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M Channel (m + channel)

Distribution by Scientific Domains

Polymers and Materials Science	50%

Selected Abstracts

Guest-Induced Chirality in the Ferrimagnetic Nanoporous Diamond Framework Mn3(HCOO)6,

ADVANCED FUNCTIONAL MATERIALS, Issue 4 2007
B. Zhang
Abstract Chiral magnets are obtained by inclusion of chiral guest molecules into the channels of an achiral nanoporous ferrimagnet consisting of the Mn3(HCOO)6 (1) framework. Insertion of the R or the S enantiomer of 2-chloropropan-1-ol (CH3C*HClCH2OH) in the chiral pores of the previously emptied framework (space group P21/c) results in the two corresponding chiral solids (1R and 1S, space group P21), while insertion of a racemic mixture of the two enantiomers retains the achirality of the host for the meso solid (1RS, space group P21/c). The R guest is ordered in the M channels while the S guest is ordered in the P channels. In contrast, the R guests in the P channels and the S guests in the M channels are disordered on two crystallographic orientations. For the racemic mixture of the two enantiomers in 1RS, random disorder of guests in both channels is observed. Thus, the localization of the guest molecule depends on the nature of the surface to recognize the guest of a particular chirality. The guest inclusion compounds are thermally stable. The 1R and 1S compounds are optically active. All the compounds adopt a ferrimagnetic ground state. Compared to the host framework of 1 without guest, the Curie temperature decreases for both 1R and 1S but increases for 1RS. The additional interactions between the framework and the inserted guest alcohols strengthen the lattice via hydrogen bonds and other electrostatic forces, and it might account for the significant lowering of the lattice contribution as well as the magnetic component to the specific heat capacity upon guest loading. [source]

Wood distribution in neotropical forested headwater streams of La Selva, Costa Rica

EARTH SURFACE PROCESSES AND LANDFORMS, Issue 9 2009
Daniel Cadol
Abstract Surveys of wood along 30 forested headwater stream reaches in La Selva Biological Station in north-eastern Costa Rica represent the first systematic data reported on wood loads in neotropical streams. For streams with drainage areas of 0·1,8·5 km2 and gradients of 0·2,8%, wood load ranged from 3 to 34·7 m3 wood/100 m channel and 41,612 m3 wood/ha channel. These values are within the range reported for temperate streams. The variables wood diameter/flow depth, stream power, the presence of backflooding, and channel width/depth are consistently selected as significant predictors by statistical models for wood load. These variables explain half to two-thirds of the variability in wood load. These results, along with the spatial distribution of wood with respect to the thalweg, suggest that transport processes exert a greater influence on wood loads than recruitment processes. Wood appears to be more geomorphically effective in altering bed elevations in gravel-bed reaches than in reaches with coarser or finer substrate. Copyright © 2009 John Wiley & Sons, Ltd. [source]

Stochastic approach for output SINR computation at SC diversity systems with correlated Nakagami- m fading

EUROPEAN TRANSACTIONS ON TELECOMMUNICATIONS, Issue 5 2009
Daniela M. Milovi
In this paper, we derive the cumulative distribution function of the signal-to-interference,+,,noise ratio (SINR) achieved by the selection combining (SC) diversity receiver operating over correlated Nakagami- m channel in the presence of co-channel interference. Numerical and simulation results are presented to show the effects of fading severity and signal and interference imbalance on the system's performance. Copyright © 2009 John Wiley & Sons, Ltd. [source]

UV-embossed microchannel in biocompatible polymeric film: Application to control of cell shape and orientation of muscle cells

JOURNAL OF BIOMEDICAL MATERIALS RESEARCH, Issue 2 2006
Jin-Ye Shen
Abstract This article shows that ultra violet (UV) micro-embossing can be successfully used for fabricating biocompatible micropatterned films with microchannels separated by high aspect ratio microwalls. Eight series of micropatterns were investigated; the width of the microwall was either 10 or 25 ,m and that of the microchannel either 40, 80, 120, or 160 ,m. The material investigated was principally polyurethane diacrylate. The UV-embossed micropattern was extracted with methanol, converting the micropatterns from cytotoxic to biocompatible. The typical UV embossing method was modified by using a marginally adhesive polyester substrate, which facilitates demolding but is removable before methanol extraction to avoid fragmentation of the embossed micropatterns. The effect of the micropatterns on A7r5 smooth muscle cells and C2C12 skeletal muscle cells was investigated. The dimensions of both channel and wall have significant effects on the elongation of both muscle cells. In the narrower 40-,m channel, the C2C12 cells merged together to form myofibers. These results indicate that UV-embossed micropatterns may present a useful scaffold for in vitro cell shape and orientation control needed in vascular and muscle tissue engineering. © 2005 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 2006 [source]