt, although the texture does not support this possibility. Trapped noble gas concentrations are low and dominated by a Chassigny-like mantle component. Virtually no martian atmosphere was trapped in DaG 476 whole-rock splits. The exposure age of 1.26 ± 0.09 Ma is younger than that of most shergottites and closer to that of EETA79001. The ejection age of 1.35 ± 0.1 Ma could mark another distinct impact event. [source] Anreizkompatibilität als zentrales Element eines neu gestalteten GesundheitsmarktesPERSPEKTIVEN DER WIRTSCHAFTSPOLITIK, Issue 3 2004Thomas Gries Frequently, administrative rules defined by the government or private health (doctor) associations dominate the allocation mechanisms of the health system. These administrative rules along with asymmetric information often cause moral hazard problems leading to vast inefficiencies in the ,Physician-Patient-Market". Therefore, the discussion of efficient health systems should focus on the problem of compatible incentives within the allocation system of the health sector. Even more, without incentive consistency instruments recently suggested to cure the inefficiency of the German system like ,Managed Care", ,Disease Management" or ,Diagnosis Related Groups" will not be able to improve the efficiency of the health system. Introducing these instruments without a full incentive , compatible allocation system covering all segments of the health system will just shift the problem of asymmetric information and moral hazard to another sub-market of the system, the ,Health Insurance,Patient-Market". Therefore, the intention of the paper is to identify the major elements of a suitable incentive , compatible allocation scheme for the health market. Further, we propose an independent evaluation and information institution as a major tool to cure the problem of asymmetric information in the health market. [source] Habits of the heart: Life history and the developmental neuroendocrinology of emotionAMERICAN JOURNAL OF HUMAN BIOLOGY, Issue 6 2009Carol M. Worthman The centrality of emotion in cognition and social intelligence as well as its impact on health has intensified investigation into the causes and consequences of individual variation in emotion regulation. Central processing of experience directly informs regulation of endocrine axes, essentially forming a neuro-endocrine continuum integrating information intake, processing, and physiological and behavioral response. Two major elements of life history,resource allocation and niche partitioning,are served by linking cognitive-affective with physiologic and behavioral processes. Scarce cognitive resources (attention, memory, and time) are allocated under guidance from affective co-processing. Affective-cognitive processing, in turn, regulates physiologic activity through neuro-endocrine outflow and thereby orchestrates energetic resource allocation and trade-offs, both acutely and through time. Reciprocally, peripheral activity (e.g., immunologic, metabolic, or energetic markers) influences affective-cognitive processing. By guiding attention, memory, and behavior, affective-cognitive processing also informs individual stances toward, patterns of activity in, and relationships with the world. As such, it mediates processes of niche partitioning that adaptively exploit social and material resources. Developmental behavioral neurobiology has identified multiple factors that influence the ontogeny of emotion regulation to form affective and behavioral styles. Evidence is reviewed documenting roles for genetic, epigenetic, and experiential factors in the development of emotion regulation, social cognition, and behavior with important implications for understanding mechanisms that underlie life history construction and the sources of differential health. Overall, this dynamic arena for research promises to link the biological bases of life history theory with the psychobehavioral phenomena that figure so centrally in quotidian experience and adaptation, particularly, for humans. Am. J. Hum. Biol. 2009. © 2009 Wiley-Liss, Inc. [source] Mineralogy, Lithogeochemistry and Elemental Mass Balance of the Hydrothermal Alteration Associated with the Gold-rich Batu Hijau Porphyry Copper Deposit, Sumbawa Island, IndonesiaRESOURCE GEOLOGY, Issue 3 2009Arifudin Idrus Abstract This paper discusses the mineralogy, whole-rock geochemistry and elemental mass balance of the hydrothermal alteration zones within the Batu Hijau porphyry copper-gold deposit, Sumbawa Island, Indonesia. The hydrothermal alteration and mineralisation developed in four stages, namely (i) the early stage consisting of a central copper-gold-bearing biotite (potassic), proximal actinolite (inner propylitic) and the distal chlorite-epidote (outer propylitic) zones; (ii) the transitional stage represented by the chlorite-sericite (intermediate argillic) zone; (iii) the late stages distinguished into the sericite-paragonite (argillic) and pyrophyllite-andalusite (advanced argillic) zones; and (iv) the very late stage typified by the illite-sericite zone. In general, major elements (particularly Ca, Mg, Na and K) and some minor and rare earth elements decrease from the least altered rocks towards the late alteration zones as a consequence of the breakdown of Ca-bearing hornblende, biotite and plagioclase. Chemical discrimination by means of millicationic R1 -R2 diagram indicates that R1 [4Si , 11(Na + K) , 2(Fe + Ti)] increases while R2[6Ca + 2Mg + Al] decreases with increasing alteration intensity, from least-altered, through early, transitional, to late alteration zones. Rare earth elements-chondrite (C1) normalised patterns also exhibit the depletion of the elements through the subsequent alteration zones. These results are consistent with the elemental mass balance calculation using the isocon method which shows that the degree of mass and volume depletion systematically increases during alteration. A decrease of the elements as well as mass and volume from early, through transitional to late alteration stages may imply a general decrease of the element activities in hydrothermal fluids during the formation of the alteration zones. [source] THE SACRISTY OF SAN MARCO, VENICE: FORM AND FUNCTION ILLUMINATEDART HISTORY, Issue 3 2009LYDIA HAMLETT The sacristy at San Marco in Venice had a crucial functional role, both within the daily liturgical life of the basilica and especially during the ritual activity of Holy Week, which is reflected through its artistic programmes. This article focuses solely on the sacristy as a key site within the church, and its renaissance rebuilding and decoration c. 1491,1546. It examines the major elements of the programme in turn, including the mosaics, door, tarsie and tapestries. For the first time, each of these developments is viewed as complementary to a deliberate and coherent programme revolving around liturgical requirements, iconography of the Passion and overarching themes of triumph and redemption. Without surviving documentary evidence for the instigation of such a monolithic project, this article argues that the sacristy be looked at anew in light of contemporary understanding of the sacristy as a space. The practical and symbolic associations of the sacristy at San Marco are thus considered in this wider typological context in order to illuminate our own appreciation of the development of the sacristy's artistic programme. [source] The Third Dimension: cultural awareness for Non-English speaking background health professionalsAUSTRALIAN AND NEW ZEALAND JOURNAL OF PUBLIC HEALTH, Issue 2 2001Indrani Ganguly The complexity of the relationships between Aboriginal and Torres Strait Islander peoples and non-English speaking background (NESB) communities is difficult to capture in cultural awareness programs that are based on binary (Indigenous/non-Indigenous) models. This is illustrated by an examination of three major elements of cross-cultural programs, the historical/socio-political context of Indigenous people's positioning in Australia, cultural differences and racism. It is acknowledged that these are only a few ideas that may be useful in thinking about NESB-Indigenous relations in health care in Australia. [source] | ||||||||||||||||||||||||||||||||||